BI TP DUNG DCH CU 1: Trn ba dd H2SO4 0,1M ; HNO3 0,2M ; HCl 0,3M vi th tch bng nhau thu c ddA.

Ly 300ml ddA cho tc dng vi ddB gm NaOH 0,2M v KOH 0,29M. Tnh th tch ddB dd thu c c pH = 12. CU 2: Mt dd cha 0,2 mol Fe3+ ; 0,1 mol Al3+ ; x mol SO42 ; y mol NO3 . C cn dd thu c 61,3g mui. Tnh x, y. CU 3: Ha tan 26g CaCO3 bng dd HCl d. Cho kh sinh ra hp th vo 400ml dd NaOH a% (D = 1,18 g/ml) thu c ddX. Thm lng d dd BaCl2 vo dd X, sau phn ng thu c 18,715g kt ta. Tnh a. CU 4: a) Dung dch CH3COOH 0,1M c a = 1%. Tnh pKa ca CH3COOH v pH dung dch. b) A l dd HCl 0,2M. B l dd H2SO4 0,1M. Trn A v B theo th tch bng nhau, tnh pH dung dch thu c. CU 5: Cho 1,92g ng vo 100ml dd ng thi cha KNO3 0,16M v H2SO4 0,4M thy sinh ra mt cht kh c t khi hi so vi hidro l 15 v ddA. Tnh th tch kh ktc, th tch dd NaOH 1M ti thiu kt ta ton b Cu2+ trong ddA. CU 6: a) Thm t t 100g dd H2SO4 98% vo nc thu c 1 lit ddA. Tnh pH ddA. b) Thm bao nhiu lit dd NaOH 1,8M vo 1 lit ddA thu c dd c pH 1 v pH 13. CU 7: Cho dd pH 4. Phi thm mt th tch nc gp bao nhiu ln th tch dd ban u thu c dd pH 5. CU 8: Trn 1 lit dd H2SO4 0,005M vi 4 lit dd NaOH 0,005M. Tnh pH. CU 9: Cho phn ng : A + a B ABa . Vit biu thc tnh tc phn ng. Xc nh a bit nu tng nng A,B ln hai ln th tc phn ng tng 16 ln. CU 10: Dung dch cha Cu2+, Na+, Cl-, SO42.Hi dd ny c to thnh khi ha tan mui no vo nc? Khi c cn dung dch ny c th thu c mui no? CU 11: Tnh th tch dd KOH 14% (D = 1,12g/ml) cha s mol OH- bng s mol OH- c trong 200ml dd c pH = 12. CU 12: Ha tan 12,5 g CuSO4.5H2O vo nc thu c 300ml dd. Tnh th tch dd KOH 2M kt ta ht Cu2+ trong 100ml dd trn. CU 13: Tnh nng mol/l ca dd HNO3 v dd KOH bit :20ml dd HNO3 trung ha ht bi 60 ml dd KOH, 20ml dd HNO3 sau khi tc dng vi 2 g CuO th trung ha ht bi 10ml dd KOH. CU 14: C bn dd NH3 , FeSO4 , BaCl2 , HNO3 . Vit cc phng trnh phn ng (dng phn t v ion) xy ra khi trn ln lt cc dd vi nhau. CU 15: C hai dd A , B. Mi dd cha hai loi cation v hai loi anion trong s cc ion sau : K+ : 0,15 mol ; Mg2+ : 0,1mol ; : 0,25 mol; H+ : 0,2 mol ; Cl- : 0,1 mol; SO42 : 0,075 mol ; NO3 : 0,25 mol ; CO32 : 0,15mol. Xc nh A,B. CU 16: Dung dch A cha NaHCO3 v Na2CO3. Trung ha 300 ml dd A cn 100ml dd NaOH 1M thu c dd B. Cho dd CaCl2 d vo ddB thu c 30g kt ta. Xc nh nng mol/l cc cht trong ddA. CU 17: C dd D cha Zn2+, Fe2+ v Cl-. Thm t t dd NaOH 1,5M vo 50ml ml dd D khi lng kt ta cc i th thy tn 40ml. Mt khc nu thm dd KOH 2M vo 500ml dd D n khi lng kt ta khng thay i th cn dng 500ml. Xc nh nng mol/l ca mi mui trong ddD. CU 18: Vit phng trnh phn ng xy ra khi : a) Cho NH3 d vo dd CuSO4 . b) Trn dd FeCl3 vi dd Na2CO3. c) Cho t t dd KOH vo dd AlCl3 . d) Cho kh CO2 li t t qua dd Ba(OH)2. CU 19: Nhn bit cc l mt nhn sau: a) NaCl, KBr, Na2CO3, NH4Cl, H2SO4, HCl, Na3PO4. b) CaCO3, BaCl2, Mg(OH)2, (NH4)2CO3, NH4NO3, Ba(NO3)2. CU 20: Cc cht v ion sau l axit, baz hay trung tnh : Na+, Zn(OH)2 , Cr(OH)3, Fe3+, CH3COO -, HS- , NH4+ , CO32, HPO42 . CU 21: Tnh [H+] ca dd H2SO4 80% (D = 1,4 g/ml). Tnh th tch dd KOH c pH = 10 cn dng trung ha 100 ml dd trn. CU 22: Dung dch A cha AlCl3. Tnh nng mol/l ca mui v ion c trong dd A trong cc trng hp sau : a) Cho sud vo 100ml dd A, lng kt ta cc i thu c l 7,8g. b) Cho dd KOH 2M vo 200 ml ddA n khi kt ta va tan ht th tn 400ml. CU 23: Ha tan km trong 240ml dd axit nitric va thu c 2,24 lit kh hi nh hn khng kh ktc. a) Tnh khi lng km b ha tan. b) Thm 500ml dd KOH a M vo dd thu c thy xut hin 39,6g kt ta. Tnh a.

CU 24: Mt ddX cha : Ba2+ , Cl- , NH4+ , NO3 . Ly 100ml dd X tc dng vi NaOH nng, d thu c 5600 cm3 kh 00C, 760 mmHg. Nu cho axit sunfuric d vo 400 ml ddX th thu c 93,2 g kt ta. Tnh nng mol/l ca cc ion trong dd bit t l mol gia Cl- v NO3 l 1:2. CU 25: Trn 2,24 lit nit v 78,4 lit hidro (ktc). un nng, phn ng xy ra vi hiu sut l 25%. Dn hh sn phm qua 5 lit nc. Tnh th tch kh khng b hp th. Tnh pH dd thu c bit in li ca NH4OH l 20% v ch c 10% amoniac tan trong nc tc dng vi nc. CU 26: Cp cht no sau y khng tn ti trong cng mt dung dch, vit phng trnh dng phn t v ion rt gn : KNO3 v BaCl2 ; Fe(NO3)3 v NaOH ; (NH4)3PO4 v Ba(OH)2 ; FeCl2 v Na2CO3; AlCl3 v ddNH3 ; ZnCl2 v Ba(OH)2. CU 27: Ha tan 6,4g S trong 147g dd HNO3 60% ( c), nng. Pha long dd thu c bng nc n 600ml. Tnh pH. Tnh C% ca cc cht trong dd trc khi pha long. CU 28 : Cn bng cc phn ng sau bng phng php electron. Vit di dng phn t v ion rt gn : a) FeSO4 + H2SO4 + KMnO4 K2SO4 + MnSO4 + Fe2(SO4)3 + H2O. b) FexOy + HNO3 Fe(NO3)3 + NO2 + H2O . c) Na + H+ + NO3 Na+ + NH4+ + H2O. d) Cu + H+ + SO42 Cu2+ + SO2 + H2O. CU 29 : Nguyn t ca nguyn t A c phn lp ngoi cng l 2p. S electron trn phn lp ny bng 0,75 ln tng s electron cn li. T n cht A hy iu ch axit trong A c s oxi ha cao nht. CU 30 : Tnh nng mol/l ca mui v ion trong dd thu c khi : a) Cho 3,36 lit NH3 (ktc) vo 100ml dd H2SO4 1M. b) Cho 8,96 lit CO2 (ktc) vo 500ml dd NaOH 1M. c) Cho 16,8 lit CO2 (ktc) vo 400ml dd Ba(OH)2 2M. d) Trn 100ml dd NaOH 2M vi 400ml dd H3PO4 0,4M. e) Cho V lit CO2 vo 200ml dd Ba(OH)2 a M thu c 29,55g kt ta, lc b kt ta, thm 500ml KOH 3M vo phn nc lc li thu c 9,85g kt ta na. Tnh V, a. CU 31: Dung dch A gm HCl 2M v H2SO4 1M. Dung dch B gm NaOH 1M v Ba(OH)2 1,5M. trn A v B theo t l no v th tch thu c dung dch c pH l 0; 7; 14. CU 32: Cho 5g hn hp gm Zn v Al vo 220ml dung dch HNO3. Sau khi phn ng xong thy c 2,013g kim loi cha tan, thu c 0,896lit ( ktc ) hn hp NO v N2O c t khi so vi hidro l 16,75. Tnh khi lng mui v CM dung dch HNO3 ban u. CU 33: Trn NH3 vi Cl2, phn ng xy ra hon ton, lm ngui hn hp sn phm ch thu c 24,075g cht rn. Cng ly lng NH3 nh trn iu ch HNO3 th thu c 65,625ml dung dch 40% (D=1,2g/ml). Tnh hiu sut qu trnh iu ch axit nitric. CU 34: a) Tnh lng qung pyrit 2% tp cht cn dng iu ch 800ml dung dch H2SO4 c pH=2. b) Tnh lng NH3 cn thit iu ch 600ml dung dch HNO3 c pH=1. c) Trn dung dch cu a vi dung dch cu b th thu c dung dch c pH l bao nhiu? CU 35: Ha tan 42,9g Na2CO3.10H2O vo nc thnh 700ml ddA . a) Dung dch A c mi trng g? vit phng trnh phn ng xy ra khi cho AlCl3 vo ddA. b) Thm 150ml dung dch MgCl2 1M vo ddA. Xc nh nng ion trong dung dch mi. CU 36: a) Ly 400ml dung dch hn hp hai axit HCl v HBr ha tan mt lng qung dolomit thu c V lit kh ktc. Cho ton b kh qua dung dch Ca(OH)2 thu c 20g kt ta, lc b kt ta, un si dung dch nc lc th thu c 10g kt ta na. Tnh pH dung dch axit ban u v khi lng dolomit 25% tp cht. b) Cho V/2 lit kh trn vo 34,2g dung dch Ba(OH)2 5%. Tnh C% dung dch thu c. CU 37: Ha tan Fe trong dung dch HNO3 long, lnh thu c dung dch A v hn hp ng mol B gm hai kh, dB/hidro=11,5. Thm NaOH vo dung dch sau phn ng ch thu c mt kt ta trng nh lc ha nu trong khng kh. Vit phng trnh phn ng di dng phn t v ion rt gn. CU 38: T FeS2, Ca3(PO4)2, K2CO3, khng kh, than , xc tc v iu kin c , iu ch: supephotphat n, supephotphat kp, ure, kali nitrat, amophot, st. CU 39: M t v gii thch hin tng xy ra khi: a) Cho Fe d vo dung dch HNO3 c. b) Cho Cu vo dung dch HNO3 thu c dung dch B. c) Cho Fe vo dung dch B ch thu c dung dch C. Cho ddKOH t t vo dung dch C. CU 40: Hy chn bn dung dch mi dung dch cha hai ion trong s cc ion sau (khng trng lp): SO42 , NO3 , CO32 , Cl-, K+, Ba2+, Mg2+, Pb2+.

CU 41: Nhn bit cc l mt nhn sau: a) Ch dng mt thuc th : (NH4)2SO4, K2SO4, NaCl, NH4Cl. b) Ch dng qu tm : NaOH, H2SO4, Na2SO4, Ba(OH)2, NaCl. c) CO2, SO2, SO3, N2, CO. CU 42: Trn dung dch c pH=5 vi dung dch c pH=8 theo t l no th thu c dung dch c pH=6. CU 43: Vit phng trnh phn ng nhit phn: CaCO3, NH4Cl, Na2SO4, KCl, NaHCO3, Ca(NO3)2, Hg(NO3)2. CU 45: trung ha 100ml dung dch (HNO3 + H2SO4) cn 40ml dung dch KOH 0,5M. Nu ly mt lit dung dch axit trn em trung ha bng NaOH ri c cn dung dch sau phn ng th thu c 15,32g mui khan. a) Tnh pH dung dch axit v nng mi axit trong dung dch. b) trung ha 50ml dung dch axit cn bao nhiu ml dung dch gm NaOH 1M v Ba(OH)2 2M ? CU 46: Dn 600g hn hp N2 v H2 c t l 1:1 v th tch qua bt Pt nung nng, c 30% hidro b phn ng. a) Xc nh phn trm hn hp kh sau phn ng. b) Ly ton b lng NH3 thu c i iu ch HNO3, tnh th tch dung dch HNO3 50% (D=1,42g/ml) thu c. Bit hiu sut qu trnh l 80%. CU 47: Ha tan ht mui sunfit ca kim loi ha tr II bng dung dch HCl va thu c dung dch A. Thm Na2CO3.10H2O cho n khi thu c kt ta cc i, nung kt ta n khi lng khng i thu c 30,6g cht rn v 4,48 lit CO2 ktc. a) Xc nh kim loi. b) Tnh th tch dung dch HCl 20% (D=1,2g/ml) v lng Na2CO3.10H2O dng. CU 48: Thm dung dch HCl 0,5M vo 100ml dung dch hai mui Na2CO3 , NaHCO3 n khi ht si bt kh thu c 3,36 lit kh ktc. C cn 50ml dung dch hai mui trn thu c 14,4g Na2CO3.10H2O. a) Tnh nng mol mi mui trong dung dch. b) Tnh th tch dung dch HCl bit dng d 10%. c) Thm phenolphtalein vo dung dch mui th c hin tng g? CU 49: Ha tan 40,25g ZnSO4 vo nc thu c 400ml dung dch A. Tnh th tch dung dch NaOH 5M ti thiu cn cho vo 200ml dung dch A thu c kt ta ln nht, nh nht. CU 50: Cho 2,24 lit NH3 ktc qua 16g CuO un nng thu c cht rn X. Ha tan ht X trong dung dch HNO3 c. Cc phn ng xy ra hon ton. Tnh s mol sn phm thu c? CU 51: Nung 24,2g mui nitrat n khi lng khng i thu c 8g oxit kim loi. Xc nh cng thc mui. CU 52: Ch dng thm mt ha cht nhn bit cc cht mt nhn sau: Na2SO4, CaCO3, FeS, BaSO4, ZnS, HgI2, PbI2, CuSO4,Fe(OH)3. CU 53: a) Ch dng mt ha cht hy phn bit Fe2O3, Fe3O4. b) So snh pH ca cc dung dch c cng nng : NH3, NaOH, Ba(OH)2. Gii thch. c) Cho hai dung dch H2SO4 c pH=2 v pH=1. Thm 100ml dung dch KOH 0,1M vo 100ml mi dung dch trn. Tnh nng mol/lit mi dung dch thu c. CU 54: Cho 18,5g hn hp Z gm Fe, Fe3O4 tc dng vi 200ml dung dch HNO3 long nng. Sau khi phn ng xy ra hon ton thu c 2,24 lit NO duy nht ktc, dung dch Z1 v cn li 1,46g kim loi. a) Tnh nng mol/lit ca dung dch HNO3. b) Tnh khi lng mui trong dung dch Z1. CU 55: Cho phng trnh: M2Ox + HNO3 M(NO3)3 + NO + H2O a) Hy cn bng phng trnh theo phng php thng bng e. b) Vi gi tr no ca x phn ng trn l phn ng oxi ha kh. CU 56: Tnh pH ca dung dch axit yu HX 0,01M c pKa = 6. CU 57: Cho 13,5 g bt nhm phn ng ht vi 300 ml dung dch HNO3 8M thu c dung dch X v kh NO. Thm 200ml dung dch KOH 22,4% (D = 1.2 g/ml) vo dung dch X th thu c bao nhiu gam kt ta. CU 58:a) Vit cng thc cu to ca H3PO4 v H3PO3v phng trnh in li ca hai axit ny. b) Trn hai axit trn theo t l 1:1 v khi lng thu c 18 g hn hp. Tnh khi lng dung dch NaOH 20% cn trung ha hn hp trn. CU 59:Kh m g qung photphorit 96% tinh cht bng C nhit cao vi hiu sut 80%. Lng photpho thu c iu ch c 1kg dung dch H3PO4 19,6%. Tnh m. CU 60: T qung apatit hy vit cc phng trnh iu ch P; PH3; Zn3P2; P2O5.

CU 61: Nu cc qui lut bin thin tnh cht ca cc n cht cng nh hp cht trong phn nhm chnh. Minh ha bng cc nhm IVA; VA. CU 62: So snh kim cng v than ch. CU 63: Nu thnh phn v phn ng ca thuc n en, thuc u que dim. CU 64:Thm t t dung dch HCl 1M vo 500 ml dung dch cha ng thi Na2CO3 v KHCO3 khi c kh bt u thot ra th dng ht 0,5 lit; khi va ht bt kh th dng ht 1,2 lit. Tnh CM ca mi mui trong dung dch ban u. CU 65: Ti sao SiH4 km bn hn CH4? Nu ng dng ca cc mui silicat. CU 66: Cho 100ml dung dch A cha Na2CO3 1M v K2CO3 1,5M phn ng va vi 200 ml dung dch B cha MCl2 v NCl2 thu c 23,4 g kt ta. Xc nh M, N bit chng l kim loi IIA thuc 2 chu k k tip. CU 67: 10,08 g Fe ngoi khng kh sau mt thi gian thu c m gam 4 cht rn, ha tan ht lng cht rn ny trong dung dch HNO3 thu c 2,24 lit NO ktc. Tnh m. CU 68: Cho 5,5 g hn hp MgO v Al2O3 tc dng vi dung dch NaOH d thu c cht rn B, ha tan B trong HCl d thu c dung dch C, thm KOH d vo dung dch C thu c kt ta D, nung D n khi lng khng i th thy khi lng cht ny gim 0,18 g. Tnh % khi lng mi cht trong hn hp ban u. CU 69: Vit phng trnh oxi ha FeSO4 bng KMnO4; K2Cr2O7 trong mi trng H2SO4. (Di dng phn t v ion rt gn.) CU 70: Lp cng thc tnh in li, nng H+, pH ca dung dch axit yu HA c nng C mol/lit v hng s cn bng phn li l Ka. CU 71: Ha tan hn hp 3 kim loi kim trong nc thu c 500 ml dung dch A v 17,92 lit kh 273oC; 2at. Tnh pH dung dch thu c. CU 72: Cho m g Na vo 200 ml dung dch HCl 1M thu c dung dch A. Cho t t Fe2(SO4)3 vo dung dch A thu c kt ta B, nung B trong khng kh n khi lng khng i thu c 3,2 g cht rn. Tnh m. CU 73: Ly 10 ml dung dch NH4Cl 0,1M ri thm vi git phenolphtalein, thm tip 10ml dung dch NaOH 0,1M vo, khuy u, un si. M t v gii thch hin tng. CU 74: Vit cc phng trnh phn ng xy ra khi: a) Thm t t ddCa(OH)2 vo ddH3PO4 sau li thm t t dung dch HCl vo. b) Cho HCl vo ddNa2SiO3, lc kt ta v nung, ngm cht rn thu c trong ddHF. CU 75: a) Trn 10 lit NO vi 50 lit khng kh (20% O2). Tnh th tch kh thu c sau khi phn ng xy ra hon ton. b) un 150 lit hn hp H2 v N2 (t l 3:1 v th tch) thu c 140 lit hn hp. Tnh hiu sut.