NAND VIDYA NIKETAN-ESSAR SCHOOL JAMNAGAR 2012-2013 SUBJECT : CHEMISTRY CLASS: Xl M MARKS: 30 DATE : JANUARY 2013 TIME : 1 Hour

Q.1 London forces are also known as______________ . Q.2 Draw a Graph between pressure and volume at different temperature. Q.3 Calculate the volume R( gas constant in j/k mol. Q.4 Write down the expression for compressibility factor. Q.5 What is critical temperature. Q.6 Drive the expression for coefficient of viscosity. Q.7 Define Law of mass action and derive the expression for equilibrium constant. Q.8 derive the relation between Kp and Kc. Q.9 Explain Bronsted-Lowry concept of acid and base with an example. Q.10 Define: i) Common ion effect. ii) PH of a solution. iii) Buffer solution. Q.11 Write down the Ksp for the following Equilibrium.

[1] [1] [1] [1] [1] [2] [2] [2] [2] [3]

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MxNy

---------

xMy+ + yNx[3]

Q.12 Ethyl acetate is formed by the reaction between ethanol and acetic acid and the Equilibrium is represented as: CH3COOH ( l ) + C2H5OH ( l ) ------------ CH3COO C2H5 ( l ) + H2O ( l )

i) ii)

Write the concentration ratio (reaction quotient), Qc, for this reaction (note: water is not in excess and is not a solvent in this reaction) At 293K, if one starts with 1.00 mol of acetic acid and 0.18 mol of ethanol, there is 0.171 mol ethyl acetate in the final equilibrium mixture. Calculate the equilibrium constant. [3]

Q.13 At 473 K, equilibrium constant Kc for the decomposition of phosphorus pentachloride, PCl5 is 8.3 x 10-3 . If decomposition is depicted as, PCl5 (g) PCl3 (g) + Cl2 (g) r kJ mol-1

Q.14 i) The Concentration of hydrogen ion in sample of soft drink is 3.8 x 10-4 M. What is pH? ii) The Species: H2O, HCO-3, HSO-4 and NH3 can act both as Bronsted acids and bases For each case give the corr

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