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Soil Chemistry
Soil Chemistry
Soil Chemistry
Ion Exchange
Ions adsorbed to soil surfaces can be exchanged with ions in soil solution. Cations and anions
Ion exchange
Organic colloids and inorganic micelles (clays) are sites of ion exchange Where do ions in soil come from?
Release Rain Weathering
Ion exchange
Ion exchange
Exchangeable ions on soil surface trading places with ions in solution.
CEC
Expressed in: milliequivalents per 100 g (meq/100g)
Base saturation
% of exchange sites occupied by basic cations Basic cations are cations other than H+ and Al+3
Base saturation + H+ ion saturation should equal 100%
equilibrium
Strive for equivalent proportions of solution and exchangeable ions. Upset equilibrium by:
removal by plants leaching fertilization weathering
Initiate ion exchange
H+ Ca+ H+ Ca+
H+
H+ solution
exchangeable
solution
exchangeable
solution
Add K fertilizer
Ca+2 + Ca+2
K+ K+ K+ K+ K+ Ca+2 + K+ K+ K+ Ca+2
1 Ca : 2 K Same ratio
1 Ca : 2 K
Energy of adsorption
Strong --------------------------------------Weak Al+3 > Ca+2 > Mg+2 > [K+ = NH4+ ] > Na+ > H+ (based on charge and hydrated radius)
Soil pH importance
Before plants can get nutrients, they must be dissolved in soil solution
pH
negative log of the hydrogen ion concentration (also a measure of OH- concentration) If H+ concentration > OH- : acidic If OH- > H+ : basic Soil pH is pH of solution, NOT exchange complex
In soil, both H+ and Al+3 ions produce acidity Al+3 produces H+ ions when it reacts with water. (when pH below 6: Al+3 is the cause of acidity)
1. 2.
energy of adsorption
So, K+ and Na+ are hydrolyzed easily and yield higher pHs .
2. Hydrolysis of carbonates
(especially CaCO3, MgCO3, Na2CO3)
As long as there are carbonates in the soil, carbonate hydrolysis controls pH.
Calcareous soils remain alkaline because H+ ions combine with OH- to form H2O. For those soils to become acid, all carbonates must be leached.
1. 2.
a.
Carbonic acid
(respiration and atmospheric CO2)
2. Exchangeable acids
Exch. H+ or Al+3 dissociate Al+3 ties up OH- from water, releases an equivalent amount of H+ ions.
Al+3 + H2O
AlOH+2 + H+
CEC and pH
Only 2:1 silicate clays do not have pH-dependent CECs. Others are pH-dependent: 1:1 kaolinite: low pH: low CEC high pH: high CEC
Oxidic clays