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Bloch Theorem
Bloch Theorem
Bloch Theorem
for all vectors ‘a’ of the Crystal lattice of the crystal. Block's
theorem is interpreted to mean that the wave function for an
electron in a periodic potential is a plane wave modulated by a
periodic function. This explains why a free-electron model has
some success in describing the properties of certain metals
although it is inadequate to give a quantitative description of
the properties of most metals.
In order to understand the physical properties of the system, it
is required to solve the Schrödinger’s equation. However, it is
extremely difficult to solve the Schrödinger’s equation with
periodic potential described above. Hence the Kronig –
Penney Model is adopted for simplification.
Substituting α2 = 2 m E / ħ2
---------------(4)
β2 = 2 m ( V – E ) / ħ2
----------------(5)
d2Ψ / dx2 + α2 Ψ = 0 for region 0 < x < a
---------------(6)
The solution for the eqn’s (6) and (7) can be written as
Ψ ( x ) = Uk ( x ) eikx
---------------(8)
d 2ψ d 2u du du
= e ikx k + iKe iKx k + ike ikx k − k 2 e ikx u
2 2 dx dx k
dx dx
d 2ψ du d 2u
i.e., dx 2
2
=− K e ikx u + 2iKe
k
iKx
dx
k +e ikx
dx 2
k
d 2u du 1
dx
+ 2iK dx + (α
2
1 2
− K 2 )u1 = 0 ; for 0<x<a
---------------------(10)
and dx 22 +2iK dx - ( β )
d 2u du 2 2
+ K 2 u 2 = 0; for –b<x<0
------------------------(11)
U1 = emx
du 1 d 2 u1
dx
= me mx and dx 2
= m 2 e mx
m = -ik ± iα
m1 = -ik +iα = i (α -K)
m2 = -iK-iα = -i (α +K)
u1 = Aem1x + B em2x
α α
u1 = Aei( -K)x + B e-I ( +k)x
[u1 ( x ) ] x =0 = [u 2 ( x ) ] x =0 ; du1 ( x ) du ( x )
= 2 and
dx x =0 dx x =0
β2 - α2 = ( 2 m / ħ2 ) (Vo – E ) – ( 2 m E / ħ2 )
= ( 2 m / ħ2 ) (Vo – E - E ) = ( 2 m /
ħ2 ) (Vo – 2 E )
= 2 m Vo / ħ2 ( since Vo >> E )
( m Vo b a / ħ2 ) ( sin α a / α a ) + cos α a ==
cos k a
3π
This plot for a value of P assumed arbitrarily as 2 . Indicated
in the figure are the permitted values of this function, show as
solid lines between thin portions. This, then gives rise to the
concept of ranges of permitted values of α for a given ion
α h
2 2
α 2 = a . Referring equation
2
n 2π 2 2mE
α =
2
a 2
= 2
n 2π 2 h 2 n2 π 2 h 2
i.e. E =
2ma
2
=
2m
4π
2
n2h2
E= 8ma 2
Cos α a = cos Ka
Thus α = K
i.e. α 2 = K2
2
2 2 2 2π
E=
2m
K
E= 2
8π m λ
2 1
E=
2m
λ2
2 p2 p2 1
E=
2m h 2
=
2 m
= mv
2
2
Energy bands