, CHEMISTY FORM 5 RATE OF REACTION

Exercise 1 : 1. The table shows the total volume of gas collected at regular time intervals in a reaction. Time (s) Volume of gas (cm3) 0 0.00 30 12.50 60 19.70 90 24.60 120 28.70 150 31.50 180 31.50

18 Januari 2011

What is the average rate of reaction in the second minute ? 2. The diagram shows the graph of total volume of hydrogen released against time for a reaction between hydrochloric acid and excess zinc. Volume of gas (cm3)

v/2

20

40

60

80

time (s)

Which of the following statements can be deduced from the graph ? A There is no more hydrochloric acid left at the 80 th second. B The volume of gas produced at the 40 th second is v/2. C The rate of reaction is highest at the 20 th second. D The average rate of reaction is v/40 cm3 s-1.

3.

2 H2O2 (aq) -------

2 H2O (l) + O2 (g)

Which of the hydrogen peroxide solutions will liberate oxygen gas at the highest rate ? Concentration of H2O2 (mol dm-3) 0.2 0.4 0.6 0.8 Mass of manganese (IV) oxide added (g) 0.2 0.2 0.4 0.4

A B C D 4.

The rate of reaction between calcium carbonate and sulphuric acid decreases with time because A Product of reaction increases B Pressure of the reaction decreases C temperature of sulphuric acid decreases D concentration of sulphuric acid increases

Exercise 2 : Paper 3 1. An experiment was carried out to investigate the rate of reaction between 5.0 g of zinc granules and 50 cm3 of 0.2 mol dm-3 of hydrochloric acid. The volume of hydrogen produced was measured by displacement of water in a burette as shown in Diagram 1.

Diagram 1 (a) Diagram 2 shows the burette readings at 30 second intervals. Record the burette readings in the spaces provided.

Diagram 2 (b) (c) [6 marks] How can the total volume of gas collected for each 30 second interval be calculated ? [3 marks] Calculate the total volume of gas collected for each 30 second interval. Construct a table to record all the burette readings and the volumes of gas collected in the experiment. [3 marks] State the operational definition of the rate of reaction based on this experiment. [3 marks] State three factors that can affect the rate of this experiment. [3 marks]

(d) (e)

(f) (g) (h) (i)

(j)

Plot a graph of volume of gas in cm3 produced against time in seconds on the graph paper. [3 marks] Use the graph in (f) to calculate the rate of reaction at 90 seconds. Show on the graph how you determine this rate of reaction. [3 marks] How does the rate of reaction change with time in this experiment ? Explain this change of rate. [3 marks] Sketch the curve you would expect to obtain on the graph in (f) if the experiment is repeated using 5.0 g of zinc powder and 50 cm 3 and 0.2 mol dm-3 of hydrochloric acid. [3 marks] Suggest another method to measure the volume of hydrogen gas produced in this experiment other than by using displacement of water in a burette. [3 marks] TOTAL MARKS : 33 marks

(k) (l) (m) (n)

(o)

Plot a graph of volume of gas in cm3 produced against time in seconds on the graph paper. [3 marks] Use the graph in (f) to calculate the rate of reaction at 90 seconds. Show on the graph how you determine this rate of reaction. [3 marks] How does the rate of reaction change with time in this experiment ? Explain this change of rate. [3 marks] Sketch the curve you would expect to obtain on the graph in (f) if the experiment is repeated using 5.0 g of zinc powder and 50 cm 3 and 0.2 mol dm-3 of hydrochloric acid. [3 marks] Suggest another method to measure the volume of hydrogen gas produced in this experiment other than by using displacement of water in a burette. [3 marks] TOTAL MARKS : 33 marks

Answer 1. 2. 3. 4. A A D A