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  • Hess's Law Lab Calculator

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    This document summarizes three calorimetry experiments: 1) It determines the specific heat capacity of the calorimeter to be 56 J/°C. 2) It measures the heat of reaction for two reactions, calculating ΔH = -58.9 kJ for HCl + NaOH and ΔH = -5.6 kJ for NH4Cl + NaOH. 3) It verifies Hess's law by experimentally measuring ΔH = -47.2 kJ for NH3 + HCl and calculating ΔH = -53.3 kJ, with a 11.42% difference.

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    This document summarizes three calorimetry experiments: 1) It determines the specific heat capacity of the calorimeter to be 56 J/°C. 2) It measures the heat of reaction for two reactions, calculating ΔH = -58.9 kJ for HCl + NaOH and ΔH = -5.6 kJ for NH4Cl + NaOH. 3) It verifies Hess's law by experimentally measuring ΔH = -47.2 kJ for NH3 + HCl and calculating ΔH = -53.3 kJ, with a 11.42% difference.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as XLS, PDF, TXT or read online from Scribd
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    Download as xls, pdf, or txt
    6K views1 page

    Hess's Law Lab Calculator

    Uploaded by

    tyrantking8
    This document summarizes three calorimetry experiments: 1) It determines the specific heat capacity of the calorimeter to be 56 J/°C. 2) It measures the heat of reaction for two reactions, calculating ΔH = -58.9 kJ for HCl + NaOH and ΔH = -5.6 kJ for NH4Cl + NaOH. 3) It verifies Hess's law by experimentally measuring ΔH = -47.2 kJ for NH3 + HCl and calculating ΔH = -53.3 kJ, with a 11.42% difference.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as XLS, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    Download as xls, pdf, or txt
    of 1

    Part 1: Find specific heat capacity of the Calorimeter

    Ti (cold) = 22.5
    Ti (hot) = 76.5
    Tave = 49.5
    Tmix = 46.3
    (read from graph)
    C(calorimeter) [J/oC] = 56
    Part 2: Calculate DH for Each Reaction
    Reaction 1: HCl + NaOH

    Reaction 2: NH4Cl + NaOH

    Ti (NaOH) = 22.5
    Ti (HCl) = 22.7

    Ti (NaOH) = 22.5
    Ti (NH4Cl) = 22.2
    Ti (soln) = 22.6
    Tmix = 23.5
    (read from graph)

    q(rxn) [kJ] = -5.89


    DH(rxn) [kJ]= -58.9

    q(rxn) [kJ] = -0.560


    DH(rxn) [kJ] = -5.6

    DH(rxn 3) (Hess) =
    DH(rxn 3) (experimental) =
    % Diff =

    -53.3 kJ
    -47.2 kJ
    -11.42%

    Ti (NH3) = 22
    Ti (HCl) = 22
    Ti(soln) = 22.4

    Tmix = 34.7
    (read from graph)

    Verify Hess's Law

    Reaction 3: NH3 + HCl

    Ti(soln) = 22
    Tmix = 31.7
    (read from graph)
    q(rxn) [kJ]= -4.72
    DH(rxn) [kJ] = -47.2

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