Soal-soal Titrasi Redoks

sample mass=
KMnO4 titration=

0,4185g
0,025M

%Fe2O3=?
mol Fe2O3=1/2*mol Fe=1/2*5*mol KMNO4

=5/2*(V*M)KMnO4
2,5794mmol
massa Fe2O3=

412,7mg
98,61%

41,27mL

sample=
2+
Titration Fe
KMnO4
Vol=
M=
Mol KMnO4= (M*V)=

0,4185 g=

418,5 mg

41,27 mL
0,025 M
1,03175 mmol

Reaction: 5 Fe2+ + KMnO4 === 5 Fe3+ + Mn2+

mol Fe2+ = 5* mol KMnO4=

5,15875 mmol

Reaction: 2 Fe2+ === 2 Fe3+ ===== Fe2O3

2+

mol Fe2O3 = 0,5*mol Fe =

2,579375 mmol
mass Fe2O3= mol*Mr Fe2O3=
412,7 mg
%Fe2O3= mass Fe2O3/mass sample*100%=

98,61%

Walden reductor: UO22+ --> U4+

Addition of Fe3+: U4++ 2Fe3+ ---> U6+ + 2Fe2+
Titration: 6 Fe2+ + K2Cr2O7 --> 6 Fe3+ + 2 Cr3+
sample=
0,315 g=
315 mg
Titration:
Vol=
10,52 mL
M=
0,00987 M
mmol K2Cr2O7= (V*M)=
0,103832 mmol
mmol Fe2+ =6 * mmol K2Cr2O7=
0,622994 mmol
mmol U4+ =0,5 * mmol Fe2+ =
mass U= mmol U4+ * Ar (U)=
%U= mass U/mass sample *100=
Ar U=

238,0289

0,311497 mmol
74,14534 mg
23,54%

Cr=
51,9961
Fe
55,8
Area=
30 cm2
density Cr=
7,2 g/cm3
oxidizing: 2Cr3+ === Cr2O72Addition of Fe(NH4)2(SO4)26H2O=
500,0 mg
Cr2O72- + 6Fe2+ === 2Cr3+ + 6Fe3+
Reaction
Backtitration
22+
3+
3+
Cr2O7 + 6Fe === 2Cr + 6Fe
Reaction
vol=
18,29 mL
M=
0,00389 M
mmol back titration = Fe2+ excess= (V*M) backtitration=
=
0,071148 mmol
mmol Fe total = mmol Fe-amm-sulfat=mass/Mr Fe-amm-sulfat
=
1,276015 mmol
mmol Fe2+ bereaksi dengan Cr2O72- sampel=
1,20487 mmol
2-

2+

mmol Cr2O7 = 1/6 * mmol Fe =

mmol Cr

3+

0,20081 mmol

2-

= 2 x mmol Cr2O7 =

mass Cr3+=
vol Cr3+= mass/density=
thickness=volume/area=

0,40162 mmol
20,9 mg=

=
Mr Fe-amm-sulfat=

391,85 g/mol

0,02088
0,0029
9,7E-05
0,9668

g
cm3
cm
m