Cu 1. Hp cht X (cha C, H, O, N) c cng thc phn t trng vi cng thc n gin nht, va tc dng vi axit va tc dng vi kim.

Trong X, % khi lng ca cc nguyn t C, H, N ln lt bng 40,449%; 7,865% v 15,73%. Khi cho 4,45 gam X phn ng hon ton vi NaOH (un nng) c 4,85 gam mui khan. Cng thc cu to ca X l. A. CH2 = CHCOONH4. B. H2NCH2COOCH3. C. H2NCOOC2H5. D. H2NC2H4COOH. Cu 2. Dung dch metylamin khng tc dng vi cht no sau y? A. HNO2. B. Dung dch HCl. C. Dung dch FeCl3. D. Dung dch Br2. Cu 3. Dung dch cht no sau y khng lm chuyn mu qu tm? A. CH3 - CHOH - COOH. B. H2N(CH2)2CH(NH2)COOH. C. H2N - CH2 - COOH. D. C6H5NH3Cl. Cu 4. Trong cc cht sau, dung dch cht no khng lm chuyn mu qu tm? A. HOOC-CH2-CH2CH(NH2)COOH B. H2N-CH2-COOH 2 2 2 2 2 2 3 C. H N-CH CH CH CH -CH(NH )-COOH D. CH -CHOH-COOH Cu 5. Cho 8,9 gam mt hp cht hu c X c cng thc phn t C3H7O2N phn ng vi 100 ml dung dch

NaOH 1,5M. Sau khi phn ng xy ra hon ton, c cn dung dch thu c 11,7 gam cht rn. Cng thc cu to thu gn ca X l A. H2NCH2CH2COOH. B. H2NCH2COOCH3. C. HCOOH3NCH=CH2. D. CH2=CHCOONH4.
Cu 6. Hp cht khng lm i mu giy qu m l. A. CH3NH2. B. H2NCH2COOH. C. C6H5ONa. D. H2N - CH2 CH(NH2)COOH. Cu 7. 0,01 mol aminoaxit Y phn ng va vi 0,01 mol HCl c cht Z. Cht Z phn ng va vi 0,02 mol NaOH. Cng thc ca Y c dng l. A. (H2N)2R(COOH)2. B. (H2N)2RCOOH. C. H2NR(COOH)2. D. H2NRCOOH. Cu 8. Anilin v phenol u c phn ng vi: A. Dung dch NaOH. B. Dung dch NaCl. C. Dung dch Br2. D. Dung dch HCl. Cu 9. un nng cht H2N-CH2-CONH-CH(CH3)-CONH-CH2-COOH trong dung dch HCl (d), sau khi

cc phn ng kt thc thu c sn phm l: A. H2N-CH2-COOH, H2N-CH(CH3)-COOH. B. H3N+-CH2-COOHCl-, H3N+-CH(CH3)-COOHCl-. C. H3N+-CH2-COOHCl-, H3N+-CH2-CH2-COOHCl-. D. H2N-CH2-COOH, H2NCH2-CH2-COOH.
Cu 10. t chy hon ton 1 lng cht hu c X thu c 3,36 lt CO2; 0,56 lt N2 (cc kh o ktc) v 3,15 gam H2O. Khi X tc dng vi dung dch NaOH thu c sn phm c mui C2H4O2NNa. Cng thc cu to ca X l. A. H2NCH2CH2COOH. B. H2NCH2COOC3H7. C. H2NCH2COOCH3. D. H2NCH2COOC2H5. Cu 11. Hp cht hu c X to bi cc nguyn t C, H v N. X l cht lng, khng mu, rt c, t tan trong nc, d tc dng vi cc axit HCl, HNO2 v c th tc dng vi nc Br2 to ra kt ta. Cng thc phn t ca X l. A. C4H12N2. B. C6H7N. C. C6H13N. D. C2H7N. Cu 12. C 3 cht lng: benzen, anilin, stiren ng ring bit trong 3 l mt nhn. Thuc th phn bit 3 cht lng trn l. A. Dung dch phenolphtalein. B. Dung dch NaOH. C. Qu tm. D. Nc Br2. Cu 13. Mt trong nhng im khc nhau ca protit so vi lipit v glucoz l. A. Protit c khi lng phn t ln hn. B. Protit lun cha chc hiroxyl. C. Protit lun cha nit. D. Protit lun l cht hu c no. Cu 14. Tng s ng phn amin ca cht c cng thc phn t C3H9N l A. 5 B. 1 C. 4 D. 3 Cu 15. t chy hon ton m gam mt amin X bng lng khng kh va , thu c 0,4 mol CO 2; 0,7 mol H2O v 3,1 mol N2. Gi s khng kh ch gm N2 v O2 trong N2 chim 80% th tch. Cng thc phn t ca X l. A. C4H14N2. B. CH3NH2. C. C3H7NH2. D. C2H5NH2. Cu 16. Dng nc Br2 khng phn bit c 2 cht trong cp no sau y? A. Anilin v stiren. B. Anilin v amoniac. C. Anilin v alylamin (CH2 = CH - CH2 - NH2). D. Anilin v phenol. Cu 17. Nhn nh no sau y khng ng? A. Metyl amin c tnh baz mnh hn anilin. B. Cng thc tng qut ca amin no, mch h l CnH2n+2+kNk. C. Tnh baz ca cc amin u mnh hn NH3. D. Cc amin u c kh nng nhn proton. Cu 18. 0,1 mol aminoaxit X phn ng va vi 0,2 mol HCl hoc 0,1 mol NaOH. Cng thc ca X c dng l. A. (H2N)2R(COOH)2. B. H2NRCOOH. C. H2NR(COOH)2. D. (H2N)2RCOOH. Cu 19. Mt cht khi thy phn trong mi trng axit, un nng khng to ra glucoz. Cht l. A. Tinh bt. B. Xenluloz. C. Saccaroz. D. Protit.

Cu 20. Cho 0,76 gam hn hp hai amin no n chc c s mol bng nhau tc dng va vi 200 ml dung dch HCl c 1,49 gam mui. Kt lun no sau y khng chnh xc: A. Cng thc ca hai amin l CH5N v C2H7N. B. S mol ca mi cht l 0,01 mol. C. Nng mol ca dung dch HCl bng 0,1M. D. Tn gi ca hai amin l metylamin v etylamin. Cu 21. Phn ng no di y khng th hin tnh baz ca amin?

C6H5NH3Cl . A. C6H5NH2 + HCl RNH2 +HNO2 ROH + N 2 + H2O .

Cu 22. Phng trnh no sau y khng ng?

B. C.
+ RNH3 +OH . D. RNH2 +H2O

+ Fe3+ +3RNH2 + 3H2O Fe(OH)3 + 3RNH3 .

(CH3)2 NH2Cl . A. CH3NHCH3 +HCl

B. C.

C6H5NO2 +3Fe +7HCl C6H5NH3Cl +3FeCl 2 +2H2O . C6H5NH3Cl +NaOH C6H5NH2 +NaCl +H2O . D. C6H5NH 2 +2Br2 3,5 Br2C6H3NH 2 +2HBr .
CuO 3 2 X Y Z. Cu 23. Cho s phn ng: NH3 (1:1) t0 CH I HNO

Bit Z c kh nng tham gia phn ng trng gng. Hai cht Y v Z ln lt l. A. CH3OH, HCHO. B. CH3OH, HCOOH. C. C2H5OH, HCHO. D. C2H5OH, CH3CHO. Cu 24. Anilin v phenol u c phn ng vi: A. Dung dch Br2. B. Dung dch NaOH. C. Dung dch NaCl. D. Dung dch HCl. Cu 25. Hp cht hu c X c cng thc tng qut CxHyOzNt. Thnh phn % khi lng ca N v O trong X ln lt l 15,730% v 35,955%. Khi X tc dng vi HCl ch to ra mui R(Oz)NH3Cl (R l gc hirocacbon). Bit X c trong thin nhin v tham gia phn ng trng ngng. Cng thc cu to ca X l. A. CH2 = CHCOONH4. B. H2NCH(CH3)COOH. C. H2NCH2CH2COOH. D. H2NCH2COOCH3. Cu 26. Cho s chuyn ho sau: + CH3OH / HCl + NH3 + HNO2 Alanin X Y Z. Cht Z l. A. H2N - CH2 - COOCH3. B. CH3 - CH(OH) - COOH. C. CH3 - CH(OH) - COOCH3. D. H2N - CH(CH3) - COOCH3. Cu 27. Cho anilin tc dng vi cc cht sau: dung dch Br2, H2, CH3I, dung dch HCl, dung dch NaOH, HNO2. S phn ng xy ra l. A. 5. B. 3. C. 4. D. 6. Cu 28. B thuc th no sau y c th phn bit c cc dung dch mt nhn sau: C 2H5NH2, C6H5NH2, glucoz, glixerol: A. Qi tm, dung dch Br2. B. C A, B, C u ng. C. Phenolphtalein, Cu(OH)2.D. AgNO3/NH3, dung dch Br2, qi tm. Cu 29. Cho 20 gam hn hp 3 amin no, n chc, l ng ng lin tip ca nhau tc dng vi dung dch HCl va , c cn dung dch c 31,68 gam hn hp mui. Nu cho 3 amin trn trn theo t l mol 1:10:5 v th t phn t khi tng dn th cng thc phn t ca 3 amin l. A. C3H9N, C4H11N, C5H13N. B. C3H7N, C4H9N, C5H11N. C. CH5N, C2H7N, C3H9N. D. C2H7N, C3H9N, C4H11N. Cu 30. Chn phng n tt nht phn bit dung dch cc cht mt nhn ring bit sau: CH 3NH2, H2NCH2COOH, CH3COONH4, anbumin. A. Qi tm, dung dch HNO3 c, dung dch NaOH. B. Dung dch AgNO3/NH3, dung dch Br2, dung dch HNO3 c. C. Cu(OH)2, qy tm, ung dch Br2. D. Dung dch Br2, dung dch HNO3 c, dung dch I2. Cu 31. Cho dy chuyn ho sau: + NaOH + HCl Glyxin Z X.
+ HCl + NaOH Glyxin T Y.

X v Y ln lt l. A. ClH3NCH2COOH v ClH3NCH2COONa. B. ClH3NCH2COOH v H2NCH2COONa. C. ClH3NCH2COONa v H2NCH2COONa. D. u l ClH3NCH2COONa. Cu 32. Nhn nh no sau y cha chnh xc? A. Tc phn ng nh xc tc enzim rt chm, mi enzim ch xc tc cho mt s chuyn ho. B. Peptit l nhng hp cht c hnh thnh bng cch ngng t hai hay nhiu phn t -aminoaxit.

C. Enzim l nhng cht hu ht c bn cht protein, c kh nng xc tc cho cc qu trnh ho hc, c bit trong c th sinh vt. D. Protein l nhng polipeptit cao phn t c vai tr l nn tng v cu trc v chc nng ca mi s sng. Cu 33. tinh ch anilin t hn hp phenol, anilin, benzen, cch thc hin no di y l hp l? A. Ha tan trong dung dch brom d, lc kt ta, tch halogen thu c anilin. B. Ha tan trong dung dch NaOH d, chit ly phn tan. Thi CO2 n d vo phn tan thu c trn

s thu c anilin tinh khit. C. Ha tan trong dung dch HCl d, chit ly phn tan. Thm NaOH d vo phn tan thu c trn v chit ly anilin tinh khit. D. Dng dung dch NaOH tch phenol, sau dng brom tch anilin ra khi benzen.
Cu 34. Hp cht X gm cc nguyn t C, H, O, N vi t l khi lng tng ng l 3: 1: 4: 7. Bit X c 2 nguyn t N. Cng thc phn t ca X l. A. C3H7O2N2. B. C3H8O2N2. C. CH4ON2. D. C3H8ON2. Cu 35. Cho cht hu c X c cng thc phn t C2H8O3N2 tc dng vi dung dch NaOH, thu c cht

hu c n chc Y v cc cht v c. Khi lng phn t (theo vC) ca Y l A. 68. B. 46. C. 85. D. 45.
Cu 36. Nhn nh no sau y khng ng? A. Nhit nng chy ca H2NCH2COOH > CH3(CH2)3NH2 > CH3CH2COOH. B. Aminoaxit l hp cht tp chc m phn t cha ng thi nhm cacboxyl v nhm amino. C. Aminoaxit ngoi dng phn t (H2NRCOOH) cn c dng ion lng cc H3N+RCOO-. D. Cc aminoaxit l nhng cht rn, c nhit nng chy cao v d tan trong nc v chng tn ti dng ion lng cc. Cu 37. t chy hon ton 9 gam mt amin X thuc dy ng ng ca metylamin thu c kh

CO2, H2O, N2 cn 16,8 lt kh oxi (ktc).( Cho H = 1; C = 12; N =14). Cng thc phn t ca X l A. C4H9NH2 B. C2H5NH2 C. CH3NH2 D. C3H7NH2 Cu 38. -aminoaxit X cha mt nhm -NH2. Cho 10,3 gam X tc dng vi axit HCl (d), thu c 13,95 gam mui khan. Cng thc cu to thu gn ca X l (cho H = 1, C = 12, N = 14, O = 16, Cl = 35,5) A. H2NCH2CH2COOH. B. CH3CH(NH2)COOH. C. CH3CH2CH(NH2)COOH. D. H2NCH2COOH.
Cu 39. X l hp cht hu c mch h cha cc nguyn t C, H, N trong N chim 23,72%. X tc dng vi dung dch HCl theo t l mol 1:1. X c s ng phn l. A. 5. B. 3. C. 4. D. 2. Cu 40. Cht X l mt aminoaxit m phn t khng cha nhm chc no khc ngoi cc nhm amino v

cacboxyl. 100ml dung dch 0,02M ca cht X c phn ng va ht vi 160ml dung dch NaOH 0,25M. C cn dung dch sau phn ng ny th c 3,82g mui khan. Mt khc X tc dng vi HCl theo t l 1:1. Cng thc phn t ca X l: A. C5H9NO4. B. C3H7NO2. C. C4H7NO4. D. C5H11NO4. Cu 41. trung ha 25 gam dung dch ca mt amin n chc X nng 12,4% cn dng 100ml dung dch HCl 1M. Cng thc phn t ca X l (Cho H = 1; C = 12; N = 14) A. C3H7N. B. C2H7N. C. C3H5N. D. CH5N.
Cu 42. Thy phn hon ton polipeptit sau thu c bao nhiu aminoaxit? . A. 3. B. 4. C. 5. Cu 43. tch ring hn hp kh CH4 v CH3NH2 ta dng: A. HCl, NaOH. B. HNO2. C. HCl. Cu 44. Phng trnh no sau y khng ng? D. 2. D. NaOH, HCl. B.

C6H5NH3Cl +3FeCl 2 +2H2O . A. C6H5NO2 +3Fe +7HCl C6H5NH3Cl +NaOH C6H5NH2 +NaCl +H2O . C. C6H5NH 2 +2Br2 3,5 Br2C6H3NH 2 +2HBr .

Cu 45. Cht X cng thc phn t C3H7O2N. X c th tc dng vi NaOH, HCl v lm mt mu dung dch

brom. X c cng thc cu to l A. H2N - CH2 - CH2 - COOH B. CH3 - CH(NH2) - COOH COONH4 D. CH3 - CH2 - CH2 - NO2

C. CH2 = CH -

Cu 46. Dung dch metylamin khng tc dng vi cht no sau y? A. Dung dch FeCl3. B. HNO2. C. Dung dch HCl. D. Dung dch Br2. Cu 47. Chn phng php tt nht phn bit dung dch cc cht: Glixerol, glucoz, anilin, alanin, anbumin. A. Dng ln lt cc dung dch AgNO3/NH3, CuSO4, NaOH. B. Dng ln lt cc dung dch CuSO4, H2SO4, I2. C. Dng Cu(OH)2 ri un nng nh, sau dng dung dch Br2. D. Dng ln lt cc dung dch HNO3, NaOH, H2SO4. Cu 48. S ipeptit to thnh t glyxin v alanin l. A. 1. B. 2. C. 4. D. 3. Cu 49. t chy hon ton 1 amin thm X bc 1 c 3,08 gam CO2; 0,99 gam H2O v 336 ml N2 ( ktc). trung ho 0,1 mol X cn 600 ml dung dch HCl 0,5M. Cng thc cu to ca X l. A. CH3C6H2(NH2)3. B. CH3NHC6H3(NH2)2. C. H2NCH2C6H3(NH2)2. D. A, B, C u ng. Cu 50. Nhn nh no sau y cha hp l? A. Do nhm -NH2 y electron nn anilin d tham gia phn ng th vo vng benzen v u tin vo v tr o-, p-. B. Amin bc 1 dy ankyl tc dng vi HNO 2 0 - 50C cho mui iazoni. C. Metylamin v nhiu ng ng ca n lm xanh qu m, kt hp vi proton mnh hn NH 3 v nhm ankyl c nh hng lm tng mt electron nguyn t N v do lm tng tnh baz. D. Tnh (lc) baz ca amin cng mnh khi mt electron trn nguyn t N cng ln. Cu 51. Cho Tirozin (HOC6H4CH2CH(NH2)COOH) (X) phn ng vi cc cht sau, trng hp no phng trnh ho hc vit khng ng:

Cl C6H 4 CH 2 CH(COOH) NH3Cl +H 2O . A. X +2HCl X +2NaOH NaOC6H4CH2CH(NH2 )COONa +2H 2O . C.

B.

X +C2H5OH HO C6H4 CH2 CH(NH2)COOC2H5 +H2O .

khHCl

D.

X +HNO2 HO C6H 4 CH 2 CH(OH)COOH +N 2 +H2O .

Cu 52. Ch dng Cu(OH)2 c th phn bit dy no di y cha cc dung dch ring bit? A. Glucoz, mantoz, glixerol, anehit axetic. B. Glucoz, lng trng trng, glixerol, ancol etylic. C. Saccaroz, glixerol, anehit axetic, ancol etylic. D. Lng trng trng, glucoz, fructoz, glixerol. Cu 53. Cc cht NH3, CH3 - NH2 v C6H5 - NH2 (anilin) u th hin tnh baz. Tnh baz ca chng

c sp xp theo th t tng dn nh sau A. CH3 - NH2 ; C6H5 - NH2 ; NH3 B. NH3 ; CH3 - NH2 ; C6H5 - NH2 C. CH3 - NH2 ; NH3 ; C6H5 - NH2 D. C6H5 - NH2 ; NH3 ; CH3 - NH2 CH3I HNO2 CuO X Y Z . Bit Z c kh nng tham gia phn ng trng Cu 54. Cho s phn ng: NH3 (1:1) t0
gng. Hai cht Y v Z ln lt l. A. CH3OH, HCHO. B. C2H5OH, HCHO. C. CH3OH, HCOOH. D. C2H5OH, CH3CHO. Cu 55. Cho hp cht sau: H3N+ - CH(COOH) - COO- tc dng vi cc cht sau: HNO2, CH3OH (d)/HCl, NaOH d, CH3COOH, CuO. S phn ng xy ra l. A. 2. B. 5. C. 4. D. 3. Cu 56. ng dng no ca aminoaxit di y khng ng? A. Cc axit amin c nhm -NH2 t v tr s 6 tr ln l nguyn liu sn xut t nilon. B. Aminoaxit thin nhin (hu ht l - aminoaxit) l c s kin to nn cc loi protein ca c th sng. C. Mui inatri glutamat dng lm gia v thc n (gi l m chnh hay bt ngt). D. Axit glutamic l thuc b thn kinh. Cu 57. X l mt aminoaxit ch cha 1 nhm - NH2 v 1 nhm - COOH. Cho 0,445 gam X phn ng va vi NaOH to ra 0,555 gam mui. Vy cng thc cu to ca X c th l: A. CH3 - CH(NH2) - COOH. B. CH3 - CH(NH2) - CH2 COOH. C. H2N - CH = CH - COOH. D. NH2 - CH2 - COOH. C 3 cht lng: benzen, anilin, stiren ng ring bit trong 3 l mt nhn. Thuc th phn bit 3 cht lng Cu 58. trn l. A. Dung dch phenolphtalein. B. Qu tm. C. Dung dch NaOH. D. Nc Br2. Cu 59. Cht X tc dng vi dung dch NaOH to ra cht Y. t chy hon ton 11,1 gam cht Y c 0,3 mol hn hp CO2 v N2 c t khi so vi H2 bng 20,667, ngoi ra cn 0,3 mol H2O v 0,05 mol Na2CO3. Bit X c tnh lng tnh v Y ch cha 1 nguyn t N. Cng thc cu to ca Y l. A. H2NCH = CHCOOONa. B. CH3CH(NH2)COOONa. C. H2NCH2COONa. D. CH2 = CHCOONH4.

Cu 60. Pht biu khng ng l. A. Phenol phn ng vi dung dch NaOH, ly mui thu c cho tc dng vi dung dch HCl li thu c phenol. B. Dung dch natri phenolat phn ng vi kh CO2, ly kt ta thu c tc dng vi dung dch NaOH li thu c natri phenolat. C. Axit axetic phn ng vi NaOH, ly mui thu c cho tc dng vi CO 2 li thu c axit axetic. D. Anilin phn ng vi dung dch HCl, ly mui thu c cho tc dng vi dung dch NaOH li thu c anilin. Cu 61. Ghp cc cm t ct 1 vi cc cm t ct 2 ph hp sao cho khng c cm t no tha: Ct 1 Ct 2 1 p - nitroanilin A kh [A(NH3)2]OH cho Ag. 2 Lng trng trng B thu phn n cng cho glucoz, tham gia phn ng trng gng. 3 ng mch nha C phn ng vi [Cu(NH3)4](OH)2. 4 Xenluloz D khng lm mt mu giy qu tm. 5 Tinh bt E nhn bit bng dung dch HNO3 c. Th t ghp ng l. A. 1d, 2e, 3a, 4c, 5b. B. 1c, 2b, 3e, 4a, 5d. C. 1b, 2e, 3c, 4a, 5d. D. 1d, 2e, 3c, 4a, 5b. Cu 62. X l cht hu c c cng thc phn t C5H11O2N. un X vi dung dch NaOH thu c mt hn hp cht c cng thc phn t C2H4O2NNa v cht hu c Y. Cho hi Y qua CuO, t0 c cht Z c kh nng trng gng. Cng thc cu to ca X l. A. H2NCH2CH2COOC2H5. B. CH3(CH2)4NO2. C. H2NCH2COOCH2CH2CH3. D. H2NCH2COOCH(CH3)2. Cu 63. 28,1 gam hn hp propylamin, axit aminoaxetic v etylaxetat c th phn ng vi 6,72 lt hiroclorua ( ktc). Cng mt lng hn hp trn c th phn ng vi 100 ml dung dch KOH 1M (cc phn ng va ). % khi lng ca aminoaxit trong hn hp l. A. 23,3%. B. 26,69%. C. 54,7%. D. 22%. Cu 64. Cho cc cht: etyl axetat, etanol, axit acrylic, phenol, anilin, phenylamoniclorua, ancol benzylic, p - crezol. Trong cc cht trn, s cht tc dng vi dung dch NaOH l. A. 3. B. 6. C. 4. D. 5. Cu 65. Nhn nh no sau y khng ng? A. Anilin c tnh baz nn lm mt mu nc brom. B. Anilin khng lm i mu qu tm. C. Trong phn t anilin c nh hng qua li gia nhm amino v gc phenyl. D. Amin c tnh baz v trn nguyn t N c i electron t do nn c kh nng nhn proton. Cu 66. Dy gm cc cht u lm giy qi tm m chuyn sang mu xanh l. A. Anilin, metylamin, amoniac. B. Anilin, amoniac, natri hiroxit. C. Metylamin, amoniac, natri axetat. D. Amoniclorua, metylamin, natri hiroxit. Cu 67. Khi thy phn mt protein (X) thu c hn hp gm 2 aminoaxit no k tip nhau trong dy ng ng. Bit mi cht u cha mt nhm - NH2 v mt nhm - COOH. t chy hon ton 0,2 mol hn hp 2 aminoaxit ri cho sn phm chy qua bnh ng dung dch NaOH d, thy khi lng bnh tng 32,8 gam. Cng thc cu to ca 2 aminoaxit l. A. H2NCH2COOH, H2NCH(CH3)COOH. B. H2NCH(CH3)COOH, H2N(CH2)3COOH. C. H2NCH2COOH, H2NCH2CH2COOH. D. H2NCH(CH3)COOH, C2H5CH(NH2)COOH. Cu 68. Cho cc cht sau: C6H5NH2 (1); C2H5NH2 (2); (C2H5)2NH2 (3); NaOH (4); NH3 (5) Trt t tng dn tnh baz (t tri qua phi) l: A. (1), (2), (5), (3), (4). B. (1), (5), (3), (2), (4). C. (1), (5), (2), (3), (4). D. (2), (1), (3), (5), (4). Cu 69. Khi thy phn hon ton mt polipeptit ta thu c cc aminoaxit X, Y, Z, E, F. Cn khi thu phn tng phn th thu c cc i- v tripeptit XE, ZY, EZ, YF, EZY. Trnh t cc aminoaxit trong polipeptit trn l. A. X - Z - Y - F - E. B. X - E - Z - Y - F. C. X - Z - Y - E - F. D. X - E - Y - Z - F. Cu 70. Nhn nh no sau y khng ng? A. Cc amin u c kh nng nhn proton. B. Cng thc tng qut ca amin no, mch h l CnH2n+2+kNk. C. Metyl amin c tnh baz mnh hn anilin. D. Tnh baz ca cc amin u mnh hn NH3. Cu 71. Cht X (cha C, H, O, N) c thnh phn % cc nguyn t C, H, O ln lt l 40,45%; 7,86%; 35,96%. X tc dng vi NaOH v vi HCl. X c ngun gc t thin nhin v MX <100. Cng thc cu to ca X l. A. H2NCH2COOH. B. CH3CH(NH2)COOH. C. H2NCH2CH2COOH. D. H2NCH2CH(NH2)COOH. Cu 72. Khi t chy hon ton mt amin n chc X, thu c 8,4 lt kh CO2, 1,4 lt kh N2 (cc th tch

kh o ktc) v 10,125 gam H2O. Cng thc phn t ca X l (cho H = 1, O = 16) A. C2H7N. B. C4H9N. C. C3H7N. D. C3H9N.
Cu 73. Axit glutamic (HOOC[CH2]2CH(NH2)COOH) l cht c tnh. A. trung tnh. B. axit. C. baz. D. lng tnh. Cu 74. phn bit phenol, anilin, benzen, stiren ngi ta ln lt s dng cp thuc th l.

A. dung dch NaOH, dung dch Br2. B. dung dch HCl, dung dch NaOH. C. dung dch Br2, qu tm. D. qu tm, dung dch Br2. Cu 75. Cho cc cht sau: (1) NH3; (2) CH3NH2; (3) (CH3)2NH; (4) C6H5NH2; (5) (C6H5)2NH. Cu 76. Trong 4 ng nghim mt nhn cha ring bit tng cht: glixerol, lng trng trng, h tinh bt, x phng. Th t cc cht dng lm thuc th nhn ra mi cht trn l. A. dung dch I2, Cu(OH)2. B. dung dch HNO3 c, qy tm, dung dch Br2. C. dung dch Br2, dung dch HNO3 c, dung dch I2. D. qy tm, dung dch HNO3 c, dung dch NaOH. Cu 77. S lng cc cu to mch h (mui amoni, aminoaxit bc mt, hp cht nitro) ng vi cng thc

phn t C3H7O2N l: A. 5 cu to.

B. 7 cu to. C. 6 cu to. D. 4 cu to. Cu 78. Cho hn hp X cha NH3, C6H5OH, C6H5NH2. trung ho 1 lt dung dch X cn 0,1 mol HCl hoc 0,01 mol NaOH. Mt khc 1 lt dung dch X phn ng vi nc Br2 d c 5,41 gam kt ta. Nng mol ca NH3, C6H5OH v C6H5NH2 c trong dung dch X ln lt l. A. 0,036; 0,01; 0,064. B. 0,09; 0,02; 0,04. C. 0,018; 0,01; 0,032. D. 0,036; 0,02; 0,064. Cu 79. -aminoaxit X cha mt nhm -NH2. Cho 10,3 gam X tc dng vi axit HCl d thu c 13,95 gam mui khan. Cng thc cu to ca X l. A. H2NCH2COOH. B. CH3CH(NH2)COOH. C. H2NCH2CH2COOH. D. CH3CH2CH(NH2)COOH. Cu 80. Trong phn t hp cht hu c no sau y c lin kt peptit? A. Xenluloz. B. alanin. C. Protein. D. Glucoz. Cu 81. Dy gm cc cht c xp theo chiu tnh baz gim dn t tri qua phi l. A. C6H5NH2, NH3, CH3NH2. B. NH3, CH3NH2, C6H5NH2. C. CH3NH2, C6H5NH2, NH3. D. CH3NH2, NH3, C6H5NH2. Cu 82. Gii php thc t no sau y khng hp l? A. Tng hp phm nhum azo bng phn ng ca amin thm bc 1 vi hn hp HNO 2 v HCl 0 - 50C. B. Kh mi tanh ca c trc khi nu bng gim n. C. Ra l ng anilin bng axit mnh sau ra li bng nc. D. To phm nhum azo bng phn ng ca amin thm bc 1 vi HNO 2 nhit cao. Cu 83. Cho 0,1 mol hp cht X tc dng va vi 80 ml dung dch HCl 1,25M, sau c cn dung dch thu c 18,75 gam mui. Mt khc, cho 0,1 mol X tc dng vi NaOH va ri c cn th c 17,3 gam mui. Bit X l mt - aminoaxit v c kh nng phn ng vi Br2/Fe cho hp cht C8H9O2NBr. Cng thc cu to ca X l. A. C6H5CH(NH2)COOH. B. H2NCH2C6H4COOH. C. H2NC6H4CH2COOH. D. H2NC6H4COOH. Cu 84. Dung dch X cha HCl v H2SO4 c pH = 2. trung ha hon ton 0,59 gam hn hp hai amin no, n chc, bc 1 (c s nguyn t C nh hn hoc bng 4 v cc cht c cng s mol) phi dng 1 lt dung dch X. Cng thc phn t ca 2 amin ln lt l. A. CH3NH2 v C4H9NH2. B. C2H5NH2 v C4H9NH2. C. C3H7NH2 v C4H9NH2. D. CH3CH2CH2NH2 v CH3CH(CH3)NH2. Cu 85. chng minh glyxin C2H5O2N l mt aminoaxit, ch cn cho phn ng vi: A. NaOH v HCl. B. HCl. C. NaOH. D. CH3OH/HCl. Cu 86. C 4 dung dch khng mu: glucoz, glixerol, h tinh bt v lng trng trng trong bn l mt nhn ring bit. Ha cht dng phn bit c 4 cht trn l. A. Dung dch I2. B. Dung dch HNO3 c. C. Cu(OH)2/OH-. D. Dung dch AgNO3/NH3. Cu 87. phn bit cc dung dch: CH3NH2, C6H5OH, CH3COOH, CH3CHO ta c th dng: A. Qu tm, dung dch Br2. B. C A, B, C u ng. C. Qu tm, AgNO3/NH3. D. Dung dch Br2, phenolphtalein. Cu 88. Trnh t tng dn tnh baz ca cc cht trn l;. A. (4) < (5) < (1) < (2) < (3). B. (1) < (4) < (5) < (2) < (3). C. (1) < (5) < (2) < (3) < (4). D. (5) < (4) < (1) < (2) < (3). Cu 89. Cho s chuyn ho sau:
(1)

Benzen

Clobenzen

(2)

X Y

(3)

Phenol Anilin
.

Nitrobenzen (5) (4)

(6)

X, Y ln lt l. A. C6H5NH3Cl, C6H5ONa. B. C6H5Br, C6H5CH2NH3Cl. C. C6H5ONa, C6H5CH2NH3Cl. D. C6H5ONa, C6H5NH3Cl. Cu 90. t chy hon ton 0,02 mol mt amin bc 1 (X) vi lng O2 va , cho ton b sn phm chy qua bnh cha Ca(OH)2 d thy khi lng bnh tng 3,02 gam v cn li 0,224 lt ( ktc) mt cht kh khng b hp th. Khi lc dung dch thu c 4 gam kt ta. Cng thc cu to ca X l. A. (CH2)2(NH2)2. B. CH3CH(NH2)2. C. CH2 = CHNH2. D. CH3CH2NH2.

Cu 91. Cht X c cng thc phn t C3H7O2N. X c th tc dng vi NaOH, HCl v lm mt mu dung dch Brom. Cng thc cu to ca X l. A. H2NCH2CH2COOH. B. CH3CH2CH2NO2. C. CH2 = CHCOONH4. D. CH3CH(NH2)COOH. Cu 92. Cho s sau:

C6H6 X C6H5NH2 Y Z C6H5NH2 . X, Y, Z ln lt l.

A. C6H5NO2, C6H5Br, C6H5NH3Cl. B. C6H5Cl, C6H5NO2, C6H5NH3Cl. C. C6H5CH3, C6H5NO2, (C6H5NH3)2SO4. D. C6H5NO2, C6H5NH3Cl, C6H5NH3NO3. Cu 93. Cho 100 ml dung dch aminoaxit X 0,2M tc dng va vi 80 ml dung dch NaOH 0,25M. Sau phn ng c 2,5 gam mui khan. Mt khc ly 100 gam dung dch aminoaxit ni trn c nng 20,6% phn ng va vi 400 ml dung dch HCl 0,5M. Cng thc phn t ca X l. A. H2NC3H6COOH. B. H2N(CH2)2COOH. C. H2NCH2COOH. D. H2NCH(CH3)COOH. Cu 94. Hy chn mt thuc th sau y phn bit cc dung dch: glucoz, glixerol, etanol, lng trng trng. A. Dung dch HNO3. B. Dung dch AgNO3/NH3. C. Cu(OH)2. D. Dung dch NaOH. Cu 95. Nhn nh no sau y khng ng? A. Sa ti lu s b vn cc, to thnh kt ta do b ln men lm ng t protein. B. Vi lng trng trng, Cu(OH)2 phn ng vi cc nhm peptit - CO - NH - cho sn phm mu tm. C. Lp vng ni ln khi nu tht, c l hin tng ng t protein. D. Protein d tan trong nc to thnh dung dch keo. Cu 96. Pht biu khng ng l. A. Dung dch natri phenolat phn ng vi kh CO2, ly kt ta thu c tc dng vi dung dch NaOH li thu c natri phenolat. B. Axit axetic phn ng vi NaOH, ly mui thu c cho tc dng vi CO 2 li thu c axit axetic. C. Anilin phn ng vi dung dch HCl, ly mui thu c cho tc dng vi dung dch NaOH li thu c anilin. D. Phenol phn ng vi dung dch NaOH, ly mui thu c cho tc dng vi dung dch HCl li thu c phenol. Cu 97. Cho cc loi hp cht: aminoaxit (X), mui amoni ca axit cacboxylic (Y), amin (Z), este ca aminoaxit (T). Dy gm cc hp cht u tc dng c vi dung dch NaOH v u tc dng vi dung dch HCl l. A. X, Y, T. B. X, Y, Z, T. C. X, Y, Z. D. Y, Z, T. Cu 98. Sn phm cui cng ca qu trnh thu phn cc protein n gin nh xc tc thch hp l. A. aminoaxit. B. aminoaxit. C. Axit cacboxylic. D. Este. Cu 99. Cho hn hp X gm 2 cht hu c c cng cng thc phn t C2H7NO2 tc dng va vi dung dch NaOH v un nng, thu c dung dch Y v 4,48 lt hn hp Z ( ktc) gm 2 kh (u lm xanh qu m). T khi hi ca Z i vi H2 bng 13,75. C cn dung dch Y thu c khi lng mui khan l. A. 14,3 gam. B. 16,5 gam. C. 8,9 gam. D. 15,7 gam. Cu 100. Phn ng no di y khng th hin tnh baz ca amin?
+ RNH3 +OH . A. RNH2 +H2O

C6H5NH3Cl . C. B. C6H5NH 2 + HCl

D.

+ Fe3+ +3RNH2 + 3H2O Fe(OH)3 + 3RNH3 .

RNH2 +HNO2 ROH + N 2 + H2O .

Cu 101. Dy gm cc cht c xp theo chiu tnh baz gim dn t tri qua phi l. A. CH3NH2, C6H5NH2, NH3. B. C6H5NH2, NH3, CH3NH2. C. CH3NH2, NH3, C6H5NH2. D. NH3, CH3NH2, C6H5NH2. Cu 102. tinh ch anilin t hn hp phenol, anilin, benzen cch thc hin no di y l ng: A. Ha tan trong dung dch HCl d, chit ly phn tan. Thm dung dch NaOH d vo phn tan thu c trn v chit ly anilin tinh khit. B. Ha tan trong dung dch Br2 d, lc ly kt ta, tch halogen c anilin. C. Dng dung dch NaOH tch phenol, sau dng dung dch Br2 tch anilin ra khi benzen. D. Ha tan trong dung dch NaOH d, chit ly phn tan. Thi CO2 d vo phn tan s c anilin tinh khit. Cu 103. trung ho 25 gam dung dch ca 1 amin n chc X nng 12,4% cn dng 100 ml dung dch HCl 1M. Cng thc phn t ca X l. A. C2H7N. B. CH5N. C. C3H7N. D. C3H5N. Cu 104. Phn t khi ca mt cht hu c X nm trong khong 140 < M < 150. 1 mol X phn ng c vi 2 mol NaOH nhng ch phn ng c vi 1 mol HCl. X c th l. A. HOOC(CH2)2CH(NH2)COOH. B. HOOCCH2CH(NH2)COOH. C. H2N(CH2)4CH(NH2)COOH. D. H2NCH2CH(NH2)COOH. Cu 105. C3H7O2N c bao nhiu ng phn aminoaxit (vi nhm amin bc 1)? A. 5. B. 2. C. 3. D. 4. t chy hon ton mt amin n chc X c 8,4 lt CO , 1,4 lt N (cc th tch kh c o ktc) v Cu 106. 2 2 10,125 gam H2O. Cng thc ca X l. A. C3H7N. B. C3H9N. C. C2H7N. D. C4H9N.

Cu 107. C bao nhiu ng phn cu to ca amin c cng thc phn t C3H9N? A. 3. B. 4. C. 5. Cu 108. Cho cc phn ng:

D. 2.

H2NCH2COOH + HCl Cl H3N + CH2COOH . H2NCH2COOH + NaOH H2NCH 2COONa +H2O .

Hai phn ng trn chng t axit aminoaxetic. A. ch c tnh baz. B. ch c tnh axit. C. va c tnh oxi ho, va c tnh kh. D. c tnh lng tnh. Cu 109. Cho cc cht: etyl axetat, etanol, axit acrylic, phenol, anilin, phenylamoniclorua, ancol benzylic, p - crezol. Trong cc cht trn, s cht tc dng vi dung dch NaOH l. A. 6. B. 5. C. 3. D. 4. Cu 110. Dy gm cc cht u lm giy qi tm m chuyn sang mu xanh l. A. Anilin, amoniac, natri hiroxit. B. Metylamin, amoniac, natri axetat. C. Amoniclorua, metylamin, natri hiroxit. D. Anilin, metylamin, amoniac. Cu 111. S ng phn tripeptit to thnh t glyxin, alanin v phenylalanin l. A. 6. B. 5. C. 4. D. 3. Cu 112. Este X c iu ch t aminoaxit Y (cha C, H, N, O) v ancol metylic, t khi hi ca X so vi H2 bng 44,5. t chy hon ton 8,9 gam este X c 0,3 mol CO2; 0,35 mol H2O v 0,05 mol N2. Cng thc cu to ca X l. A. H2NCH2COOCH3. B. H2NCH2COOC2H5. C. H2NCOOC2H5. D. H2NCH(CH3)COOCH3. Cu 113. C hai amin bc 1: X (ng ng ca anilin) v Y (ng ng ca metylamin). t chy hon ton 3,21 gam amin X c 336 ml N2 ( ktc). Khi t chy amin Y thy VCO2 : VH2O = 2:3. Cng thc phn t ca X, Y ln lt l. A. CH3C6H4NH2 v C2H5NH2. D. C6H5NH2 v C3H7NH2. B. C6H5NH2 v C2H5NH2. C. CH3C6H4NH2 v C3H7NH2.