SURFACE PRE-TREATMENT BY PHOSPHATE CONVERSION COATINGS

GUIDED BY:- Mrs. SWARNALATA BEHERA PROJECT BY:-

NAME- SANGRAM KESHARI JENA ROLL NO- 27632 REGN NO- 0921105014

INTRODUCTION
1. 2. 3. 1.

METALS WHICH ARE EXTRACTED FROM THEIR ORES SHOW A STRONG TENDENCY TO REVERT BACK TO THEIR OXIDE FORM. THE METHODS OF CORROSION PREVENTION ARE MANY AND VARIED. MOST COMMONLY USED METHODS ARE :MODIFICATION OF METAL BY ALLOYING MODIFICATION OF ENVIRONMENT CHANGE OF POTENTIAL SOME OTHER METHODS ARE:PHYSICAL VAPOUR DEPOSITION CHEMICAL VAPOUR DEPOSITION IMPLEMENTATION LASER TREATMENT DEPOSITION BY THERMAL TREATMENT

CHEMICAL CONVERSION TECHNIQUES

ADHERENT, INSOLUBLE, INORGANIC, CRYSTALLINE OR AMORPHOUS SURFACE FILM. 2. A PORTION OF BASEMETAL CONVERTED TO LESS REACTIVE OXIDE. 3. THIS FILM IMPARTS AN EQUAL POTENTIAL TO THE SURFACE. 4. THEY ALSO SERVE AS ABSORPTIVE BASES AS ABSORPTIVE BASES AND HIGH SPEED COATING FORMATION BESIDES BEING ECONOMICAL.
1.

HISTORY AND DEVELOPMENT

IN 1869, RED HOT IRON ARTICLES WERE PLUNGED IN TO THE PHOSPHORIC ACID TO PREVENT THEM FROM CORROSION. NEW TYPES OF PHOSPHATE COATING SUCH AS TIN,NICKEL AND LEAD PHOSPHATE COATINGS HAVE BEEN INTRODUCED. DURING THE 30 YEARS WORK HAS BEEN CONCENTRATED MAINLY ON IMPROVEMENTS IN QUALITY.

PHOSPHATING
1. TREATMENT OF METAL SURFACE SO AS TO

GIVE A REASONABLY HARD, ELECTRICALLY NON- CONDUCTIVE SURFACE COATING. 2. THE COATING IS FORMED AS A RESULT OF TOPOCHEMICAL REACTION, WHICH CAUSES THE SURFACE TO INTEGRATE ITSELF AS A PART OF CORROSION RESISTANT FILM.

ACCELERATION OF THE PHOSPHATING PROCESS

TYPES

OF ACCELERATING PROCESS:CHEMICAL ACCELERATION MECHANICAL ACCELERATION ELECTROCHEMICAL ACCELERATION

KINETICS OF PHOSPHATING PROCESS

THREE DIFFERENT METHODS USED: GRAVIMETRIC

ELECTROCHEMICAL METHOD
RADIOGRAPHY

CHEMISTRY OF PHOSPHATING
PHOSPHATING SOLUTION CONTAINS DILUTE PHOSPHORIC ACID BASED SOLUTIONS OF ONE OR MORE ALKALI METAL/ HEAVY METAL IONS + 23 4 2 4 )2 + 2

POTENTIAL-TIME CURVE

PROCESS DETAILS

COATING CHARACTERISTICS
PHOSPHATE COATINGS ARE PRODUCED

ON STEEL, ZINC, ALUMINIUM.

THE FACTORS AFFECTING ARE:-

METHOD OF APPLICATIONS DEGREE OF AGITATION OF BATH BATH CHEMISTRY TYPES OF ACCELERATOR

PHOSPHATE LAYER FORMATION

IN Zn-PHOSPHATE STEEL THE FORMATION OF GROWTH IS IN 3 STAGES

104 106 / 2 platelet crystal are formed. NUCLEATION AND GROWTH OF SEVERAL CRYSTALS ON THE UPPER SURFACE OF ORIGINAL CRYSTAL START. A THIN LAYER OF ZINC PHOSPHATE IS FORMED.

COATING THICKNESS

IT IS MEASURED BY GRAVITY METER. IT RANGES FROM 1 TO 10 MICRON. THE RATIO BETWEEN WEIGHT TO THICKNESS IS 1.5 TO 3.5 .

COATING POROSIT Y

NUMBER OF CRYSTAL OF DIFFERENT SIZE. GENERALLY VERY LOW ABOUT 0.5-1.5% OF THE PHOSPHATE SURFACE. POROSITY IS INVERSELY PROPORTIONAL TO THICKNESS. IT DEPENDS UPON: TIME OF TREATMENT TYPE OF PHOSPHATE SOLUTION. IRON CONTENT

STABILITY OF PHOSPHIDE COATING i. CHANGE BY USING CATHODIC ELECTROPHOSPHORIC PAINTING ii.HUMID SERVICE iii.VARIATION IN TEMPERATURE

DEFECTS
LOW

CORROSION RESISTANCE OVERHEATING OF BATH EXCESS ACIDITY SLUDGE FORMATION INCORRECT SOLUTION COMPOSITION STAINED COATING

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