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  • IR Analysis: Characteristic Infrared Absorption Frequencies Bond Compound Type Frequency Range, CM

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    The document provides a table to help users interpret infrared spectra by correlating absorption bands in an unknown compound's spectrum with known absorption frequencies of different bond types. The table lists characteristic infrared absorption frequencies, including the frequency range and intensity, for common bond types like C-H, C=C, C≡C, C-O, C=O, and O-H. Understanding the position, intensity, and shape of absorption bands is significant for identifying the source of bands in an infrared spectrum.

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    analysis of ir spectra

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    i r Analysis

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    The document provides a table to help users interpret infrared spectra by correlating absorption bands in an unknown compound's spectrum with known absorption frequencies of different bond types. The table lists characteristic infrared absorption frequencies, including the frequency range and intensity, for common bond types like C-H, C=C, C≡C, C-O, C=O, and O-H. Understanding the position, intensity, and shape of absorption bands is significant for identifying the source of bands in an infrared spectrum.

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    6 views1 page

    IR Analysis: Characteristic Infrared Absorption Frequencies Bond Compound Type Frequency Range, CM

    Uploaded by

    aamer_shahbaaz
    The document provides a table to help users interpret infrared spectra by correlating absorption bands in an unknown compound's spectrum with known absorption frequencies of different bond types. The table lists characteristic infrared absorption frequencies, including the frequency range and intensity, for common bond types like C-H, C=C, C≡C, C-O, C=O, and O-H. Understanding the position, intensity, and shape of absorption bands is significant for identifying the source of bands in an infrared spectrum.

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    IR Analysis The interpretation of infrared spectra involves the correlation of absorption bands in the spectrum of an unknown compound with

    the known absorption frequencies for types of bonds. This table will help users become more familiar with the process. Significant for the identification of the source of an absorption band are intensity (weak, medium or strong), shape (broad or sharp), and position (cm-1) in the spectrum. Characteristic examples are provided in the table below to assist the user in becoming familiar with the intensity and shape absorption bands for representative absorptions. You can make use of this Table by doing the set of practice problems given at the end of this page.
    CHARACTERISTIC INFRARED ABSORPTION FREQUENCIES Bond C-H Alkanes CH3 Umbrella Deformation C-H Alkenes Aromatic Rings C-H Phenyl Ring Substitution Bands Phenyl Ring Substitution Overtones C-H Alkynes C=C Alkenes C Compound Type Frequency range, cm-1 2960-2850(s) stretch 1470-1350(v) scissoring and bending 1380(m-w) - Doublet - isopropyl, t-butyl 3080-3020(m) stretch 1000-675(s) bend 3100-3000(m) stretch 870-675(s) bend 2000-1600(w) - fingerprint region 3333-3267(s) stretch 700-610(b) bend 1680-1640(m,w)) stretch 2260-2100(w,sh) stretch 1600, 1500(w) stretch 1260-1000(s) stretch 1760-1670(s) stretch 3640-3160(s,br) stretch 3600-3200(b) stretch 3000-2500(b) stretch 3500-3300(m) stretch 1650-1580 (m) bend 1340-1020(m) stretch 2260-2220(v) stretch 1660-1500(s) asymmetrical stretch 1390-1260(s) symmetrical stretch

    Alkynes

    C=C Aromatic Rings C-O Alcohols, Ethers, Carboxylic acids, Esters C=O Aldehydes, Ketones, Carboxylic acids, Esters Monomeric -- Alcohols, Phenols O-H Hydrogen-bonded -- Alcohols, Phenols Carboxylic acids N-H Amines C-N Amines C N Nitriles NO2 Nitro Compounds

    v - variable, m - medium, s - strong, br - broad, w - weak

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