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    Basic Powers & Their Orders (Chemistry Fact Sheet-2) : Basic Power Order Why ?

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    DEEPAK KUMAR MALLICK
    This document outlines 10 orders of basicity for substituted aniline compounds. 1) Anilines with an electron donating methoxy group are more basic than ortho-substituted anilines due to steric hindrance. 2) Nitroanilines are less basic than aniline because the nitro group is electron-withdrawing. 3) Aromatic amines where the lone pair on nitrogen is delocalized in the aromatic ring are more basic than those where it is not delocalized or is delocalized across two rings.

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    Basic Powers & Their Orders (Chemistry Fact Sheet-2) : Basic Power Order Why ?

    Uploaded by

    DEEPAK KUMAR MALLICK
    3 views2 pages
    This document outlines 10 orders of basicity for substituted aniline compounds. 1) Anilines with an electron donating methoxy group are more basic than ortho-substituted anilines due to steric hindrance. 2) Nitroanilines are less basic than aniline because the nitro group is electron-withdrawing. 3) Aromatic amines where the lone pair on nitrogen is delocalized in the aromatic ring are more basic than those where it is not delocalized or is delocalized across two rings.

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    Basic Powers2

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    Basic Powers2

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    This document outlines 10 orders of basicity for substituted aniline compounds. 1) Anilines with an electron donating methoxy group are more basic than ortho-substituted anilines due to steric hindrance. 2) Nitroanilines are less basic than aniline because the nitro group is electron-withdrawing. 3) Aromatic amines where the lone pair on nitrogen is delocalized in the aromatic ring are more basic than those where it is not delocalized or is delocalized across two rings.

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    3 views2 pages

    Basic Powers & Their Orders (Chemistry Fact Sheet-2) : Basic Power Order Why ?

    Uploaded by

    DEEPAK KUMAR MALLICK
    This document outlines 10 orders of basicity for substituted aniline compounds. 1) Anilines with an electron donating methoxy group are more basic than ortho-substituted anilines due to steric hindrance. 2) Nitroanilines are less basic than aniline because the nitro group is electron-withdrawing. 3) Aromatic amines where the lone pair on nitrogen is delocalized in the aromatic ring are more basic than those where it is not delocalized or is delocalized across two rings.

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    Basic Powers & Their Orders (Chemistry Fact Sheet- 2)

    Basic power Why ? lone pair on N is not used in resonance of -electrons in I. In II lone pair of the ring is I > III > II itself used in delocalisation while that of outside ring in III. OCH3 is strong electron donating group. This is due to I > II > III ortho effect, all the > IV aniline are less basic than p-substituted aniline due to steric hindrance. I (hyper conugation and induction) II I > II > III (induction) IV (ortho > IV effect), ortho effect normally decreases basic nature. Order

    1.

    2.

    3.

    4.

    In II there is sp3 hybridised C, In I, sp2. II > I > III NO2 is electron withdrawing.

    5.

    lone pair on N is used in delocalisation of electrons in aromatic amines while III > I > II cyclohexyl is electron repelling (III); in II, lone pair on N is used by two benzene ring. NO2 is electronwithdrawing, thus nitro-anilines are less I > II > III basic than aniline. IV is > IV less basic than III because NO2 is closer and exerts a stronger inductive effect.

    6.

    7.

    phenyl and COCH3 are electronwithdraIII > I > II wing and C6H5 < COCH3

    8.

    Electron donating I < II < III nature of C2H5 > CH3 So more basic strength.

    9.

    I < II < III ortho effect in I.

    10.

    I < II < III ortho effect in (I)

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