Chemical Stockroom Essentials Fisher Chemical Fisher BioReagents Acros Organics

Chemical Storage Guidelines

Chemical Stockroom Handbook

Introduction
As the stockroom manager, you are charged with the safe handling of hazardous chemicals every single day. Your responsibilities are far-reaching extending beyond the storeroom walls to lab personnel, building staff, campus residents and the environment. Fisher Scientific offers this littlebig-book of safety resources. Inside youll find storage recommendations, chemical compatibility charts, and recommended essential products to stock to accommodate various research applications undertaken by your customers.

Table of Contents
Introduction........................................................................................................... 2 Periodic Table of the Elements........................................................................... 2 Fisher Chemical* Purity Chart............................................................................ 3 Fisher Chemical Stockroom Essentials..........................................................4-5 Fisher BioReagents* Purity Grades................................................................... 6 Fisher BioReagents Stockroom Essentials....................................................7-8 Acros Organics* Stockroom Essentials.......................................................9-10 Chemical Storage/Handling Recommendations............................................ 11 Incompatibilities by Hazard Class.................................................................... 11 Chemical Incompatibilities................................................................................ 12 NFPA Hazard Code Ratings............................................................................... 13 Understanding Chemical Labels...................................................................... 14 Chemical Resistance and Physical Properties of Plastics.......................... 15 Chemical Resistance of Labware Materials.............................................16-17 Fisher Chemical Solvent Safety Packaging Features................................... 18 Fisher Chemical Products in the Safe-Cote* Bottle...................................... 19

Periodic Table of the Elements

HOW BLUE IS YOUR LAB?
P Chemicals P Consumables P Laboratory Equipment

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Fisher Chemical* Products Purity Grades

Grade
Biotechnology

Definition
Solvents and reagents that have been specially purified and assayed for biotechnology applications. Reagent chemicals for which the purity standard is established by Fisher Scientific. Purity is guaranteed to meet published maximum limits of impurities. Reagent chemicals that meet or exceed the latest ACS specifications. Actual lot analysis on label.

Application
Electrophoresis, molecular biology, sequencing, and peptide and oligonucleotide synthesis General analytical procedures

Certificate of Analysis
Available on request

Certified Certified ACS Certified ACS Plus Electronic Environmental Grade GC Resolv*

Available on request

Analytical applications requir- Available on request ing tight specifications Available on request Available on request Provided with each shipment Provided with each shipment Available on request Available on request Available on request Provided with each shipment

"Acids that, in addition to meeting or exceeding the latest specifications of Analytical applications with tighter metal specifications the ACS, are analyzed for more than 16 metals. Actual lot analysis on label." Solvents manufactured to ensure low levels of metal contamination. Meet Semiconductor Equipment and Materials Institute (SEMI) requirements. Actual lot analysis on label. Solvents for use in HPLC analysis, trace-organic analysis, and environmental testing. Packaged in precleaned glass bottles in M3.5 (Class 100) cleanroom. Shipped with Certificate of Analysis. "Solvents with the highest purity and lot-to-lot consistency. Free of contaminants to the ppb level, including those listed in Contract Laboratory Program Target Compound List. Meet ACS specifications. Chromatogram available on request." Solvents and products that are specially prepared for use in the histology laboratory setting. Solvents are filtered for tissue processing applications. Solvents manufactured specifically for use with HPLC instruments. Meet all ACS specifications. Submicron filtered. "Chemicals of reasonable quality and purity for use in procedures where no official standards are required. " Acids and solvents of extremely high purity. Acids are analyzed for 65 metals by ICP/MS; impurity levels in ppt. Solvent impurity levels in ppm. UV absorbance curves and sample chromatograms available on request. For Optima acids, a typical lot analysis is given in the catalog. Impurity levels in an actual lot may vary from the amount listed. Solvents and additives of exceptionally high purity specially designed and use-tested on LC/MS instruments. Solvent impurity levels in ppb. Solvents for use in analysis of pesticide residue. Meet or exceed ACS standards of purity for pesticide residue analysis. Solvents, fluors, and prepared cocktails for liquid scintillation counting. Includes nonflammable, nontoxic, biodegradable ScintiSafe* cocktails. Solvents for use in spectrophotometry. Also meet ACS specifications. Actual lot analysis on label. Acids manufactured to achieve low metal contamination measurable in ppm to ppb range. Each lot is analyzed for more than 55 metals by ICP/ MS. For TraceMetal acids, a typical lot analysis is given in the catalog. Impurity levels in an actual lot may vary from amounts listed. Solvents manufactured for use with plasma/ICP instruments. Impurity levels in ppt. Packaged in acid-cleaned polyethylene bottles. Reagent chemicals that meet or surpass specifications of the United States Pharmacopeia (USP), the National Formulary (NF), the Food Chemicals Codex (FCC), the European Pharmacopeia (EP), the British Pharmacopeia (BP), and/or the Japanese Pharmacopeia (JP). Electronics and circuit board manufacturing HPLC, trace organic analysis, environmental testing Gas Chromatography (GC)

Histology HPLC Laboratory and Technical Optima*

Tissue processing, clinical or histology procedures HPLC and spectrophotometry procedures Manufacturing and general laboratory use HPLC, GC, plasma/ICP, spectrophotometry, and pesticide residue analysis LC/MS, HPLC, GC and spectrophotometry GC with electron capture detector (ECD), pesticide residue analysis Liquid scintillation counting Ultraviolet and visible wavelength detectors (UV-Vis) Primarily used in digestion of samples prior to instrument (ICP) analysis Plasma/ICP, environmental testing, trace metal analysis Food and drug laboratories, biological testing

Optima LC/MS Pesticide Scintanalyzed* Spectranalyzed* TraceMetal

Provided with each shipment Available on request Available on request Available on request Provided with each shipment Available on request 20L or greater; 10kg or greater

Ultra Trace Elemental Analysis USP/NF/FCC/ EP/BP/JP

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Fisher Chemical* Stockroom Essentials

Quality, purity and certainty
All chemicals are manufactured in Fisher Chemical, FDA licensed, ISO 9001:2008- and cGMP-certified facilities Rigorous quality assurance and testing procedures throughout the production process ensure the lot-to-lot consistency required for uniform analysis Optima* and HPLC-grade solvents are sealed with FisherLOCK* Tamper Evident Caps, packaged in Safe-Cote* bottles to prevent spills, and arrive in EcoSafPak* containers, a 100% recyclable shipper For the complete portfolio of Fisher Chemical products and promotions, please visit www.fishersci.com/chemicals

Fisher Chemical Products

Optima Grade: Ultra-high purity for more reliable analysis and cost savings
Description
2-Propanol, Optima, also meets ACS specifications Acetonitrile, Optima, also meets ACS specifications Hexanes, Optima, also meets ACS specifications Methanol, Optima, also meets ACS specifications Methylene Chloride, Optima, also meets ACS specifications

Pack Size
4L 4L 4L 4L 4L

Fisher Scientific Cat. No.

A4644 A9964 H3034 A4544 D1514

EMD Millipore* Equivalent

PX18341 AX01421 HX02961 MX04881 DX08311

Sigma* Equivalent
X X X X X

JT Baker* Equivalent
X X X X 926403

Macron* Equivalent
V55510 H45410 H48710 H48810 H48510

HPLC Grade Solvents

Description
Acetone, HPLC, also meets ACS specifications Acetonitrile, HPLC, also meets ACS specifications Hexanes, HPLC, also meets ACS specifications Methanol, HPLC, also meets ACS specifications Methanol, HPLC, also meets ACS specifications Water, HPLC grade

Pack Size
4L 4L 4L 4L 4L 4L

Fisher Scientific Cat. No.

A9494 A9984 H3024 A4524 A452SK4 W54

EMD Millipore Equivalent

AX01151 AX01451 HX02901 MX04751 MX0475P1 X

Sigma Equivalent
270725 270717 X X X X

JT Baker Equivalent
900203 901703 930803 909303 909333 X

Macron Equivalent
243510 285610 516710 304110 H08010 X

Histology Grade Solvents: The only products that offer the environmentally friendly F-Style poly bottle, which maximizes bench and shelf space
Description
Acetone, histological Acetone, histological Alcohol, Reagent, histological Ethanol, Anhydrous, histological Methanol, histological Xylenes, histological

Pack Size
4L 20L 4L 4L 4L 1 gal.

Fisher Scientific Cat. No.

A16P4 A16S20 A962P4 A405P4 A433P4 X3P1GAL

EMD Millipore Equivalent

AX01254 AX01253 AX044114 X MX04904 X

Sigma Equivalent
X X X X X X

JT Baker Equivalent
A13409 A13401 X A47809 907603 X

Macron Equivalent
X X X X X X

Products might not be available in all regions. Contact your local sales representative for details.

To order, please call 1-800-766-7000.

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Fisher Chemical* Products (Contd.)

ACS Grade
Description
2-Propanol, certified ACS plus 2-Propanol, certified ACS plus Acetic Acid, glacial, certified ACS Acetone, certified ACS Acetone, certified ACS Acetone, certified ACS Chloroform, approx. 0.75% ethanol as preservative, certified ACS Chloroform, approx. 0.75% ethanol as preservative, certified ACS Ethyl acetate, certified ACS Ethyl acetate, certified ACS Ethyl acetate, HPLC, also meets ACS specifications Ethyl ether, anhydrous, BHT stabilized, certified ACS Ethyl ether, anhydrous, BHT stabilized, certified ACS Hexanes, certified ACS Hexanes, certified ACS Hydrochloric acid, certified ACS plus Hydrogen peroxide, 30%, certified ACS Hydrogen peroxide, 30%, certified ACS Methanol, certified ACS Methanol, certified ACS Methanol, certified ACS Methanol, certified ACS Methanol, certified ACS Methylene chloride, stabilized, certified ACS Methylene chloride, stabilized, certified ACS Methylene chloride, stabilized, HPLC, also meets ACS specifications Sodium chloride, crystalline, certified ACS Sodium chloride, crystalline, certified ACS Sodium hydroxide, pellets, certified ACS

Pack Size
4L 500mL 500mL 20L 4L 500mL 4L

Fisher Scientific Cat. No.

A4164 A416500 A38500 A1820 A184 A18500 C2984

EMD Millipore* Equivalent

PX18355 PX183513 AX007313 AX01203 AX01208 AX01206 cx10559 cx105513 EX024014 EX02403 EX02451 EX01906 EX01903 HX02993 HX02995 HX060313 HX06351 HX06352 MX0485P4 MX04853 MX04858 MX04857 MX04856 dx083514 dx08355 dx08381 SX04203 SX04201 SX059013

Sigma* Equivalent
190764 190764 242853 179124 179124 179124 319988 319988 319902 319902 270520 X 179264 178918 178918 258148 216763 216763 X X 179337 179337 179337 443484 d65100 270563 223514 223514 221465

JT Baker* Equivalent
908403 908401 950802 900607 900603 900601 918003 918001 928003 928007 928203 924422 924403 930907 930903 953502 X 218601 907033 907005 X 907003 907001 932403 932407 931503 362405 362401 372201

Macron* Equivalent
303208 303204 V19314 244019 244008 244004 444008 444004 499208 499219 344210 84812 84810 518919 518908 H61314 524002 524004 302410 X 301606 301608 301604 488108 488119 487910 758106 758112 770810

500mL C298500 4L 20L 4L 1L 4L 20L 4L 500mL 100mL 500mL 4L 4L 1L 4L 500mL 4L 20L 4L 3kg 500g 500g E1454 E14520 E1954 E1381 E1384 H29220 H2924 A144500 H325100 H325500 A412SK4 A412P4 A4121 A4124 A412500 D374 D3720 D1434 S2713 S271500 S318500

Certified
Description
Buffer solution, pH 7.00, color-coded yellow, certified Buffer solution, pH 10.00, color-coded blue, certified Buffer solution, pH 4.00, color-coded red, certified

Pack Size

Fisher Scientific Cat. No.

EMD Millipore Equivalent

BX16321 BX16411 BX16281

Sigma Equivalent
223565 223573 223557

JT Baker Equivalent
565601 565501 565701

Macron Equivalent
9804 9904 9704

500mL SB107500 500mL SB115500 500mL SB101500

Laboratory Grade
Description
Buffer Solution, Total Ionic Strength Adjustment Buffer (TISAB II) Iodine (Iodine-Iodide) Solution, 0.1 N Methanol, laboratory Perchloric Acid Solution, 0.1 N Potassium Iodide Solution 10% w/v

Pack Size
20L 4L 4L 4L 20L

Fisher Scientific Cat. No.

SB175-20 SI86-4 A4114 SP339-4 SP242-20

EMD Millipore Equivalent

X X X X X

Sigma Equivalent
318981-500ML X 319228-2L X

JT Baker Equivalent
X X X X

Macron Equivalent
X X H60310 X X

89466-500ML X

Products might not be available in all regions. Contact your local sales representative for details.

To order, please call 1-800-766-7000.

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Fisher BioReagents*: Purity Grades for Every Application

Material Grade
Analytical Grade Certified Certified ACS Certified ACS Plus DNA Grade DNA Synthesis Electrophoresis Genetic Analysis Grade HPLC IEF Grade Islet Isolation Grade Molecular Biology Grade Molecular Genetics PCR Grade Peptide Synthesis Protein Electrophoresis Grade Sequencing Super Pure Tissue Culture Grade

Definition
Designates reagents suitable for use in analytical procedures. Reagent chemicals for which the purity standard is established by Fisher Chemical*. Purity is guaranteed to meet published maximum limits of impurities. Reagent chemicals that meet or exceed the latest ACS specifications. Acids which meet or exceed the latest ACS specifications, and analyzed for more than 16 metals. Designates reagents suitable for use in Molecular Biology applications involving the manipulation of DNA. Tested for specific contaminants such as DNase and protease. Designates reagents suitable for use with automated DNA synthesis instrumentation. Material used specifically for electrophoresis applications. Material that is specially prepared for various molecular cloning applications. Tested for specific contaminants such as DNase and RNase. Solvents manufactured specifically for use with HPLC instruments. Meet all ACS specifications. Submicron filtered. Material suitable for use with isoelectric focusing of proteins. Material suitable for isolation of pancreatic islets. Designates reagents suitable for use in Molecular Biology applications. Tested for specific contaminants such as nucleases and bacteria where appropriate. Reagent chemicals that have been specifically purified and assayed for Molecular Genetics applications. Material suitable for use in Polymerase Chain Reaction (PCR). Designates reagents suitable for use with protein synthesis instrumentation. Material used specifically for protein electrophoresis applications. Material designed for use with automated DNA or protein sequencing equipment. Material with a purity level exceeding the various monograph grades. Materials of superior quality where there are no published standards, and that are suitable for use in Tissue Culture applications.

Purity Grades for every application

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Fisher BioReagents* Stockroom Essentials

Vital Reagents for Life Science
High-purity products that meet stringent industry specifications and application requirements Pre-qualified for dedicated applications; eliminate the need for redundant testing Designed for a wide range of molecular biology, protein chemistry, cell biology and microbiology applications For more product choices and promotions, please visit www.fishersci.com/chemicals.

Fisher BioReagents
Core Bioreagents
Description
Bovine serum albumin, fraction V, heat shock treated, suitable for immunological studies Dimethyl sulfoxide Ethanol, Molecular Biology Grade Ethylenediamine tetraacetic acid, disodium salt dihydrate, crystalline powder, electrophoresis Formamide, molecular biology Formamide, super pure Glycerol, molecular biology Glycerol, molecular biology Isopropanol, Molecular Biology Grade JustPURE Ethylenediaminetetraacetic Acid Disodium Salt Dihydrate Methanol, peroxide-free, sequencing PBS Tablets Phosphate buffered saline, 10X powder concentrate, white granular powder Phosphate buffered saline, 10X solution Phosphate buffered saline, 10X solution Sodium chloride (dry basis), >99.5% Sodium chloride (dry basis), >99.5% Sodium dodecyl sulfate, white powder, electrophoresis Tris base, white crystals or crystalline powder, molecular biology Tris base, white crystals or crystalline powder, molecular biology Tris base, white crystals or crystalline powder, molecular biology Tris buffered saline, 10X Solution, pH 7.4, molecular biology Tween* 20 Tween 20 Water, Molecular Biology Grade Water, sterile, DNA grade Water, sterile, for RNA work, DEPC-treated and nuclease-free, molecular biology Water, sterile, nuclease free Water, sterile, nuclease free

Pack
100g 100mL 4L 500g 500mL 100mL 1L 4L 500mL 100g 4L 100g 2 x 1L 1L 500mL 1kg 2.5kg 500g 1kg 5kg 500g 1L 100mL 500mL 1L 1L 1L 100mL 50mL

Storage Condition
RT RT RT RT 4C 4C RT RT RT RT RT RT RT RT RT RT RT RT RT RT RT RT RT RT RT RT RT RT RT

Fisher Scientific Cat. No.

BP1600100 BP231100 BP2818-4 BP120500 BP227500 BP228100 BP2291 BP2294 BP2618-500 BP2927-100 BP11054 BP2944-100 BP6651 BP3991 BP399500 BP3581 BP358212 BP166500 BP1521 BP1525 BP152500 BP24711 BP337100 BP337500 BP2819-1 BP24701 BP5611 BP2484100 BP248450

Sigma* Equivalent
A3294-100G 34869-100ML E7023-4x4L E5134-500G F5786-250ML F9037-100ML G7893-1L G7893-4L I9516-500ML E1644-100G M1770-1L P4417-100TAB X 79378-1L 79378-1L 71379-1KG 71379-5KG L4509-500G 93362-1KG 93362-1KG 93362-250G T5912-1L P5927-100ML P5927-500ML W4502-1L W4502-1L 95289-1L 95284-100ML 95284-100ML

Invitrogen* Equivalent
15561-020 X X 15576-028 15515-026 15515-026 15514-011 15514-011 X X 0 X X 70011-044 70011-044 X X 15525-017 15504-020 15504-020 15504-020 R017R.0000 00-3005 00-3005 X 10977-015 750024 750024 750024

Bio-Rad* Equivalent
X X X X X X X X X X 0 X 31098 161-0780 161-0780 X X 161-0302 161-0719 161-0719 161-0716 170-6435 170-6531 170-6531 X 163-2091 700-7253 700-7253 700-7253

Products might not be available in all regions. Contact your local sales representative for details.

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Fisher BioReagents* (Contd.)

Protein and Nucleic Acid Electrophoresis
Description
Agarose, broad separation range for DNA/RNA, genetic analysis grade Agarose, low-EEO/multi-purpose, molecular biology grade Agarose, low-EEO/multi-purpose, molecular biology grade Ethidium bromide, 1% solution, molecular biology MES, fine white crystals Methanol, peroxide-free, sequencing Phenol, saturated, liquid, pH 6.6/7.9 TEMED, Electrophoresis TrisBorateEDTA, 10X solution, electrophoresis

Pack
100g 100g 500g 10mL 100g 4L 400mL 20g 1L

Storage Condition
RT RT RT RT RT RT 4C RT RT

Fisher Scientific Cat. No.

BP1356100 BP160100 BP160500 BP130210 BP300100 BP11054 BP1750I400 BP15020 BP13331

Sigma* Equivalent
A9539-100G A6013-100G A6013-500G E1510-10ML M3671-50G M1770-1L P4557-400ML T9281-25ML T4323-1L

Invitrogen* Equivalent
15510-019 X X 15585-011 X X 15513-047 X 15581-044

Bio-Rad* Equivalent
161-3101 161-3101 161-3102 161-0433 X X X X 161-0733

Cell and Tissue Culture

Description
Agar, granulated Ampicillin Sodium Salt, crystalline powder CellPURE* PBS 10X, Cell Culture Grade D-Sucrose, molecular biology Glycine, white crystals or crystalline powder Glycine, white crystals or crystalline powder Glycine, white crystals or crystalline powder Isopropyl-8-D-thiogalactopyranoside, dioxane-free Kanamycin Sulfate, white powder LB Agar, Miller (Granulated) LB Agar, Miller (Granulated) LB Agar, Miller (Granulated) LB Broth, Miller (Granulated) LB Broth, Miller (Granulated) LB Broth, Lennox (Granulated) LB Broth, Lennox (Granulated) LB Broth, Lennox, (Powder) LB Broth, Miller, (Powder) LB Broth, Miller, (Powder) Phosphate Buffered Saline, 10X solution Puromycin Dihydrochloride Rapamycin SOB Broth (Capsules) Tryptone Tryptone (Granulated) Tryptone (Granulated) Vancomycin Water, Microbial Cell Culture Grade Yeast Extract Yeast Extract (Granulated) Yeast Extract (Granulated)

Pack
500g 25g 4L 1kg 1kg 5kg 500g 1g 5g 500g 2kg 500g 2kg 500g 2kg 500g 500g 500g 2kg 4L 100mg 1mg 500g 500g 2kg 500g 1g 500mL 500g 2kg 500g

Storage Condition
RT 4C RT RT RT RT RT 4C RT RT RT RT RT RT RT RT RT RT RT RT RT RT RT RT RT RT RT RT RT RT RT

Fisher Scientific Cat. No.

BP1423500 BP176025 BP2940-4 BP2201 BP3811 BP3815 BP381500 BP17551 BP9065 BP9724-500 BP9724-2 BP1425500 BP9723-2 BP9723-500 BP9722-2 BP9722-500 BP1427500 BP1426500 BP14262 BP3994 BP2956-100 BP2963-1 BP9737-500 BP1421500 BP9726-2 BP9726-500 BP2958-1 BP2820-500 BP1422500 BP9727-2 BP9727-500

Sigma Equivalent
A1296-500G A0166-5G P5493-4L S0389-1KG 50052-1KG 50052-5KG 50052-1KG I6758-1G K3763-5G L3147-1KG L3147-1KG L3147-1KG L1900-1KG L1900-1KG L7658-1KG L7658-1KG 28713-500G-F L3522-1KG L3522-1KG 79378-1L P7255-100MG R0395-1MG H8032-500G T7293-1KG T2559-1KG T2559-1KG V1764-1G W3500-500ML Y4250-500G Y1626-1KG Y1626-1KG

Invitrogen Equivalent
30391-023 11593-027 X 15503-022 15527-013 15527-013 15527-013 I-6621 11815-024 X X X X X X X 22700-025 12795-027 12795-084 70011-069 X X X X X X X X X X X

Bio-Rad Equivalent
X 166-0407EDU X 161-0720 161-0718 161-0724 161-0718 X X X X X X X X X X #REF! X 161-0780 X X X X X X X X 64343 X X

Immunodetection
Description
Bovine serum albumin, fraction V, cold-ethanol precipitated

Pack
100g

Storage Condition
RT

Fisher Scientific Cat. No.

BP1605100

Sigma Equivalent
B4287-25G

Invitrogen Equivalent
11018-041

Bio-Rad Equivalent
X

Products might not be available in all regions. Contact your local sales representative for details.

To order, please call 1-800-766-7000.

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Acros Organics* Stockroom Essentials

Off-the-Shelf Products Backed by Expertise in Sourcing, Manufacturing and Technology
A leading supplier of fine chemicals, Acros Organics continues to expand its range of products and services to meet todays requirements for organic, medicinal, analytical and biological chemistry. AcroSeal* Dry Solvents and Organometallic Compounds feature: Next-generation, triple-sandwich septum, which reseals even the most aggressive solvent/reagent and enables multiple puncture points Quadrant-style cap for a tight seal between septum and bottle For a full listing of products, please visit www.acros.com.

Acros Organics
AcroSeal
Solvent
Acetonitrile, anhydrous Acetonitrile, anhydrous Chloroform, anhydrous Dichloromethane, anhydrous Dichloromethane, anhydrous Methanol, anhydrous Methanol, anhydrous Methyl Sulfoxide, anhydrous Methyl Sulfoxide, anhydrous N,N-Dimethylformamide, anhydrous N,N-Dimethylformamide, anhydrous Tetrahydrofuran, anhydrous Tetrahydrofuran, anhydrous Tetrahydrofuran, stabilized, anhydrous Tetrahydrofuran, stabilized, anhydrous Toluene, anhydrous Toluene, anhydrous

Purity
99.9%, Extra Dry 99.9%, Extra Dry Extra Dry Extra Dry Extra Dry 99.8%, Extra Dry 99.8%, Extra Dry 99.7%, Extra Dry 99.7%, Extra Dry 99.8%, Extra Dry 99.8%, Extra Dry 99.9%, Extra Dry 99.9%, Extra Dry 99.9%, Extra Dry 99.9%, Extra Dry 99.8%, Extra Dry 99.8%, Extra Dry

Quantity
1L 100mL 100mL 1L 100mL 1L 100mL 1L 100mL 1L 100mL 1L 100mL 1L 100mL 1L 100mL

Packaging
Amber Glass Amber Glass, Safe-Cote* Amber Glass Amber Glass Amber Glass, Safe-Cote Amber Glass Amber Glass, Safe-Cote Amber Glass Amber Glass, Safe-Cote Amber Glass Amber Glass, Safe-Cote Amber Glass Amber Glass, Safe-Cote Amber Glass Amber Glass, Safe-Cote Amber Glass Amber Glass, Safe-Cote

Fisher Scientific Cat. No.

AC610220010 AC610961000 AC610281000 AC610300010 AC610931000 AC610400010 AC610981000 AC610420010 AC610971000 AC610320010 AC610941000 AC610450010 AC610921000 AC610900010 AC610911000 AC610460010 AC610951000

Sigma* Equivalent
271004 271004 372978 270997 270997 322415 322415 276855 276855 227056 227056 401757 401757 186562 186562 244511 244511

Deuterated Solvents
Solvent
Chloroform-d, 99.6+ atom % D Chloroform-d, 99.8+ atom % D, contains 0.03 v/v% TMS Chloroform-d, 99.8 atom % D, contains 1 v/v% TMS Chloroform-d, 99.8 atom % D, contains 1 v/v% TMS Chloroform-d, 99.8 atom % D Chloroform-d, 99.8 atom % D Deuterium Oxide, 99.8 atom % D Methanol-d4, packaged in 0.75mL ampules, 99.8 atom % D Methyl sulfoxide-d6, 99.5+ atom % D Methyl Sulfoxide-d6, 99.9+ atom % D

Purity
For NMR For NMR For NMR For NMR For NMR For NMR For NMR For NMR For NMR For NMR

Quantity
100mL 100mL 100mL 50mL 100mL 50mL 100mL 10 x 0.75mL

Packaging
Amber Glass Amber Glass Amber Glass Amber Glass Amber Glass Amber Glass Amber Glass .75 Ampules

Fisher Scientific Cat. No.

AC174881000 AC209561000 AC166261000 AC166260500 AC166251000 AC166250500 AC166301000 AC320750075 AC321290100 AC320770075

Sigma Equivalent
151823 225789 151831 151831 181823 151823 617385 441384 175943 441392

10g Amber Glass 10 x 0.75mL .75 Ampules

Products might not be available in all regions. Contact your local sales representative for details.

To order, please call 1-800-766-7000.

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Acros Organics* (Contd.)

Ethanol
Solvent
Ethanol, absolute, 200 proof, ACS reagent Ethanol, 190 proof, for spectroscopy ACS Ethanol, 190 proof, for spectroscopy ACS Ethanol, absolute, 200 proof, ACS reagent Ethanol, absolute, 200 proof, ACS reagent Ethanol, absolute, 200 proof, ACS reagent Ethanol, anhydrous, 200 proof Ethanol, anhydrous, 200 proof Ethanol, denatured, for HPLC

Quantity
4L 4L 1L 500mL 1L 2L 100mL 2L 4L

Packaging
Amber Glass Amber Glass Amber Glass Amber Glass Amber Glass Amber Glass Amber Glass Amber Glass Amber Glass

Fisher Scientific Cat. No.

AC615090040 AC615110040 AC615110010 AC615095000 AC615090010 AC615090020 AC615101000 AC615100020 AC611050040

Sigma* Equivalent
X X X X X X 459836 459836 X

Organometallic and Reactive

Solvent
Boron Trichloride, stab., 1M sol. in methylene chloride Diisobutylaluminium Hydride, 1M solution in hexane Diisobutylaluminium Hydride, 20% wt. solution in toluene, 1.2M Lithium aluminium Hydride, 1M solution in THF Lithium Diisopropylamide, 2M solution in THF/n-heptane/ethylbenzene Lithium Triethylborohydride, 1M solution in THF Methyllithium, 1.6M solution in diethyl ether ( 5% w/v) n-Butyllithium, 1.6M solution in hexanes n-Butyllithium, 1.6M solution in hexanes n-Butyllithium, 2.5M solution in hexanes n-Butyllithium, 2.5M solution in hexanes sec-Butyllithium, 1.3M solution in cyclohexane/hexane (92/8) tert-Butyllithium, 1.6M solution in pentane

Quantity
100mL 100mL 100mL 100mL 100mL 100mL 100mL 100mL 800mL 100mL 800mL 100mL 100mL

Packaging
Amber Glass, AcroSeal* Amber Glass, AcroSeal Amber Glass, AcroSeal Amber Glass, AcroSeal Amber Glass, AcroSeal Amber Glass, AcroSeal Amber Glass, AcroSeal Amber Glass, AcroSeal Amber Glass, AcroSeal Amber Glass, AcroSeal Amber Glass, AcroSeal Amber Glass, AcroSeal Amber Glass, AcroSeal

Fisher Scientific Cat. No.

AC176681000 AC183791000 AC201081000 AC199491000 AC268831000 AC176991000 AC188751000 AC181271000 AC181278000 AC213351000 AC213358000 AC187541000 AC181281000

Sigma Equivalent
178934 190306 192724 212776 361798 179728 197343 186171 186171 X X X 186198

Products might not be available in all regions. Contact your local sales representative for details.

Fisherbrand* Products Offer Excellent Quality and Value for Your Lab!
When making buying decisions, look for Fisherbrand products for quality, reliability and value. With a portfolio of over 10,000 products in 126 product categories and more than 100 years of experience in serving the scientific community, you can trust Fisher Scientific to have the products you need, when you need them.

Fisherbrand Premium and Recycled Delicate Task Wipers

The Fisherbrand Delicate Task Wipers are a piece of tissue made with 100% virgin fiber used to clean without damaging delicate surfaces, parts and equipment. This three-tier product offering includes: Fisherbrand Premium Plus, Fisherbrand Premium and Fisherbrand Recycled Delicate Task Wipers. Top-selling Fisherbrand Wipers Cat. Nos.: 07-301-003 07-301-004 07-301-005

Fisherbrand Glassware
The Fisherbrand Reusable Glassware portfolio includes beakers, graduated cylinders, volumetric flasks, Erlenmeyer flasks, boiling flasks, filter flasks, funnels, media bottles and test tubes! All products meet ASTM* specifications and come in a variety of sizes to support daily use in every laboratory. Several top-selling Fisherbrand Glassware Cat. Nos. including: FB100-250 (Beaker) Also available from Fisherbrand: Balances, Hotplates, Pipets, Scoops, Spatulas, Vials, Weigh dishes and more! Visit www.fishersci.com/fisherbrand for a complete listing of our Fisherbrand product offering FB201-250 (Round bottom flask)

10

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Chemical Storage/Handling Recommendations

Chemical Incompatibility
Chemicals should react in the lab, not in the stockroom. The inadvertent mixing of inventory can produce toxic vapor/gas, fire or explosion. Stay safe in the storeroom; adhere to the following prescribed precautions and consult the chemical compatibility tables (below) for caustic combinations. For product-specific information, refer to the Material Safety Data Sheet (MSDS) provided with purchase.

Acids and Bases

Isolate acids: From reactive metals, including sodium, potassium and magnesium From sodium cyanide, iron sulfide, calcium carbide and other compounds that can react to produce toxic fumes/gases Place combustible organic carboxylic acids (i.e., acetic acid) in a flammable storage locker; store inorganic acids in acid storage cabinets Store acids and bases in air-tight containers with snug-fitting caps; avoid loose lids or glass stoppers; use vented caps when necessary to prevent over-pressurization Keep piranha etch and aqua regia in a fume hood at all times Use non-aluminum drip trays for aqueous sodium and potassium hydroxide solutions; isolate nitric acid when utilizing secondary containment Safely transfer containers of acid and base solutions using bottle carriers Never pour water into acid; slowly add the acid to the water and stir

General Guidelines
Protect eyes and skin: lab safety glasses with side shields, lab coats and closed-toe shoes must be worn for basic personal protection Safely space shelves and racks to accommodate the upright removal of the largest chemical container; prevent tipping and dripping with adequate clearance Identify and substitute safer chemical alternatives Keep hazardous materials away from heat and direct sunlight to prevent the degradation of chemicals and deterioration of storage containers and labels Do not store hazardous materials (except cleaners) under sinks Avoid chemical stockpiling; procure hazardous materials as needed Limit fume hood storage of hazardous materials Conduct periodic cleanouts to minimize accumulation of chemicals Keep all food (including gum), beverages, tobacco and open cosmetics outside the work area

Flammable and Combustible Liquids

Store flammable and combustible liquids away from oxidizers and heat producers House flammable and combustible liquids in excess of 10 gallons (per room) in approved flammable storage cabinets (under the hood or stand-alone); limit liquids in secondary containers (i.e., squeeze bottles) to 10 gallons or less Adhere to OSHA regulations for safe storage: 60 gallons of Class I and/or Class II liquids or 120 gallons of Class III liquids per cabinet; Class I liquids cannot be stored in a basement or pit without an approved ventilation system Use only approved and well-labeled refrigerators and freezers for storing flammable liquids; never store lunch with science

Incompatibilities by Hazard Class

Acids, Inorganic
Acids, inorganic Acids, oxidizing Acids, organic Alkalis (bases) Oxidizers Poisons, inorganic Poisons, organic Water-reactives Organic solvents X X X X X X X X X X X X X X X X X X X X X X X X X X

Acids, Oxidizing

Acids, Organic
X X

Alkalis Oxidizers (Bases)

X X X X

Poisons, Poisons, Inorganic Organic

X X X X X X X X X

WaterReactives
X X X X X X

Organic Solvents
X X X X X

X indicates incompatibility between two chemical product groups. Incompatible products should not be stored in close proximity.

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11

Chemical Incompatibilities
Chemical
Acetic acid Acetone Acetylene Alkali metals Ammonia, anhydrous Ammonium nitrate Aniline Arsenic materials Azides Bromine Calcium oxide Carbon (activated) Carbon tetrachloride Chlorates Chromic acid and chromium trioxide Chlorine Chlorine dioxide Copper Cumene hydroperoxide Cyanides Flammable liquids Hydrocarbons Hydrocyanic acid Hydrofluoric acid Hydrogen peroxide Hydrogen sulfide Hypochlorites Iodine Mercury Nitrates Nitric acid (concentrated) Nitrites Nitroparaffins Oxalic acid Oxygen Perchloric acid Peroxides, organic Phosphorus (white) Potassium Potassium chlorate and perchlorate Potassium permanganate Selenides Silver Sodium Sodium nitrite Sodium peroxide Sulfides Sulfuric Acid Tellurides

Store Separately From

Chromic acid, nitric acid, perchloric acid, peroxides, permanganates and other oxidizers Concentrated nitric and sulfuric acid mixtures, and strong bases Chlorine, bromine, copper, fluorine, silver, mercury Water, carbon tetrachloride or other chlorinated hydrocarbons, carbon dioxide, halogens Mercury, chlorine, calcium hypochlorite, iodine, bromine, hydrofluoric acid Acids, metal powders, flammable liquids, chlorates, nitrites, sulfur, finely divided organic or combustible materials Nitric acid, hydrogen peroxide Any reducing agent Acids Ammonia, acetylene, butadiene, butane, methane, propane (or other petroleum gases), hydrogen, sodium carbide, turpentine, benzene, finely divided metals Water Calcium hypochlorite, all oxidizing agents Sodium Ammonium salts, acids, metal powders, sulfur, finely divided organic or combustible materials Acetic acid, naphthalene, camphor, glycerol, glycerin, turpentine, alcohol, flammable liquids in general Same as Bromine Ammonia, methane, phosphine, hydrogen sulfide Acetylene, hydrogen peroxide Acids, organic or inorganic Acids Ammonium nitrate, chromic acid, hydrogen peroxide, nitric acid, sodium peroxide, halogens Fluorine, chlorine, bromine, chromic acid, sodium peroxide Acids Ammonia, aqueous or anhydrous bases and silica Copper, chromium, iron, most metals or their salts, alcohols, acetone, organic materials, aniline, nitromethane, flammable liquids Fuming nitric acid, other acids, oxidizing gases, acetylene, ammonia (aqueous or anhydrous), hydrogen Acids, activated carbon Acetylene, ammonia (aqueous or anhydrous), hydrogen Acetylene, fulminic acid, ammonia Sulfuric acid Acetic acid, aniline, chromic acid, hydrocyanic acid, hydrogen sulfide, flammable liquids, flammable gases, copper, brass, any heavy metals Acids Inorganic bases, amines Silver, mercury Oils, grease, hydrogen; flammable liquids, solids, or gases Acetic anhydride, bismuth and its alloys, alcohol, paper, wood, grease and oils Acids (organic or mineral), avoid friction, store cold Air, oxygen, alkalis, reducing agents Carbon tetrachloride, carbon dioxide, water Sulfuric and other acids, alkali metals, magnesium and calcium Glycerin, ethylene glycol, benzaldehyde, sulfuric acid Reducing agents Acetylene, oxalic acid, tartaric acid, ammonium compounds, fulminic acid Carbon tetrachloride, carbon dioxide, water Ammonium nitrate and other ammonium salts Ethyl or methyl alcohol, glacial acetic acid, acetic anhydride, benzaldehyde, carbon disulfide, glycerin, ethylene glycol, ethyl acetate, methyl acetate, furfural Acids Potassium chlorate, potassium perchlorate, potassium permanganate (or compounds with similar light metals: sodium, lithium, etc.) Reducing agents

(From Manufacturing Chemists Association, Guide for Safety in the Chemical Laboratory, pp. 215217, Van Nostrand)

12

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Hazards Ahead Take Care

Red Flammability
Blue Health Yellow Reactivity

NFPA Hazard Code Ratings

The National Fire Protection Association has developed a numerical rating system that reflects the health, flammability, self-reactivity and other hazards of materials, including reaction with water, as specified in NFPA 704, Standard System for the Identification of the Hazards of Materials for Emergency Response. Potential hazards are evaluated based on the degree of hazard, and the numerical rating is placed inside the universal NFPA symbol. (Included on all Fisher Chemical* labels)

White Special Warnings

Health

Reactivity

Health Hazards
4 3 2 Very short exposure to material can cause death or major residual injury even if prompt medical treatment is given. Short exposure to material can cause serious temporary or residual injury even if prompt medical treatment is given. Intense or continued exposure to material can cause temporary incapacitation or possibly residual injury unless prompt medical treatment is given. Exposure to material will cause irritation but only minor residual injury, even if no treatment is given. Exposure to materials under fire conditions will offer no hazard beyond that of ordinary combustible materials. 4 3

Reactivity
Material is readily capable of detonation, explosive decomposition or instability at normal temperatures and pressures. Material is capable of detonation or explosive reaction but requires a strong initiating source; or which must be heated under confinement before initiation; or may react explosively with water. Material is normally unstable and readily undergoes violent chemical change but does not detonate. Also may react violently with water or may form potentially explosive mixtures with water. Material is normally stable but can become unstable at elevated temperatures and pressures or may react with water with some release of energy, but not violently. Material is normally stable even under fire exposure conditions, and is not reactive with water.

1 0

Flammability

Flammability
4 Material will rapidly or completely vaporize at atmospheric pressure and normal ambient temperature, or will burn readily when dispersed in air. A liquid or solid that can be ignited under almost all ambient temperature conditions. Material that must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur. Material that must be preheated before ignition can occur. Material that will not burn.

Special Warnings

Special Warnings
0X W Oxidizing material Material is hazardous when in contact with moisture or water.

3 2 1 0

Examples:
2

1,1,1-Trichloroethane

Isopropyl ether

2 Calcium
Picric acid, wet, with not less than 10% water

Benzene

Acetic acid, glacial

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13

Whats On the Label? Safety Guidelines!

2
Caution! May cause eye, skin, and respiratory tract irritation. FIRST AID: EYES: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. SKIN: Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. INGESTION: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. INHALATION: Remove from exposure and more to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. IMPORTANT! Do not use this product until Material Safety Data Sheet has been read and understood. Avoid contact with skin and eyes. viter le contact avec la peau et les yeux. Berhrung mit den Augen und der Haut vermeiden. Aanraking met de ogen en de huid vermijden. Evitare il contaatto con gli occhi e con la pelle.
Product of United States
DNase, RNase and Protease-Free Filtered Through a 0.2 Micron Filter 1X Solution. pH 7.40.1 Contains: 11.9mM Phosphates. 137mM Sodium Chloride and 2.7mM Potassium Chloride CAS 7732-18-5 Water CAS 7447-40-7

Buffered Saline, 10X Solution

Recd / / Opened / /

5 Phosphate

4L BP399-4

11

CAS 7647-14-5 Sodium chloride CAS 7558-79-4

Potassium chloride Sodium phosphate dibasic CAS 7778-77-0 Potassium phosphate monobasic

LOT 091697

For laboratory and manufacturing use only. Not for drug, food, or household use.

12

Fisher BioReagents

ChemAlert

M-5402 EU-971

1 0

Storage Code Gray

S24/25

8
Fair Lawn, New Jersey 07410 Tel. (201) 796-7100 Fax. (201) 796-7102 www.fishersci.com

do not transfer to an unmarked container

6 1
The bar code is an alphanumeric code widely used by industry for inventory and tracking control. This three-of-nine code meets the Health Industry Bar Code (HIBC) Supplier Labeling Standard as prepared by the Health Industry Business Communication Council (HIBCC). This area contains the appropriate precautionary signal word, i.e., DANGER, WARNING, CAUTION, and highlights the potential health hazards, both acute and chronic, of the product. In this area product composition is listed along with the product Chemical Abstract Service (CAS) Registry Number and lot number. The Maximum Limits of Impurities are indicated. The full Product Name and Purity Grade are listed. ChemAlert Guide: A three-part guide that provides the Safety Code, the NFPA Code and a Storage Code.

10 7
NFPA Code: The National Fire Protection Association (NFPA) ratings provide information relating to the severity of health, flammability, reactivity, and related hazards that may be presented by shortterm, acute exposure to material during handling under emergency conditions such as spills, leaks, and fires. Each section displays a numerical severity rating from four (most severe) to zero (least severe). The fourth section, as stipulated by NFPA, is left blank and is reserved for indicating any unusual reactivity with water or oxidizing properties. Storage Code: This color-coded bar provides an instant guide to storage. The storage code is also spelled out for clarification. The five storage colors and their descriptions are listed below. The catalog number is shown for identification and reference. The address and telephone number of the manufacturer, Fisher Chemical, is listed. Package Size: The amount of material per unit or case. Lot Number

2 3 4 5 6

8 9 10 11 12

NOTE: ChemAlert is an instant guide only. It should be supplemented by reading the rest of the label (which provides detailed instructions in the event of accidental exposure, spill or fire, and applicable OSHA, DOT and ANSI* data), the appropriate Material Safety Data Sheet (MSDS) and standard references.

ChemAlert storage codes provide guidelines

Red (R): Flammable. Store in area segregated for flammable reagents. Blue (B): Health hazard. Toxic if inhaled, ingested or absorbed through skin. Store in secure area. Yellow (Y): Reactive and oxidizing reagents. May react violently with air, water or other substances. Store away from flammable and combustible materials. White (W): Corrosive. May harm skin, eyes, mucous membrane. Store away from red-, yellow- and blue-coded reagents. Gray (G): Presents no more than moderate hazard in any of the categories above. For general chemical storage.
Exception: Reagent incompatible with other reagents of the same color bar. Store separately.

14

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All Plastics Are Not Created Equal

Differentiating between glass and plastic for chemical storage is fairly intuitive; selecting the most compatible plastic, well, thats another story. Labware is constructed from a variety of polymers polyethylene (low and high density), polypropylene, PVC, etc. possessing unique and varying degrees of resistance to the laundry list of chemicals. To maintain the structural integrity of the chemical containers and ensure safe handling, please consult the chemical resistance tables before transferring materials.

Chemical Resistance and Physical Properties of Plastics

Resin Codes
ECTFE:  Ethylene- chlorotrifluoroethylene copolymer ETFE: Ethylenetetrafluoroethylene FEP:  Fluorinated ethylene propylene FLPE:  Fluorinated high-density polyethylene FLPP: Fluorinated polypropylene HDPE: High-density polyethylene LDPE: Low-density polyethylene NYL: Nylon (polyamide) PPCO: Polypropylene copolymer PC: Polycarbonate PETG:  Polyethylene terephthalate copolyester PK: Polyketone PFA: Perfluoroalkoxy PMMA: Polymethyl methacrylate PMP: Polymethylpentene PP: Polypropylene PS: Polystyrene PSF: Polysulfone PTFE: Polytetrafluoroethylene PUR: Polyurethane PVC: Polyvinyl chloride PVDF: Polyvinylidene fluoride TPE: Thermoplastic elastomer XLPE:  Cross-linked high-density polyethylene Do not store strong oxidizing agents in plastic labware except if made of FEP, PFA or PTFE. Other plastics will become brittle after prolonged exposure. Do not place plastic labware directly in a flame or on a hotplate unless specified. Use these charts as a reference only. They are recommendations, not guarantees, of fitness for particular uses. Test materials under actual conditions before using them for your applications.

Chemical Resistance Summary

FEP/PTFE/PFA ECTFE/ETFE HDPE/XLPE PP/PPCO

E No damage after 30 days of constant exposure. PMMA G Little or no damage after 30 days of constant exposure. F Some effect after seven days of constant exposure. Depending on the plastic, the effect may be cracking, crazing, loss of strength or discoloration. Solvents may cause softening, swelling and permeation losses with PPCO, PP, PMP, LDPE and HDPE; the solvent effects on these materials are normally reversible. N Not recommended for continuous use. Immediate damage may occur. Depending on the plastic, the effect will be severe cracking, crazing, loss of strength, discoloration, deformation, dissolution or permeation loss.

PETG

Classes of substances; temperature 68F (20C)

Acids, weak or dilute Acids, strong or concentrated Alcohols, aliphatic Aldehydes Bases Esters Hydrocarbons, aliphatic Hydrocarbons, aromatic Hydrocarbons, halogenated Ketones Oxidizing agents, strong

PVDF
E E E E E G E E N N G

LDPE

PMP

FLPE

E G E E E E E E E G F

E E E E E E E E E E E

E E E G F E E E G E F

E E E G E G G G F G F

E E E G E G F F N G F

F N N F F E E E G E N

E N G F N N F N N N N

E N E N N N E N N N N

E G G E G E E E E E G

G N N G F N G N N N N

E E E G E G F F N F F

E E E G E G G F F G F

E F E N E N N N N N N

E G G F E N G N N N G

G F F G N N E N N N N

E E E N E N E N N N G

For oxidizing acids, see table entry Oxidizing agents, strong. TPE gaskets

New Poly Packaging for Fisher Chemical* TraceMetal Grade Acids and Bases
Selected TraceMetal Grade Acids and Bases are now available in poly bottles. Constructed with a new, high-density polyethylene made from a proprietary resin the innovative bottles provide up to 80% less metallic extractables (vs. glass).

Packaging Advantages
Poly bottles are lighter, easier to handle and less likely to break during transport FisherLOCK* tamper-evident cap safeguards chemicals; drip lip feature prevents spills when pouring 100% recyclable package reduces waste and all-poly bottle facilitates disposal (no PVC coating to be removed) Poly bottles occupy less space than glass bottles and enable better storage space utilization in the lab
A508-P500 and A508-P212

TPE
E F E N E N N N N N N

PUR

PVC

NYL

PSF

PC

PK

PS

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15

Chemical Resistance of Labware Materials

Use This Chart as a General Guide Only. Test each chemical before storing in labware. The first letter of each pair represents the resistance rating at 20C; the second at 50C. E No damage after 30 days of constant exposure. G Little or no damage after 30 days of constant exposure. F Some effect after 7 days of constant exposure. Depending on the material, the effect may be cracking, crazing, loss of strength or discoloration. Solvents may cause softening, swelling, and permeation losses with PA, PP, PMP, LDPE and HDPE; the solvent effects on these mate rials are normally reversible. N Not recommended for continuous use. Immediate damage may occur. Depending on the material, the effect will be severe cracking,c razing, loss of strength, discoloration, deformation, dissolution or permeation loss.
E H DP E PP /P PC

CHEMICAL
Acetaldehyde Acetamide, sat. Acetic acid, 5% Acetic acid, 50% Acetone Acetonitrile Acrylonitrile Adipic acid Alanine Allyl alcohol Aluminum hydroxide Aluminum salts Amino acids Ammonia Ammonium acetate, sat. Ammonium glycolate Ammonium hydroxide, 5% Ammonium hydroxide, 30% Ammonium oxalate Ammonium salts n-Amyl acetate Amyl chloride Aniline Benzaldehyde Benzene Benzoic acid, sat. Benzyl acetate Benzyl alcohol Bromine Bromobenzene Bromoform Butadiene n-Butyl acetate n-Butyl alcohol sec-Butyl alcohol tert-Butyl alcohol Butyric acid Calcium hydroxide, conc. Calcium hypochlorite, sat. Carbazole Carbon disulfide Carbon tetrachloride Cedarwood oil Cellosolve acetate Chlorine, 10% in air Chlorine, 10% (moist) Chloroacetic acid p-Chloroacetophenone Chloroform Chromic acid, 10% Chromic acid, 50% Cinnamon oil Citric acid, 10% Cresol Cyclohexane DeCalin o-Dichlorobenzene p-Dichlorobenzene Diethyl benzene Diethyl ether Diethyl ketone Diethyl malonate Diethylene glycol Diethylene glycol ethyl ether Dimethyl formamide Dimethylsulfoxide 1,4-Dioxane Dipropylene glycol Ether Ethyl acetate Ethyl alcohol (absolute) Ethyl alcohol, 40% Ethyl benzene Ethyl benzoate Ethyl butyrate Ethyl chloride, liquid Ethyl cyanoacetate Ethyl lactate Ethylene chloride Ethylene glycol Ethylene glycol methyl ether Ethylene oxide Fluorides Fluorine Formaldehyde, 10%

FE P/ PT FE /P E FA CT FE / ET FE P C

Effects of Chemicals on Labware

Chemicals may affect the weight, strength, color, dimensions, flexibility and surface appearance of labware. The basic models of interaction that cause these changes are: (1) chemical attack on the polymer chain, with resultant reduction in physical properties, including oxidation; reaction of functional groups in or on the chain; and depolymerization; (2) physical change, including absorption of solvents, resulting in softening and swelling of the plastic; permeation of solvent through the plastic; or dissolution in a solvent; and (3) stress-cracking from the interaction of a stress-cracking agent with molded-in or external stresses. The reactive combination of compounds of two or more classes may cause a synergistic or undesirable chemical effect. Other factors affecting chemical resistance include: temperature, pressure, internal or external stresses (such as centrifugation), and length of exposure to and concentration of the chemical. As temperature increases, resistance to attack decreases. Warning!
Do not store strong oxidizing agents in plastic containers except those made of Teflon* FEP, PFA or PTFE. Other plastics will become brittle after p rolonged exposure.

GN EE EE EE NN EE EE EG EE EE EG EE EE EE EE EG EE EG EG EE GF NN EG EG FN EE EG NN NN NN NN NN GF EE EG EG NN EE EE EE NN FN NN EG GN GN EE EE FN EE EE NN EE NN FN GF FN FN NN NN NN EE EE EE EE EE GF EE NN EE EG EG FN FF GN FN EE EE GN EE EE FF EE FN EE

GF EE EE EE NN EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EG FN EG EE NN EE EE FN FN FN NN FN EG EE EE EE FN EE EE EE NN GF FN EE EF GF EE EE FN EE EE FN EE FN FN EG FF GF FN FN NN EE EE EE EE EE GG EE FN EE EE EE GF GG GF FF EE EE GF EE EE GF EE GN EE

GN EE EE EE EE FN FN EE EE EE EG EE EE EE EE EG EE EG EG EE GF NN GF EG GF EG EG NN NN NN NN NN GF EE EG EG NN EE EE EE NN GF NN EG GN FN EG EE GF EE GF NN EE GF FN GF FN GF NN NN GG EE EE EE EE EE GF EE NN EE EG EG FN GF GN FN EE EE FN EE EE FF EE FN EE

GN EE EE EE EE FN FN EE EE EG EG EE EE EE EE EG EE EG EG EE GF NN GF EG GF EG EG NN NN NN NN NN GF EG EG EG NN EE EG EE NN NN NN EG GN GN EG EE NN EE GF NN EE NN NN FN FN GF NN NN GF EG EE EE EE EE GF EE NN FN EG EG FN GF FN FN EE EE NN EE EE FN EE FN EG

EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EG EE

GF EE EE EG GF EE EG EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE GN EF EG EE EG EE EG GN GF EE EG EE EE EE EE EE EE EE EF EE EG EG EE EE EE EE GF EE EE EG EE EG EG EE EF EF EG EG GF EE EE EE GG EG EF EE EG EE EE EE GF EG EG EE EE EE EE EE EE EE EE EF EE

FN NN EG EG NN NN NN EE NN GF FN EG EE NN EE GF FN NN EE EG NN NN FN FN NN EG FN NN FN NN NN NN NN GF GF GF FN NN FN NN NN NN GF FN EG GF FN NN NN GF FN GF EG NN EG NN NN NN FN NN NN FN GF FN NN NN GF GF NN NN EG EG NN NN NN NN FN FN NN GF FN FN EE GF EG

GN NN EE EG NN NN NN EG NN GF EG EE EE EG EE EE EE EG EE EG NN NN NN NN NN EG NN GF GN NN NN FN NN GF GG EG GN EE GF NN NN GF FN FN EE EG FN NN NN EG EF NN GG NN GF EG NN NN NN FN NN GN FN FN FN NN FN GF FN NN EG EE NN NN NN NN FN FN NN EE FN FN EE EG GF

NN NN EE GG NN NN NN GG NN GF GG EE EE GF EE GG GG GG EE EE NN NN NN FF NN FF NN NN NN NN NN NN NN GF GF GF GG GG EE NN NN NN FF NN NN NN NN NN NN NN NN FF EE NN NN NN NN NN NN NN NN FF GG FF NN NN GF GG NN NN EG EG NN NN NN NN FF FF NN EE FF EE EE NN GF

EE EE EE NN EE GF EE EE EE EE EE EE EE EE EE EE EE EE EF EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EG EE EE E EE EE EG EE EE EE EE EE EG NN EG EE NN NN EG NN EE EE NN NN EE NN NN EE EE EE EE EE

NN EE EG GG NN NN NN EE EE GF GG GG EE GF EE EE EF GF EE GG NN NN NN NN NN GG NN NN NN NN NN NN NN EG GG EE NN GG GF EE NN NN NN NN FN NN GN NN NN EE FF NN EG NN NN NN NN NN NN NN NN NN GG NN NN EG NN EE NN NN FN GF NN NN NN NN GN FN NN EE NN NN GG NN FN

N YL
EG EE FN NN EE EE EG EF EG NN EE NN EG FF EG GG GF FN GF NN EE EG GF EG EE NN EG NN NN EG FF FF EE NN NN NN FN NN NN EE EG EE EG EE NN NN NN EG FF NN NN GF NN NN EE EE EG EG EE EE EE EE EE EE GF EE EF EE EE EE NN NN EE EE EE GF GF EG EG EE EE EE EE NN GF

LDP

PS

EE EE EE EE EE EG EG EG EE EE GG EE EG EE EE EE EE EE EG EG GG GG EG GG GG EE GG GG GG GG EE EE EE GG GG EE EE GG GG FF FF GG EE GG FF EE GG EE EE GG GG GG GG GG EE EE EE EE GG EE GG EE EE GG EG EE GG GG GG EG EE

16

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St ai nl es sS Gl te as el s Ce ra m ic
EE EE EE EE EE EE EE EE EG NN EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EG GG EE EE EE EE EE EE EE NN EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EG EE EE EE EE EE EE EE EE EG EE EE EE EE EE EE EE GG GG EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE NN EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE

How to Use This Chart

PM P

F PS

PV

PV

DF

Chemical Resistance of Labware Materials (contd.)

FA

/E

E HDP E PP /P PC

PT

FE

nl

PM P

N YL

LDP

E CT

P S

P C

PV

PS

PV

FE

Gl a

St

Formaldehyde, 40% Formic acid, 3% Formic acid, 50% Formic acid, 98 to 100% Freon TF Fuel oil Gasoline Glacial acetic acid Glycerine n-Heptane Hexane Hydrochloric acid, 1 to 5% Hydrochloric acid, 20% Hydrochloric acid, 35% Hydrofluoric acid, 4% Hydrofluoric acid, 48% Hydrogen peroxide, 3% Hydrogen peroxide, 30% Hydrogen peroxide, 90% Isobutyl alcohol Isopropyl acetate Isopropyl alcohol Isopropyl benzene Kerosene Lactic acid, 3% Lactic acid, 85% Methoxyethyl oleate Methyl alcohol Methyl ethyl ketone Methyl isobutyl ketone Methyl propyl ketone Methylene chloride Mineral oil Nitric acid, 1 to 10% Nitric acid, 50% Nitric acid, 70% Nitrobenzene n-Octane Orange oil Ozone Perchloric acid Perchloroethylene Phenol, crystals Phosphoric acid, 1 to 5% Phosphoric acid, 85% Pine oil Potassium hydroxide, 1% Potassium hydroxide, conc. Propane gas Propylene glycol Propylene oxide Resorcinol, sat. Resorcinol, 5% Salicylaldehyde Salicylic acid, powder Salicylic acid, sat. Salt solutions, metallic Silver acetate Silver nitrate Sodium acetate, sat. Sodium hydroxide, 1% Sodium hydroxide, 50% to sat. Sodium hypochlorite, 15% Stearic acid, crystals Sulfuric acid, 1 to 6% Sulfuric acid, 20% Sulfuric acid, 60% Sulfuric acid, 98% Sulfur dioxide, liq., 46 psi Sulfur dioxide, wet or dry Sulfur salts Tartaric acid Tetrahydrofuran Thionyl chloride Toluene Tributyl citrate Trichloroethane Trichloroethylene Triethylene glycol Tripropylene glycol Turpentine Undecyl alcohol Urea Vinylidene chloride Xylene Zinc stearate

EG EG EG EG EG FN FN EG EE FN NN EE EE EE EG EE EE EG EG EE GF EE FN FN EG EE EG EE NN NN GF FN GN EE GN FN NN EE FN EG GN NN GN EE EE GN EE EE NN EE EG EE EE EG EE EE EE EE EG EE EE GG EE EE EE EE EG GG NN EE FN EE FN NN FN GF NN NN EE EE FN EF EE NN GN EE

EE EE EE EE EG GF GG EE EE GF GF EE EE EE EE EE EE EE EE EE EG EE GF GG EE EE EE EE NN NN EG FN EE EE GN GN FN EE GF EE GN NN GF EE EE EG EE EE FN EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE GG FN EE GF EE GF NN GG EG FN FN EE EE GG EG EE FN GF EE

EG EG EG EG EG EG GF EG EE FF GF EE EE EG EG EE EE EG EG EE GF EE FN GF EG EG EG EE EG GF GF FN EE EE FN NN NN EE GF EG GN NN GN EE EG EG EE EE NN EE EG EE EE EG EE EE EE EE EG EE EE EE GF EE EE EG EG FN NN EE FN EE GF NN GF GF NN NN EE EE GF EG EE NN FN EE

EG EG EG EF FN GF GF EG EE FF FN EG EG EG EG EE EE EG EG EG GF EE NN GF EG EG EG EE NN FF FF FN EG EE GN GF NN EE FF EE GN NN FG EE EG GF EE EE NN EE EG EE EE EG EG EE EE EE EE EE EE EE EE EE EE EG EG GG NN EE FN EE FF NN FF GF NN NN EE EE FF EG EG NN FN EE

EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE GF EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EG EE EE EE EE EE EE EE EE EE

EE EE EE EE EG EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EG EE EG GF EE EG EE EE GF GF EG GG EE EE EE EE EG EE EE EE EG EE EE EE EE EG EE EE EE EE FN EE EF EN EE EE EE EE EE EE EE EE EE EE EE EE EE EE EG EE EG EE GF EE EE EG NN EG EE EE EE EG EE GF EG EE

EG EG EG EF GF EG FF NN EE EG FN EE GF NN GF NN EE EE EE EG NN EE NN EE EG EG FN GF NN NN NN NN EG EG GF NN NN GF FF EG NN NN NN EE EG GF FN NN FN GF GF GF GF GF EG EG EE EG EE EG FN NN GF EG EE EG GF NN GN EG FN EG NN NN FN NN NN NN EG EG FN GF NN NN NN EE

GF GF GF FN GF EE GN EG EE GF GN EE EG GF GF GF EE EE EG EG NN EG NN EE GF GF NN EF NN NN NN NN EG EG GF FN NN FN FN EG GN NN FN EE EG FN EE EG EG FN FN FN GN FN GF GF EE GG EG GF EE NN EE EG EG EG EG GN FN EG NN EG NN NN NN FN NN NN GF GF GF EF GN NN NN EG

GF GG GG FF EG EG FF FN EE EG EG EE EE EE GF FN EE EE EE EG NN EE NN GF EE EE NN GF NN NN NN NN EE EF GF NN NN GF FF EE NN NN FF EE EE FF EE EE FF GG GG NN NN FF EE EE EE EE EE EE EE EG EE GG EE EE EE NN GG GG GG EE NN NN NN FF NN NN EE EE NN FF FF NN NN EE

EE EE EE EE EE EE EE EG EE EE EE EE EE EE EE EE EE EE EEE EE EE EG GF EE NN GN NN NN EE EE EG GF EN EE EE EE EE EE EE EE EE EE EE EG EE FN EG EE EE EE EE EE EE EE EG EE EE EE EE EE EG EE GE GF EE FN EE EF EE EE EE EE EE EE EE

NN EG FF FF FN NN NN NN EE NN NN EE EE FF GF NN EG EG EG GG NN EG NN NN GG GG NN FN NN NN NN NN EE GN NN NN NN NN NN FF GF NN NN GG EG NN GG GG NN EE NN GF GF NN EE EG GG GG GF GG GG EE EE EG EG EG GN NN NN FN NN GG NN NN NN NN NN NN EG EE NN GG EG NN NN EE

GF NN NN NN EE EE NN EE EE EE NN NN NN NN NN NN NN NN NN EE NN EG EE NN NN EG NN EE EE EE GF EE NN NN NN FF EE GF EG NN EE NN NN NN GF FF FF FF EE EE NN NN EG EG NN FF EF NN FF EE GF NN EF NN NN NN NN NN NN NN EF EE NN EE EG EE EE EE EE EE EE EE NN EE EE

EE GG GG GG EE EE EE EG EE EE EE NN NN NN NN NN GG GG GG EE GG GG EE GG GG EE EE GG EE GG EE EE EG GG GG EE EE EG FF EG GG NN NN EE EG EG GF GG EE GG GG EG GG GG GG GF NN EG FN NN NN NN FN FN FF EE NN EE GG GG EE GG GG GG EE

EE EE EE EE EE EE EE EE EE EE EE EE EE EE NN NN EE EE EE EE EE EE EE EE EE EE EE EE EE EE EE EG EE EE EE EE EE EE EE EE EE GF NN NN EE EE EE EE EE GE NN EE EE EE EE EE EE NN EE EE EE EE EE EE EE EE EE EE EE

Ce

EE EE EE EE EE EE EE EE EE EE EE EE EE EE NN EG EG EG EE EE EE EE EE EE EE EE EE EE EE EE NN NN EE EE EE EE EE EE EE EE GF NN NN EE EE EE EE EE GE NN EG EE EG GG NN NN NN EE EE EE EE EE EE EE EE EE EE EE

ra m

DF

P/

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CHEMICAL

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Warning!
The plastic resin information in these tables (does not include SS, glass or ceramic) has been provided by Thermo Scientific* Nalgene* and is reprinted with their permission. It should be used ONLY as a guide for selecting labware for testing. Test the labware for 72 hours under expected or proposed conditions of use, BEFORE putting into service. Test with care to avoid injury or property damage. Fisher Scientific does not warrant (neither express nor implied) that the information in these tables is accurate or complete.

To order, please call 1-800-766-7000.

www.fishersci.com/chemicals

17

Fisher Chemical* Solvent Safety Packaging Features

Lock in Quality and Safety
Fisher Chemical products are now packaged with the innovative, new FisherLOCK* Cap, designed to help maintain the highest standards in product quality and chemical safety practices. With an exclusive color-coded design (patent pending), the FisherLOCK Cap is engineered to lock to the transfer bead of the bottle when it is applied during manufacturing to a filled bottle of laboratory chemicals. The cap design includes an interior ring, visible from various angles, that offers resistance until it separates from the cap when the bottle is first opened. The presence and location of that ring imparts tamper evidence to the configuration without the drawbacks and complications of a plastic seal over the cap. The FisherLOCK Cap is easy to use, and supports product quality, reliability of use, and safety in use of the chemical products you purchase.

Exclusive color-coded design provides storage guidelines

Red (R): Flammable. Store in area segregated for flammable reagents. Blue (B): Health hazard. Toxic if inhaled, ingested or absorbed through skin. Store in secure area. Yellow (Y): Reactive and oxidizing reagents. May react violently with air, water or other substances. Store away from flammable and combustible materials. White (W): Corrosive. May harm skin, eyes, mucous membrane. Store away from red-, yellow- and blue-coded reagents. Gray (G): Presents no more than moderate hazard in any of the categories above. For general chemical storage.
Exception: Reagent incompatible with other reagents of the same color bar. Store separately.

The FisherLOCK Cap LOCKS in quality, safety, reliability and convenience: QUALITY
Provides a tight, tamper-evident, secure seal to ensure chemical contents arrive fresh and unopened Eliminates polyethylene glycol contamination that is possible with a plastic overseal

RELIABILITY
Rigorously tested for chemical compatibility Bottle threads are unchanged, allowing attachment of the opened bottle to standard equipment

SAFETY
Caps are designed to resist back-off during transport, reducing risk of leakage Color-coded rings indicate storage requirements and hazard categories, and enhance proper recognition, handling and storage even before the bottle is removed from the case

CONVENIENCE
Cap design facilitates correct initial torque application during manufacturing, thus eliminating caps that may be hard to open Larger ridges on the exterior of the cap make it easier to open Caps readily reseal after initial opening

18

To order, please call 1-800-766-7000.

www.fishersci.com/chemicals

For Safetys Sake:

Fisher Chemical* Products in the Safe-Cote* Bottle

These Fisher Chemical products are protected by Safe-Cote PVC bottles that provide the purity of glass and most of the benefits of plastic for storing and dispensing chemicals. If they break, glass fragments and liquids are more likely to remain trapped. q Innovative safety bottle with FisherLOCK* tamper evident cap q Convenient storing and dispensing q Packaged in the 100% recyclable Styrofoam*-free EcoSafPak*
Description 1-Butanol 1-Butanol 2-Propanol 2-Propanol 2-Propanol 2-Propanol Acetic Acid Acetic Acid Acetic Acid Acetone Acetone Acetone Acetone Acetone Acetone Acetonitrile Acetonitrile Acetonitrile Acetonitrile Acetonitrile Ammon. Hydrox. Ammon. Hydrox. Chloroform Chloroform Chloroform Chloroform Chloroform with Pentene Chloroform with Pentene Cyclohexane Cyclohexane Ethyl Acetate Ethyl Acetate Ethyl Acetate Ethyl Acetate Ethyl Alcohol Denatur Heptane Heptane Hexane Hexane Hexane Hexanes

Purity Grade HPLC/ACS HPLC/ACS Certified ACS Plus HPLC/ACS HPLC/ACS Optima Certified ACS Certified ACS Certified ACS Certified ACS HPLC HPLC HPLC HPLC/ACS Optima/ACS HPLC/ACS HPLC/ACS HPLC HPLC/ACS Optima/ACS Certified ACS Plus Certified ACS Plus HPLC/ACS Certified ACS Plus HPLC/ACS Spectranalyzed HPLC/ACS HPLC/ACS HPLC/ACS HPLC/ACS HPLC/ACS HPLC/ACS Certified ACS Plus Optima Denatured HPLC HPLC HPLC HPLC Optima/ACS Certified ACS Plus

Size 1L 4L 4L 1L 4L 4L 2.5L 2.5L 4L 1L 1L 4L 4L 4L 1L 1L 4L 4L 4L 2.5L 4L 4L 1L 4L 1L 4L 1L 4L 1L 4L 4L 4L 4L 1L 4L 1L 4L 4L 4L

Cat. No. A383SK1 A383SK4 A416SK4 A451SK1 A451SK4 A464SK4 A38SI212 A38S212 A18SK4 BP2404SK1 A949SK1 BP2404SK4 A949SK4 A929SK4 BP2405SK1 A998SK1 BP2405SK4 A998SK4 A996SK4 A669S212 C606SK4 C298SK4 C606SK1 C574SK4 C607SK1 C607SK4 C620SK1 C620SK4 E195SK1 E195SK4 E145SK4 E196SK4 A407SK4 H350SK1 H350SK4 H302SK1 H302SK4 H303SK4 H292SK4

Description Hydrochloric Acid Hydrochloric Acid Hydrochloric Acid Isooctane Isooctane Methanol Methanol Methanol Methanol Methanol Methchloride Methchloride

Purity Grade Certified ACS Plus Certified ACS Plus Certified ACS Plus HPLC/ACS HPLC/ACS Certified ACS Plus HPLC/ACS HPLC/ACS Optima/ACS HPLC HPLC

Size 2.5L 2.5L 1L 4L 4L 1L 4L 4L 1L 4L 1L 4L 4L 4L 4L 4L 4L 2.5L 2.5L

Cat. No. A144S212 A144SI212 O296SK1 O296SK4 A412SK4 A452SK1 A452SK4 A454SK4 A408SK4 D150SK1 D150SK4 D143SK1 D37SK4 D143SK4 D151SK4 D138SK4 B429SK4 H306SK4 A200S212 A200SI212 A242SK212

500mL A144S500

500mL A28S500

Scintanalyzed/ACS 4L

Methylene Chloride HPLC/ACS Methylene Chloride Certified ACS Plus Methylene Chloride HPLC/ACS Methylene Chloride Optima Methylene Chloride HPLC/ACS W/Cyclohexene N-Butyl Chloride N-Hexane95%L Nitric Acid Nitric Acid Nitric Acid O-Phospho Acid Pentane Pentane Petroleum Ether Petroleum Ether Sulfuric Acid Sulfuric Acid Sulfuric Acid Tetrahydrofuran Tetrahydrofuran Tetrahydrofuran Tetrahydrofuran Toluene Toluene Toluene Toluene Toluene Water Water Water Xylenes HPLC Optima/ACS Certified ACS Plus Certified ACS Plus Certified ACS Plus ACS HPLC HPLC Certified ACS Optima/ACS Certified ACS Plus Certified ACS Plus Certified ACS Plus Certified HPLC/ACS HPLC/ACS Optima/ACS Certified ACS HPLC/ACS HPLC/ACS Optima HPLC HPLC Optima Certified ACS

500mL A669S500

500mL A200S500 1L 4L 4L 4L 2.5L 2.5L 4L 1L 4L 4L 4L 1L 4L 4L 1L 4L 4L 4L P399SK1 P399SK4 E139SK1 E139SK4 A300S212 A300SI212 T397SK4 T425SK1 T425SK4 T427SK4 T324SK4 T290SK1 T290SK4 T291SK4 T313SK4 W5SK1 W5SK4 W7SK4 X5SK4

500mL A300S500

Scintanalyzed/ACS 4L

Products might not be available in all regions. Contact your local sales representative for details.

To order, please call 1-800-766-7000.

www.fishersci.com/chemicals

19

Global Locations
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