Scribd Logo
Upload

Welcome to Scribd!

  • 10 views

    Acidic Powers & Their Orders (Chemistry Fact Sheet-1) : Acidic Power Order Why ?

    Uploaded by

    DEEPAK KUMAR MALLICK
    1. Acidic strength decreases as the distance of a halogen (-I) substituent increases in the order Cl > Br > I, due to their increasing electronegativity. Alkyl groups like -CH3 are electron donating and increase acidic strength, while electron withdrawing groups like -NO2 decrease acidic strength. 2. The presence of an additional -COOH group decreases acidic strength as the distance between the two carboxyl groups increases. A dinitro compound is more acidic than a mononitro due to electron withdrawing effects. 3. The position of substituents on the aromatic ring influences acidic strength. An -OH group is electron withdrawing at the ortho- and

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as DOC, PDF, TXT or read online from Scribd
    Flag for inappropriate content

    You might also like

    Acidic Powers & Their Orders (Chemistry Fact Sheet-1) : Acidic Power Order Why ?

    Uploaded by

    DEEPAK KUMAR MALLICK
    10 views2 pages
    1. Acidic strength decreases as the distance of a halogen (-I) substituent increases in the order Cl > Br > I, due to their increasing electronegativity. Alkyl groups like -CH3 are electron donating and increase acidic strength, while electron withdrawing groups like -NO2 decrease acidic strength. 2. The presence of an additional -COOH group decreases acidic strength as the distance between the two carboxyl groups increases. A dinitro compound is more acidic than a mononitro due to electron withdrawing effects. 3. The position of substituents on the aromatic ring influences acidic strength. An -OH group is electron withdrawing at the ortho- and

    Original Description:

    Acidic Powers1

    Original Title

    Acidic Powers1

    Copyright

    © Attribution Non-Commercial (BY-NC)

    Available Formats

    DOC, PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Report this Document
    1. Acidic strength decreases as the distance of a halogen (-I) substituent increases in the order Cl > Br > I, due to their increasing electronegativity. Alkyl groups like -CH3 are electron donating and increase acidic strength, while electron withdrawing groups like -NO2 decrease acidic strength. 2. The presence of an additional -COOH group decreases acidic strength as the distance between the two carboxyl groups increases. A dinitro compound is more acidic than a mononitro due to electron withdrawing effects. 3. The position of substituents on the aromatic ring influences acidic strength. An -OH group is electron withdrawing at the ortho- and

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as DOC, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    Download as doc, pdf, or txt
    10 views2 pages

    Acidic Powers & Their Orders (Chemistry Fact Sheet-1) : Acidic Power Order Why ?

    Uploaded by

    DEEPAK KUMAR MALLICK
    1. Acidic strength decreases as the distance of a halogen (-I) substituent increases in the order Cl > Br > I, due to their increasing electronegativity. Alkyl groups like -CH3 are electron donating and increase acidic strength, while electron withdrawing groups like -NO2 decrease acidic strength. 2. The presence of an additional -COOH group decreases acidic strength as the distance between the two carboxyl groups increases. A dinitro compound is more acidic than a mononitro due to electron withdrawing effects. 3. The position of substituents on the aromatic ring influences acidic strength. An -OH group is electron withdrawing at the ortho- and

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as DOC, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    Download as doc, pdf, or txt
    of 2

    Acidic Powers & Their Orders (Chemistry Fact Sheet- 1)

    Acidic power 1.

    Order

    Why ?

    2.

    Farther the (I) group (Cl), lesser III < II < I the acidic strength Farther the (+I) I < II < III group, greater the acidic power CH3 is electron donating and II < I < III NO2 is electron attracting

    3.

    4.

    CH3 is electron repelling; II < I < III decreases acidic strength of phenol

    5.

    OCH3 group contains +M effect III < I < II and decreases acidic poer.

    6.

    7.

    NO2 is electron attracting; III is more resonance stabilised than I I < II < III and also than II. In I, only inductive effect is operative. I > II > III sp2 hybridised carbon of I, II are more electronegative hence acid strength is increased. Benzylic (C6H5CH2) is more stab-ilised than allylic

    (CH2==CHCH2).

    8.

    Effect of one COOH on the other decr-eases I > II > III > as its distance IV between them increases, (COOH)2 is maximum acidic. NO2 is electron II < III < I attracting (I effect) OH shows electron withdrawing nature at o - and m - and electron repelling at p -, o III < II < I - isomer due to intramolecular bonding in salicylate ion is stronger than m isomer III < II < I do I < III < II NH2 is electron donating.

    9.

    10.

    11. 12.

    You might also like