B GIO DC V O TO

THI CHNH THC

K THI CHN HC SINH GII QUC GIA

LP 12 THPT NM 2011
Mn: HO HC
Thi gian: 180 pht (khng k thi gian giao )
Ngy thi th nht: 11/01/2011
thi c 02 trang, gm 06 cu

Cu 1. (3,5 im)
1. Clo, brom, iot c th kt hp vi flo to thnh cc hp cht dng XFm. Thc nghim cho thy
rng m c 3 gi tr khc nhau nu X l Cl hoc Br, m c 4 gi tr khc nhau nu X l I.
a) Hy vit cng thc cc hp cht dng XFm ca mi nguyn t Cl, Br, I.
b) Da vo cu to nguyn t v m in ca cc nguyn t, hy gii thch s hnh thnh cc
hp cht trn.
Cho: m in ca F l 4,0; Cl l 3,2; Br l 3,0; I l 2,7.
32
2. P phn r - vi chu k bn hu 14,28 ngy, c iu ch bng phn ng gia ntron vi
ht nhn 32S.
a) Vit cc phng trnh phn ng ht nhn iu ch 32P v biu din s phn r phng x ca 32P.
b) C hai mu phng x 32P c k hiu l mu I v mu II. Mu I c hot phng x 20 mCi
c lu gi trong bnh t ti bung lm mt c nhit 10 oC. Mu II c hot phng x 2 Ci
bt u c lu gi cng thi im vi mu I nhng nhit 20 oC. Khi hot phng x ca
mu II ch cn 5.10-1 Ci th lng lu hunh xut hin trong bnh cha mu I l bao nhiu gam?
Trc khi lu gi, trong bnh khng c lu hunh.
Cho: 1 Ci = 3,7.1010 Bq (1Bq = 1 phn r/giy); s Avogaro NA = 6,02.1023 mol-1; hot
phng x A = .N ( l hng s tc phn r, N l s ht nhn phng x thi im t).
Cu 2. (3,5 im)
Mt phn ng pha kh xy ra theo phng trnh: X(k) Y(k) (1). Khi nng u [X]0 = 0,02 mol.L-1
th tc u ca phn ng v0 ( 25 oC) l 4.10-4 mol.L-1.pht-1; nh lut tc ca phn ng c
dng: v = k.[X] (2), trong k l hng s tc ca phn ng.
1. Tm biu thc lin h lgv (logarit ca tc phn ng) vi thi gian phn ng t v tnh cc h
s trong biu thc ny cho trng hp ca phn ng (1).
2. Tnh thi gian phn ng mt na trong cc iu kin ni trn.
3. Phn ng 2NO (k) + 2H2 (k) N2 (k) + 2H2O (k) tun theo quy lut ng hc thc
nghim: v = k[NO]2[H2]. Hai c ch c xut cho phn ng ny:
C ch 2:
C ch 1:
2 NO (k) N2O2 (k)
(nhanh)
2 NO (k)
N2O2 (k)
(nhanh)
N2O2 (k) + H2 (k) 2HON (k)
(nhanh)
N2O2 (k) + H2 (k) N2O (k) + H2O (k) (chm)
HON (k) + H2 (k) H2O (k) + HN (k) (chm)
N2O (k) + H2 (k) N2 (k) + H2O (k) (nhanh).
HN (k) + HON (k) N2 (k) + H2O (k) (nhanh).
C ch no ph hp vi quy lut ng hc thc nghim? Ti sao?
Cu 3. (3,5 im)
Cho hng s kh R = 8,314 J.mol1.K1. p sut tiu chun P0 = 1,000 bar = 1,000.105 Pa,
nhit 298 K, ta c cc d kin nhit ng hc:
Kh
H2
N2
NH3
0
-1
0
0
45,9
Bin thin entanpi hnh thnh H f (kJ.mol )
Entropi S0(J.mol1.K1)
130,7
191,6
192,8
Lin kt
Bin thin entanpi phn li lin kt H 0b (kJ.mol1)

NN
945

N=N
466

N-N
159

H-H
436

Trang 1/2

1. Tnh bin thin entanpi, bin thin entropi, bin thin nng lng t do Gibbs v hng s cn
bng K ca phn ng tng hp amoniac t nit v hiro iu kin nhit v p sut trn.
2. Trong thc t sn xut, phn ng tng hp amoniac c thc hin nhit cao.
a) Chp nhn gn ng vic b qua s ph thuc nhit ca H v S, hy tnh hng s cn
bng K ca phn ng T = 773 K.
b) Nhn xt v hng u tin ca phn ng 298 K v 773 K. Gii thch ti sao li tin hnh
tng hp NH3 nhit cao. tng hiu sut tng hp amoniac trong cng nghip, c th a
ra bin php g? Gii thch.
3. Tnh bin thin entanpi phn li lin kt H 0b ca mt lin kt N-H trong phn t amoniac.
4. Tnh bin thin entanpi hnh thnh tiu chun H 0f ca gc NH2. Cho H 0b(H-NH 2 ) = 380 kJ.mol-1.
Cu 4. (3,0 im)
Trong mi trng axit, H2C2O4 b KMnO4 oxi ho thnh CO2. Trn 50,00 mL dung dch KMnO4
0,0080 M vi 25,00 mL H2C2O4 0,20 M v 25,00 mL dung dch HClO4 0,80 M c dung dch A.
1. Vit phng trnh phn ng xy ra. Tnh hng s cn bng ca phn ng v xc nh thnh
phn ca dung dch A.
2. Trn 10,00 mL dung dch A vi 10,00 mL dung dch B gm Ca(NO3)2 0,020 M v Ba(NO3)2 0,10 M.
C kt ta no tch ra?
Chp nhn s cng kt l khng ng k; th tch dung dch to thnh khi pha trn bng tng
th tch ca cc dung dch thnh phn.
RT
= 0,0592 ;
Cho: E 0 - + 2+ = 1,51 V; E 0CO2/H2C2O4 = - 0,49 V ; 25 oC: 2,303
MnO4 , H /Mn
F
pK a1(H 2C2O4 ) = 1,25; pK a2(H 2C2O4 ) = 4,27; pK a1(H 2O + CO2 ) = 6,35; pK a2(H2O + CO2 ) = 10,33 ;
pK s(CaC2O4 ) = 8,75; pK s(CaCO3 ) = 8,35; pK s(BaC2O4 ) = 6,80; pK s(BaCO3 ) = 8,30 ;

(pKS = - lgKS, vi KS l tch s tan; pKa = - lgKa, vi Ka l hng s phn li axit).

tan ca CO2 trong nc 25 oC l LCO2 = 0,030 M.
Cu 5. (3,0 im)
1. Cho: E 0 - +

= 1,51 V; E 0

a) Tnh E 0

v E 0

MnO4 , H /Mn 2+

MnO-4 , H 2O/MnO 2

MnO 42- , H + /MnO2

MnO-4 /MnO 42-

= 2,26 V; E 0

MnO2 , H + /Mn 2+

= 1,23 V.

b) Nhn xt v kh nng oxi ha ca MnO-4 trong mi trng axit, trung tnh v baz. Gii thch.
2. Vit phng trnh ion ca cc phn ng minh ha kh nng oxi ha ca ion pemanganat
ph thuc vo pH ca mi trng.
Cu 6. (3,5 im)
xc nh hm lng ca crom v st trong mt mu gm Cr2O3 v Fe2O3, ngi ta un
nng chy 1,98 gam mu vi Na2O2 oxi ha Cr2O3 thnh CrO24 . Cho khi nung chy vo
nc, un si phn hu ht Na2O2. Thm H2SO4 long n d vo hn hp thu c v pha thnh
100,00 mL, c dung dch A c mu vng da cam. Cho dung dch KI (d) vo 10,00 mL dung dch
A, lng I3- (sn phm ca phn ng gia I v I2) gii phng ra phn ng ht vi 10,50 mL dung dch
Na2S2O3 0,40 M. Nu cho dung dch NaF (d) vo 10,00 mL dung dch A ri nh tip dung dch KI
n d th lng I3- gii phng ra ch phn ng ht vi 7,50 mL dung dch Na2S2O3 0,40 M.
1. Vit cc phng trnh phn ng xy ra.
2. Gii thch vai tr ca dung dch NaF.
3. Tnh thnh phn % khi lng ca crom v st trong mu ban u. Cho: Fe = 56; Cr = 52.
---------------------HT-------------------* Th sinh khng c s dng ti liu.
* Gim th khng gii thch g thm.
Trang 2/2

B GIO DC V O TO

K THI CHN HC SINH GII QUC GIA

LP 12 THPT NM 2011
P N THI CHNH THC
Mn: HO HC
Ngy thi th nht: 11/01/2011
(Gm 06 trang)

Cu 1

1
(2,0
im)

a) Cng thc cc hp cht XFm:

X l Cl c ClF; ClF3; ClF5 (a); X l Br c BrF; BrF3; BrF5 (b);
X l I c IF; IF3; IF5; IF7 (c).
b) Cc hp cht trn u c lin kt cng ha tr, mi lin kt c to thnh do 2
electron c spin i song song ca 2 nguyn t gp chung.
* F (Z = 9; n = 2) c 4 AO ha tr, v vy cu hnh ch c 1 electron c thn:
* Cl (Z = 17; n = 3), Br (Z = 35; 9n = 4), I (Z = 53; n = 5) ging nhau u c 9 AO
ha tr, c th c:
1 electron c thn:
hoc 3 electron c thn:
5 electron c thn:
7 electron c thn:
- Hp cht ClF7 khng tn ti v th tch nguyn t clo rt nh, lc y ca cc v
nguyn t flo s ph v lin kt trong phn t. Hp cht BrF7 tng t hp cht ClF7
(hp cht BrF7 hin nay cha iu ch c).
- Hp cht IF7 tn ti v th tch nguyn t iot rt ln so vi th tch nguyn t flo, lc
y ca cc v nguyn t flo khng ph v c cc lin kt trong phn t.

2
(1,5

im)

a) Phng trnh phn ng ht nhn iu ch 32P:

v phn r phng x ca 32P:

16

32

15

S + 01n 1532P + 11p

P
1632S + -

32

t/t1/2

A
5.10-1Ci 1 1
t/t1/2 = 2 t = 2.t1/2. Vy thi gian lu gi l 2
=
= =
A0
2Ci
4 2
chu k bn hu.
Tc phn r phng x khng ph thuc vo nng u v nhit , nn sau
thi gian lng 32P ca mu I cng ch cn li 1/4 so vi lc u gim hot
3
phng x trong mu I l: 20 mCi =15 mCi = 15.10-3.3,7.1010 Bq = 15.3,7.107 Bq.
4
S ht nhn bin i phng x l:
A A.t1/2 15.3,7.107 .14,28.24.3600
=
=
= 9,9.1014 nguyn t
N=

ln2
0,693
b)

32.9,9.1014
= 5,3.10-8 (g) = 5,3.10-2 (g)
Khi lng P phn r l: m 32 P =
23
6,02.10
Khi b qua s ht khi ca phn r phng x, khi lng 32S to thnh ng bng
khi lng 32P phn r: m(32S) = 5,3.10-2g.
32

Trang 1/6

Cu 2
1
(1,0
im)

2
(0,75
im)
3
(1,75
im)

Phn ng l bc 1 nn: [X] = [X]0.e-kt (1) v = k[X] = k.[X]0.e-kt

lnv = ln(k[X]0) - kt (2) Hay: lnv = lnv0 - kt (3) (v0 l tc u ca phn
ng) lgv = lgv0 kt/2,303.
v
k = 0 = 4.10-4/2.10-2 = 2.10-2(pht-1) lgv = -3,4 - 8,7.10-3t
[X]0
(t: pht; v: mol.L-1.pht-1).
(Nhng biu thc trong lgv l hm ca mt bin s c lp t u coi l ng).

i vi phn ng bc 1:
ln2
0,693
=
= 34, 7 (pht)
k 2.10-2 (pht) 1
Phn ng 2NO (k) + 2H2 (k) N2 (k) + 2H2O (k) tun theo quy lut ng
hc thc nghim: v = k[NO]2[H2].
C ch 1:
k1
2NO (k)
N2O2 (k)
(nhanh)
(1)
k2
(nhanh)
(2)
N2O2 (k) + H2 (k) 2HON (k)
k3
(chm)
(3)
HON (k) + H2 (k) H2O (k) +HN (k)
t1/2 =

4
HN (k) + HON (k)
N2 (k) + H2O (k) (nhanh)
(4)
Chp nhn gn ng rng giai on quyt nh tc phn ng l giai on
chm nht.
* Trong c ch cho, giai on 3 chm, quyt nh tc phn ng, nn:
v = k3.[HON][H2]
(5)
Khi nng cc sn phm trung gian t c trng thi dng
d[N 2 O 2 ] 1
k [NO]2
= k1[NO]2 k2[H2][N2O2] = 0 (6) [N2O2] = 1
(7)
2
dt
2k 2 [H 2 ]
d[HON]
= 2k2[H2][N2O2] - k3.[HON][H2] k4[HON][HN] = 0
(8)
dt
d[HN]
= k3.[HON][H2] k4[HON][HN] = 0
(9)
dt
k [N O ]
(10)
Ly (8) tr (9) v bin i n gin, ta c: [HON] = 2 2 2
k3

Thay (7) vo (10) rt ra:

[HON] =

k1[NO]2
2k 3 [H 2 ]

(11)

k1[NO]2
= k[NO]2. Kt qu ny khng ph hp
2
vi inh lut tc thc nghim. C ch 1 l khng c kh nng.
C ch 2:
2NO
N2O2
Kcb
(nhanh)
(12)
k5
(chm)
(13)
N2O2 + H2 N2O + H2O
k6
N2O + H2 N2 + H2O
(nhanh)
(14)
Tc phn ng c quyt nh bi (13), nn: v = k5[N2O2].[H2] (15)
Da vo cn bng 2 NO
N2O2, rt ra: [N2O2] = Kcb.[NO]2
(16)
Thay (16) vo (15) thu c: v = Kcb.k5[NO]2.[H2] = k[NO]2.[H2].
Kt lun: C ch 2 cho php rt ra biu thc ca nh lut tc thc nghim. C
ch ny l c kh nng.
Thay (11) vo (5) thu c: v =

Trang 2/6

Cu 3
1
(0,75
im)

N2 + 3H2

2NH3

(1)

298K, H 0r = - 91,8 kJ.mol-1; S0r = -198,1 J.mol-1.K-1;

G 0r = H 0r 298. S0r = -32,8 (kJ.mol-1);
G 0r = -R.T.lnK lnK = - G 0r (R.T)-1 = 13,24 K = 5,62.105.

2
(1,5
im)

a) Tnh hng s cn bng K ca phn ng T = 773 K:

773K: G 0r (773 K) = H 0r - T. S0r - 91,8 + 773.198,1.10-3 = 61,3 (kJ.mol-1)
lnK = - 61,3.103.(8,314.773)-1 = - 9,54 K = e-9,54 = 7,2.10-5.
b) 298 K, hng s cn bng K >> 1. Phn ng (1) din ra u tin theo chiu thun.
773 K, hng s cn bng K << 1. Phn ng (1) din ra u tin theo chiu nghch.
Mc d nhit cao (773K), phn ng (1) din ra u tin theo chiu nghch,
nhng tc phn ng ln, cn tc phn ng 298 K qu nh. tng tc phn
ng, lm h nhanh t n cn bng, ngi ta buc phi tin hnh phn ng nhit
cao.
tng hiu sut tng hp amoniac trong cng nghip:
- Phn ng (1) gim s mol kh. cn bng chuyn dch theo chiu thun, tng hiu
sut tng hp amoniac cn thc hin phn ng p sut cao.
- Hiu sut to thnh amoniac l cc i khi t l ca kh H2 v kh N2 c ly ng
bng t l cc h s ca chng trong phng trnh phn ng, ngha l H2 : N2 l 3 : 1.

3
(0,5
im)

Tnh bin thin entanpi phn li lin kt H 0b ca mt lin kt N-H trong phn t amoniac:
N2 + 3H2 2NH3
2H1 = 2.(-45,9) kJ.mol-1 (1)
N2
2 Ni
H2 = 945 kJ.mol-1
(2)
-1
3H2
6 Hi
3H3 = 3.436 kJ.mol
(3)
0
T (1), (2), (3), ta c: 2 Ni + 6 Hi 2NH3
6 H (N-H)
6 H 0(N-H) = -2.45,9 945 3.436 = - 2344,8 (kJ.mol-1) H 0b(N-H) = 390,8 kJ.mol-1

4
(0,75
im)

Tnh bin thin entanpi hnh thnh tiu chun H 0f ca gc NH2:

N2 + 3H2 2NH3
2H1 = 2.(-45,9) kJ.mol-1
H2
2 Hi
H3 = 436 kJ.mol-1
2NH3
2 i NH 2 + 2 Hi 2H4 = 2.380 kJ.mol-1
T (1), (3), (4), c: N2 + 2H2 2 i NH 2

(1)
(3)
(4)

2 H 0f( i NH 2 )

2 H 0f( i NH 2 ) = - 2.45,9 436 + 2.380 = 232,2 (kJ/mol) H 0f( i NH 2 ) = 116,1 kJ/mol

Cu 4
1
(1,0
im)

Sau khi trn: CMnO- = 0,0040 M; CH 2C2O4 = 0,050 M ; CH + = 0,20 M

4

Mn2+ + 4H2O
2CO2 + 2H+ + 2e
2 MnO-4 + 5H2C2O4 + 6H+ 2Mn2+ + 10CO2 + 8H2O

Phn ng: 2
5

0,0040
-

MnO-4 + 8H+ + 5e
H2C2O4

0,050
0,040

0,20
0,188

0,0040

K = 10337,84

0,020

TPGH: H2C2O4 0,040 M; H+ 0,188 M; CO2 0,020 M (< LCO2 = 0,030 M); Mn2+ 0,0040 M.

Trang 3/6

2
(2,0
im)

Trn dung dch A v dung dch B:

CH 2C2O 4 = 0,020 M; CH + = 0,094 M; CCO2 = 0,010 M; CMn 2+ = 0,0020 M;
CCa 2+ = 0,010 M; CBa 2+ = 0,050 M.

V s phn li ca axit cacbonic (hn hp H2O+CO2) khng ng k trong mi trng

axit, do c th coi [CO2] 0,010 M v kh nng ch xut hin kt ta oxalat (nu c).
Xt th t kt ta:
K s(CaC2O4 )
10-8,75
- c kt ta CaC2O4: C'C O2- (1)
=
= 10-6,75 M
'
2 4
0,01
CCa 2+
- c kt ta BaC2O4: C'C O2- (2)
2

K s(BaC2O4 )
C'Ba 2+

10-6,8
= 10-5,5 M
0,05

V C'C O2- (1) < C'C O2- (2) CaC2O4 s kt ta trc. Do K a1(H 2C2O4 )
2

nng cc cu t c tnh theo cn bng:

H+
H2C2O4
C' 0,020 x

C'H+

= x = 7,15.10 M;

K a1 = 101,25

HC2 O-4

0,094+x

-3

C'HC O2 4

K a2(H2C2O4 ) nn

= 0,1012 M

x
C'C O22 4

= K a2

C'HC O2

C'H+

= 10-5,42 M

C'Ca 2+ . C'C O2- = 0,01.10-5,42 =10-7,42 > 10-8,75 = K s(CaC2O4 ) c CaC2O4 kt ta theo
2

Ca2+ + H2C2O4 CaC2O4 + 2H+

phn ng:

0,010
-

0,020
0,010

K = 103,23

0,094
0,114

nh gi kh nng kt ta BaC2O4 t lng d H2C2O4:

H+ + HC2 O-4
Tng t:
H2C2O4

K a1 = 101,25

C' 0,010 y
0,114+y
y
-3
'
'
CHC O- = y = 3,24.10 M; CH+ = 0,117 M C'C O2- = 10-5,83 M
2

C'Ba 2+
Khi

. C'C O22 4

C'Ca 2+

-5,83

= 0,05.10

K s(CaC2O4 )
C,C O22

'
Kim tra: CCO
2- =
3

-7,13

=10

-6,8

< 10

= K s(BaC2O4 ) khng c BaC2O4 kt ta.

108,75
= 5,83 = 102,92 (M)
10

K 'a1.K 'a2 .[CO 2 ] 1016,68.0, 01

=
= 1,53.10-17 (M)
+ 2
2
[H ]
(0,117)

C'Ca 2+ .C'CO2- < K s(CaCO3 ) ;C'Ba 2+ .C'CO2- < K s(BaCO3 ) khng c CaCO3 v BaCO3 tch ra.
3

Trang 4/6

Cu 5
1
(2,25
im)

a) Tnh E 0

MnO-4 , H 2O/MnO 2

v E 0

MnO-4 /MnO24

MnO-4 + 8H+ + 5e

Mn2+ + 4H2O

K1 = 105.1,51/ 0,0592

Mn2+ + 2H2O

MnO2 + 4H+ + 2e

2.1,23 / 0,0592
K -1
2 = 10

MnO2 + 2H2O

+
MnO 24 + 4H + 2e

K 3-1 = 102.2,26 / 0,0592

MnO-4

MnO 24

+e

K 4 = K1.K -12 .K 3-1 E 0

MnO-4 /MnO24

K 4 = 10

(E 0

MnO-4 /MnO24

) / 0,0592

= 5.1,51 2.(1,23+2,26) = 0,57 (V)

MnO-4 + 8H+ + 5e

Mn2+ + 4H2O

K1 = 105.1,51/ 0,0592

Mn2+ + 2H2O

MnO2 + 4H+ + 2e

2.1,23 / 0,0592
K -1
2 = 10

OH- + H+

K w = 1014

4 H2O
MnO-4

+ 2H2O + 3e

K 5 = K1.K -12 .K 4w E 0

MnO-4 , H 2O/MnO 2

b) E 0

MnO-4 , H + /Mn 2+

K 5 = 10

MnO2 + 4OH

> E0

MnO-4 , H 2O/MnO 2

(3E 0

MnO-4 /MnO 2

) / 0,0592

5.1,51 2.1, 23 14.4.0, 0592

= 0,59 (V)
3

> E0

MnO-4 /MnO24

kh nng oxi ha ca

MnO-4 mnh nht trong mi trng axit v yu nht trong mi trng baz, bi v:

MnO-4 , H + /Mn 2+

= E

MnO-4 , H + /Mn 2+

0,0592 [MnO-4 ][H + ]8

lg
5
[Mn 2+ ]

do khi pH tng, [H+] gim, tnh oxi ha ca MnO-4 gim.

2
(0,75
im)

Cc phn ng minh ha kh nng oxi ha ca ion pemanganat ph thuc vo pH

ca mi trng:
MnO-4 + 5Fe2+ + 8H+
Mn2+ + 5Fe3+ + 4H2O
2 MnO-4 + 3 Mn 2+ + 2H2O
5MnO2 + 4H+
t

2 MnO-4 + SO32- + 2OHCu 6

1
(2,25
im)

22 MnO 24 + SO 4 + H2O

t
Cr2O3 + 3Na2O2 + H2O
2 CrO24 + 2OH- + 6Na+ (1)
t
O2 + 4OH- + 4Na+
2Na2O2 + 2H2O
+
OH
+ H
H2O
+
2
2 CrO4 + 2H
Cr2 O27 + H2O
Fe2O3 + 6H+ 2Fe3+ + 3H2O
Cr2 O27 + 9I- + 4 H+ 2 Cr3+ + 3 I3- + 7H2O

2Fe3+

3I-

2 S 2 O32 + I3Fe3+ + 3F2

(0,25
im)

(2)
(3)
(4)
(5)
(6)

2Fe2+ + I3-

(7)

S 4 O62 + 3IFeF3

(8)
(9)

Vai tr ca dung dch NaF: F- c mt trong dung dch to phc bn, khng mu vi
Fe3+, dng che Fe3+.

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3
(1,0
im)

t s mol ca Cr2O3 v Fe2O3 trong 1,98 gam mu ln lt l n Cr2O3 = x; n Fe2O3 = y

T (1), (4) v (5) trong 10,00 mL dung dch A s mol ca Cr2 O27 l n Cr O2- = 0,1x;
2

3+

s mol ca Fe l n Fe3+ = 0,2y.

Trng hp NaF khng c mt trong dung dch A, c Cr2 O72 v Fe3+ u b kh bi I-.
Theo (6) v (7) ta c: n I- (1) = 3 n Cr O2- + 0,5 n Fe3+ = 3.0,1x + 0,5.0,2y = 0,3x + 0,1y
3

T (8): n S O2- (1) = 2 n I- (1) 0,40.10,50.10-3 = 2.(0,1y + 0,3x)

2

Trng hp NaF c mt trong dung dch A, ch c Cr2 O27 b kh:

n I- (2) = 3 n Cr O2- = 0,3x 0,40.7,50.10-3 = n S O2- (2) = 2 n I- (2) = 0,6x
3

(10)
(11)

T (11) v (10) x = 0,005 (mol) v y = 0,006 (mol).

52.0, 01
.100 = 26,26%
1,98
56.0, 012
.100 = 33,94%.
n Fe = 2 n Fe2O3 = 2.0,006 = 0,012 (mol) %Fe trong mu l:
1,98
n Cr = 2 n Cr2O3 = 2.0,005 = 0,01 (mol) %Cr trong mu l:

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