PHN NG NHIT PHN

1) Nhit phn mui: LOI MUI Nitrat PHM VI Trc Mg ( Tr Ba) Mg n Cu+ Ba Sau Cu Kim loi kim Ca v kim loi trc Cu, tr kim Sau Cu Hidro Cacbonnat Cc KL K, Na, Ba Sunfat Mg n Cu Sau Cu Ca axit d bay hi SN PHM M(NO2)+O2 MxOY+NO2+O2 M+ NO2+O2 K b nhit phn Oxit kim loi+ CO2 Kim loi + CO2+ O2 Cacbonat+ CO2+H2O K b nhit phn Oxit kim loi+ SO2+O2 Kim loi+ SO2+O2 Axit+ NH3 V D
t NaNO3 NaNO2 + O2 t Mg(NO3)2 MgO + O2 t AgNO3 Ag+ NO2+O2
0 0 0

Cacbonat

t CaCO3 CaO +CO2

0

t Ag2CO3 Ag+CO2+ O2
0

t NaHCO3 Na2CO3+CO2+H2O
0

t FeSO4 Fe2O3 + SO2+O2 t Ag2SO4 Ag+SO2+ O2 t NH4Cl NH3+ HCl t (NH4)2SO4 NH3 + NH 4 HSO4
0 0 0

Amoni

Ca axit oxi ho mnh

NH3 b o xi ho thnh kh N2O hoc N2

t NH4NO3 N2O + 2H2O (Nu nung > 5000C c th cho N2 v H2O t (NH4)2Cr2O7 Cr2O3+N2+H2O t NH4NO2 N2 + 2H2O
0 0

t (NH4)2Cr2O4 Cr2O3 + N2 + 4H2O

NH4NO2 Cr2O3+N2+H2O
t VD1: 2NaClO 2NaCl + O2
0

Ca axit cha oxi ca halogen M(XOm)n

Mui halogen+ oxi

(thuc phn ng oxi ho ni phn t). VD2: Phn ng nhit phn mui KClO3 xy ra theo 2 hng.
400 C 4KClO3 KCl + 3KClO4
0

> 600 C 2KClO3 2KCl + 3O2 xt :MnO

2 0

(2)

t VD3: 2CaOCl2 2CaCl2 + O2

Nhit phn mui sunfit Nhit phn mui photphat Mt s mui c bit

Mui sunfat+mui sunfua K b nhit phn

t 4M2(SO3)n 3M2(SO4)n + M2Sn

0

2. Nhit phn hidroxit * NX: Cc baz khng tan u b phn hu t0 cao: P:

t 2M(OH)n M2On + nH2O. (Vi M khc Li; Na; K; Ca; Ba)
0

* Lu : + Phn ng nhit phn Fe(OH)2 c mt khng kh:

t 4Fe(OH)2 + O2 2Fe2O3 + 4H2O
0

+ Vi AgOH v Hg(OH)2 : Khng tn ti nhit thng. 2AgOH Ag2O + H2O Hg(OH)2 HgO + H2O nhit cao th Ag2O v HgO tip tc b phn hu:
t 2Ag2O 4Ag + O2
0

t 2HgO 2Hg + O2