Chemical Kinetics

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CHEMICAL KINETICS Kinetics is a study of motion. It comes from Greek word kinesis, which means the movement.

Chemical kinetics is the quantitative study of chemical systems that are changing with time. It is the study and discussion about the chemical reactions with respect to reaction rates and many more. For the study of chemical reactions, a chemical reaction mechanism has to be considered. These are the several considerations: Molecules or atoms of reactants must collide with each other in chemical reactions. The molecules must have sufficient energy to initiate the reaction. The orientation of the molecules during the collision (some case).

Reaction rates Chemical reaction rates are the rates of change in concentrations or amounts of reactants or products. For changes in amounts, the units can be one of mol/s and g/s. For changes in concentrations, the units can be one of mol/ (L s) and g/ (L s). Factors Influence Reaction Rates Thermodynamics and kinetics are two factors that affect reaction rates. The study of energy gained or released in chemical reactions is called thermodynamics. Other than thermodynamic and kinetics, there are many other factors that will influence the reaction rates such as: i. Nature of Reactants Acid-base reactions, formation of salts, and exchange of ions are fast reactions. Reactions in which large molecules are formed or break apart are usually slow. Reactions breaking strong covalent bonds are also slow. ii. Temperature The higher the temperature of the reactants, the faster the reaction. iii. Concentration Effect The dependences of reaction rates on concentrations are called rate laws. Rate laws are expression of rates in terms of concentrations of reactants. The rate laws can be in differential forms or integrated forms. They are called differential rate laws and integrated rate laws.

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