DN XUT HALOGEN - ANCOL PHENOL

D liu cho cc cu 1; 2; 3
Cho cc cht sau:
CH3-CH2-CH2-Cl (1); CH3-CHCl-CH3 (2); (CH3)3CCl (3); (CH3)2CH-CH2Cl (4);
CH3-CHF-CH3 (5); (CH3)2CCl-CH2-CH3 (6); BrCH2-CH2-CH2-CH2Br (7).
Cu 1. Cc dn xut bc I l:
A. (1); (4); (7).

B. (1); (4).

C. (1); (3); (4).

D. (1); (3); (4); (7).

C. (2); (5); (6).

D. (2); (5); (6); (7).

C. (3); (6).

D. (3).

Cu 2. Cc dn xut bc II l:
A. (2); (6).

B. (2); (5).

Cu 3. Cc dn xut bc III l:
A. (2); (3); (6).

B. (5); (7).

Cu 4. Dn etilen vo dung dch nc brom d. Hin tng quan st c l;

A. To hn hp ng nht khng mu.

B. To 2 lp cht lng u khng mu.

C. To 2 lp cht lng, lp di khng mu. D. To 2 lp cht lng, lp trn khng mu.

Cu 5. Dy cht c xp theo chiu tng dn nhit si l:
A. CCl4; CHCl3; CH3Cl; CH3F; CH4.

B. CH3Cl; CHCl3; CCl4; CH3F; CH4.

C. CH4; CH3F; CH3Cl; CHCl3, CCl4.

D. CH4; CCl4; CHCl3; CH3Cl; CH3F.

Cu 6. Tn gi no di y khng ng vi cng thc:

A. CHCl3: triclometan.

B. CHCl3: clorofom.

C. CH2=CH-CH2Cl: anlyl clorua.

D. CH2=CH-CH2Cl: clopropen.

Cu 7. S ng phn cu to c cng phn thc phn t C3H5Cl l:

A. 3.

B. 4.

C. 5.

D. 6.

Cu 8. S ng phn cu to c cng phn thc phn t C3H6Cl2 l:

A. 4.

B. 5.

C. 6.

D. 3.

Cu 9. Khi nh vi git AgNO3 vo ng nghim cha CH2=CH-CH2Cl, lc nh. Quan st thy:

A. Khng c hin tng g xy ra.

B. To 2 lp cht lng khng mu.

C. To hn hp ng nht khng mu.

D. Xut hin kt ta trng.

Cu 10. Nhn xt no sau y khng ng:

A. Anlyl bromua d tham gia phn ng th hn phenyl bromua.
B. Vinyl clorua c th iu ch t 1,2-icloetan.
C. Etyl clorua thuc loi halogen dn xut bc II.
D. ng vi cng thc C3H5Br c 4 ng phn cu to.
Cu 11. Khi un nng etyl clorua trong dung dch cha KOH v C2H5OH, thu c:
A. Etanol.

B. Etilen.

C. Axetilen.

D. Etan.

Cu 12. C 2 ng nghim: ng 1 ng 1 ml etylbromua, ng 2 ng 1 ml brombenzen. Thm tip

vo mi ng 1 ml dung dch AgNO3. un si 2 ng nghim. Quan st thy:
. C 2 ng khng c hin tng g.
B. ng 1 xut hin kt ta vng nht; ng 2 khng c kt ta.
C. ng 1 khng c hin tng; ng 2 xut hin kt ta vng nht.
D. ng 1 to hn hp ng nht; ng 2 to 2 lp cht lng.
Cu 13. phn bit cc cht: CH3-CH2-CH2-Cl; CH3-CH2-CH2-Br; CH3-CH2-CH2I, ngi ta
dng:
A. Bt Mg(ete khan). B. dd NaOH.

C. dd HBr.

D. dd AgNO3.

Cu 14. phn bit 3 l ng 3 cht l butyl clorua, anlyl clorua, m-iclobenzen ngi ta dng:
A. dd AgNO3.

B. dd NaOH v dd Br2.

C. dd NaOH v dd AgNO3.

D. dd Br2.

Cu 15. Cho s chuyn ha sau:

X1, X2 ln lt l:
A. CH2=CH-CH2-CH3; CH3-CHOH-CH2-CH3.
B. CH3-CHOH-CH2-CH3; CH2=CH-CH2-CH3.
C. CH3-CHOH-CH2-CH3; CH3-CH=CH-CH3.
D. CH2=CH-CH2-CH3; CH3-CH=CH-CH3.
Cu 16. Sn phm chnh ca phn ng tch nc ca 2-metylpentan-3-ol l:
A. 4-metylpent-2-en. B. 4-metylpent-3-en. C. 2-metylpent-3-en. D. 2-metylpent-2-en.
Cu 17. X c cng thc phn t l C4H10O. X tch nc cho 3 anken ng phn. X l:
A. Butan-2-ol.

B. Ancol isobutylic. C. Ancol butylic.

D. metylpropan-1-ol.

Cu 18. S cht ng phn c cng cng thc phn t C4H10O tha mn tnh cht: tch nc thu
c anken, khi oxi ha c xc tc thu c sn phm c kh nng tham gia phn ng trng bc
l:
A. 2.

B. 3.

C. 4.

D. 1.

Cu 19. un nng ru X vi H2SO4 c 170oC, ch thu c 1 anken duy nht. Cng thc cu
to ca X l:
A. CH3-CH(CH3)CH2-OH.

B. CH3-CH(OH)-CH2-CH3.

C. CH3-CH2-CHOH-CH(CH3)2.

D. C6H5-CH2-CH2-OH.

Cu 20. Cht no sau y khi b oxi ha ( c xc tc) to ra anehit:

A. CH3CHOHCH3.

B. (CH3)3COH.

C. CH3CH2OCH3.

D. CH3CH2CH2OH.

Cu 21. Cho dy chuyn ha sau:

Y l sn phm chnh ca phn ng, cng thc cu to ca X, Y ln lt l:

A. CH3-CH2-CH2-CH2OH; CH3-CH=CH-CH3.
B. CH3-CH(CH3)-CH2OH; CH3-CH=CH-CH3.
C. CH3-CHOH-CH2-CH3; CH3-CH=CH-CH3.
D. CH3-CHOH-CH2-CH3; CH2=CH-CH2-CH3.
Cu 40. Ancol no di y thuc dy ng ng c cng thc chung CnH2nO:
A. CH3CH2OH.

B. CH2=CH-CH2OH. C. C6H5CH2OH.

D. CH2OH-CH2OH.

Cu 41. phn bit: etylbenzen, xiclopropaan, o-crosol v phenol ngi ta c th dng thuc
th:
A. dd Br2 d v dd HNO3.

B. dd KMnO4 v Na.

C. dd Br2 d v Na.

D. dd Br2 v Cu(OH)2.

Cu 42. phn bit cc cht: NH4HCO3, C6H5ONa, C3H7OH, C6H6 c th dng thuc th:
A. dd Br2.

B. dd NaOH.

C. dd HCl.

D. Nc.

Cu 43. C 4 l mt nhn ng: etilen glycol, phenol, stieren, etanol. nhn bit 4 l trn c th
dng:
A. dd NaOH v Na.

B. Na v Cu(OH)2.

C. dd Br2 v Cu(OH)2.

D. dd Br2 v Na.

Cu 44. Cng thc tng qut ca ancol no, mch h, n chc, bc I l:

A. R-CH2OH.

B. CnH2n+1OH.

C. CnH2n+1CH2OH.

D. CnH2n+2O.

Cu 45. t chy ancol X, thu c s mol H2O ln hn s mol CO2. X l ancol:

A. No, mch h.

B. No, n chc, mch h.

C. Khng no, mch h.

D. No, a chc.

Cu 46. Ancol no sau y c sai tn:

A. 2-metylhexan-1-ol

CH3-CH2-CH2-CH2-CH(CH3)-CH2-OH.

B. 4,4-imetylpentan-2-ol

CH3-C(CH3)2-CH(OH)-CH3.

C. 3-etylbutan-2-ol

CH3-CH(C2H5)-CH(OH)-CH3.

D. 3-metylpentan-2-ol

CH3-CH2-CH(CH3)-CH(OH)-CH3.

Cu 47. Cho cc hp cht sau: HO-CH2-CH2OH (1); HO-CH2-CHOH-CH2OH (2);

HO-CH2-CH2-CH2OH (3); HO-CH2-CHOH-CH3 (4); HO-CH2-CH2-CHOH-CH2OH (5);
HO-CH2-CH2-CHOH-CH2-CH2OH (6). Cht to c vi Cu(OH)2 phc mu xanh l:

A. (1), (2), (3), (4).

B. (1), (2), (4), (5), (6).

C. (1), (2), (5), (4).

D. (1), (2), (4).

Cu 48. Dy cc cht u phn ng c vi C2H5OH l:

A. K, HBr, dd Br2, HCOOH, CuO, O2.

B. K, NaOH, dd Br2, CuO, O2, C2H5OH.

C. Na, HBr, CH3COOH, CuO, O2, CH3OH. D. Na, HCl, CuO, O2, C2H5OH, dd Br2.
Cu 49. X c cng thc phn t C4H10O. X tch nc cho 2 anken ng phn. X l:
A. Butan-2-ol.

B. Ancol isobutylic. C. Ancol butylic.

D. metylpropan-1-ol.

Cu 50. A, B c cng cng thc phn t C3H8O. A tc dng vi Na, khi b oxi ha khng hon
ton thu c sn phm tham gia phn ng trng bc. B khng tc dng vi Na. A, B ln lt l:
A. Propan-2-ol v etyl metyl ete.

B. Propan-1-ol v etyl metyl ete.

C. Propan-2-ol v ietyl ete.

D. Propan-1-ol v ietyl ete.

Cu 51. Mt ancol no, mch h c cng thc thc nghim (C2H5O)n. Vy CTPT ca ancol l:
A. C6H15O3.

B. C4H10O2.

C. C4H10O.

D. C6H14O2.

Cu 52. Cht no sau y khng nn dng lm khan ancol:

A. H2SO4 c.

B. CaO mi nung.

D. P2O5 rn.

C. CuSO4 khan.
o

Cu 53. un nng mt ancol A vi H2SO4 m c 170 C ch thu c mt olefin duy nht.

Cng thc tng qut ca ancol A l:
A. CnH2n+1CH2OH.

B. CnH2n+1OH.

C. CnH2nO.

D. CnH2n-1CH2OH.

Cu 54. Trong s cc phng php iu ch ru etylic sau y, phng php no ch dng trong
phng th nghim:
A. un nng anken vi nc c xc tc thch hp.
B. un nng dn xut halogen vi dung dch kim.
C. Ln men glucozo c xc tc.
D. Hidro ha anehit.
Cu 55. C bao nhiu ng phn c cng cng thc phn t l C5H10 khi cng nc cho sn phm
l ancol bc 3:
A. 6.

B. 2.

C. 4.

D. 3.

Cu 56. C cc cht hu c: C2H5Cl; C2H5OH; n-C4H9OH; CH3OCH3. Cht tan tt nht trong
nc l:
A. C2H5Cl.

B. C2H5OH.

C. CH3OCH3.

D. n-C4H9OH.

Cu 57. X l mt dn xut ca benzen, khng phn ng vi dung dch NaOH, c cng thc phn
t C7H8O. S ng phn ph hp ca X l:
A. 2.

B. 3.

C. 4.

D. 5.

Cu 58. Cht hu c X c cng thc phn t C6H6O2. Bit X l hp cht thm v c tc dng vi
KOH theo t l mol 1:2. S ng phn cu to ca X l:
A. 1.

B. 2.

C. 3.

D. 4.

Cu 59. Trong s cc dn xut ca benzene c cng thc phn t C8H10O. C bao nhiu ng
phn (X) tha mn:
(X) + NaOH Khng phn ng.

A. 1.

B. 2.

C. 3.

D. 4.

Cu 60. Cho dy chuyn ha: A1 A2 A3 n-C3H7OH.

Bit A2, A3 u l sn phm chnh ca cc phn ng. Cng thc cu to ca A1, A2, A3 ln lt l:
A. CHC-CH3; CH3-CH2-CH3; CH2=CH-CH3.
B. CH3-CH2-CH3; CH2=CH-CH3; CH2=CH-CH2Cl.
C. CH2=CH-CH3; CH2=CH-CH2Cl; CH2=CH-CH2OH.
D. CH2=CH-CH3; CHC-CH3; CH3-CH2-CHO.
Cu 61. Cho dy chuyn ha sau: C3H8 A B CH3-CH(OH)-CH3.
Bit B l sn phm chnh ca phn ng. Cng thc cu to ca A, B ln lt l:
A. CH2=CH-CH3; CH3-CH2-CH2Cl.

B. C2H2; CH2=CH-CH3.

C. (CH3COO)2Ca; CH3-CO-CH3.

D. CH2=CH-CH3; CH3-CHCl-CH3.

Cu 62. Cht hu c A c cng thc phn t l C3H8O2.

A c cc tnh cht:
Tc dng vi Na gii phng hidro.
Ha tan c Cu(OH)2 to dung dch c mu xanh thm.
A c cng thc cu to l:
A. CH3-CH2-CH(OH)2.

B. CH2OH-CH2-CH2OH.

C. CH3-CHOH-CH2OH.

D. CH3-CH2-COOH.

Cu 63. Cho dy chuyn ha sau: C3H8 X Y Z glixerin.

X, Y, Z u l sn phm chnh ca cc phn ng. Cng thc cu to ca X, Y, Z ln lt l:
A. CH2=CH-CH3; CH3-CH2-CH2Cl; CH2Cl-CHCl-CH2OH.
B. CHC-CH3; CH3-CO-CH3; CH3-CHOH-CH3.
C. CH2=CH-CH3; CH3-CH2-CH2Cl; CH2Cl-CHOH-CH2Cl.
D. C2H2; CH2=CH-CH3; CH2Cl-CHCl-CH2Cl.
Cu 64. . Cho dy chuyn ha sau:

Y l sn phm chnh ca phn ng, cng thc cu to ca X, Y ln lt l:

A. CH3-CH2-CH2-CH2OH; CH3-CH=CH-CH3.
B. CH3-CH(CH3)-CH2OH; CH3-CH=CH-CH3.
C. CH3-CHOH-CH2-CH3; CH3-CH=CH-CH3.
D. CH3-CHOH-CH2-CH3; CH2=CH-CH2-CH3.
Cu 65. Cht hu c X mch h, c cng thc phn t C4H8O. X tc dng c vi Na gii phng
hidro; X lm mt mu dung dch brom; tn ca X bt u bng ch trans. Cng thc cu to ca X
l:
A. CH3-CH=CH-CH2OH.

B. CH2=CH-CH2-CH2OH.

C. CH3-CH(CH3)-CH2OH.

D. CH3-CH2-CH=CHOH.

Cu 66. iu ch C2H4 ngi ta un nng C2H5OH vi axit H2SO4 c 170oC. Hiu sut ca
phn ng t 60%. Khi lng ring ca etylic bng 0,8 gam/ml. thu c 13,44 lt ( ktc)
C2H4 th th thch ru 95o cn l:
A. 57,5 ml.

B. 60,53 ml.

C. 36,32 ml.

D. 34,50 ml.

Cu 67. Cho 1,24 gam hn hp 2 ru n chc tc dng va vi Na, thy thot ra 336 ml kh
H2 ( ktc) v m gam mui natri. m c gi tr bng:
A. 1,93 gam.

B. 2,93 gam.

C. 1,90 gam.

D. 1,47 gam.

Cu 68. X, Y l 2 ru no n chc, mch h k tip nhau trong dy ng ng. Cho hn hp

gm 1,6 gam X v 2,8 gam Y tc dng ht vi Na thu c 1,12 lt H2 ktc. X, Y c cng thc
phn t ln lt l:
A. CH3OH v C2H5OH.

B. C2H5OH v C3H7OH.

C. C3H7OH v C4H9OH.

D. C4H9OH v C5H11OH.

Cu 69. Hn hp X gm 2 ru no, n chc, mch h. Chia mt lng X thnh 2 phn bng

nhau. t chy hon ton phn 1 thu c 0,2 mol CO2. Tch nc hon ton phn 2, thu c
hn hp Y ch gm 2 anken. t chy hon ton hn hp Y thu c m gam nc. m c gi tr
bng:
A. 1,8 gam.

B. 3,6 gam.

C. 2,7 gam.

D. 8,8 gam.

Cu 70. t chy hon ton mt ru n chc A thu c 8,8 gam CO2 v 7,2 gam H2O. Cng
thc phn t ca A l:
A. C2H5OH.

B. C3H5OH.

C. C3H7OH.

D. CH3OH.

Cu 71. Trong sn xut, iu ch ru vang, ngi ta ln men glucozo c trong nc qu nho.

Phn ng ln men glucozo iu ch ru etylic t hiu sut 90%. Bit ru etylic nguyn cht
c khi lng ring 0,80 g/ml. Khi lng glucozo cn iu ch 100 lt ru vang 9,2o l:
A. 14,40 kg.

B. 16,00 kg.

C. 1,600 kg.

D. 1,440 kg.

Cu 72. Mt ru n chc A tc dng vi HBr cho hp cht B cha 58,40% Br v khi lng.
Mt khc nu un nng A vi H2SO4 c 170oC thu c hn hp 3 anken. Cng thc cu to
ca A l:
A. CH3-CHOH-CH2-CH3.

B. CH3-CH2-CH2-CH2OH.

C. CH3-CHOH-CH3.

D. CH3-CH(CH3)-CH2OH.

Cu 73. t chy hon ton mt lng hn hp hai ru n chc ( X, Y) k tip nhau trong dy
ng ng thu c 4,48 lt CO2 ( ktc) v 4,95 gam H2O. Bit rng khi oxi ha hon ton X, Y
thu c sn phm u c kh nng tham gia phn ng trng bc. Cng thc cu to ca X, Y l:
A. C2H5OH v n-C3H7OH.

B. C2H5OH v i-C3H7OH.

C. n-C3H7OH v n-C4H9OH.

D. CH3OH v C2H5OH.

Cu 74. iu ch C2H4 ngi ta un nng C2H5OH vi axit H2SO4 c 170oC. Hiu sut ca
phn ng t 60%. Khi lng ring ca etylic bng 0,8 gam/ml. thu c 13,44 lt ( ktc)
C2H4 th th thch ru 95o cn l:
A. 57,5 ml.

B. 60,53 ml.

C. 36,32 ml.

D. 34,50 ml.

Cu 75. Hp cht B cha C, H, O c cng thc phn t trng vi cng thc n gin. Khi phn
tch a gam B, thy tng khi lng C v H trong l 0,46 gam. t chy hon ton a gam B
cn 0,896 lt oxi ( ktc). Cho ton b sn phm chy qua bnh ng dung dch NaOH d, thy khi
lng bnh tng 1,9 gam. B c cng thc phn t l:
A. C2H6O.

B. C6H6O2.

C. C7H8O2.

D. C4H8O2.

Cu 76. Ti mt nh my ru, ngi ta dng khoai ty cha 20% tinh bt sn xut ru etylic.
Cn phi dng bao nhiu tn khoai ty thu c 1 tn ru, bit s hao ht trong sn xut l
15%.
A. 10,358 tn.

B. 2,0716 tn.

C. 1,7609 tn.

D. 7,484 tn.