Repulsion (I.e. The One That Causes The Smallest Deviation From The Ideal Shape) Is

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Three types of repulsion take place between the electrons of a molecule:

The lone pair-lone pair repulsion The lone pair-bonding pair repulsion between the atoms The bonding pair-bonding pair repulsion.

A molecule must avoid these repulsions to remain/stay stable. The theory states that; repulsion becomes zero at ~115-120. When repulsion cannot be avoided, the weaker repulsion (i.e. the one that causes the smallest deviation from the ideal shape) is preferred. The lone pair-lone pair (lp-lp) repulsion is considered to be stronger than the lone pair-bonding pair (lp-bp) repulsion, which in turn is stronger than the bonding pairbonding pair (bp-bp) repulsion. Hence, the weaker bp-bp repulsion is preferred over the lp-lp or lp-bp repulsion. Larger molecules which fail to even maintain 90 between their electron pairs prefer to lie in more than one plane.

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