Test 1

Fall 2010

Physical Chemistry I

Constants g = 9.81 m s2
23

gravitational acceleration Avogadro constant gas constant

N A = 6.022 10 mol1

R = 8.314 J mol1 K1 = 0.08206 L atm mol1 K1 1 atm 760 Torr = 760 mmHg 1.01325 105 Pa 1 bar 105 Pa Formulas 1 = 1 x + x 2 x 3 + x 4 , 1 < x < 1 1+x xn x2 x3 exp(x ) = 1 + x + + + = 2! 3! n =0 n ! hydrostatic pressure P = g h compression factor Z= V PV = RT V

virial expansion PV = RT [1 + B (T )P + C (T )P 2 + . . .], virial expansion Z = 1 + B (T )P + C (T )P 2 + . . . , B (T ) = B (T ) , RT C (T ) = C (T ) B (T )2 (RT )2 RT a V

PV = RT 1 + B (T ) 1 V + C (T ) 1 V
2

1 V

+ C (T )

1 V
2

+...

Z = 1 + B (T )

+...

Boyle temperature TB : B (TB ) = 0 or B (TB ) = 0 van der Waals equation P = V b a van der Waals gas B (T ) = b RT 2 dP d P critical point = 0, =0 2 dV dV , 2 V b+
3

RT a ab 2 V + V =0 P P P

van der Waals critical constants V c = 3b, Dieterici equation P = RT V b exp a RT V Tc =

Vf Vi

Tc =

8a , 27bR

Pc =

a 27b 2

Dieterici critical constants V c = 2b, expansion/compression work w =

a , 4bR

Pc =

a 4e2 b 2

P ex dV Vf Vi

ideal gas, isothermal, reversible expansion w rev = nRT ln

Test 1

Fall 2010

Physical Chemistry I

isobaric thermal expansivity = general C P C V =

r H =

1 V V T

,
P

isothermal compressibility T =

1 V V P

VT ; T

ideal gas C P C V = nR
react. f H (react.)

prod. f H (prod.) products

reactants

Kirchhoffs law r H (T2 ) = r H (T 1 ) +

T2 T1

C P (T )d T

P = const react.C P (react.)

C P (T ) =

prod.C P (prod.)
products

reactants

ideal gas, all changes U = C V T ,

H = C P T