Indian Staadard

METHODOF CHEMCAT ANAIYSISOFTIYDRAT]LIC CEMENT

( First Revision )
F@nhRarrii SEPTETDEi r99z

ACwltE t ) 4 FS*AU Oi9 tnBlilt s?AtEi;E S

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^*w;1?'"9lff#J3l'**
( First Rerision)
Alil Condac s@tio!.I comircc' Raqa*

-";*t#;*-'t'i::L;;-*--d*-*-

-" aifir,.j'* '"1

tt'"t
Jor odd' I rindr )

"'F*iifl%.,-.rc-".:"'

"T#:.;i-"* TeBdiii *)
il

W,*,x#e1g#"rgi-tWg

3'"',#'*,"#*"**. ","*"

cdd

rur&s

Ris&i

h,iu!

{Gri),

srkrdr

Ei4&dl4

R4i&h

co,e

(ctrR),

( svD Dre!

) ( !rd,!)

lndian Standard
METHODOF CHEMICAL ANALYSIS OF HYDRAUIICCLMENT

( Fitsl Revision )
O .F O R E W O R D
0.r rhis I'dirn sraidiid (Fnn R.lnioi ) '! c.ftfl and contrd. sdiord Cdn d*i!t adnnds to rh. idopi.d by 'hc Indiir

.en.ir

rhi5 n

drdloKri

ndho

tiic rrcn lor Jdermird on ornftior orslrsn6 ltr rhi!E! ! or,,hs? (LDra) ndhods 'lsllop.d by Nd6rL , FqO ild A ,o" h oldDlrv&'d rov

rs:rr$0t
rRd-

rrrc ' d i r d o fs j 5 i 6 c
ird64ir dld

q s h il l b c r o u n d < i o I i ' ]a . n \ d . i a r , h

G @6rq

( ,!!,

).

1.1 rbjr sbndard sv4 lhc prcedurc for ib. chdjot !mly* of rbc dirdd! ryp6 of lydnulic &@i r.2 ln rdditio! b rL. rd! ror d@jsl rqnirdob Fddib.d i! difiaer /d.f 'tsrtud'oD, thi : pu oldiciry t.* ror Ponlud p@ .ior ol Ii* [tu jn Ponhnd edr, l.n'..dotandndnins16.lqu'oi'y6d!'

tl rn .drLr or rh. errt sh Is: r3rtre66' r'd r6c i.leanl skidard spsifcario' for tl| ryp.
!boEsh'||b.lbolfugn|ynikdefocsiDs'

3. RIPRODUCIBTIITY OF RISULTS 3.r Bh ddqdiBrtioi' siaU h. n fu6.j!tbc4D.i.3idlhc.r,fuio Il all q6 cb(L dddEiralioN sir pqdi ror sili.a,ndalmio.,3.d0.! prrccot for

Thl ditrdae t rq4n cn ct d4@iraliorr bv EDT Ddhod3hau @! dcd 0'2 pcn6r ror shim ond! ,od rasndir, 015 pqcdr Io. ,I, CHf,MICAL ANTLYSF CIMENTS OTggR IIIAN PORTL^ND SLAC CEMENTTND IORTI"IND POZZG

..hrtl b. mploy.d in tns, ,nd disiiba du ae ls I l0tH977l ) slnu b. c.d ttd. rh" sc ol -.E. gaEsdilid6n.d. of an ylidl H&d FdB 3r? iquirrd (#e Is:226r-le?91 3!d
rd,r@ tspdiddd drFndd w(M tu Fd hM-tq !4 ( rdl,tu d bd;&r ldldotu L&n ,xr6)-

).

l
IS:a032-t935 4.r.r.r Iltito.hbn eid- spEt t-t6 t c@fohtrg b Is : 261r976i)LLr.t Nihi. o.id-sp st r'42l@\tomiq 6 Is : 25+1976t). 4,r.8 &n hrt ada-'p er 13. lcorfornj.lioIs :?66-197t). a,r'ra Ptuqttt tid -tp v r.7. 4Lr.5 Et*rllutic s.td, 40rtt6r 4tr.6 ,{M@tudE dtund. - sps.cgo, .,Lrt ar.tk dd- gariar. a,|'|.3D|.'hJhd|._Eid' a,r.t.9 Stnlninqn o.td-sotid. a.r.r,tr Ptutua wdodat sotid. 4.rx, Diu, sotabnt aJR..t ,r - F.Fr rhl roilom* d'rrk $ba.r'i"z Niit cit -t | 1, | | t1lbt tufitu} .-\:r,t rtudnla hfln'td. -rtt 'd l:6(br, rcr@). {rr.. sltlroi crd- I : I ( bJ volue ) 412.. Pha$hdt ea,t : t tb.! \.\Nr). -. N ( rpFolb'ktl ). lr,oln soa,w ntuioa 4,r.tc bdto'u. i0ror,odi!{ brdaidc,nr00.orlord*ic [$red 4 raup 'o rh. ..rr,7 dterol- r r I (by rcrum). l:l(brv.lutu). r0 Fffi erlrd. .:.

wlid

50 s of

1,1,t Stafroa Chht;d. totlt6-Di$orr \0 ! dr *rroB.blor:d. (sicl) ii r00 d or rrdrorbbn. kid and dlrGo dd i!c. x*p ! . \ i <dbbd rirh rh. &hno!,
isFii&!6d6dldl!&). $F*-i-G'd!!'d(d'..).

a.t.t M.'tu i. chta'\1. sptql;on- PnFc or ndtunc cnbrde (Hscr,) i

1'|'1'o4o'4.''phlrsaluaor

! $turnc'r $ru'ioi I 5 6 c

r 7) lnd 6J ml or srlphui. ac'd {sp sr I 11). pertuigtdc ( KMnor) in on.lit of rv.rr

(NHiNor) i! r00mt orrat6. 4.r tt /'rrll 0'r F!*rsolurion.

o:rlsk t( NH!), c,o,.H'o I ii o Rtdtuse Phovtak satrti4 ( BiCr,.2H,O)i^ oor ritc or v*{. r < H . o l i 0 0 , db " ' { . ^ o , l r a o i ' . . i, .d sru-frd' u..4'l 3bo' .0 70 g or :lmoiun 1.r.r! hiti satdbn- tE 1o- Dir5orv. ii 570hl orannoird hYdroxide( .iloride

00lNl'DiJotkr:[d.Iygtigh.d xid(r.rJ Mar.!phLh.

rha,oru(: r r
60.c. ndd 50 liB cric.hroceBra

rillrhc.olour.h.nes tm 'nr Ed to cl.n blu! carcuhr rh.fo EDTA6.d ( /) Moh"' of EDra = 'ri-:

Nokrhc

volucof

Adju{ rhc ror&ily F 0.0r M, jf!4un.d.

Lr,19 Thr\o! Phthat rc,. hltbda1 0 l p.!dr solution in dhvl llcohol ( t///). ob.

a.\.rn drtnot Bb.

.ii.arbk(seo'..r.trr,rbL rJ d:;,oloo'11

Pddtlosotr

isinio! - tos ii P.jsit x r00

r, .;.0ol.i onp{.td ,t;,ili'_ o. r' io drYeson r sdn.br'h :tl''blbj0dlo

L"

w Dilut 'ht slttid ;r LoiDkE idolnii{.t nhd ttuou8hmardl*sfrr'rFpq

( wbiEa!No,l0orjt

?qdvslmt), ahl *rh

iltr *ruiiled sili.r ( sioj)

trD,.ushl) lirf

rr'

I11ndr rh. ;.dlcq.,h 0 0I' wd fo' ;tr ntu j.0rbrlo. 'd of hvdrehrolic rcid r r : t ) rnd hlar rhc $lution on wder balh or ho!ebr;. Dil[. tt. loln on $n aad *sh rh. smsn ,mond of silio it @obins .i atulbtr rilrd Dr@r or llnbind ilF lor ibc ddmiiiLior R.gv. ihc fltaie lnd hsiiics

rubl.'DDdd'Fk.(ppcc I I00 'o | ,00'c urilrlrc leiahLr.mJinscornrni. a1,l Trat rba iFit d rcsidr thu onbiied, {hich 'ill I d.n|.'{r coad.h! id4 d " doF o. *rprr{.td d@.s. Fdlly na' '}c q'0 'r,d t'o:@laidwach' rh. amub ot sili6: ol jsnir.d $nplc cpresc Si[ca p.rn! - ?00 ( ,/t - t1) % . *.gh .I i:[r - ( ir,olubL 'Epu'rr!

conhh sixu r "rl/ ro

rrdc

r,

rI-v.jgh'ofinpEnies

r6D rhe Gidu dedrd fron rbe onbin.d DrcciDitrt6 of !luri!! ard Gil ic oxid. is irdiBted Bd* 1.3.5. 1,r.3 Add 0 r sof.odiJd or tsrj:h F * phik b 'be fl r.bb rd biduofinpJi':Fid'ol'eJnL\! L'r rccd m*s in \:E! dd add i. ro rir frltdc rnd @h cooL dlslE mrbbE i6ned f6 !h. dd.m;inion ofrho conbin.n snhixa and nidc

4a,r T. rh. 6ltBr r*{!ed in a.3,2 vbich rhdl nav. a volm. ot 4@nr xnd har b b,iiriis 200 d! add a Gw drops or 1be robyl Ed ;disbr, z r.v drcF ol btr@i! @ iddq eroi'olfotd-odjdno'fho hydiojde ( r : I ) dbp br droe udl rh. oloE df r!. der *i1! aiiuiu

picciDilr. 10 senre( whicrrshotrldrrdr dc iorc ih$ t ninur.s t flbr \o {lor F ( w\'.i

i$q'db.Lo'J!LLrc'j@b.'

chrdli. r.id ( r: r). dirub rresorurio! 'd abour r00br 'nd E o(. oidc 'h. hldrord( . s NoE ). lh Dnr,c elu,ion conbinc dc

ghd pldjih .dn.m.. -d r-*h

duciuc, ner :loqly Lb.!.d ',a'

1.1.!r C.k4tdbt-ctt$ttt the pE!rla8. oi conbiled f.trk ondc rnd i dmnrbr nutdplyirs ihowcish.n,shqs orrh. ilsidue by ?00 ( 100divdcd ri $tisbr or s.Lmph Nd l: R.o|p.E.Dl.|Y,igjnor.tsidtrr'200

.*it\l

dro.olMtr'

abot5dlol q.iFn P'w'.

cs rb: e.J.''r'h"

odr rb.!"dok.:dd 0n d .dd nsor@:'y ,da rr E .d ddol

hLod) t !

. b ars od uiii

B 6. ' .vidm'

v*$l *id

wdrr, ahd idd l5 Elo

vnh raldard iolurio! of Fhs5ium L52 Mdhan 1 \ EDr,l M4rad) 4l.2l P!.pd.6hBb rs si!.r iD 4 4''2'2 Tst. ?J !.f aihdiun hydroxid. ( L 6) ti! rur a ni'imun amotrr ol dirutehydrocrbricacid ll,101!'d 3dludoDqlcful]Jtoa@ldglsso!p:ley.l]oalolutoD

ldd a fc{

r 'n oto 0l M EDTA=0'933 ns ofFcror

trd ono.{ r.r ch ) Fror 6 --t

/ : volMeotEDTA N.d in nl, xnd

J.sl''.Ib..':.J:JqlbL

loud uDi{ 4,a,3, 4,6.1Mdhod 2 IEDTA tI4ror)-',ftka daieDi\ orL:o AdI dd!s6dqc csned 2J nl or soluddn

rs: $'- l93s

p h f c r o d ( | I J e d d . d ' o p o f r n y m o l b l u i n ' ot h . t r t r & b n nrll chr F L.m AddBtud um r;bb hlDld 6v srinrs url th. coloL, ih aaLk m .,cr roobm:nrH aeN,;nd.ly 5 Hr rh. blurion b boilrr ro, on. n iruk md 'i.q @1. ^dd l0 ilg ot Ftd al4ol odr& iidsror rnd bndb 'iE. iol ujor dovly 'iln siditrg trD rh6 6lou or lbc orLLior cb! F io b y.Uosror..d.Addz b r ol orbsnu.6 niuat,hdon t ac+. T:rRE virh 0 0r M EDra slul6 i. . d 4p y.rlov6d r.iDr rcdcohu. 4,5a1 c.tohnbn- ciltular. rhr pade3. of,al Or G b.lor: y'_ (t1t E) !-u1 / = Joll$ of PDT fo! alumin in nL 4 - robr wruo. orEDra qd i. rh. riu'uon r mr. v!- volM.of EDIA u.dlb.n@ Ga4,5:2)hml, %- Toral hluc or bisurh nihrc sdlurid B.d n rb. lihtion in d. ud r'- rquiEl4e of l d.f badlib !ir.h olaioD {g. Nd! t row). l nl ofo{l M EDTA = 0 509r ng orAL o, Armiuiu qjd. ( Al| o! ) e.@' i! s, - :=:-

|/ - Wcisht or rhc spL

4,1.L M.tttod t lct Etutt t{4had)-acidifr rn @bin.d flriB K de o.dE .M,l rri h,do.llorc orrbou mnL ^ddao dorsrrdrd brolretuhb r!. bd elo@ hrdroJd. Ellrho soluio! n tn:t dly dd jturdilr.ry {dd rmoniu

,r!ali!..

Eo rb. sdruridn lor r ninutu d norc. mLirp c{bh lhaihi 1' e. Arroq,hrF.iipi'k' ..'ej

did ( rJr ) .h'r hs be' prBiocry

5moiiuD o*Lcr $ldo!. lmornnhJd'orid.

r. i.d '1Jnrd. . d 30nl of wJn

r *ilho(d'oirl rtr, couiz rh. dr,rr0 s huPli6r.d n -o'!h Nh.', r rh 6 F, No .7 o:4Litird, s, rsid. ri.6lrnr.and esbinB ro! sriDrjns EjFdh.

6 posibre, and tu?lry her vi'h rh. m.Lb,. id{y in aD defE sdcd 0I t 100 ro I ?00rc cel dsrhr. ii a ddr6,.(,o sL d13 o,id..) nd w.is\ _\ i4rc'd o!l

d-" (c o) b' :00 tr00d.vd-d or .n. pfl3bror srbpr. &d ( 0r s ) I clo FkDl ' '.igbr ot rsidu.x 200 412 rrthoA t tEDTl eiad)- Tard l0 n1 of eruriotr r$ .d
udd 45.:.t i! r llcr otr(h. iaL Add I bl or i r.!Got$ii e q.u b !djr,, pH b hsr v .t..{il.

car.ru oiid. (crol FBir =

/ - volb.ofEDr usd in !r, fd n - wlish! ot rhaFbplc io s.

4A1 Mth.d I ( e4vn

ni

n4h.d ) - Acidiaythe nhhrd *t sidc nud bdrcsfr PhaP! r \ r{ gir)

Addrihrnim

hydorid; rrci by droD,while$ni!8 conrdly, udl th. rr!r '1.,!lL'o oi \eil'io' ), 'Lmin1s.Sq'h.{ ' io1i d. ror

No.41 frk* oa@rq ns .quiv,'rdr vish ib? prsipirdc vnh iEno'im Dnftr vtrh sorudon ( r00srEidniuminue dlsolicdi! *i{. x)0 mr ot i morilm hrd ondc ;doed 'd d'u.d to ons Jr.). P' k 1 3
J?Lhcdp-U.uTnuc|o('.!q|J.n inrD'*r''k'l|'0n'dl&0.cloo$'14' v.ighhliicq'bbdoabinging p od!!r.r'he$.i$' oi riFRi.r v f r o o r , 0 r d 1 r , - l, [ & ' h ! L o s , s L 43,11 cald,c//o' - Crcuhi. th. p.

- ghns of 6ide byl00,

(M3&o'), ifd

ald (05 3j 31d mlr,p,.d

.82 vlhod , tEDrA r.,rod)-Tal. r0 ml or solDlionrc$rwd rrdq {.s.?.r. Add 5 ft ol1 :1 lidhaidrmhe rnh b'noi shikiD' ftdrE ir' ro mllfd il d wrk'

g'{'h..Jno''('nF''d d.id. k obkinid by $bnadirs 1!. rn( y{le ot Qldm o:idc rdn rh"

.'3.r,r Cd.lrox@r - Clhuhte

{'.

thlorool MEDT 0--F01017,?5,(y,_/)

v - volm

of IDTA uscd i! cao ddcmirarion in nl,

.d riprolly sddro or b/drc.ho'n n ind Find rhcnareridwnh trnd?d dd or Ngltus iod urll jr is .viddt lnd rh?dlMFsnio! of rhe eDn! o r 0 n l D d d ' * i r o ,i ) m r r ' 6 { i 'dpfl-,rcj6' b.lav boirng I ntr /nd qlh .bc re,dk roroqh.y r FF *nh $c Bi'rE Ditur rhc LoL b r : r c b t oi , r .( t 0 0s t ) o t , .' Fera'hrr o,.micr'. r h u e F.ierbr $.ord " wr 'b. . t!. 4) b.FEip'Lktbdolgn|JPl'.elh. holt irganiis rhmiFn. ai 300ro dsidr.. sd wdd rbc birih 3!rph4. .tuine4 rhc sulphuic alhydride 6tu'. of rb. nddi:t 6letr ror 4e cahuLG ,h' po.EhgJ or sq q fo[oys]

arc'r{.

sO.p.rc. = rx

34,

n/ - rcithl or rt.id& ( Brso, ) in r; ard J4r- nol*uhr F io or 30, .o &sq tfiOj,

EL|1pticd

o.hc ,!.oru,.o, r r 3 b , . d, j E r
cool in r d6ic6&r 3!d *.i*bond._Thiso.lLdd@tlb.

4'11.|ko'dkedMo|.li']' leiak 0r?i.qutdl ! l14a,rl12 )lball oluin not mortdio00zopdft'ltokls|kdks3tr|Dbilc' E drcchhti artdlHc\l <r! st 1te ) 6mdtr.d bytuclhin PctuiM choru. I K.t ) rodi@ c,vorr. ( Nacr ) 41L1.2 Prcpatatid ot ,ohnh r) cdhi6 chtdtd. sbtk sohtid of crrciuD erboD4c i. a r r00-nr bekcr. whiL nn*,s jo*t ,dd roJ d or byd.ochlfic !cid, cool rh. soturionri roo4 ro 61000ppo( 610 p*e!r )a c trmold.. tr) sodih chtond..Pabnin chto'id2 sto.k sotutiar - DB&t$ ( b o r h d ' r d . r 0 rr o I l 0 " r r o rf . . . ! r h o r ! i , : o . b , . s b r y l in mrr. Dirur to o!. lirrc iD a votum.'ir 8sk aid dix ( o r 0 pc@r ) 6.b or sodim oid c) edndatd\ahtb4 - ?rcarc thr , r.61. ( ?-\o.). M.r<u! rr. rqw.,l voui. o. roo{d c'ro ,oe .r cr btu, od ;iy M

h6irdicardvotuD. 'nd sn

FlycrbyLa!

irviir

a wlu lbickn$

'ah4'$d'Ib.n'd.oflhi!n.d{.'l} of ar l4r oDc lm.

y d rL. rtutrua4! e{{hdyd<rdbt

4r13a Frcinqaf

tE turb4t

{Ndro, .,d (.o{orerr N3s sudid s,op.

ulciorachalk'lidiidesba!!o.

amd(r$ ( '.. No,c )i

io4q i.,r

co. dii,btv!,b d,'I..',4_r.Ln.r

a(c.dxice,nh r

r-i. JlDJdd a.n*dly sb!!t rhe.rocedrc Pys b.6;: l.F o le.' iur.1 vi,h h-,. f-, L'a!. !.1 'dr (r nn,bif o lo m ,uF! 1rfl. r. Adja! | Fr! rd o{sn o r

(N,;or ror is-!i\

qrbs

orEilgd dv dh-

th.p,.vior y d4.m d 5djb'@m t. hd-n"r

d ro, 61o b{n.mdr, i!. Hri@stod!L ro' son ot rh. erJm-e4

*ld

the roF 6f4 fo. sod.'n did. iGnno '\.d"rdFriior or

soluion ( $lution No. 7 ) 'trd frovfg

ndidadwf|trslb(k"NoFjro of m' m@ krnsi5ion *Ehrsrh slldor i thr piDt Th. sdsirivit b dv- ibourerF Grt b.d6s
r okr4d d$e 4 6r Ddr@ de ( N.o

@!tdh

should

1yp. sioniz*

rirs

'irh

disrilLd

$ LLionNo | ( r00 ppo) . d ddjri d" ootos b pFqd. tull cL 'qdi'F FoF gM d $\ir'q1 Fcdt rrbrbitrft. r. { @.6 rdding or rco q 16'0 {} AEhk rro&d P!F). Pq itrr'lodB rbo .ouDyd wirh r krorJiNos ;; For d,,rud$Rion ''.'d-L.trR.F|'h! (r)nd,, m rLnr'd d.i'ni'v q uc 1.t&,iy no rd,amat tu@jtu ud un ( c ihe india&d niqilru ) {hd pi!3 rr arol :q ,udd!'d $ 'uoi No.2 ( 75 ptb I !r d rc'e 'h. rr! {DdiLd .oluuon niaaud ) 1trd r00

tor drr

tu'l b

_1c35 IS :'1031 soliionnYbetunri&rtd

prcEdtmdddbcd b G')od(rr u,d r.Lko rbihdftidhi

b'bc

lr) Duu@incxrd 5 0 , - , ! . 0 ! p ' j) Rep*r tl'c dthe pro.eduE dH oid.( (!o ) m*i!3 in (b) ro (l') ror pobsum

4.\r.1.1 Sddian of .q.^t -Ptr@ r 000+ 0 001g or rh. smlir

,00-dr vorh&d
l$lboiugl'W[hot{t{'

fl6(

wrh-s.*{

ed
NoE F-

irrhc soLu'ion rhoro!3hrr (!g aleau4a,k $,.

:djsi

4.r.4.2 P ta!. rrr H:Lffit

lq d".F tlqv ror de d.trm

r.di's I f"

No( r l uifg mli&dioi or$. aeEu's rr poi i5 rbr' rhe orti'ar c,Llbarion

q@-..;.*-r

' i o 't - - ! o r 0

i r

a.tt.a ! P x.dr.

otF \e at ph,Ln ovJ. h, d.r'^nu.h r-d F rei',1'nci.\Ib". i. J

lor pors'iumonde rnd sdiun dt

conr.i ol wr{'elublc

alhLi or rh

?r0 n dvdd

t r. Nrc )

hidndy'houghaBNh*.6t|

6r-..

bF

aJ

ts:4032.t93s Hcl -p F r'ro ). 8xsk. Dnr.io 500nI.

w.s!' d!5.L

_ 4,

n!pe.d!4Ni"ord!l!l!i@ddl

vtc a!r. add q0m. or rr. ;or. c cr .d"o' I b,m0pDr. ol . 0 0n . a : r , r d o , ,u . r L i r r , , " of cmh alkrti ii dc sdluiionin rbc | 00-Di ns!

Nrp, ro rbc i!r6r 00l r fouows:

^-Uar,

- !tlrg',e

orud-$tubtc

sodium oiid. ( N.,o )i

: Fns.Fr nlrion otNa,o in rhe r - F.d! or wif-$hbk pob$dn djd. ( r{to )j - Fls p.r duon or&o i! the r00-n ns*;

5.1 obid

rhr.

mdhods or icn ho? bqr d6d'6ed

ror dctrrung

5.''|.|Abfulut.'hand_^6s.||| 52.1.2 o!.cg"r - 6rr(d sbrll b

or{rq.

rlor.ri

slyeror srhlL b. r.e I'onrcid c ofrLd.hydicnrtr.

5.,'1'.PAao]Ph|h.!.hh|]i.k.

shourdbc srishry rlttine (se Norc 1)10$ejDdcro!.

lf,l'.sDlvln, is

v h ric *xxdlrd anDolih rcd're s.rurior ar- 5,t.1.5)l'd rbb 3dd n|'.|u|'P'',.o'odlo'odl'Ha' Lnd"o.n.-o.
nlri mltd ., o'a be'foLl. it. ot.1..IJrbqd.o.(fd i't,h4b.or.'igh'|J"'d'.'{d''oL-d -!d,.r n(..4, NoF 2) '+,Jii ir.ron ra. o 1d...a
P d d i d i l E r ' ; p s d i L o " ' r

,, \;..-,

a@hG {s' Ndc lii on. Jnrdor c

oJtlgi

rorririarn -0005 s.don Prarierhdsrulio' bydnsokjrs 16sol crJ5kriDe rnmoDun

whD,he (h;d cx!.lh oiid.

,r 900ro I00ec1o doosror *eisri,

r,.r aJ" 0rr, lhc flrk rke Nor r).

e]e[q''l'c{cl

cond.Nr{s.

Nor.2 ). @iun rdde blqjon. Rlpke r,:.

co.d.ns.rand 6oil th. soluiion i3 (r., Nok r ). shakerhe nrsk ft.q boilins l hc r txion is conDlde phd' m funhq

n,!k rnd proc.d n rhedxndir (ioi {ee5.!.r.5) the vh.r the conia! olle cdcildoiide n rhesnple do!5ioti4{ar
mln!h!! 00j Frcar dlringrh.l

bt

Thc'''|.!hi]]b.fuCho8lop'i''.onp|.}|l'bloLAhT!'''''''''

$au, clmn, 7s-fridoi ls snv6. cri!,r $e rsidui D x! rs4c ion{ i|is6'.doughtd

B!

smpLcn6n.soqhbp'$onpl hiiaor" si{ tor r!. d4dnira!o!. ; r ' . 1 b . d o r od . : " .n Jhi .F r d .,.r ,t

solmioD aaie .ach ol r[. sdy lihuois.

bsh]k.lhefl[kvjgdrcsl'alinla visorcsly ehih n isdkcoi..dcd tro '., 6.n- io io. *8r.,.'s o ro e

r d'opof6e phmlPhrbal.ii indiq hrr !:rxof50hnidD,diorhs *iy !o t.'A.o'lda'Ah'|'F4'|" ,il I,,ied:..,tr;i,.rrdmir.. 1.K wnb sidihr coDrtr$ in ;orher nsk ot amoriuD rera&. , ro d\cbr& lh; oinl obu! and

*hi.! eDiiils

an srcs

n&q add j6r @ough lqnoDium -cd'.

sppcr

rhe fask !i$ily.

-

whd ro.ri4
,h. F

rhc dcrcr

3.2.! .a/d/or'd

CJI! LLk

Fre ahiM

ond. ( cao ), p.l@r - rtl x 100 of rhd aoooiib

cao .quiEtnt

,Yif;"r""-t-

"*"".t'

5!3fi}uol.c|'!.dnrlidM.l[.d 5. r1e4a, - Tbctolo{i4 Esdr aE r.4uirtd. 33.r.r ph.rctphthohhkditut _rfteaF dc ildioro, as d*cjb.d 5'3.':zclyqol-.|hondlsdhd|_PEFElheso|vdtasdsrtib.d sdcr 5.2r.1. Ei!h* rnl,ydroB briur u.d ra r{cldar. rhaotutjoi of tre .rhiu onde. rmhydJ.b boriu 6 0 E jo r { r v - i b e f o rL h ! o ! 6 , i . , . u 1 - L 4 o ( . ? s N o k r . t . . o d , t r n r\. 0,,r'hn co Li"_ slEu d,d t G h / . p ' . p . r r da r r m o r i d e o . a d C -r . r ' h c " l n s d f r h . , r . m d -

( r@ D r*.c

) 4 &.i

&hlo:

id.

el,rd (0.2rt_Prcorf'nd aftlatc rs dddihed udd r2.r.5lciuqid.idinkdqPonhnd c@ni.sd.qib.dsdq516jng

.hro d.d rn "dr.r"or (."sr

by @r

or t* slcilm ord. doa,d o ft."* than 0.0r Fd.ar duing lbc lrn hou of boi14 (r?. No'? ), ot frE ahib ord. &

533 Ccr.,rcr,n - Gr.uhre ihl pq@bs.

rs: {032r$5
5J,a x's,r-Thjs thc idnod d*qib.d ndhod hsa tmddcy b EE bjgld i.slts hr ud{ sr.

5,,r &bn@qr.ot Mdr.d s,,rj lne dlyLncsqcol dhod n b 6. B.d o'ly ror *ii{riig line in lr6h clintd ard frahlt

fEc

5.{.2 n a!." - rhc rollowioer< 5,.,2,1 llhyLn. sly@l sneu ror donbn oore tnan d. pendr ol Td.J0n|of{lbl.D.3ljo lsoauislrandshal.dinldYals watfr and th. rurc A sEnnh'blle @lou indi6tB l}e DBdr.f only rabt sa,, n indicr6 Irrt.olouft !h' rh. srd .olrdi it b.low qe p b.lowon.Fc.d,ii6Dbercmo\tdb,dlpdlionb'haling'h" slyol b l]fc for I .o 2 hou6. yen 113.t Rntuttal in 3od sltrdon. in aquous $luri

5.4.23 stvn'll

t.nos hrdtochtoti a.id -o r N-

s-aj.r 1!}. on. san or cedcrr r0odr 6D,ciry ad add i0 dl ofcr[rLei! dyor. cb{ 6. n.6k qi(h ii srk drainn o:id. i o sorutio! shak. rnc n4L vi 6d ro 70'C "d 'Fttrthon rorong tr riuv %.6 drd .horc.cbl d ed rs ' lJsl ! 't !s ' b iaft' n. (ndi lrcdblrB e8r.dl n 'ur r pu. Moro*. 'h. eddHh'o Nddtn rc8u 6nd.8do! a mtr bsth* 60 to 70'c. Ir ,ht.vdr ot pu'Bt *,krft@ Edh.nol to th..rbyL'.3tr6r dom by adding ( {t

t 5 c orfom* b r0 e of lafa ) ebd oD boilirs L. o.]bdr rd o!! tou! udd rcdq d? solniionis Eadr ro. ritrrid. 5{c B&nnq l@n.l so filtr PiPdr cld g.nhichdsid scbullNo. r97 's.r ln! .ohiio, I'dm 't.3 r^ qncrb u Itd. waih lnc crai o! rlrr P'F rh. r 'rh a lu d Fn o' orrDcol rIq filrd,ior !sa60 | N hjooJlonc .cid Lrs J dro6 of I pc!6r bromq..l sRn io lbsorrbdohor * iidkro'(x. Nq.).

5..r,33 CoDdd rhlmk deiqni'arior sirh rlom qudnies of ldM oiid6 by dLolving b slrcdl rd dtriins isrjDn 0 r N lydroch]o'.eid4b..ole s,4,1 C4rnrrcrbn c:b'nac {1. D.

sldr

L bvol@.

,4d

d'R

bh-d1gof!\Dol of

6. CHEIIIICAI ANILYSTS OF PORTI,IND ST"{C CEME|irI se{ii sordioN_ rr.

( by y.ighr ). dt \ b' *ighl ), Ph$ph.n.tE t :l (byvot|s). 6.r-1,3 6.t,t.a a\rc4t@ rtnax t dh. ot4 n:m hrdtud. b'id dDdaiLs 6r-1.r ,sdrb ,i'n

- nE Fed

.o

094 sorFh$iun

Frma,Bmi,. t I(Mno.);n oi! Inrc otRtr

Allov

6'1''sldduasodiunThb'llphd.sohlia,. thc 5^ oi 74 s
6.1.1 Sta4datdP.tann lodak sot'd,, - 0'0r N, PEprE a solddon .f lin s.'d1dir

. i ' n i o dd . r k l ) F

of vftr and r0 nl dfiydrcchloricicid in i J00.nlnsk. ldd rbor 25 nl nde srdioi ( 00r N ) svnr lhe

litllio'

uni| lh; Llidi (001N) P"p4 D'iL rhc bluc corotr.

jL ' 'Lr""

iunjod]csoluljongl',

phne solulbn Equn.d slndardk{ioi or rr'. pod,iun iodic$14ior

or orc r ot solubLihrcn in 9 ml ol oforc i or sodih hr&oiid. in l0 frl ot waid, rb.n 3 s of p.rasim 6.1.6 Ahno"ta.ol zhc snlthat. solda, - D&solE 503 o f iic sutphat ( znsorTlrro ) in Filrd rh. $lurio! lnd allowins n ro nDd for d les 14 hou! 5.rJ )rmnt'c'lco.Lhi@ chltiie r,/,ri,, - Dksolv. 15s drddun .Lo"G (cdcr,?lH,o, r rlo ml or %tsr.ld r50 nlot nDonin
hyd'oij.l.'F'|'fr

6br,rc ( N !co,, ioi00nloI{rd,

4!d rhc" 0c0 s or sent

nior'dc (a,q) lsk lnd dilut il '.

aooLit b rom hsa1urc, $8fd to i rct@t:c ro onc rirs, shndadiz? ihc solutio .sq Fmdssrlb

( Krtrtro! ) i,

1)"1d 0nl F n m m i r ' 3 r , 1 . a d d 6 0 T ro f r h . d l . r . n ' r r & r d { | of3:odiun nitit solulio!( 5 F@1) ro rhd [ek. Eoil th.sluddi roduD bi$ur\rkitrd I rtr br riu de.oied @o-a dto

6,ri.2 cdcnr& the Mlgalic ond. .q nld1 ottnc 'bndard sodiun .l 0.03x 0236 r 30 "-----=-'--c - @,canic o;& cquirlor dr rh.

o = voh'n. in nl of Fil$iu rs tdby0'0rgor$diudqJldc'sd ite solurion n{uncd }Y r0 6 2 Los or tsdri0n Ld$ cn ieiiior shrll $ ddrnined i! leordrtre

6.r sftr

- Th. ndhod 'br de@D

abih dnde srrill bc the sam.rs d6di6cd h !.ar ..1| MlLod r( tDta M.,\aa q,mJ..orn01on.rd d v d , 4 r . : . r { i @ , . cr r r i.pald , aL. l irs!.ta

o id .ik. K-P o rr'

\- fl. + oid "hyr,m ^ddto"tori\., .I

: ' s. drm5n

olfiBtionnElchedwhendn.tolwod.op]ofEDTAehdnajh3lp

6.3.r tdhon r I c,crhen.

.ttdr,d ) - rh. mdhodtor dacmjiri!

6.3.2 u4ttoJ 2 \1Dt A q4hadt ,llld ' r 'r n. olllo" o, d iro, Drre ' d rdd drop by drop l: I rndoliM hydrc:id. wnh @B!nr sh;rins lill a srbidny apFs Add 2 d n, c{6s. Filb rhc rolutio! rhronsh pdpcr wnb hol wi.r !tdenqi@i!,J'&,'| 6.0 l60r!tl. Rsid& rs dso 6.d m 4.r0. 2 !o l iimd,

rg 75 d

or dilukd iitric !.id ( I :4) Add t0 nl sodiun nnric sotmim ( 5 p.rcor ) Lro! 'o b ot' .d r r.\ i, t ,,

v. i\ot I ). e.sr {d pI i , d . r _ . f l t q or o

'r0 nt rt.nn.ft n4 ^ i,' 4_,, uq Thc soluiion sho,nd rave I vorum. ot 100 ro I]5
t@d o.:dhrd rqr!

Fd+,64ds

c. :d( .r., rhch nricl.jd(r:'r. yvnh lh. naidxrd$diu 4r,ii.

b ddsf;0aroi or 'n'ain.s,

rhe h!{

sbrr b. cri';;r.d rruD .!c

!'balronbyrhene rodliid dom 'n ir,7.r.

b , b . r r m . r . b , i J r( 0 r a r j o r ' . i o n . a d rtit,.F i q- rroc d dpretdlbly oydf, i3l'r. Filrerthep*!jpihr Birsryh!6rn No,42f h( Prp* or ns .quivrlcri
plaiiiblolpot.b;nouibl.,Rn

',l:ycighj'go.blih$'lp|nt'bd

( o 1 4 3x r 0 0 ) 6,\t.r e$ ccntdas ftotk

. r n on

.q blr, oi r...i d .

,1ir

r or | . .{ f;q

'i. .

6,rt 2 Prcrt&f, - fl.ce r s nl or !h I Jg. Naic I ) rd 235! or sdd i 'o lh. fid,r $d:[-k rh. tu r 8dr/ d rh'Iollor nsoDC wcrJ'd o'l;cM rh- .!mm' omrlehrt r'i. tp !|.N'.lb.Pfo'm.d'P:d|Jrcrv rh. fl!* rh. funn;r ;d bilrb. "nh rh. rdrd .nd sh solution ibroulh chloric acid( a,I)rhrouch dc rmid dshakerh.38k. Dui!3 rh6. shrkincs, kep rhe amler clo*d an 3n, oF thc rumel srrt a slo* nr c o u r x h . b o ' L Ts 1 ' t r o or rh. hdi. aDJ otrntuL nc o-n*or..i6' r o' r E ' ' ' - D on.6.h.&rnd\ uR-0d k.r;h mihe dr rc,n Le . ",,'rn c@r r b . 5 . r ! . o o ? 0 . o1 0 . ca r e N o r d 4 0 E l o r h l d o . 1 0 r d c i da l {.rdrdDoi.i;EDd.F ouonu

td-*

'' d;rBd"r-- 'd{"

- i.rt

6,rzi ctt.utation - calrtArc $c pc(ds$

or s'lphlr a rollo*:

20 = I00 dividedby lhc veidr or snple BEd ( 5 3 ).

IS:r0rz-!e8i 7. iEEMrca! aN^r.YsIsor Po

1.tr M.thadr I ctodEki r1dh,l) 1r ni.rrni dr rloruus dssrbedjn.i,r.iccpr r 3iy iu 7,z,r.lb 7.2,r.3. -.','|rw"islo' wcirLnoriFtud 0 5(rm00 p.Fen!s
.^b&_n.l'hkd&n4jJ'!hd.16

orii'iu

{rpporiLn.rlly I roLr"c).,)d qui6e i ( ab{r 15,ri )

ovdrrr,rd{!id

'o{lJ'.''t'\'''L.i|r' lolidi.y rs x tr'ii nrerlor rhc iftrid. scr th. *u. bLrrd Rins otrrh. ousidc of dE (udbrc I or.ft rr

1.2.t v.th"tt1|ED

lktra.!)-

ddj uD \o.,r. of:50bln " 6l rr"c

t .r.

Ddnn!.

r s 8,.. hydrid.

,.3 srllLq;c adydride -T he n rhod ror dermining srlDhuric .1.Il b oI Por'r,rd @ol" d ffi.{ dur r\. -mpk Kd )hJLl b. nd',Lk 1e .i rcidr 7,,t ldehbl. R.id@-IDslubL sh:l b? dddnincd s sp.cifid i! 4.r0' 3, }OZZOLANICTTI 3r Plrts* TFITTOR PO 16r fo' cn<kin8 pozol or Ponl,nd pdzolatu

(M!

- thc pozoh'icily

ic tufr

orsiddirior, owils td ds {oilibr Ine dd rhd rlkiljs prsdt ir the liquid pha& in o

xd *irl! rh. prns

rdiviy 3' lddier. - ?doloic d.edb,th.hydntionorrbc.cf. hydnb wholc rr4ab Lrcsrs Lqciy i! 'cr{d b lhpa,rg $i" ' cJ(oH)!rprb.o',ir,.s pe2ol,r h G ro., 'h. c, t ori 3.at Elrlm6

ddpdds !p.r rh. frxdion ofcr ( oH )i, vn \- q,r "y I c. ( oH /! nrc.d 'D I lydr , d -n, n. $rh | . qu fir oI ', F r0d nlotyab

$ov rLn by 6iig:0 sof ffi6!

orc. ( oHl n! !odq lCo diuiquial.'$ of $rcne bis ( oH I Fr litrc.

h.ormdvb'cbbdioF''dG'u) onpl.klyrt@dktbcliq!orh'drcl}si'rlomlh.bindd.

3.3.2Sd otd E dn$htic A.ill - 0a N. &33 ,{,,o,i:,tol,rb, -05 N, 3,3.4,,rot ' oralar. - in s rd.n sdluiion. 8.3.6Potuitn P{nnctu Sohnian, O0t N. pr66n 337 Abo$ 20 s wax( in .4e r slds 6mk n sd I &4,r cui..] Fksk ar 300nl i! ilkRl' r.skdnA sLss o. pl.crably in Phdis nl!*b! Nnh ! nopp{ of r - vnh vidc a&nr. t,{.r Frkl - r sinrnd slr$. 3,4.4 C,r,cal r/o* - or2J0 m1{ith grotr .e1s5soppo. 3.4.s 'klri - of 250nt. 3!d6 ?-.ii,, ?rdr. - ol r0 rnd 100nl. 3.42 r/d 3.41 fh{noit.th spft. ar4i + 2'c.

3.s,rni d+a @niol shs flBk is used, od ih. iosidcofth. tas! 'nb rbour20gorr.!!d pr'si rix. Fhnlyarrdwrh.sqlusro$lidiry 3.5,2Wiih a pipdq inrodlcr 100!n ofdisrirr?dwierin ih. drst xid iito r rhcnoii '1 40.c hpqd're ir Eicbed ( abourr hourI. &fi rhm p.nr inro rhc onior fm l0 0o + o.0r g of!n. eodi i. bi r 1 2 0 . i n d \ b o r d e 'o F s c , t I h . ro.tu,do.Fn.rr tmns ir{)"c,qqrln-Lino J.

6hlro1coo|L|'"nq.|.Eoed.

4!'C qu(r'J 6kl ' c lioud

3,5'5 Pipdk oui 50 nl.f del.riin.lh. bhl.lrifiiny (oH)F rue \oq

rh? frrni. rglinn nandrd hydr..hbnc Gid{0I N), r o . Lr p r a ! h . e u x o n . i q i , h . . - k Tnnt1h.olciumon|nle

3.6 R6rlh - E4rcs rh. iohl .lxxhny 'nli'oll'Fl', ,L_qo i Fe'6dros 'hc

od rie otdm

oxidc 6d.ir

lc''Aolinsitlidb.lowll'dsotuhilityircthfim' 'oq br

Ju.'q foutud dr! 16lp.zolanjcacliril,lh.l6tbc@

ln rh.i ( .r

9. STINTNC TIST FOR MISONRI CEME|II ( DM'RMINATION O[ WATIR'SOT,UILI 1IIAI-I ) 9-r.1 To 150 3 of snpL dt rilotrry e.dr in . !mo-'l bek{. add ?50 n'r ot disriUed*xrd. Firk. 'h oLgh' Bshrfl ru n.t trJ1lrd rh.
'n$ebLLlbbe.igil ,h@'srly,;' tud i drifrclh.i'so|obleftn.islir r0 Dn i rooT FfF;,' q r,d . u rei' F rr

wah rhe ru.el rnh r00 dl or dtri0.d {a&r inb rhe bRk r 6.eiiim .heiEolrblc nds. sft rhqo4hly, rer ndd30 niidrcom&nF Firr! * ibvc. Acidifv rlr fih4tc {irb I El ot o(ol. Ed lvdrochroft idd( H. a00 n. c@l o rcon trh\ D ' Ldpd'u ( drd T i l G f t 'q*di i o . q . t 4 D r o I r h i r c l q r c nr o , , o . @ "!,3.n " rb.Frahl-v d!r@ (es.rr!!$

E Er

rP Dr*bu.
e,r.?Dd.hinc $diud oxid. aid t y . 1 , f l , r , 2 0 ) I i P b r b rr 0 0 . n

S n . @ u nd c ( o n ,

^ m,

un .iide orbnr of rbi solurili .o rlkdi ri

edih

tur.slubh oxide( N"o) b ib. ie'idr o 0r a: lollows: ,-Blt500 c-D1t500 ToEl *6iorubL rltdi:,{+,

, -,cr6bs. ol ftla-slubt sdiur oridc ( Na:o ), i - partt pd & ion of Noro iu rtu $lurim i! the l00-bl lct ('a 9.1.1), c = Frd&cc or mtd-solunh Do63i@ oiid. ( Kro ), , - N E oilrionot (,o - i! d. $ruiotr in rh. i0dDl (Ee.r.r i. hd dL&!L , -pddbgcof Nqo.quiv .i o dr(:o.

c.mst sub.onnnie,BDC?: I

ciryreiu,(Rsh?q). R-4M3 oEu { cddn

rrklbi

D+'m{,,

c@.hh4'

{ MbLrry dhtuq

), N.wDdtri

11

s,, q B,.rroh,1.

(rrhi.) !nn,{Ei:id

i:R-o\r

6ir,..

\rd,'

Ad rloc Ptrn.l tor co$idsinl EDTA v6hod ot Ararysk ud coloindrh AnlyJr !l ccn

h i 'iil,,i'-,

dld,N

o'. s

375! 4e w

lcmDn b d otun Id9b

lkbn]b*,s'E9eNldeou4hffiEa5rybfulEe[e@6

PGIFk'NuNbdsMbkq'ss

6d*d6r9k'56Fcd'gebefu fudsrBu6s'dfoAuEdlFod'colMaArchE&l@

$s'LNaupbfuqNl@lysb|q Mrs. oscbm6 TATFUF E*. ciuola om1 l'4131'savd4aN@'uNPuFa&c

h*bro

d Ei!ri46 ( @ ) &rdie

s4

stroa!N4

PUNE.flos

'sdB otu

t4scwhd'*&po* bBclJ Bd. uiiv Bu6ru.N{6hh{!!a sqs..

l*!oeEdblyci ted 6e u df

T10 o!' | l9at MFI|OD OECqEMICALANALYSTS lS ,1032 IIYDRAULIC CDMENI .

( nta fJvt:toat (?.s.4.r,6.r):h.nu.rolto*iryr!Nob ulJ:

NO. 1 MAY I99E AMENDMENT

'|t6-^!!rLd\tnd!cDdDrtb ux nr eo@@ rb'do! 'rdqr.b4h ldu ( E E tru.Net) rrrr, ' r@!d(GR re ' ltilorcbddhorF(s6 tu h*dcird!di4ed!.tdd te.0..)r'q'dL[Lddr{ dq{.dr.d.lE!sdd

(Pq. a,rdd)

- IFln ronodn8 s ro.lmb

d rlt.nd:

1L'wa.;lu*tya"ur*"r'drhftqpro r Mdonq'r!drr,ndkG"x
.Mt@&.dhdE*ldltdl'JElh9@d'

Fdqeb@hi

&|@P|'UdL16,N4Btr|6