59. A first order reaction is half completed in 45 minutes. How long does it need for 99.

9% of the
reaction to be completed?
(A) 20 hours (B) 10 hours
(C) 7.5 hours (D) 5 hours

60. The half life of a first order reaction is 10 minute. If initial amount is 0.08 mole/lit and
concentration at some instant is 0.01 mole/lit then t =
(A) 10 min (B) 30 min
(C) 20 min (D) 40 min

61. The rate constant of a zero order reaction is 0.2 mole dm
3
hr
1
. If the concentration of the
reactant after 30 minutes is 0.05 mole dm
3
, then its initial concentration would be
(A)
3
0.01mole dm

(B)
3
0.15 mole dm

(C)
3
0.25 mole dm

(D)
3
4mole dm

62. For a first order reaction A Products, the rate of reaction, at [A] = 0.2 M is 1.010
-2
mol
lt
-1
. The half life period for the reaction is:
(A) 823 sec (B) 440 sec
(C) 416 sec (D) 14 sec

63. The rate of reaction A + B + C products is given by rate = | | | | | |
1/ 2 1/ 3
k A B C .
The order of reaction is
(A) 1 (B) 3
(C) 5/6 (D) 11/6

64. The rate of reaction 2X + Y products is given by
( )
| | | |
2
d Y
k X Y
dt
= , if X is present in large
excess, the order of the reaction is
(A) zero (B) two
(C) one (D) three

65. The rate of a reaction at different times
dx
dt
| |

|
\ .
is found as follows
Time (in minutes) Rate (in mole L
1
S
1
)
0
2
2.80 10

10
2
2.78 10

20
2
2.81 10

30
2
2.79 10

The order of reaction is
(A) zero (B) one
(C) two (D) three

66. In Arhenius equation, the fraction of effective collision is given by
(A)
a
E / RT
k Ae

= (B) A
(C)
a
E / RT
e

(D) none of these

67. The plot of log k versus 1/ T is linear with a slope of
(A) E
a
/R (B) E
a
/R
(C) E
a
/2.303R (D) E
a
/2.303R