Ex 9

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‫بسم ال الرحمن الرحيم‬

Name: ayedzahran

Group:
Day:

Experiment 9
"Stoichiometry of two chemical reaction"
__________________________________________________________________

I. Observations and results:

A. Reaction between HCl and NaOH:


Table 1
ml 1 M HCl ml 1 M NaOH Temperature change
5 45 25-24=1 Cº
10 40 25-23.5=1.5 Cº
15 35 25.5-22.5=2 Cº
20 30 26-23=3 Cº
25 25 27-23=4 Cº
30 20 26-22.5=3.5 Cº
35 15 24-22=2 Cº
40 10 22.5-21.5=1 Cº
45 5 22-21.5=0.5 Cº

B. Reaction between H2SO4 and NaOH


Table 2
ml 1 M H2SO4 ml 1 M NaOH Temperature change
5 20 Cº 30.5-23=7.5
10 20 Cº 10.5=33.5-23
15 20 Cº 9.5=33-23.5
20 20 Cº 9=32-23
25 20 Cº 8=31-23
30 20 Cº 7.5=30.5-23
35 20 Cº 6.5=29.5-23
40 20 Cº 6=29-23
45 20 Cº 5.5=28-22.5
III. Answer the following questions:
1. Based on your results above, in what molar ratio do:
a. HCl and NaOH react: 1:1
b. H2SO4 and NaOH react: 1:2

2. Write balance equation for the reaction between:


a. HCl and NaOH:
HCl + NaOH NaCl + H2O + ΔH
b. H2SO4 and NaOH:
H2SO4 + 2NaOH Na2SO4 + 2H2O + ΔH

3. What is the difference between the forms of graph obtained in part A

and B of this experiment? Explain your answer.


The difference between part A and B:
A. The molar ratio in part A is 1:1, HCl:NaOH. and in B is 1:2

H2SO4:NaOH, we known that from the max change of heat, in


that’s point in A was when the volume of the reactions is the
same, and in B was when NaOH is 20 ml and H2SO4 is 10 ml.
B. The change of temperature in B mar than A, because H2SO4 is

stronger than HCl.


C. In A the curve start from 0 and end from 0, but in B start from

0 and goes to 0 after many times (when H2SO4 larger than


NaOH many times),because in A the two reactions is change
in volume so when the volume of any two reactions is 0 that’s
mean no reaction so no change in temperature, in B the
volume of NaOH is constant (20 ml) that’s mean the change
of temperature goes to 0 (≈ 0) when the volume of H2SO4
more and more than NaOH, because the large volume and low
heat.

Not: For experiment number, For calculation number, For the solution of
answers.

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