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    Thermodynamics and Kinetics: Synthesis and Real Structure of Solids

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    Hafid Papeda Sagu
    This document provides instructions for 3 exercises on thermodynamics and kinetics concepts: 1) Express the Gibbs Duhem equation in terms of activity and mole fractions, integrate for the activity coefficient, and evaluate the integration graphically with respect to reference states, showing how to calculate the integral more accurately. 2) Derive the chemical potential and activity coefficient of ionic solutes/salts, calculating for monovalent ions and Fe(ClO4)3. 3) Derive the Debye-Hückel limiting law.

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    Thermodynamics and Kinetics: Synthesis and Real Structure of Solids

    Uploaded by

    Hafid Papeda Sagu
    44 views1 page
    This document provides instructions for 3 exercises on thermodynamics and kinetics concepts: 1) Express the Gibbs Duhem equation in terms of activity and mole fractions, integrate for the activity coefficient, and evaluate the integration graphically with respect to reference states, showing how to calculate the integral more accurately. 2) Derive the chemical potential and activity coefficient of ionic solutes/salts, calculating for monovalent ions and Fe(ClO4)3. 3) Derive the Debye-Hückel limiting law.

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    Exercise 12

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    This document provides instructions for 3 exercises on thermodynamics and kinetics concepts: 1) Express the Gibbs Duhem equation in terms of activity and mole fractions, integrate for the activity coefficient, and evaluate the integration graphically with respect to reference states, showing how to calculate the integral more accurately. 2) Derive the chemical potential and activity coefficient of ionic solutes/salts, calculating for monovalent ions and Fe(ClO4)3. 3) Derive the Debye-Hückel limiting law.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    Download as pdf or txt
    44 views1 page

    Thermodynamics and Kinetics: Synthesis and Real Structure of Solids

    Uploaded by

    Hafid Papeda Sagu
    This document provides instructions for 3 exercises on thermodynamics and kinetics concepts: 1) Express the Gibbs Duhem equation in terms of activity and mole fractions, integrate for the activity coefficient, and evaluate the integration graphically with respect to reference states, showing how to calculate the integral more accurately. 2) Derive the chemical potential and activity coefficient of ionic solutes/salts, calculating for monovalent ions and Fe(ClO4)3. 3) Derive the Debye-Hückel limiting law.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
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    of 1

    Prof. Dr.

    Lorenz Kienle Synthesis and Real Structure of Solids

    Thermodynamics and Kinetics


    1. Express the Gibbs Duhem equation in terms of activity and mole fractions. Perform the integration for the activity coefficient. Evaluate the graphical integration with respect to the Raoultian and Henry reference state. Show how the calculation of the integral can be performed more accurately.

    2.

    Derive the chemical potential and the activity coefficient of ionic solutessalts. Calculate the salt for monovalent ions and for Fe(ClO4)3

    3.

    Derive the Debye-Hckel limiting law (submission for exercise 14)

    Page | 1 Submission Date: 02/06/2013 10:00 a.m. in Office Box F130

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