S GIO DC V O TO THANH HA

CHNH THC

THI KHO ST GIO VIN NM HC 2011 2012 MN THI : HA HC Thi gian lm bi: 180 pht (khng k thi gian giao ) ===========

CU 1. (4 IM) 1.Mt hp cht X c to thnh t cc ion X+, Y2-. Trong ion X+ c 10 e v gm 5 ht nhn ca hai nguyn t. Trong ion Y2- c 4 ht nhn ca hai nguyn t thuc cng mt chu k v ng cch nhau mt trong BTH. Tng s e trong ion Y 2- l 32. Hy xc nh cc nguyn t trong hp cht Z v lp cng thc ha hc ca Z. 2. Ha tan mt s mui cacbonat ( trung ha vo nc ta c dung dch A v cht rn B. Ly mt it dung dch A t nng nhit cao thy ngn la mu vng; ly mt t dung dch A cho tc dng vi dung dch xt ( un nh) thy bay ra mt cht kh lm xanh giy qu t. Ha tan cht rn B bng dung dch H2SO4 long d thau c dung dch C, kt ta D v kh E. Cho kt ta D tc dng vi NaOH c thy tan mt phn kt ta. Cho dung dch C tc dng vi xt d c dung dch F v kt ta G b ha nu hon ton trong khng kh. Cho t t dung dch HCl vo dung dch F thy xut hin kt ta trng tan trong HCl d. Hi hn hp ban u c cha mui cacbonat g? (cc mui thng thng i vi HS THPT). Vit phng trnh ha hc ca cc phn ng. Cu II ( 3 im) Cho 9,1 g hn hp X gm c Al v Cu tc dng vi dung dch hn hp gm 2 axit H 2SO4 v HNO3 c un nng, axit ly d 10% so vi lng cn thit. Thy thu c 6,72 lit ktc hn hp kh Y mu nu gm 2 kh c dY/H 2 = 29 v dung dch Z ch c mui ca hai kim loi v axit d. a. Vit phng trnh ha hc ca cc phn ng dng ion thu gn. b. Tnh phn trm khi lng mi kim loi trong hn hp X v tnh khi lng mui trong dung dch Z. c. Nh t t dung dch NaOH nng aM vo Z thy khi th tch dung dch NaOH l 600 ml th khi lng kt ta t cc i. Tnh a v khi lng kt ta thu c khi th tch NaOH cho vo l 656,4 ml Cu III ( 3 im). Phn st amoni c cng thc (NH4)aFe(SO4)b.nH2O. Ha tan 1,00 g mu phn st vo 100ml H2O, ri chia dung dch thu c thnh hai phn bng nhau. Thm dung dch NaOH d vo phn mt v un si dung dch. Lng NH 3 thot ra phn ng va vi 10,37 ml dung dch HCl 0,100 M. Dng km kim loi kh ht Fe 3+ phn hai thnh Fe2+. oxi ha ion Fe2+ thnh ion Fe3+ tr li, cn 20,74 ml dung dch KMnO4 0,0100 M trong mi trng axit. a. Vit cc phng trnh ha hc ca phn ng dng ion thu gn v xc nh cng thc ca phn st amoni. b. Gii thch ti sao cc phn khi tan trong nc u to mi trng axit? Cu IV ( 3,0 im). 1. So snh nhit si ca cc cht trong mi dy sau ( gii thch ngn gn) a. C6H6, C6H5OH, C6H5CH3, C6H5CH2CH3. b. CH3SH, C2H5OH, CH3OH. c. o-HOC6H4CHO ( andehit o hidroxibenzoic) v p- HOC6H4CHO ( andehit p- hidroxibenzoic). d. Cs CH3CH=CH-Cl v trans CH3CH=CH-Cl 2. T C2H2 v cc ha cht v c cn thit, lp s tng hp cc cht sau: a. 1,1 icloetan b. Butan 1,4 iol c. xiclohexen d. Axit Lactic ( axit 2- hidroxi propanoic). Cu V ( 3,0 im). A l hp cht hu c cha cc nguyn t C, H, O. Cho m gam cht A tc dng ht vi 1 lit dung dch NaOH 1,2 M ri c cn dung dch thu c 85,8 g cht rn B v m1 gam ancol C. Cho C i qua H2SO4 c, un nng thu c mt anken duy nht. Oxi ha m1 gam ancol C bng oxi ( c xc tc) c hn hp X. Chia X thnh ba phn theo t l khi lng 3:2:1. - Phn I. Cho tc dng vi AgNO3 d trong NH3 thu c 32,4 g Ag kt ta. - Phn II cho tc dng vi NaHCO3 d c 2,24 lit kh ktc. - Phn III cho tc dng vi Na va c 2,24 lit ktc v 12,9 g cht rn khan. a. Xc nh cng thc cu to ca ancol C v tnh thnh phn % v s mol C b oxi ha. b. Xc nh cng thc cu to ca A.

Cu VI ( 4 im). 1. Trong phng th nghim c 7 dung dch v cht lng mt nhn, ring bit gm NH 4HCO3, Ba(HCO3)2, C6H5ONa, C6H6, C6H5NH2, C2H5OH v K [Al(OH)4)]. Hy trnh by cch nhn bit cc dung dch v cht lng trn bng mt dung dch ch cha mt cht tan. 2. C mt mu dung dch axit propionic b ln axit axetic, pha long 10 g dung dch ny thnh 100 ml dung dch A. Gi tr pH ca dung dch A bng 2,91 . trung ha 20 ml dung dch A cn dng 17,6 ml dung dch NaOH 0,125M. Tnh nng phn trm ca cc axit trong dung dch ban u, bit : K CH3COOH = 1,75.10-5 v KC2H5COOH = 1,34.10-5. Ht