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    Six new oleanane saponins were isolated from the leaves of Gymnema sylvestre along with two known triterpene saponins. The structures of the new oleanane triterpene glycosides were characterized based on hydrolysis, 1D and 2D NMR spectroscopy, and FABMS analysis. The compounds included longispinogenin 3-O-beta-D-glucuronopyranoside and 21 betabenzoylsitakisogenin 3-O-beta-D-glucuronopyranoside.

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    Six new oleanane saponins were isolated from the leaves of Gymnema sylvestre along with two known triterpene saponins. The structures of the new oleanane triterpene glycosides were characterized based on hydrolysis, 1D and 2D NMR spectroscopy, and FABMS analysis. The compounds included longispinogenin 3-O-beta-D-glucuronopyranoside and 21 betabenzoylsitakisogenin 3-O-beta-D-glucuronopyranoside.

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    Gymnema Sylvestre Scientific Paper 19

    Uploaded by

    arjunisme
    Six new oleanane saponins were isolated from the leaves of Gymnema sylvestre along with two known triterpene saponins. The structures of the new oleanane triterpene glycosides were characterized based on hydrolysis, 1D and 2D NMR spectroscopy, and FABMS analysis. The compounds included longispinogenin 3-O-beta-D-glucuronopyranoside and 21 betabenzoylsitakisogenin 3-O-beta-D-glucuronopyranoside.

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    GYMNEMA SYLVESTRE -SCIENTIFIC PAPER 19

    Ye WC, Zhang QW, Liu X, Che CT, Zhao SX. Oleanane saponins from Gymnema sylvestre. Phytochemistry. 2000 Apr;53(8):893-9. Abstract Six oleanane-type saponins, along with two known triterpene saponins, were isolated from the leaves of Gymnema sylvestre. The structures of the oleanane triterpene glycosides were characterized as longispinogenin 3-O-beta-D-glucuronopyranoside, 21 betabenzoylsitakisogenin 3-O-beta-D-glucuronopyranoside, 3-O-beta-D-glucopyranosyl(1-->6)beta-D-glucopyranosyl oleanolic acid 28-O-beta-D-glucopyranosyl ester, oleanolic acid 3-Obeta-D-xylopyranosyl(1-->6)-beta-D-glucopyranosyl(1-->6)-beta-D- glucopyranoside, 3-Obeta-D-xylopyranosyl(1-->6)-beta-D-glucopyranosyl (1-->6)-beta-D-glucopyranosyl oleanolic acid 28-O-beta-D-glucopyranosyl ester and 3-O-beta-D-glucopyranosyl(1-->6)-beta-Dglucopyranosyl oleanolic acid 28-beta-D-glucopyranosyl(1-->6)-beta-D-glucopyranosyl ester on the basis of hydrolysis and spectral evidence, including 1D- and 2D-NMR (TOCSY, ROESY, HMQC and HMBC) and FABMS analyses.

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