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  • Electro Chim I e

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    Manda Andreea
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    This document contains data from experiments measuring the concentration dependence of electrode potential for various redox reactions. Tables of data show concentration (C), current (I), potential (E), and other calculated values for reactions of ions like Fe2+/Fe3+, Zn, and KCl. Graphs plot potential vs concentration, current, and other variables. The data is analyzed to determine standard electrode potentials and other electrochemical constants.

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    Original Title

    Electro Chim i e

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    This document contains data from experiments measuring the concentration dependence of electrode potential for various redox reactions. Tables of data show concentration (C), current (I), potential (E), and other calculated values for reactions of ions like Fe2+/Fe3+, Zn, and KCl. Graphs plot potential vs concentration, current, and other variables. The data is analyzed to determine standard electrode potentials and other electrochemical constants.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as XLSX, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    Download as xlsx, pdf, or txt
    13 views10 pages

    Electro Chim I e

    Uploaded by

    Manda Andreea
    This document contains data from experiments measuring the concentration dependence of electrode potential for various redox reactions. Tables of data show concentration (C), current (I), potential (E), and other calculated values for reactions of ions like Fe2+/Fe3+, Zn, and KCl. Graphs plot potential vs concentration, current, and other variables. The data is analyzed to determine standard electrode potentials and other electrochemical constants.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as XLSX, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    Download as xlsx, pdf, or txt
    of 10

    Influenta concentratiei asupra potentialului de electrod

    q
    0.1
    0.05
    0.02
    0.01
    0.005
    0.002
    0.001
    0.0005
    0.1
    0.005
    0.025
    0.0125
    0.00625
    0.00312
    0.0015625

    I
    o
    n
    o
    f
    o
    r
    i
    o
    n
    o
    g
    e
    n

    0.0036
    0.004
    0.00215
    0.0012
    0.00065
    0.000274
    0.000143
    0.000073
    0.0007
    0.0005
    0.00036
    0.00025
    0.000181
    0.00013
    0.000112

    l
    0.01021040
    0.01134489
    0.00609788
    0.00340347
    0.00184354
    0.00077712
    0.00040558
    0.00020704
    0.00198536
    0.00141811
    0.00102104
    0.00070906
    0.00051336
    0.00036871
    0.00031766

    k mediu

    102.104
    226.8977778
    304.8938889
    340.3466667
    368.7088889
    388.5624444
    405.5797778
    414.0884444
    19.85355556
    283.6222222
    40.8416
    56.72444444
    82.13699556
    118.1759259
    203.3004089

    KCl
    C

    q
    0.01
    0.02

    5.00E-04
    9.00E-04

    0.001359
    0.002659

    2.72E+00
    2.95E+00

    2.84E+00

    sqrt( c )
    0.316228
    0.223607
    0.141421
    0.1
    0.070711
    0.044721
    0.031623
    0.022361
    0.316228
    0.070711
    0.158114
    0.111803
    0.079057
    0.055857
    0.039528

    0.050815
    0.725934
    0.104534
    0.145187
    0.21023
    0.302472
    0.520349

    0.000272
    0.009614
    0.000305
    0.000308
    0.00035
    0.000409
    0.000882

    450
    400
    y = -1025.5x + 440.77
    R = 0.9926

    350
    300

    250

    Series1

    200

    Linear (Series1)

    150
    100
    50
    0
    0

    0.05

    0.1

    0.15

    0.2

    0.25

    0.3

    0.35

    R()

    I(mA)
    0
    1
    2
    3
    4
    5

    EB(V)
    111111
    811
    351
    201
    121
    71

    Ramp ()

    1.045
    1.01
    0.96
    0.933
    0.9
    0.85

    55

    1/Eb

    1/R+Ramp

    0.956938
    0.990099
    1.041667
    1.071811
    1.111111
    1.176471

    1.4

    8.99556E-06
    0.001233046
    0.002849003
    0.004975124
    0.008264463
    0.014084507

    1.2

    1
    0.8
    0.6

    Timp / min Temperatura/ C


    1
    23.5
    2
    23.5
    3
    23.5
    4
    5
    6
    7
    8
    9
    10
    16
    17
    18
    19
    20
    21
    22
    23
    24
    25
    26
    27
    28
    29

    23.5
    23.5
    23.5
    23.5
    23.5
    23.5
    23.5
    24.5
    24.6
    24.7
    24.7
    24.7
    24.7
    24.7
    24.7
    24.7
    24.7
    24.7
    25
    25
    25

    1/E
    E
    Ri/E
    Ri

    0.979
    1.02145
    14.97

    0.4

    15.29111

    0.2

    0.002

    0.004

    0.006

    25.2
    25
    24.8
    24.6
    24.4
    24.2
    24

    23.8
    23.6
    23.4

    Moli Zn
    Q1

    0.0078125
    73.96605307

    10

    Intensitatea
    T1

    15

    20

    1
    1.2

    25

    30
    31
    32
    33
    34

    25
    25
    25
    25
    25

    Q
    H

    18.49151327
    2366.913698

    T2
    Eb

    0.3
    9.1

    y = 14.97x + 0.9796
    R = 0.9524

    0.006

    0.008

    25

    0.01

    30

    0.012

    0.014

    35

    0.016

    40

    Conc
    E
    0.001
    0.002
    0.005
    0.01
    0.02

    E'
    0.69
    1.044
    0.71 1.028478
    0.73 1.001522
    0.74
    0.976
    0.741 0.941478

    c
    0.031623
    0.044721
    0.070711
    0.1
    0.141421

    Ps

    1.07
    0.926

    1.06
    1.04
    1.02
    1
    0.98
    y = -0.9264x + 1.0703
    0.96
    0.94
    0.92
    0

    0.02

    0.04

    0.06

    0.08

    0.1

    0.12

    0.14

    0.16

    Eb(V)
    0
    1.6
    1.8
    2
    2.2
    2.4
    2.6
    2.8
    3
    3.2
    3.4
    3.8
    4

    I(A)
    0
    0.014
    0.038
    0.046
    0.056
    0.066
    0.076
    0.086
    0.096
    0.1
    0.108
    0.122
    0.13

    i-(A/cm2) -(V)
    (V)
    lg|I_|
    ||
    0
    -0.526
    0
    0
    0
    0.000667
    -0.567
    -0.041 -3.17609
    0.041
    0.00181
    -0.656
    -0.13 -2.74244
    0.13
    0.00219
    -0.736
    -0.21 -2.65946
    0.21
    0.002667
    -0.78
    -0.254 -2.57403
    0.254
    0.003143
    -0.801
    -0.275 -2.50268
    0.275
    0.003619
    -0.817
    -0.291 -2.44141
    0.291
    0.004095
    -0.834
    -0.308 -2.38772
    0.308
    0.004571
    -0.85
    -0.324 -2.33995
    0.324
    0.004762
    -0.866
    -0.34 -2.32222
    0.34
    0.005143
    -0.881
    -0.355
    -2.2888
    0.355
    0.00581
    -0.915
    -0.389 -2.23586
    0.389
    0.00619
    -1.05
    -0.524 -2.20828
    0.524

    y = 0.4247x + 1.3442

    -3.4

    I /a

    Determinarea potentialului de descarcare

    0.18
    0.16
    0.14
    0.12
    0.1
    0.08
    0.06
    0.04
    0.02
    0
    -0.02 0.5
    -0.04

    1.5

    2.5
    Eb / v

    3.5

    0.6

    y = 0.4247x + 1.3442

    Verificarea relatiei Tafel

    0.5
    0.4
    0.3
    0.2
    0.1
    0

    -3.4

    -3.2

    -3

    -2.8

    -2.6

    -2.4

    -2.2

    -2
    -0.1

    i0

    c
    0.057
    0.039
    0.023
    0.011

    lg c
    0.1
    0.01
    0.001
    0.0001

    -1
    -2
    -3
    -4

    j
    0.302
    0.284
    0.268
    0.256

    0.2
    0.02
    0.002
    0.0002

    lg f
    lg a
    -0.48524 -1.48524
    -0.22569 -2.22569
    -0.08385 -3.08385
    -0.02807 -4.02807

    Calcul potential standard si z


    y = 0.018x + 0.3262

    -4.5

    -4

    -3.5

    Z
    0

    -3

    -2.5

    -2

    -1.5

    0.31
    0.3
    0.29
    0.28
    0.27
    0.26
    0.25
    0.24
    -1.5

    -1

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