Sistema

Burb P (Gamma-Phi c/Wilson)

etanol(1) - tolueno(2)

T (C)
T(K)
X1
X2
R(cm3bar/mol k)
R(cm3kPa/mol k)
R(cal/mol k)
ij

80
353.15
0.9 1
0.1 2
83.14
8314
1.987

Cte. De la Ec. Antoine lnPsat(kPa)=A- B/T(C) + C

A
1
16.8958
2
13.932

1
1

Tcij(K)
11
22
12
i
1
2

Pcij (bar)
Vcij(cm3/mol) Zcij
512.6
80.97
118
591.8
41.06
316
550.7782494 55.57910391 201.0319510

Pisat(kPa)
108.7947019
38.8932154

i
1.0180099
3.8761386

RESULTADOS
P(kPa)
115.4195337

P(kPa)
114.7542241

Y1
0.8646517

ij
0.224
0.264
0.244

Iteraciones
0
1
2
3
4
Y2
0.1353483

0.564
0.262
0.413
Y1
0.8686275
0.8646779
0.8646523
0.8646517
0.8646517

Modelo Wilson

. Antoine lnPsat(kPa)=A- B/T(C) + C

B
C
3795.17
230.918
3056.96
217.625

Trij

B0

A12
A21
V1
V2
12
21

B1

0.6889387
0.5967388
0.6411836

-0.6829907
-0.8809570
-0.7762916

Y2
0.1313725
0.1353221
0.1353477
0.1353483
0.1353483

1
0.9989299
0.9988107
0.9988075
0.9988074
0.9988074

1556.45 cal/mol
210.52
58.68 cm3/mol
106.85
0.198144737
0.406839138

Bij

P sat(kPa)
-0.6835644
-562.4028732 108.7947019
-1.3649542 -1484.1860110 38.8932154
-0.9732496
-970.7566506
2
0.9653651
0.9650387
0.9650305
0.9650303
0.9650303

P(kPa)recalc
115.4018768
115.4190645
115.4195216
115.4195337
115.4195341

P <
0.6476527
0.0171877
0.0004571
0.0000122
0.0000003

12

105.075583 cm3/mol

Roco P (Antoine/Gamma-Phi /Wilson)

Sistema etanol(1) - tolueno(2)
T (C)
T(K)
Y1
Y2
R(cm3bar/mol k)
R(cm3kPa/mol k)
R(cal/mol k)
ij

90
363.15
0.9
0.1
83.14
8314
1.987

1
2
1
2

Cte. De la Ec. Antoine lnPsat(kPa)=A- B/T(C) + C

A
B
1
16.8958
3795.17
2
13.932
3056.96

1
1
1
1

Tcij(K)

Pcij (bar)
Vcij(cm3/mol)Zcij
11
512.6
80.97
118
22
591.8
41.06
316
12 550.7782494 55.5791039 201.0319510

Pisat(kPa)
P(kPa)
1 159.1456040 133.3958672
2 54.3098830

RESULTADOS
iteraciones
0
1
2
3
4

1
1.0087604
1.0087808
1.0087861
1.0087873
1.0087876

2
4.1974975
4.1963619
4.1960677
4.1959996
4.1959841

Xi
0.7543801
0.2456199

P(kPa)
166.3183225
166.1629643
166.1580814
166.1579279
166.1579231

ij
0.224
0.264
0.244

Trij
0.564
0.7084471
0.262
0.6136364
0.413
0.6593398

i
P(kPa)recalc
1.1031708 171.2594308
2.5832387

i
0.9979833
0.9524073

Pi <
4.9411082
0.1553582
0.0048829
0.0001535
0.0000048

2
0.9544322
0.9544959
0.9544979
0.9544980
0.9544980

1
0.9988276
0.9988541
0.9988550
0.9988550
0.9988550

Modelo Wilson

at(kPa)=A- B/T(C) + C
C
230.918
217.625

A12
A21
V1
V2
12
21

1556.45 cal/mol
210.52
58.68 cm3/mol
106.85
0.2106245
0.4102141

B0
B1
Bij
P sat(kPa)
-0.6495218 -0.5925385 -517.7654898 159.1456040
-0.8388382 -1.1985249 -1381.4637646 54.3098830
-0.7387460 -0.8501668 -897.9412826

X1 recalc
0.9313018
0.9304378
0.9304064
0.9304044
0.9304041

12

103.3466892

Iteraciones
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17

X1 recalc
0.8761588
0.9436690
0.9553054
0.9575374
0.9580191
0.9581273
0.9581518
0.9581574
0.9581587
0.9581589
0.9581590
0.9581590
0.9581590
0.9581590
0.9581590
0.9581590
0.9581590
0.9581590

X2 recalc
0.1162609
0.0829948
0.0742249
0.0721618
0.0716891
0.0715814
0.0715569
0.0715513
0.0715501
0.0715498
0.0715497
0.0715497
0.0715497
0.0715497
0.0715497
0.0715497
0.0715497
0.0715497

X1 normal
0.8828511
0.9191607
0.9279041
0.9299195
0.9303792
0.9304838
0.9305076
0.9305130
0.9305143
0.9305145
0.9305146
0.9305146
0.9305146
0.9305146
0.9305146
0.9305146
0.9305146
0.9305146

X2 normal
0.1171489
0.0808393
0.0720959
0.0700805
0.0696208
0.0695162
0.0694924
0.0694870
0.0694857
0.0694855
0.0694854
0.0694854
0.0694854
0.0694854
0.0694854
0.0694854
0.0694854
0.0694854

1
1.0242499
1.0117737
1.0094153
1.0089077
1.0087938
1.0087680
1.0087621
1.0087608
1.0087605
1.0087604
1.0087604
1.0087604
1.0087604
1.0087604
1.0087604
1.0087604
1.0087604
1.0087604

X2 recalc
0.0696331
0.0695915
0.0695945
0.0695956
0.0695959

X1 normal
0.9304319
0.9304105
0.9304055
0.9304044
0.9304041

X2 normal
0.0695681
0.0695895
0.0695945
0.0695956
0.0695959

1
1.0087808
1.0087861
1.0087873
1.0087876
1.0087876

1 <
0.0000204
0.0000053
0.0000012
0.0000003
0.0000001

2
4.1963619
4.1960677
4.1959996
4.1959841
4.1959805

cm3/mol

1 <
0.0789209
0.0124762
0.0023584
0.0005076
0.0001139
0.0000258
0.0000059
0.0000013
0.0000003
0.0000001
0.0000000
0.0000000
0.0000000
0.0000000
0.0000000
0.0000000
0.0000000
0.0000000

2 <
0.0011356
0.0002942
0.0000681
0.0000155
0.0000035

2
3.6186575
4.0462135
4.1618913
4.1893359
4.1956382
4.1970745
4.1974013
4.1974756
4.1974925
4.1974964
4.1974972
4.1974974
4.1974975
4.1974975
4.1974975
4.1974975
4.1974975
4.1974975

2 <
1.0354188
0.4275560
0.1156777
0.0274447
0.0063023
0.0014363
0.0003268
0.0000743
0.0000169
0.0000038
0.0000009
0.0000002
0.0000000
0.0000000
0.0000000
0.0000000
0.0000000
0.0000000

Burb T (Antoine/Gamma-Phi /Wilson)

Sistema etanol(1) - tolueno(2)
P (kPa)
75
X1
0.9
1
1
X2
0.1
2
1
R(cm3bar/mol k)
83.14
1
1
R(cm3kPa/mol k)
8314
2
1
R(cal/mol k)
1.987
ij
Tcij(K)
Pcij (bar)
Vcij(cm3/mol)Zcij
11
512.6
80.97
118
22
591.8
41.06
316
12 550.7782494 55.5791039 201.0319510
i

T1sat
T2sat
1 70.8053182 100.327699

Cte. De la Ec. Antoine lnPsat(kPa)=A- B/T(C) + C

A
B
1
16.8958
3795.17
2
13.932
3056.96

0.224
0.264
0.244

ij
0.564
0.262
0.413

Trij
0.6671321
0.5778504
0.6208885

T(C)
T(K)
73.7575563 346.9075563

P1sat
84.7214778

P2sat
31.211133

T(C)
T(K)
68.82189631 341.9718963
Iteraciones
0
1
2
3
4
RESULTADOS

12
0.1842871
0.1847847
0.1847400
0.1847440
0.1847436

21
0.4028690
0.4030159
0.4030027
0.4030039
0.4030038

P1sat
69.0102896
70.1937044
70.0866667
70.0962669
70.0954052

P2sat
26.0496533
26.4432218
26.4076587
26.4108486
26.4105623

Y1
0.8431383
0.8587539
0.8572120
0.8573502
0.8573378

Y2
0.1360853
0.1429684
0.1426335
0.1426636
0.1426609

T(C)
69.1917194

Y1
0.8573380

Y2
0.1426610

1
0.9989900

2
0.9748174

1
1.0182218

Modelo Wilson

at(kPa)=A- B/T(C) + C
C
230.918
217.625

A12
A21
V1
V2
12
21

1556.45 cal/mol
210.52
58.68 cm3/mol
106.85
0.1903919
0.4046487

B0
B1
Bij
P sat
-0.7234428 -0.8025401 -619.0128172 84.7214778
-0.9318637 -1.5824861 -1613.4828561 31.2111330
-0.8216709 -1.1341254 -1062.8861730
1
1.0181311

2
3.9180539

Pjsat
26.0496533

1
0.9987488
0.9990116
0.9989881
0.9989902
0.9989900

2
0.9745515
0.9748422
0.9748152
0.9748176
0.9748174

1
1.0182293
1.0182212
1.0182219
1.0182218
1.0182218

2
P1sat
3.9492281 70.0954052

P2sat
26.4105623

2
3.9517723
3.9489994
3.9492485
3.9492261
3.9492281

12

106.7233273

La especie "j" siempre es la mas pesad

La que presenta la mayor Tisat

Pjsat
T(C)recalc
26.4432218 69.2249540
26.4076587 69.1887345
26.4108486 69.1919849
26.4105623 69.1916932
26.4105880 69.1917194

T(K)recalc
342.3749540
342.3387345
342.3419849
342.3416932
342.3417194

cm3/mol

"j" siempre es la mas pesada

e presenta la mayor Tisat

T<
0.4030577
0.0362195
0.0032504
0.0002918
0.0000262

Roco T (Antoine/Gamma-Phi /Wilson)

Sistema 2-propanol(1) - agua (2)
P (kPa)
Y1
Y2
R(cm3bar/mol k)
R(cm3kPa/mol k)
R(cal/mol k)

ij

101.3
0.9
0.1
83.14
8314
1.987

1
2
1
2

Cte. De la Ec. Antoine lnPsat(kPa)=A- B/T(C) + C

A
B
1
16.8958
3795.17
2
13.932
3056.96

1
1
1
1

Tcij(K)
11
22
12
i
1
2

i
1
2
12
21

RESULTADOS
Iteraciones
0
1
2
3
4

Pcij (bar)
Vcij(cm3/mol)Zcij
512.6
80.97
118
591.8
41.06
316
550.7782494 55.5791039 201.0319510

ij
0.224
0.264
0.244

Trij
0.564 0.69173268
0.262
0.5991588
0.413
0.6437839

Tisat(C)
T(C)
Pisat(KPa)
Pjsat(Kpa)
Trecalc(C)
Pisat(KPa)
78.1924848 81.43217033 115.0573207 42.50231102 82.5937624 120.3553679
110.5893399
T(K)
40.8541337
Trecalc(K)
42.5023110
354.5821703
355.7437624
Pisat(KPa)
90.11348047
32.9535717
0.192272425
0.405187022

i
0.9978930
0.9688125

X1
1.0021664
1.0021701
1.0021709
1.0021711
1.0021711

X2
0.0676635
0.0676598
0.0676590
0.0676588
0.0676588

Iteraciones

X1 normal
0.9367531
0.9367565
0.9367572
0.9367574
0.9367574

0
1
2
3
4
5
6

X1
0.9155671
0.9890185
0.9997710
1.0016813
1.0020678
1.0021491
1.0021664

X2
0.1101795
0.0779760
0.0699137
0.0681418
0.0677618
0.0676807
0.0676635

X2 normal
0.0632469
0.0632435
0.0632428
0.0632426
0.0632426

1
1.0074064
1.0074057
1.0074055
1.0074055
1.0074054

1<
0.0000037
7.8835E-07
1.6795E-07
3.5781E-08
7.6229E-09

Modelo Wilson

at(kPa)=A- B/T(C) + C
C
230.918
217.625

A12
A21
V1
V2
12
21

1556.45 cal/mol
210.52
58.68 cm3/mol
106.85
0.20137524
0.407730034

La especie "j" siempre es la mas pesad

La que presenta la mayor Tisat

B0
B1
Bij
P sat
-0.6780465 -0.6697003 -555.6849639 115.0573207
-0.8747350 -1.3396055 -1468.7718806 40.8541337
-0.7707452 -0.9545030 -959.8080390
i
1.0036345
0.9739683

Xi
0.7602599
0.2321356

X1 normal
0.8925860
0.9269200
0.9346408
0.9363055
0.9366611
0.9367369
0.9367531

X2 normal
0.1074140
0.0730800
0.0653592
0.0636945
0.0633389
0.0632631
0.0632469

2
4.4016559
4.4017069
4.4017178
4.4017201
4.4017206

2<
0.0002395
5.1019E-05
1.087E-05
2.3157E-06
4.9335E-07

12

104.840767

i
Pjsat recalc T(C)RECALC
1.1026965 32.9535717 75.2742228
2.7029983
T(K)RECALC
348.4242228
1<
0.0818939
0.0109788
0.0019258
0.0003887
0.0000818
0.0000174
0.0000037

2
3.8193185
4.2597527
4.3705197
4.3950285
4.4002929
4.4014165
4.4016559

2<
1.1163202
0.4404342
0.1107670
0.0245088
0.0052644
0.0011235
0.0002395

P1sat(KPa)
P2sat(KPa)
90.1134805 32.9535717
97.2974614 35.2547158
96.5000662 35.0003941
96.5436696 35.0143079
96.5391333 35.0128604

1
0.9978930
0.9992731
0.9990009
0.9990103
0.9990094

2
0.9688125
0.9701046
0.9659417
0.9659510
0.9659500

1
1.0208026
1.0098238
1.0078980
1.0075093
1.0074275
1.0074101
1.0074064

Pjsat(KPa)
35.2547158
35.0003941
35.0143079
35.0128604
35.0130110

e "j" siempre es la mas pesada

e presenta la mayor Tisat

cm3/mol

T(C)
77.1808513
76.9751596
76.986444
76.9852702
76.9853923

T<
1.9066285
0.2056917
0.0112844
0.0011738
0.0001221

T(K)
350.3308513
308.1503941
308.1643079
308.1628604
308.1630110