Electrical Conductance and Insulation

OVERVIEW:

Every thing in the world is differentiable on the basis of its electrical conductance. Some things are called insulators and these substances never conduct electricity. they include things such as cold air,wood and plastic. Then there are things that conduct electricity and current flows through them, they are called conductors. examples of conductors are most metals like copper and steel. Other materials that are sometimes used as conductors are silver, gold, and aluminum. Copper is still the most popular material used for wires because it is a very good conductor of electrical current and it is fairly inexpensive when compared to gold and silver. Aluminum and most other metals do not conduct electricity quite as good as copper.
The electrons of different types of atoms have different degrees of freedom to move around. With some types of materials, such as metals, the outermost electrons in the atoms are so loosely bound that they chaotically move in the space between the atoms of that material by nothing more than the influence of room-temperature heat energy. Because these virtually unbound electrons are free to leave their respective atoms and float around in the space between adjacent atoms, they are often called free electrons. Also, this relative mobility of electrons within a material is known as electric conductivity. Conductivity is determined by the types of atoms in a material (the number of protons in each atom's nucleus, determining its chemical identity) and how the atoms are linked together with one another. Materials with high electron mobility (many free electrons) are called conductors, while materials with low electron mobility (few or no free electrons) are called insulators.

Some substances that conduct at high temperatures are called semi conductors. they do not conduct as good as conductors but have various uses that make them more versatile than conductors themselves. Lastly, are materials of recent times, called superconductors, that at very low temperatures, such as 230 Kelvin, can conduct freely without any resistance whatsoever. The difference comes down to nothing more than how the electrons are arranged around the nucleus. The laws of quantum physics say that there are only specific bands (or tracks) in which any electron can travel. There are some interesting facts about these bands. First of all, only a very specific number of electrons can travel in each one; once it's full, it's full. Second, which track an electron is in corresponds to how much energy that electron has. And third, some of the bands are closer to each other than others. Different atoms have different numbers of electrons, and how those electrons are arranged in the bands defines whether a material made of those atoms will conduct. In every atom, the electrons get as close to the nucleus as possible, since the bands that

are closest to the nucleus are also the ones that require the least energy. That means that the outermost shell might not be completely filled, and thus an electron from a nearby atom can join this atom in its outermost shell. these moving electrons create an electrical current. therefore we can say that atoms with empty spaces in the outermost electron bands are conductors. the materials with no empty spaces in the outermost electron band are insulators. They do not let electrons flow very easily from one atom to another. Insulators are materials whose atoms have tightly bound electrons. These electrons are not free to roam around and be shared by neighboring atoms. However there are materials that fall in between conductors and insulators. Their conductance is in between metals and insulators. And their conductance can be modified by shining a light on them or injecting charges. They're known as semiconductors. They are mostly made of atoms that don't conduct electricity, but they have a handful of atoms with loose electrons. Under certain circumstances -- by changing things like temperature or how much energy is injected -- these loose electrons will start a flowing current. Superconductors are very different from the first three, since no material known today superconducts except at very cold temperatures. Scientists are discovering materials that do superconduct closer and closer to room temperature all the time, but no one is quite sure how that happens. However, some scientists have come up with a theory for how the very coldest superconductors work, known as the BCS theory. In such materials, at low temperatures, the atoms vibrate in a way that forces the moving electrons closer together. Normally electrons don't like to huddle so close, since they're all electrically negative and therefore repel each other. But in superconductors, the electrons actually achieve almost an attraction for each other. The result is that as one electron moves, it pulls the next electron along right behind it. Electrons slip from atom to atom more easily than they ever do normally. Therefore, atoms which, at the right temperature, can make electrons attract instead of repel each other are superconductors. CONDUCTORS In a conductor, electric current can flow freely, in an insulator it cannot. Metals such as copper typify conductors, while most non-metallic solids are said to be good insulators, having extremely high resistance to the flow of charge through them. "Conductor" implies that the outer electrons of the atoms are loosely bound and free to move through the material. Most atoms hold on to their electrons tightly and are insulators. In copper, the valence electrons are essentially free and strongly repel each other. Any external influence which moves one of them will cause a repulsion of other electrons which propagates, "domino fashion" through the conductor. Simply stated, most metals are good electrical conductors, most nonmetals are not. Metals are also generally good heat conductors while nonmetals are not.

While the normal motion of "free" electrons in a conductor is random, with no particular direction or speed, electrons can be influenced to move in a coordinated fashion through a conductive material. This uniform motion of electrons is what we call electricity, or electric current. To be more precise, it could be called dynamic electricity in contrast to static electricity, which is an unmoving accumulation of electric charge. Just like water flowing through the emptiness of a pipe, electrons are able to move within the empty space within and between the atoms of a conductor. The conductor may appear to be solid to our eyes, but any material composed of atoms is mostly empty space! The liquid-flow analogy is so fitting that the motion of electrons through a conductor is often referred to as a "flow." With electricity, the overall effect from one end of a conductor to the other happens at the speed of light: a swift 186,000 miles per second!!! Each individual electron, though, travels through the conductor at a much slower pace.

Effects on conductance:
Different conductors have different levels of conductance. Silver is the best conductor, offering easier passage for electrons than any other material cited. Dirty water and concrete are also listed as conductors, but these materials are substantially less conductive than any metal. Physical dimension also impacts conductivity. For instance, if we take two strips of the same conductive material -- one thin and the other thick -- the thick strip will prove to be a better conductor than the thin for the same length. If we take another pair of strips -- this time both with the same thickness but one shorter than the other -- the shorter one will offer easier passage to electrons than the long one. Most metals become poorer conductors when heated, and better conductors when cooled. Conductors:

silver copper gold aluminum iron steel brass bronze mercury graphite dirty water concrete

INSULATORS:

Most solid materials are classified as insulators because they offer very large resistance to the flow of electric current. Metals are classified as conductors because their outer electrons are not tightly bound, but in most materials even the outermost electrons are so tightly bound that there is essentially zero electron flow through them with ordinary voltages. Some materials are particularly good insulators and can be characterized by their high resistivities. For example, most insulators have resistivities of the order of 1012 while good conductors like copper have resistivities like 1.7x10-8.
It should also be understood that some materials experience changes in their electrical properties under different conditions. Glass, for instance, is a very good insulator at room temperature, but becomes a conductor when heated to a very high temperature. Gases such as air, normally insulating materials, also become conductive if heated to very high temperatures. Insulators:

glass rubber oil asphalt fiberglass porcelain ceramic quartz (dry) cotton (dry) paper (dry) wood plastic air diamond pure water

SEMICONDUCTORS:

A silicon crystal is different from an insulator because at any temperature above absolute zero temperature, there is a finite probability that an electron in the lattice will be knocked loose from its position, leaving behind an electron deficiency called a "hole". If a voltage is applied, then both the electron and the hole can contribute to a small current flow. The conductivity of a semiconductor can be modeled in terms of the band theory of solids. The band model of a semiconductor suggests that at ordinary temperatures there is a finite possibility that electrons can reach the conduction band and contribute to electrical conduction. In a semiconductor like silicon at temperatures above absolute zero, there will be some electrons which are excited across the band gap into the conduction band and which can produce current. When the electron in pure silicon crosses the gap, it leaves behind an electron vacancy or "hole" in the regular silicon lattice. Under the influence of an external voltage, both the electron and the hole can move across the material. In an n-type semiconductor, the dopant contributes extra electrons, dramatically increasing the conductivity. In a p-type semiconductor, the dopant produces extra vacancies or holes, which likewise increase the conductivity. It is however the behavior of the p-n junction which is the key to the enormous variety of solid-state electronic devices. The current which will flow in an undoped semiconductor consists of both electron and hole current. That is, the electrons which have been freed from their lattice positions into the conduction band can move through the material. In addition, other electrons can hop between lattice positions to fill the vacancies left by the freed electrons. This additional mechanism is called hole conduction because it is as if the holes are migrating across the material in the direction opposite to the free electron movement.

The Doping of Semiconductors

The addition of a small percentage of foreign atoms in the regular crystal lattice of silicon or germanium produces dramatic changes in their electrical properties, producing n-type and p-type semiconductors.

The addition of pentavalent impurities such as antimony, arsenic or phosphorous contributes free electrons, greatly increasing the conductivity of the intrinsic semiconductor. Phosphorous may be added by diffusion of phosphine gas (PH3).

The addition of trivalent impurities such as boron, aluminum or gallium to an intrinsic semiconductor creates deficiencies of valence electrons,called "holes". It is typical to use B2H6 diborane gas to diffuse boron into the silicon material.

Band Theory of Solids

A useful way to visualize the difference between conductors, insulators and semiconductors is to plot the available energies for electrons in the materials. Instead of having discrete energies as in the case of free atoms, the available energy states form bands. Crucial to the conduction process is whether or not there are electrons in the

conduction band. In insulators the electrons in the valence band are separated by a large gap from the conduction band, in conductors like metals the valence band overlaps the conduction band, and in semiconductors there is a small enough gap between the valence and conduction bands that thermal or other excitations can bridge the gap. With such a small gap, the presence of a small percentage of a doping material can increase conductivity dramatically. An important parameter in the band theory is the Fermi level, the top of the available electron energy levels at low temperatures. The position of the Fermi level with the relation to the conduction band is a crucial factor in determining electrical properties.

SUPERCONDUCTORS: An element, inter-metallic alloy or compound that will conduct electricity without resistance below a certain temperature. Resistance is undesirable because it produces losses in the energy flowing through the material. Once set in motion, current will flow forever in a closed loop of superconducting material.

If mercury is cooled below 4.1 K, it loses all electric resistance. This discovery of superconductivity by H. Kammerlingh Onnes in 1911 was followed by the observation of other metals which exhibit zero resistivity below a certain critical temperature (Tc). The fact that the resistance is zero has been demonstrated by sustaining currents in superconducting lead rings for many years with no measurable reduction. An induced current in an ordinary metal ring would decay rapidly from the dissipation of ordinary resistance, but superconducting rings had exhibited a decay constant of over a billion years! The first widely-accepted theoretical understanding of superconductivity was advanced in 1957 by American physicists John Bardeen, Leon Cooper, and John Schrieffer (above). Their Theories of Superconductivity became know as the BCS theory - derived from the first letter of each man's last name - and won them a

Nobel prize in 1972. The mathematically-complex BCS theory explained superconductivity at temperatures close to absolute zero for elements and simple alloys. However, at higher temperatures and with different superconductor systems, the BCS theory has subsequently become inadequate to fully explain how superconductivity is occurring. In recent years, many discoveries regarding the novel nature of superconductivity have been made. In 1997 researchers found that at a temperature very near absolute zero an alloy of gold and indium was both a superconductor and a natural magnet. Conventional wisdom held that a material with such properties could not exist! Since then, over a half-dozen such compounds have been found.

Critical Temperature for Superconductors

The critical temperature for superconductors is the temperature at which the electrical resistivity of a metal drops to zero. The transition is so sudden and complete that it appears to be a transition to a different phase of matter; this superconducting phase is described by the BCS theory. Several materials exhibit superconducting phase transitions at low temperatures. The highest critical temperature was about 23 K until the discovery in 1986 of some high temperature superconductors. Materials with critical temperatures in the range 120 K have received a great deal of attention because they can be maintained in the superconducting state with liquid nitrogen (77 K). The world record Tc of 138 K is now held by a thallium-doped, mercuric-cuprate comprised of the elements Mercury, Thallium, Barium, Calcium, Copper and Oxygen. The Tc of this ceramic superconductor was confirmed by Dr. Ron Goldfarb at the National Institute of Standards and TechnologyColorado in February of 1994. Material T-Critical Gallium 1.1 K Aluminum 1.2 K Indium 3.4 K Tin 3.7 K Mercury 4.2 K Lead 7.2 K Niobium 9.3 K

Niobium-Tin 17.9 K La-Ba-Cu-oxide 30 K Y-Ba-Cu-oxide 92 K Tl-Ba-Cu-oxide 125 K

USES:
Magnetic-levitation is an application where superconductors perform extremely well. Transport vehicles such as trains can be made to "float" on strong superconducting magnets, virtually eliminating friction between the train and its tracks. Not only would conventional electromagnets waste much of the electrical energy as heat, they would have to be physically much larger than superconducting magnets Electric generators made with superconducting wire are far more efficient than conventional generators wound with copper wire. In fact, their efficiency is above 99% and their size about half that of conventional generators. These facts make them very lucrative ventures for power utilities. NASA and DARPA and various universities, are currently researching "petaflop" computers. A petaflop is a thousand-trillion floating point operations per second. Today's fastest computers have reached "petaflop" speeds - quadrillions of operations per second. Currently the fastest is a U.S. Military Supercomputer call the "Road Runner" operating at 1.026 petaflops per second (with multiple CPU's). The fastest single processor is a Lenslet optical DSP running at 8 teraflops. It has been conjectured that devices on the order of 50 nanometers in size along with unconventional switching mechanisms, such as the Josephson junctions associated with superconductors, will be necessary to achieve the next level of processing speeds.