S GD & T THANH HA

Trng THPT Hm Rng

THI CHN T HC SINH GII LP 12

Mn thi: Ho hc Thi gian lm bi: 150 pht Ngy thi: 14/9/2010

Cu 1: (4 im) Sc kh A vo dung dch cha cht B ta c cht rn C c mu vng v dung dch D. Kh X c mu vng lc, tc dng vi kh A to ra cht C v F. Nu X tc dng vi kh A trong nc th to ra cht Y v F. Thm tip dung dch BaCl2 vo th c kt ta trng xut hin. A tc dng vi dung dch cht G l mui nitrat kim loi to ra kt ta H mu en. t chy H bi oxi th thu c cht lng I mu trng bc. Xc nh A, B, C, F, G, H, I, X, Y v vit phng trnh ha hc ca cc phn ng. Cu 2: (4 im) Cho m gam hn hp X gm hai ancol no, n chc bc 1, k tip nhau trong dy ng ng tc dng vi CuO d, nung nng th thu c hn hp rn Z v hn hp hi Y (c t khi hi so vi H2 l 13,75). Cho ton b Y phn ng vi lng d AgNO3/NH3 un nng, sinh ra 64,8 gam Ag. Xc nh cng thc ca ancol v gi tr ca m. Cu 3: (4 im) - Cho a gam bt Al tc dng va vi dung dch HNO3 long th thu c dung dch A v 0,1792 lt (ktc) hn hp kh NO v N2 c t khi so vi H2 l 14,25. Tnh a. - Cho 6,4 gam hn hp Ba, Na vo b gam nc th thu c 1,344 lt (ktc) H2 v dung dch B. Tm b sao cho khi phn ng xong th nng ca Ba(OH)2 trong dung dch B l 3,42%. Tnh nng % ca NaOH trong dung dch B. - Cho 1/2 dung dch B tc dng vi dung dch A th thu c bao nhiu gam kt ta? Cho tip 1/2 dung dch B cn li vo th thu c bao nhiu gam kt ta? Cu 4: (3,5 im) Cho bit trong cc s sau y c im no sai? Nu c sai, hy sa li v vit cc phng trnh ho hc. -iu ch axit p hidroxi Benzoic t toluen:
CH3

COOH

COOH

COONa

COOH

Cl

OH

OH
CH3

- iu ch 2-clo-4-nitrotoluen:
CH3 CH3 Cl Cl

NO2

Cu 5: (4,5 im) Cc cht DDT; 666 v 2,4-D l mt s nng dc trc y c s dng. - Vit cng thc cu to ca chng, trnh by ng dng cho mi cht v nu tc dng ph c hi ca cht trn khin vic s dng chng nh l nng dc b hn ch v ngn cm. - T nguyn liu ban u l CH4 v cc cht v c (iu kin c ), vit s iu ch 666 v DDT. Cho: H = 1; N = 14; O = 16; Na = 23; Al = 27; Ag = 108; Ba = 137 Ch : Cn b coi thi khng gii thch g thm