Axit cacboxylic.....

....

......N2P

Axit cacboxylic
Cu 131: A la axit cacboxylic n chc cha no (1 ni i C=C). A tac dung vi brom cho san phm cha 65,04% brom (theo khi lng). Vy A co cng thc phn t la A. C3H4O2. B. C4H6O2. C. C5H8O2. D. C5H6O2. Cu 132: Mun trung ha 6,72 gam mt axit hu c A cn dng 200 gam dung dch NaOH 2,24%. A l A. CH3COOH. B. CH3CH2COOH. C. HCOOH. D. CH2=CHCOOH. Cu 133: trung hoa 40 ml gim n cn 25 ml dung dich NaOH 1M. Bit khi lng ring cua gim la 1 g/ml. Vy mu gim n nay co nng la A. 3,5%. B. 3,75%. C. 4%. D. 5%. Cu 134: Trung hoa 9 gam axit cacbonxylic A bng NaOH va u c can dung dich c 13,4 gam mui khan. A co cng thc phn t la A. C2H4O2. B. C2H2O4. C. C3H4O2. D. C4H6O4. Cu 135: Trung hoa 2,7 gam axit cacboxylic A cn va u 60 ml dung dich NaOH 1M. A co cng thc phn t la A. C2H4O2. B. C3H4O2. C. C4H6O4. D. C2H2O4. Cu 136: Trung ha hon ton 1,8 gam mt axit hu c n chc bng dung dch NaOH va ri c cn dung dch sau phn ng c 2,46 gam mui khan. Axit l A. HCOOH. B. CH2=CHCOOH. C. CH3CH2COOH. D. CH3COOH. Cu 137: Cho 3,6 gam axit cacboxylic no, n chc X tc dng hon ton vi 500 ml dung dch gm KOH 0,12M v NaOH 0,12M. C cn dung dch thu c 8,28 gam hn hp cht rn khan. Cng thc phn t ca X l A. C2H5COOH. B. CH3COOH. C. HCOOH. D. C3H7COOH. Cu 138: A v B l 2 axit cacboxylic n chc. Trn 1,2 gam A vi 5,18 gam B c hn hp X. trung ha ht X cn 90 ml dung dch NaOH 1M. A, B ln lt l A. Axit propionic, axit axetic. B. axit axetic, axit propionic. C. Axit acrylic, axit propionic. D. Axit axetic, axit acrylic. Cu 139: Cho 2,46 gam hn hp gm HCOOH, CH3COOH, C6H5OH tc dng va vi 400 ml dung dch NaOH 1M. Tng khi lng mui thu c sau phn ng l A. 3,54 gam. B. 4,46 gam. C. 5,32 gam. D. 11,26 gam. Cu 140: Cho 5,76 gam axit hu c X n chc, mch h tc dng ht vi CaCO3 thu c 7,28 gam mui ca axit hu c. Cng thc cu to thu gn ca X l A. CH2=CHCOOH. B. CH3COOH. C. HCCCOOH. D. CH3CH2COOH. Cu 141: Cho 0,1 mol axit hu c X tc dng vi 11,5 gam hn hp Na v K thu c 21,7 gam cht rn v thy thot ra 2,24 lt kh H2 (ktc). Cng thc cu to ca X l A. (COOH)2. B. CH3COOH. C. CH2(COOH)2. D. CH2=CHCOOH. Cu 142: Cho 16,6 gam hn hp gm HCOOH, CH3COOH tc dng ht vi Mg thu c 3,36 lt H2 (ktc). Khi lng CH3COOH l A. 12 gam. B. 9 gam. C. 6 gam. D. 4,6 gam. Cu 143: X la hn hp gm HCOOH va CH3COOH (ti l mol 1:1). Ly 21,2 gam X tac dung vi 23 gam C2H5OH (xuc tac H2SO4 c, un nong) thu c m gam hn hp este (hiu sut este hoa u at 80%). Gia tri m la A. 40,48 gam. B. 23,4 gam. C. 48,8 gam. D. 25,92 gam. Cu 144: un nong 6 gam CH3COOH vi 9,2 gam C2H5OH (co H2SO4 c lam xuc tac) n khi phan ng at ti trang thai cn cn bng thi c 5,5 gam este. Hiu sut phan ng este hoa la A. 55%. B. 62,5%. C. 75%. D. 80%. Cu 145: Cho 0,3 mol axit X n chc trn vi 0,25 mol ancol etylic em thc hin phn ng este ha thu c thu c 18 gam este. Tch ly lng ancol v axit d cho tc dng vi Na thy thot ra 2,128 lt H2. Vy cng thc ca axit v hiu sut phn ng este ha l A. CH3COOH, H% = 68%. B. CH2=CHCOOH, H%= 78%. C. CH2=CHCOOH, H% = 72%. D. CH3COOH, H% = 72%. Cu 146: Oxi ho anehit OHCCH2CH2CHO trong iu kin thch hp thu c hp cht hu c X. un nng hn hp gm 1 mol X v 1 mol ancol metylic vi xc tc H2SO4 c thu c 2 este Z v Q (MZ < MQ) vi t l khi lng mZ : mQ = 1,81. Bit ch c 72% ancol chuyn thnh este. S mol Z v Q ln lt l A. 0,36 v 0,18. B. 0,48 v 0,12. C. 0,24 v 0,24. D. 0,12 v 0,24. Cu 147: t chy hon ton 2,22 gam mt axit hu c no A thu c 1,62 gam H2O. A l A. C3H7COOH. B. C2H5COOH. C. HCOOH. D. CH3COOH. Cu 148: t chay hoan toan 0,1 mol axit n chc cn V lit O2 ktc, thu c 0,3 mol CO2 va 0,2 mol H2O. Gia tri V la

Axit cacboxylic..... .... ......N2P A. 6,72 lit. B. 8,96 lit. C. 4,48 lit. D. 5,6 lit. Cu 149: t chay hoan toan mt axit A thu c 0,2 mol CO2 va 0,15 mol H2O. A co cng thc phn t la A. C3H4O4. B. C4H8O2. C. C4H6O4. D. C5H8O4. Cu 150: t chy hon ton 4,38 gam mt axit E no, mch thng thu c 4,032 lt CO2 (kc) v 2,7 gam H2O. CTCT ca E l A. CH3COOH. B. C17H35COOH. C. HOOC(CH2)4COOH. D. CH2=C(CH3)COOH. Cu 151: t chay hoan toan 0,1 mol axit cacboxylic A thu c cha n 8 gam hn hp CO2 va H2O. A la A. axit fomic. B. axit axetic. C. axit acrylic. D. axit oxalic. Cu 152: Z l mt axit hu c. t chy 0,1 mol Z cn 6,72 lt O2 (ktc). CTCT ca Z l A. CH3COOH. B. CH2=CHCOOH. C. HCOOH. D. Kt qu khc. Cu 153: t chy ht 1 th tch hi axit hu c A c 3 th tch hn hp CO2 v hi nc khi o cng iu kin. CTPT ca A l A. HCOOH. B. CH3COOH. C. HOOCCOOH. D. HOOCCH2COOH. Cu 154: t chy hon ton 0,44 gam mt axit hu c, sn phm chy cho hp th hon ton vo bnh 1 ng P 2O5, bnh 2 ng dung dch KOH. Sau th nghim thy khi lng bnh 1 tng 0,36 gam v bnh 2 tng 0,88 gam. CTPT ca axit l A. C4H8O2. B. C5H10O2. C. C2H6O2. D. C2H4O2. Cu 155: t chy ht 10ml th tch hi mt hp cht hu c A cn dng 30 ml O 2, sn phm thu c ch gm CO2 v H2O c th tch bng nhau v u bng th tch O2 phn ng. CTPT ca A l A. C2H4O2. B. C3H6O3. C. C3H6O2. D. C4H8O2. Cu 156: X la hn hp 2 axit cacboxylic no, h, phn t mi axit cha khng qua 2 nhom -COOH. t chay hoan toan 9,8 gam X c 11 gam CO2 va 3,6 gam H2O. X gm A. HCOOH va CH3COOH. B. HCOOH va HOOCCH2COOH. C. HCOOH va HOOCCOOH. D. CH3COOH va HOOCCH2COOH. Cu 157: Cc sn phm thu c khi t chy hon ton 3 gam axit hu c X c dn ln lt qua bnh 1 ng H2SO4 c v bnh 2 ng dung dch NaOH. Sau th nghim thy khi lng bnh 1 tng 1,8 gam v khi lng bnh 2 tng 4,4 gam. CTCT ca A l A. HCOOH. B. C2H5COOH. C. CH3COOH. D. A hoc B hoc C. o Cu 158: Oxi hoa 0,125 mol ancol n chc A bng 0,05 mol O2 (xt, t ) c 5,6 gam hn hp X gm axit cacboxylic ; anehit ; ancol d va nc. A co cng thc phn t la A. CH4O. B. C2H6O. C. C3H6O. D. C3H8O. Cu 159: Hn hp X gm axit Y n chc v axit Z hai chc (Y, Z c cng s nguyn t cacbon). Chia X thnh hai phn bng nhau. Cho phn mt tc dng ht vi Na, sinh ra 4,48 lt kh H2 ( ktc). t chy hon ton phn hai, sinh ra 26,4 gam CO2. Cng thc cu to thu gn v phn trm v khi lng ca Z trong hn hp X ln lt l A. HOOCCOOH v 42,86%. B. HOOCCOOH v 60,00%. C. HOOCCH2COOH v 70,87%. D. HOOCCH2COOH v 54,88%. Cu 160: Cht A c ngun gc t thc vt v thng gp trong i sng (cha C, H, O), mch h. Ly cng s mol ca A cho phn ng ht vi Na2CO3 hay vi Na th thu c s mol CO2 bng 3/4 s mol H2. Cht A l A. axit malic : HOOCCH(OH)CH2COOH. B. axit xitric : HOOCCH2C(OH)(COOH)CH2COOH. C. axit lauric : CH3(CH2)10COOH. D. axit tactaric : HOOCCH(OH)CH(OH)COOH. Cu 161: Khi cho a mol mt hp cht hu c X (cha C, H, O) phn ng hon ton vi Na hoc vi NaHCO 3 th u sinh ra a mol kh. Cht X l A. ancol o-hiroxibenzylic. B. axit aipic. C. axit 3-hiroxipropanoic. D. etylen glicol. Cu 162: Chia 0,3 mol axit cacobxylic A thanh hai phn bng nhau. - t chay phn 1 c 19,8 gam CO2. - Cho phn 2 tac dung hoan toan vi 0,2 mol NaOH, thy sau phan ng khng con NaOH. Vy A co cng thc phn t la A. C3H6O2. B. C3H4O2. C. C3H4O4. D. C6H8O4. Cu 163: Cho 10 gam hn hp X gm HCHO va HCOOH tac dung vi lng (d) dung dich AgNO 3/NH3 c 99,36 gam bac. % khi lng HCHO trong hn hp X la A. 54%. B. 69%. C. 64,28%. D. 46%. Cu 164: trung hoa a mol axit cacboxylic A cn 2a mol NaOH. t chay hoan toan a mol A thu c 3a mol CO2. A co cng thc phn t la A. C3H4O2. B. C3H6O2. C. C6H10O4. D. C3H4O4.

Axit cacboxylic..... .... ......N2P Cu 165: t chay hoan toan 3,12 gam axit cacboxylic A c 3,96 gam CO2. Trung hoa cung lng axit nay cn 30 ml dung dich NaOH 2M. A co cng thc phn t la A. C2H4O2. B. C4H6O2. C. C3H4O2. D. C3H4O4. Cu 166: Hn hp X gm 2 axit no A1 v A2. t chy hon ton 0,3 mol X thu c 11,2 lt CO2 (kc). trung ha 0,3 mol X cn 500 ml dung dch NaOH 1M. CTCT ca 2 axit l A. HCOOH v C2H5COOH. B. CH3COOH v C2H5COOH. C. HCOOH v HOOCCOOH. D. CH3COOH v HOOCCH2COOH. Cu 167: Trung ha a mol axit hu c A cn 2a mol NaOH. t chy ht a mol A c 2a mol CO2. A l A. CH3COOH. B. HOOCCOOH. C. axit n chc no. D. axit n chc khng no. Cu 168: Hp cht hu c E mch h c CTPT C 3H6O3 c nhiu trong sa chua. E c th tc dng vi Na v Na2CO3, cn khi tc dng vi CuO nung nng th to ra hp cht hu c khng tham gia phn ng trng gng. CTCT ca E l A. CH3COOCH2OH. B. CH3CH(OH)COOH. C. HOCH2COOCH3. D. HOCH2CH2COOH. Cu 169: t chy hon ton 0,1 mol cht X l mui Na ca mt axit hu c thu c 0,15 mol CO2, hi H2O v Na2CO3. CTCT ca X l A. C3H7COONa. B. CH3COONa. C. CH3COONa. D. HCOONa. Cu 170: Hn hp X gm 0,01 mol HCOONa v a mol mui natri ca hai axit no n chc mch h l ng ng lin tip. t chy hn hp X v cho sn phm chy (CO2, hi nc) ln lt qua bnh 1 ng H2SO4 c bnh 2 ng KOH thy khi lng bnh 2 tng nhiu hn bnh mt l 3,51 gam. Phn cht rn Y cn li sau khi t l Na 2CO3 cn nng 2,65 gam. Cng thc phn t ca hai mui natri l A. C2H5COONa v C3H7COONa. B. C3H7COONa v C4H9COONa. C. CH3COONa v C2H5COONa. D. CH3COONa v C3H7COONa. Cu 171: Khi lng axit axetic thu c khi ln men 1 lit ancol etylic 8o la bao nhiu ? Cho d = 0,8 g/ml va hiu sut phan ng at 92%. A. 76,8 gam. B. 90,8 gam. C. 73,6 gam. D. 58,88 gam. Cu 172: Thc hin phn ng oxi ha m gam ancol etylic nguyn cht thnh axit axetic (hiu sut phn ng t 25%) thu c hn hp Y, cho Y tc dng vi Na d thu c 5,6 lt H2 (ktc). Gi tr ca m l A. 18,4 gam. B. 9,2 gam. C. 23 gam. D. 4,6 gam. Cu 173: Cho s phn ng sau: + HCN + H3O+, to + H2SO4 , to xt, to, p CH3CH=O A B C3H4O2 C C3H4O2 c tn l A. axit axetic. B. axit metacrylic. C. axit acrylic. D. anehit acrylic. Mg,ete A CO2 Cu 174: Cho s sau : C2H5Br B + HCl C . C c cng thc l A. CH3COOH. B. CH3CH2COOH. C. CH3CH2OH. D. CH3CH2CH2COOH. (C O O H2) B D Cu 175: Cho s chuyn ho sau: H C O O N a C2H5O H A Cc cht A, B, D c th l A. H2 ; C4H6 ; C2H4(OH)2. B. H2 ; C2H4 ; C2H4(OH)2. C. CH4 ; C2H2 ; (CHO)2. D. C2H6 ; C2H4(OH)2. Cu 176 : Cho 19,8 gam mt anehit n chc A phan ng hoan toan vi dung dich AgNO3/NH3 (d). Lng Ag sinh ra phan ng ht vi dung dich HNO3 loang c 6,72 lit NO ktc. A co cng thc phn t la A. C2H4O. B. C3H6O. C. C3H4O. D. C4H8O. Cu 177: Cho 10,90 gam hn hp gm axit acrylic v axit propionic phn ng hon ton vi Na thot ra 1,68 lt kh (ktc). Nu cho hn hp trn tham gia phn ng cng H2 hon ton th khi lng sn phm cui cng l A. 11,1 gam. B. 7,4 gam. C. 11,2 gam. D. 11,0 gam. Cu 178: Cho 3,15 gam hn hp X gm axit axetic, axit acrylic, axit propionic va lm mt mu hon ton dung dch cha 3,2 gam brom. trung han ton 3,15 gam hn hp X cn 90 ml dd NaOH 0,5M. Thnh phn phn trm khi lng ca axit axetic trong hn hp X l A. 35,24%. B. 45,71%. C. 19,05%. D. 23,49%. Cu 179: Ha tan 26,8 gam hn hp hai axit cacboxylic no, n chc, mch h vo nc c dung dch X. Chia X thnh hai phn bng nhau. Cho phn 1 phn ng hon ton vi dung dch AgNO 3/NH3 d thu c 21,6 gam bc kim loi. trung ha hon ton phn 2 cn 200,0 ml dung dch NaOH 1,0M. Cng thc ca hai axit l A. HCOOH, C3H7COOH. B. CH3COOH, C2H5COOH. C. CH3COOH, C3H7COOH. D. HCOOH, C2H5COOH.

Axit cacboxylic..... .... ......N2P Cu 180: Cho 13,4 gam hn hp X gm hai axit no, n chc, mch h, k tip nhau trong cng dy ng ng tc dng vi Na d, thu c 17,8 gam mui. Khi lng ca axit c s nguyn t cacbon t hn c trong X l A. 3,0 gam. B. 4,6 gam. C. 7,4 gam. D. 6,0 gam.