N CHNG HIROCACBON Cu 1 : Hn hp kh X gm anken M v ankin N c cng s nguyn t cacbon trong phn t.

Hn hp X c khi lng 12,4g v th tch 6,72 lt( ktc).S mol v cng thc phn t ca M, N ln lt l: A. 0,1 mol C2H4 v 0,2 mol C2H2 B. 0,1 mol C3H6 v 0,2 mol C3H4 C. 0,2 mol C2H4 v 0,1 mol C2H2 D. 0,2 mol C3H6 v 0,1 mol C3H4 Cu 2 : Hirocacbon X khng lm mt mu dung dch brom nhit thng.Tn gi ca X l : A. Etilen B. Xiclopropan C. Xiclohexan D. Stiren Cu 3 : Dy gm cc cht u c kh nng tham gia phn ng trng hp l A. 1,1,2,2-tetrafloeten;propilen;stiren;vinyl clorua B. Buta-1,3-ien; cumen; etilen;trans-but-2-en C. Stiren; clobenzen; isopren;but-1-en D. 1,2-iclopropan; vinylaxetilen; vinylbenzen; toluen Cu 4 :Hn hp kh X gm H2 v mt anken c kh nng cng HBr cho mt sn phm hu c duy nht. T khi ca X so vi H2 bng 9,1. un nng X c xc tc Ni, sau khi phn ng xy ra hon ton, thu c hn hp kh Y khng lm mt mu nc brom; t khi ca Y so vi H2 bng 13. Cng thc cu to ca anken l A. CH3-CH=CH-CH3 B. CH2=CH-CH2-CH3 C. CH2=C(CH3)2 D. CH2=CH2 Cu 5: cho hn hp X gm CH4, C2H4 v C2H2.Ly 8,6 gam X tc dng ht vi dung dch brom (d) th khi lng brom phn ng l 48 gam.Mt khc,nu cho 13,44 lt( ktc) hn hp kh X tc dng vi lng d dung dch AgNO3 trong NH3,thu c 36 gam kt ta.Phn trm th tch CH4 c trong X l: A. 40% B. 20% C. 25% D. 50% Cu 6 : Cho hirocacbon X phn ng vi brom (trong dung dch)theo t l mol 1:1, thu c cht hu c Y(cha 74,08% Br v khi lng).Khi X phn ng vi HBr th thu c 2 sn phm hu c khc nhau.Tn gi ca X l A. But-1-en B. But-2-en C. Propilen D. Xiclopropan Cu 7: Hn hp kh X gm H2 v C2H4 c t khi so vi He l 3,75.Dn X qua Ni nung nng.thu c hn hp kh Y c t khi so vi He l 5.Hiu sut ca phn ng hiro ha l A. 25% B. 20% C. 50% D. 40% Cu 8: kh hon ton 200ml dung dch KMnO4 0,2M to thnh cht rn mu nu en cn V lt kh C2H4( kc). Gi tr ti thiu ca V l A. 1,344 B. 4,480 C. 2,240 D. 2,688 Cu 9 : Cho cc cht : xixlobutan, 2-metylpropen, but-1-en, cis-but-2-en, 2-metyl but-2-en. Dy gm cc cht khi phn ng vi H2 d(xc tc Ni,to),cho cng mt sn phm l: A. 2-metylpropen, cis-but-2-en v xiclobutan B. But-1-en, 2-metylpropen v cis-but-2-en C. Xiclobutan, cis-but-2-en, v but-1-en D. Xiclobutan, 2-metylbut-2-en v but-1-en Cu 10 : Cho cc cht: CH2=CH-CH=CH2; CH3-CH2-CH=C(CH3)2; CH3-CH=CH-CH=CH2; CH3-CH=CH2; CH3-CH=CH-COOH.S cht c ng phn hnh hc l: A. 1 B. 3 C. 4 D. 2 Cu 11 : un nng hn hp kh gm 0,06 mol C2H2 v 0,04 mol H2vi xc tc Ni,sau mt thi gian thu c hn hp kh Y.dn ton b hn hp Y li t t qua bnh ng dung dch brom (d)th cn li 0,448 lt hn hp kh Z ( ktc) c t khi so vi O2 l 0,5.Khi lng bnh d8ng dung dch Brom tng l: A. 1.04gam B. 1,32 gam C. 1,64 gam D. 1,20 gam Cu 12: S ng phn hirocacbon thm ng vi CTPT C8H10 l: A. 2 B. 4 C. 5 D. 3 Cu 13 : Hn hp X c t khi so vi H2 l 21,2 gm propan,propen v propin.Khi t chy hon ton 0,1 mol X,tng khi lng CO2 v H2O thu c l : A. 20,40gam B. 18,60 gam C. 18,96 gam D. 16,80 gam Cu 14 : cho s chuyn ha sau : CH4C2H2C2H3ClPVC. tng hp 250 kg PVC theo s trn th cn V m3 kh thin nhin ktc. Gi tr ca V l (bit CH4 chim 80% th tch kh thin nhin v hiu sut ca qu trnh l 50%) A. 358,4 B. 448,0 C. 286,7 D. 224,0 Cu 15 : Khi crkinh hon ton mt th tch ankan X thu c 3 th tch hn hp Y ( cc th tch kh o cng iu kin nhit v p sut)t khi ca Y so vi hiro bng 12.CTPT ca X l A. C6H14 B. C3H8 C. C4H10 D. C5H12 Cu 16: Cho cc cht sau : CH2=CH-CH2-CH2-CH=CH2; CH2=CH-CH=CH-CH2-CH3; CH3-C(CH3)=CH-CH3; CH2=CH-CH2-CH=CH2 . S cht c ng phn hnh hc l: A. 2 B. 3 C. 1 D. 4 Cu 17 : Cho iso-pentan tc dng vi clo theo t l s mol 1:1,s sn phm monoclo ti a thu c l : A. 2 B. 3 C. 5 D. 4

Cu 18 : Dn 1,68 lit hn hp kh X gm 2 hirocacbon vo bnh ng dung dch brom d.Sau khi phn ng xy ra hon ton,c 4 g brom phn ng v cn li 1,12 lt kh.nu t chy hon ton 1,68 lt X th sinh ra 2,8 lt kh CO2.CTPT ca 2 hirocacbon l( bit cc th tch kh u o ktc) A. CH4 v C2H4 B. CH4 v C2H4 C. CH4 v C3H6 D. C2H6 v C3H6 Cu 19: Hirocacbon mch h X trong phn t ch cha lin kt v c 2 nguyn t cacbon bc 3 trong mt phn t.t chy hon ton mt th tch X sinh ra 6 th tch CO2( cng k nhit p sut).Khi cho X tc dng vi clo theo t l s mol 1:1, s dn xut monoclo ti a sinh ra l: A. 3 B. 4 C. 2 D. 5 Cu 20: t chy hon ton 1 lt hn hp kh gm C2H2 v hirocacbon X sinh ra 2 lt kh CO2 v 2 lt hi nc ( cc th tch kh v hi o cng k nhit p sut).CTPT ca X l : A. C2H6 B. C2H4 C. CH4 D. C3H8 Cu 21: ba hirocacbon X,Y,Z l ng ng k tip khi lng phn t ca Z bng 2 ln khi lng phn t ca X.cc cht X,Y,Z thuc dy ng ng ca A. Ankan B. Ankaien C. Anken D. Ankin Cu 22: CTGN ca mt hirocacbon l CnH2n+1 .Hirocacbon thuc dy ng ng ca A. Anken B. Ankin C. Ankaien D. Ankan Cu 23: t chy hon ton hn hp M gm mt ankan X v mt ankin Y thu c s mol CO2 bng s mol H2O thnh phn % s mol ca X v Y trong hn hp M ln lt l: A. 35% v 65% B. 75% v 25% C. 20% v 80% D. 50% v 50% Cu 24: t chy hon ton 20 ml hn hp X gm C3H6, CH4, CO (th tch CO gp 2 ln th tch CH4) thu c 24ml CO2 (cc th tch kh o cng k nhit , p sut). T khi ca X so vi kh H2 l A. 25,8 B. 12,9 C. 22,2 D. 11,1 Cu 25: t chy hon ton mt hirocacbon X thu c 0,11 mol CO2 v 0,132 mol H2O.Khi X tc dng vi kh clo ( theo t l s mol 1:1)thu c mt sn phm hu c duy nht.tn gi ca X l: A. 2-metylbutan B. 2-metylpropan C. 2,2-imetylpropan D. Etan Cu 26: Cho 4,48 lt hn hp X ktv gm 2 hirocacbon mch h li t t qua bnh cha 1,4 lt dung dch brom 0,5M.Sau khi phn ng hon ton s mol brom gim i mt na v khi lng bnh tng thm 6,7g.CTPT ca 2 hirocacbon l A. C2H2 v C4H6 B. C2H2 v C4H8 C. C3H4 v C4H8 D. C2H2 v C3H8 Cu 27: Ba hirocacbon X,Y,Z k tip nhau trong dy ng ng, trong khi lng phn t Z gp i khi lng phn t X.t chy 0,1 mol cht Y, sn phm kh hp th hon otn vo dung dch Ca(OH)2 d.Thu c s gam kt ta l A. 20 B. 40 C. 30 D. 10 Cu 28: Mt hirocacbon X cng hp vi axit HCl theo t l mol 1:1 to sn phm c thnh phn khi lng Clo l 45,223%.CTPT ca X l: A. C3H6 B. C3H4 C. C2H4 D. C4H8 Cu 29: Hirat ha 2 anken ch to thnh 2 ancol. 2 anken l: A. 2-metylpropen v but-1-en B. Propen v but-2-en C. Eten v but-2-en D. Eten v but-1-en Cu 30: Hn hp gm hirocacbon X v oxi c t l s mol tng ng l 1:10. t chy hon ton hn hp trn thu c hn hp kh Y. Cho Y qua dung dch H2SO4 c, thu c hn hp kh Z c t khi i vi H2 bng 19. CTPT ca X l: A. C3H8 B. C3H6 C. C4H8 D. C3H4 Cu 31: Dy gm cc cht c dng tng hp cao su buna-S l: A. CH2=CH-CH=CH2, C6H5CH=CH2 B. CH2=C(CH3)-CH=CH2, C6H5CH=CH2 C. CH2=CH-CH=CH2, , lu hunh D. CH2=CH-CH=CH2, CH3-CH=CH2 Cu 32: Khi brom ha 1 ankan ch thu c mt dn xut monobrom duy nht c t khi hi i vi H2 l 75,5. Tn ca ankan l: A. 3,3-imetyl hexan B. Isopentan C. 2,2-imetylpropan D. 2,2,3-trimetylpentan Cu 33: t chy hon ton mt th tch kh thin nhin gm metan, etan, propan bng O2 khng kh (trong khng kh O2 chim 20% th tch) thu c 7,84 lt kh CO2 ktc v 9,9 gam H2O. Th tch khng kh ktc nh nht cn dng t chy hon ton lng kh thin nhin trn l: A. 70 lt B. 78,4 lt C. 84 lt D. 56 lt Cu 34: Dn V lt ktc hn hp X gm axetilen v H2 i qua ng s ng bt Ni nung nng thu c kh Y. Dn Y vo lng d AgNO3 (hoc Ag2O) trong dd NH3 thu c 12 gam kt ta. Kh i ra khi dung dch phn ng va vi 16 gam brom v cn li kh Z. t chy hon ton kh Z thu c 2,24 lt kh CO2 ktc v 4,5 gam H2O. Gi tr ca V bng: A. 11,2 B. 13,44 C. 5,6 D. 8,96 Cu 35: Khi cho ankan X (trong phn t c % khi lng lng cacbon bng 83,72%) tc dng vi clo theo t l s mol 1:1 (trong k chiu sng)ch thu c 2 dn xut monoclo ng phn ca nhau.Tn ca X l: A. 2 metylpropan B. 2,3-imetylbutan C. Butan D. 3-metylpentan