Bio Diesel: by Jess & Abi-Jessica

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Bio diesel

By Jess & Abi-Jessica

What is Bio diesel ?

Why use Bio diesel?

Reduces greenhouse gas emissions (reduced contribution to global warming)

Transesterification
O || C 2 - O- C- R H 1 | | O | || C - O- C- R + 3C 3O H H H = > 2 | (K H O) | O | || C 2 - O- C- R H 3 T cerid rigly e m an eth ol O || C 3 - O- C- R H 1 O C 2-O H H || | C 3 - O- C- R + C - O H H H 2 | O C 2-O H H || C 3 - O- C- R H 3 m tu of fattyesters ix re g cerin ly

Oil: Triglycerides

Alcohol: Methanol -CH3OH

Catalyst: Potassium Hydroxide KOH

Reaction time

Transesterification reaction will proceed at ambient (21 C) temperatures but needs 4-8 hours to reach completion.
Reaction time can be shortened to 2-4 hours at 105F and 1-2 hours at 140F.

Higher temperatures will decrease reaction times but require pressure vessels because methanol boils at 148F (65C).

Triglyceride Sources

Process Issues

Bio diesel produced must reach ASTM D-6751 standards. Product quality is important modern diesel engines are very sensitive to fuel.

Batch vs Continuous Flow

Batch is better suited to smaller plants Batch provides greater flexibility to tune process to feedstock variations.

Continuous allows use of high-volume separation systems (centrifuges) which greatly increase throughput.

Hybrid systems are possible.

Hybrid Batch/Continuous Base Catalyzed Process


Water Alcohol Water Biodiesel Dryer Ester Ester TG TG Alcohol Alcohol Catalyst Acid Alcohol

Mixer

Wash Water

CSTR 1

Glycerol Decanter

CSTR 2

Glycerol

Crude Glycerol

Summary

Biodiesel is an alternative fuel for diesel engines that can be made from virtually any oil or fat feedstock. The technology choice is a function of desired capacity, feedstock type and quality, alcohol recovery, and catalyst recovery. Maintaining product quality is essential for the growth of the biodiesel industry.

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