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Lewis Acids and Bases
Lewis Acids and Bases
Base Concept which states: An acid substance is one which can employ an electron lone pair from another molecule in completing the stable group of one of its own atoms.
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Lewis acids and bases are defined in terms of electron pair transfers. A Lewis base is an electron pair donor, and a Lewis acid is an electron pair acceptor.
An organic transformation (the creation of products from reactants) essentially results from a process of breaking bonds and forming new ones. This process basically amounts to electron pair transfers. Ionic mechanisms involve electron pair transfers and are therefore described by the Lewis acid-base theory. The Lewis definition implies the presence of high electron density centers in Lewis bases, and low electron density centers in Lewis acids.
definitions of acids and bases, Lewis bases are sometimes called nucleophiles, and Lewis acids are called electrophiles.
Gilbert N. Lewis in 1923, specifically: An acid substance is one which can employ an electron lone pair from another molecule in completing the stable group of one of its own atoms. Thus, H3O+ is a Lewis acid, since it can accept a lone pair, completing its stable form, which requires two electrons.
electrons to a Lewis acid to form a Lewis adduct. For example, OH and NH3 are Lewis bases, because they can donate a lone pair of electrons. bases, because they can either accept a pair of electrons or donate a pair of electrons, depending upon the reaction
* Some compounds, such as H2O, are both Lewis acids and Lewis