Isobaric Vapor-Liquid Equilibrium of Binary

Mixture of Methyl Acetate with

Isopropylbenzene at 97.3 kPa

Methyl acetate

TC
PC
VpA
VpB
VpC
VpD
Volumen v
12
R

506.8
46.286548
-8.05406
2.56375
-5.12994
0.16125

isopropilbenzeno
631.1
31.680132
-7.46042
1.14486
-3.19082
-3.62628

0.55
0.08206

Patm

97.3
kPa

0 x1
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21

x2
1
0.95
0.9
0.85
0.8
0.75
0.7
0.65
0.6
0.55
0.5
0.45
0.4
0.35
0.3
0.25
0.2
0.15
0.1
0.05
0

0
0.05
0.1
0.15
0.2
0.25
0.3
0.35
0.4
0.45
0.5
0.55
0.6
0.65
0.7
0.75
0.8
0.85
0.9
0.95
1

K
atm

TOC
TK
55.79037062
57.19273909
58.7084231
60.30089264
62.02759919
63.8537694
65.86051716
67.97937777
70.32277713
72.8855039
75.66575195
78.78884813
82.29813813
86.3100186
90.90961692
96.24500958
102.6440338
110.4878208
120.3621369
133.2718759
150.9276124

0.96027316
atm

328.9403706
330.3427391
331.8584231
333.4508926
335.1775992
337.0037694
339.0105172
341.1293778
343.4727771
346.0355039
348.8157519
351.9388481
355.4481381
359.4600186
364.0596169
369.3950096
375.7940338
383.6378208
393.5121369
406.4218759
424.0776124

a1
a2
0.35094639 0.47878249
0.34817928 0.47656039
0.34518859 0.47415873
0.34204638 0.47163541
0.33863931 0.46889938
0.33503597 0.46600575
0.33107633 0.46282599
0.32689547 0.45946858
0.32227155 0.45575538
0.31721487 0.45169465
0.31172898 0.44728925
0.3055666
0.4423406
0.29864219 0.43678001
0.29072609 0.43042304
0.28165032 0.42313482
0.27112271
0.4146807
0.25849638 0.40454122
0.2430193 0.39211247
0.22353564 0.37646627
0.1980626 0.35601034
0.16322492 0.32803421

datos experimentales
T(K)
x1
329.08
0.9875
329.65
0.9409
330.81
0.8826
332.4
0.8238
333.16
0.7998
335.48
0.74
337.72
0.6856
339.95
0.6357
341.03
0.5998
343.39
0.543
348.17
0.4538
350.85
0.4061
356.81
0.3241
368.15
0.2158
373.52
0.1797
384.27
0.1176
401.07
0.0525
411.07
0.0258
414.47
0.0186
419.55
0.0085
422.18
0.0032

y1
0.9989
0.995
0.99
0.985
0.9833
0.978
0.9726
0.9675
0.965
0.9595
0.945
0.9353
0.9092
0.8437
0.804
0.7024
0.4736
0.2798
0.2173
0.1105
0.0435

x vs y
1.2
1
0.8
0.6
0.4
0.2
0
1

9 10 11 12 13 14 15 16
X

12g12_g22

21g21_g11
parametros

12

21 =

1.0438
1.0438
1.0438
1.0438
1.0438
1.0438
1.0438
1.0438
1.0438
1.0438
1.0438
1.0438
1.0438
1.0438
1.0438
1.0438
1.0438
1.0438
1.0438
1.0438
1.0438

-0.23275
-0.23275
-0.23275
-0.23275
-0.23275
-0.23275
-0.23275
-0.23275
-0.23275
-0.23275
-0.23275
-0.23275
-0.23275
-0.23275
-0.23275
-0.23275
-0.23275
-0.23275
-0.23275
-0.23275
-0.23275

12 =

0.0386695
0.03850534
0.03832948
0.03814643
0.03794991
0.03774427
0.03752084
0.03728779
0.03703339
0.03675912
0.03646613
0.03614253
0.0357857
0.0353863
0.03493923
0.03443458
0.03384822
0.03315617
0.03232419
0.03129743
0.02999442

21 =

-0.00862265
-0.00858605
-0.00854684
-0.00850602
-0.0084622
-0.00841634
-0.00836652
-0.00831456
-0.00825783
-0.00819667
-0.00813134
-0.00805918
-0.00797961
-0.00789056
-0.00779086
-0.00767834
-0.00754759
-0.00739327
-0.00720776
-0.00697881
-0.00668826

G12 =
0.97895635
0.97904474
0.97913944
0.97923802
0.97934387
0.97945464
0.97957501
0.97970058
0.97983767
0.97998549
0.98014342
0.98031788
0.98051029
0.9807257
0.98096689
0.9812392
0.98155569
0.98192937
0.9823788
0.98293372
0.9836384

G21 =
1.00475372
1.0047335
1.00471183
1.00468927
1.00466506
1.00463972
1.00461219
1.00458348
1.00455214
1.00451835
1.00448225
1.00444239
1.00439843
1.00434924
1.00429417
1.00423201
1.0041598
1.00407458
1.00397213
1.00384572
1.00368531

1 =

1
1.00007646
1.00030365
1.00067826
1.00119672
1.00185547
1.00265022
1.00357729
1.00463116
1.00580676
1.00709876
1.00849861
1.00999795
1.0115851
1.01324746
1.01496835
1.01672084
1.01847085
1.02016993
1.02174356
1.02307767

1.2
1
0.8
0.6
0.4
0.2
15 16 17 18 19 20 21

0
1

9 10 11 12 13 14 15 16 17 18 19 20

2 =

1.03046057
1.02725984
1.0242555
1.02144734
1.01882845
1.01639807
1.01414938
1.01208276
1.01019131
1.00847313
1.00692566
1.00554392
1.00432526
1.00326615
1.00236364
1.00161416
1.00101348
1.00055749
1.00024123
1.00005834
1

ln(Pvp/Pc)
pvp1
-3.87481916
0.9608204
-3.8258691 1.00902275
-3.77352602
1.0632448
-3.71915046 1.12266006
-3.66089615 1.19000229
-3.6000697 1.26463264
-3.53413928 1.35082039
-3.46553897 1.44673951
-3.39085405 1.55892632
-3.31056919 1.68924585
-3.2250685 1.84003184
-3.13095039 2.02162368
-3.02754677 2.24185715
-2.91227309 2.51576842
-2.78381108 2.86062548
-2.63951432 3.30467146
-2.47276217 3.90434179
-2.27713207
4.7479802
-2.04348712 5.99762921
-1.75708454 7.98661361
-1.39567151 11.4636352

Patm
ln(pvp/pc)
pvp2
PT
y1
-6.8810432 0.03253778
0.9608204
1
-6.81363032 0.03480687 0.96043268 0.99822805
-6.74155334 0.03740826 0.96104245 0.99650845
-6.66668751 0.04031637 0.96108544 0.99373916
-6.586493 0.04368269 0.96204214 0.99138648
-6.50277115 0.04749735
0.9623034
0.9877132
-6.41204066 0.05200835 0.96390352 0.98469301
-6.31765539
0.0571563 0.96399111 0.97928456
-6.21492253 0.06334034 0.96528192 0.97405179
-6.10451687 0.07073413 0.96658025
0.9675218
-5.98697603 0.07955662 0.96660069
0.9580773
-5.85763772 0.09054141 0.96753595 0.94736654
-5.7156054 0.10435929 0.96859485 0.93384143
-5.55736113 0.12225193 0.97044314 0.91694633
-5.38114438 0.14580945 0.97186431 0.89369117
-5.18340107 0.17769062 0.97201732 0.86034672
-4.95519308 0.22324101 0.97269894 0.81317316
-4.68798525 0.29162239 0.97336913 0.74166087
-4.36980122 0.40087265 0.97273251 0.62457532
-3.98167167 0.59097478 0.96947234 0.41585113
-3.4962008 0.96029854 0.96029854
0

X
Y

19 20 21

y2
0
0.00181234
0.00389559
0.00629764
0.00909797
0.01236558
0.01624799
0.02083231
0.0263843
0.03314719
0.04142395
0.05185793
0.065206
0.0827512
0.10628915
0.13878131
0.18598125
0.25813387
0.3757112
0.58465243
1.00002643

y1+y2
1
1.0000404
1.00040403
1.00003681
1.00048445
1.00007879
1.000941
1.00011687
1.0004361
1.00066899
0.99950126
0.99922446
0.99904743
0.99969752
0.99998032
0.99912803
0.99915441
0.99979474
1.00028653
1.00050356
1.00002643

Alumna:

RODRIGUEZ GAMARRA MARITZA

Isobaric Vapor-Liquid Equilibrium of Binary

Mixture of Methyl Acetate with
Isopropylbenzene at 97.3 kPa

TC
PC
VpA
VpB
VpC
VpD
Volumen v
12

Methyl acetate
isopropilbenzeno
506.8
631.1
46.286548
31.680132
-8.05406
-7.46042
2.56375
1.14486
-5.12994
-3.19082
0.16125
-3.62628

0.55

0.08206

Patm

97.3
kPa
z=

0 x1
1
2
3
4
5
6
7
8
9
10
11
12
13

x2
1
0.95
0.9
0.85
0.8
0.75
0.7
0.65
0.6
0.55
0.5
0.45
0.4

K
atm

0
0.05
0.1
0.15
0.2
0.25
0.3
0.35
0.4
0.45
0.5
0.55
0.6

0.96027316
atm

10

TOC
TK
a1
a2
55.7903706 328.9403706 0.35094639
0.47878249
57.1927391 330.3427391 0.34817928
0.476560388
58.7084231 331.8584231 0.34518859
0.474158734
60.3008926 333.4508926 0.34204638
0.47163541
62.0275992 335.1775992 0.33863931
0.468899383
63.8537694 337.0037694 0.33503597
0.466005753
65.8605172 339.0105172 0.33107633
0.462825991
67.9793778 341.1293778 0.32689547
0.459468582
70.3227771 343.4727771 0.32227155
0.455755384
72.8855039 346.0355039 0.31721487
0.451694654
75.6657519 348.8157519 0.31172898
0.447289254
78.7888481 351.9388481
0.3055666
0.442340599
82.2981381 355.4481381 0.29864219
0.436780006

14
15
16
17
18
19
20
21

0.35
0.3
0.25
0.2
0.15
0.1
0.05
0

0.65
0.7
0.75
0.8
0.85
0.9
0.95
1

86.3100186
90.9096169
96.2450096
102.644034
110.487821
120.362137
133.271876
150.927612

359.4600186
364.0596169
369.3950096
375.7940338
383.6378208
393.5121369
406.4218759
424.0776124

0.29072609
0.28165032
0.27112271
0.25849638
0.2430193
0.22353564
0.1980626
0.16322492

datos experimentales
T(K)
x1
329.08
0.9875
329.65
0.9409
330.81
0.8826
332.4
0.8238
333.16
0.7998
335.48
0.74
337.72
0.6856
339.95
0.6357
341.03
0.5998
343.39
0.543
348.17
0.4538
350.85
0.4061
356.81
0.3241
368.15
0.2158
373.52
0.1797
384.27
0.1176
401.07
0.0525
411.07
0.0258
414.47
0.0186
419.55
0.0085
422.18
0.0032

0.430423041
0.423134817
0.414680701
0.404541224
0.392112469
0.37646627
0.356010338
0.328034206

y1
0.9989
0.995
0.99
0.985
0.9833
0.978
0.9726
0.9675
0.965
0.9595
0.945
0.9353
0.9092
0.8437
0.804
0.7024
0.4736
0.2798
0.2173
0.1105
0.0435

GRUPOS FUNCIONALES

SUB GRUPO

Methyl Acetate C3H6O2

CH3-COO

CH3

IsopropylbenzeneC9H12

CH=CH

CH3

CH
tablas:

sub grupo

Rk

CH3
CH3-COO
CH=CH
CH
R1=
R2=
R3=
R4=

Qk

vk1 Methyl Acetate

1
2
3
4

0.9011
1.9031
1.1167
0.4469

0.848
1.728
0.867
0.22

0.9011
1.9031
1.1167
0.4469

Q1=
Q2=
Q3=
Q4=

0.848
1.728
0.867
0.22

1
1
0
0
v11=
v21=
v31=
v41=

1
1
0
0

PARAMETROS DE INTERACCION BINARIA ajk

tablas:
sub grupo

grupo principal

CH3
CH3-COO
CH=CH
CH

a11=
a21=
a31=
a41=

0
114.8
-35.36
0

r1
2.8042
2.8042
2.8042
2.8042
2.8042
2.8042
2.8042
2.8042
2.8042
2.8042
2.8042
2.8042
2.8042

r2
5.5992
5.5992
5.5992
5.5992
5.5992
5.5992
5.5992
5.5992
5.5992
5.5992
5.5992
5.5992
5.5992

CH3

1
11
2
1

1
0
114.8
-35.36
0

a12=
a22=
a32=
a42=

232.1
0
37.85
232.1

q1

q2
2.576
2.576
2.576
2.576
2.576
2.576
2.576
2.576
2.576
2.576
2.576
2.576
2.576

k
CH=CH
11
232.1
0
37.85
232.1

2
86.02
132.1
0
86.02

a13=
a23=
a33=
a43=

86.02
132.1
0
86.02

CH3-COO

4.517
4.517
4.517
4.517
4.517
4.517
4.517
4.517
4.517
4.517
4.517
4.517
4.517

PARMETROS
a12
a21
1.0438
-0.23275
1.0438
-0.23275
1.0438
-0.23275
1.0438
-0.23275
1.0438
-0.23275
1.0438
-0.23275
1.0438
-0.23275
1.0438
-0.23275
1.0438
-0.23275
1.0438
-0.23275
1.0438
-0.23275
1.0438
-0.23275
1.0438
-0.23275

2.8042
2.8042
2.8042
2.8042
2.8042
2.8042
2.8042
2.8042

5.5992
5.5992
5.5992
5.5992
5.5992
5.5992
5.5992
5.5992

2.576
2.576
2.576
2.576
2.576
2.576
2.576
2.576

4.517
4.517
4.517
4.517
4.517
4.517
4.517
4.517

1.0438
1.0438
1.0438
1.0438
1.0438
1.0438
1.0438
1.0438

-0.23275
-0.23275
-0.23275
-0.23275
-0.23275
-0.23275
-0.23275
-0.23275

1.2
1
0.8
X

0.6

Y
0.4
0.2
0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21

vk2sopropylbenzene
2
0
3
1
v12=
v22=
v32=
v42=

2
0
3
1

CH
1
0
114.8
-35.36
0
a14=
a24=
a34=
a44=

0
114.8
-35.36
0

L1
34.313896
34.313896
34.313896
34.313896
34.313896
34.313896
34.313896
34.313896
34.313896
34.313896
34.313896
34.313896
34.313896

L2
0.8118
0.8118
0.8118
0.8118
0.8118
0.8118
0.8118
0.8118
0.8118
0.8118
0.8118
0.8118
0.8118

1
1
0.904903276
0.818425917
0.739446866
0.667031399
0.600393954
0.53886952
0.481891367
0.428973535
0.379696944
0.333698265
0.290660954
0.250307953

2
0
0.095096724
0.181574083
0.260553134
0.332968601
0.399606046
0.46113048
0.518108633
0.571026465
0.620303056
0.666301735
0.709339046
0.749692047

1
0.915508502
0.836937295
0.763685193
0.695229742
0.631114741
0.570940063
0.514353295
0.461042835
0.410732146
0.363174961
0.318151254
0.275463829

0
0.0844915
0.16306271
0.23631481
0.30477026
0.36888526
0.42905994
0.4856467
0.53895717
0.58926785
0.63682504
0.68184875
0.72453617

34.313896
34.313896
34.313896
34.313896
34.313896
34.313896
34.313896
34.313896

0.8118
0.8118
0.8118
0.8118
0.8118
0.8118
0.8118
0.8118

0.212395719
0.176709307
0.143058291
0.111273362
0.081203487
0.052713499
0.025682074
0

0.787604281
0.823290693
0.856941709
0.888726638
0.918796513
0.947286501
0.974317926
1

0.234935442
0.196406333
0.159732126
0.124782019
0.091437226
0.059589627
0.029140601
0

0.76506456
0.80359367
0.84026787
0.87521798
0.90856277
0.94041037
0.9708594
1

1.2
1
0.8
X

0.6

Y
0.4
0.2
0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21

12 =

0.99683181
0.996845238
0.996859624
0.996874598
0.996890674
0.996907497
0.996925775
0.99694484
0.996965653
0.996988091
0.997012062
0.997038538
0.997067733

21 =

1.00070783
1.00070482
1.0007016
1.00069825
1.00069465
1.00069088
1.00068679
1.00068253
1.00067787
1.00067285
1.00066748
1.00066156
1.00065502

Ln 1 =
0
3.32595967
6.34992545
9.11109868
11.6421801
13.9706638
16.1198335
18.1095394
19.9568073
21.6763248
23.2808289
24.7814184
26.1878101

2 =

1 =

2 =

#DIV/0!
-63.2834112
-57.2345497
-51.7097493
-46.6438422
-41.9820334
-37.6779183
-33.6919328
-29.9901407
-26.5432647
-23.3259144
-20.3159623
-17.4940353

1
27.8256894
572.45003
9055.23828
113797.987
1167836.92
10017393.8
73261028.4
464655703
2593631342
1.2904E+10
5.7867E+10
2.3617E+11

#DIV/0!
3.2837E-28
1.3911E-25
3.4893E-23
5.5314E-21
5.8538E-19
4.332E-17
2.3323E-15
9.4503E-14
2.9676E-12
7.4077E-11
1.5028E-09
2.526E-08

Ln

pvp1
0.9608204
1.00902275
1.0632448
1.12266006
1.19000229
1.26463264
1.35082039
1.44673951
1.55892632
1.68924585
1.84003184
2.02162368
2.24185715

0.997100412
0.997136993
0.997178287
0.997226269
0.997282903
0.997350992
0.997435028
0.997541685

1.00064771
1.00063952
1.00063028
1.00061955
1.00060688
1.00059164
1.00057284
1.00054899

27.508546
28.7511668
29.9223529
31.0280427
32.0735328
33.063561
34.0023753
#DIV/0!

-14.8430994
-12.3481168
-9.99576217
-7.77418541
-5.67281312
-3.68218119
-1.79379321
0

8.8473E+11
3.0653E+12
9.8881E+12
2.9875E+13
8.4988E+13
2.2873E+14
5.8485E+14
#DIV/0!

3.5787E-07
4.3379E-06
4.5593E-05
0.00042045
0.00343818
0.02516802
0.16632805
1

2.51576842
2.86062548
3.30467146
3.90434179
4.7479802
5.99762921
7.98661361
11.4636352

pvp2
0.03253778
0.03480687
0.03740826
0.04031637
0.04368269
0.04749735
0.05200835
0.0571563
0.06334034
0.07073413
0.07955662
0.09054141
0.10435929

PT
#DIV/0!
26.6729158
547.789063
8641.06117
108335.891
1107663.52
9472189.86
68893255.6
434618404
2409704539
1.1872E+10
5.2644E+10
2.1178E+11

y1
y2
y1+y2
1.00056988
0 1.00056988
0.99822805 0.00181234
1.0000404
0.99650845 0.00389559 1.00040403
0.99373916 0.00629764 1.00003681
0.99138648 0.00909797 1.00048445
0.9877132 0.01236558 1.00007879
0.98469301 0.01624799
1.000941
0.97928456 0.02083231 1.00011687
0.97405179
0.0263843
1.0004361
0.9675218 0.03314719 1.00066899
0.9580773 0.04142395 0.99950126
0.94736654 0.05185793 0.99922446
0.93384143
0.065206 0.99904743

0.12225193
0.14580945
0.17769062
0.22324101
0.29162239
0.40087265
0.59097478
0.96029854

7.7902E+11
2.6306E+12
8.1692E+12
2.3328E+13
6.0528E+13
1.3718E+14
2.3355E+14
#DIV/0!

0.91694633
0.89369117
0.86034672
0.81317316
0.74166087
0.62457532
0.41585113
0

0.0827512
0.10628915
0.13878131
0.18598125
0.25813387
0.3757112
0.58465243
1.00002643

0.99969752
0.99998032
0.99912803
0.99915441
0.99979474
1.00028653
1.00050356
1.00002643

Alumna:

RODRIGUEZ GAMARRA MARITZA

Isobaric Vapor-Liquid Equilibrium of Binary

Mixture of Methyl Acetate with
Isopropylbenzene at 97.3 kPa

Methyl acetate
isopropilbenzeno

TC
506.8
631.1
PC
46.28655 31.680132
VpA
-8.05406
-7.46042
VpB
2.56375
1.14486
VpC
-5.12994
-3.19082
VpD
0.16125
-3.62628
Volumen v
12
0.55
R

K
atm

0.08206

Patm

97.3 0.9602732
kPa
atm
z=

10

PARTE COMBINATORIAL

0 x1
1
2
3
4
5
6
7
8
9
10
11
12
13
14

x2
1
0.95
0.9
0.85
0.8
0.75
0.7
0.65
0.6
0.55
0.5
0.45
0.4
0.35

0
0.05
0.1
0.15
0.2
0.25
0.3
0.35
0.4
0.45
0.5
0.55
0.6
0.65

TOC
55.79037
57.19274
58.70842
60.30089
62.0276
63.85377
65.86052
67.97938
70.32278
72.8855
75.66575
78.78885
82.29814
86.31002

TK
a1
a2
328.940371 0.350946 0.47878
330.342739 0.348179 0.47656
331.858423 0.345189 0.47416
333.450893 0.342046 0.47164
335.177599 0.338639
0.4689
337.003769 0.335036 0.46601
339.010517 0.331076 0.46283
341.129378 0.326895 0.45947
343.472777 0.322272 0.45576
346.035504 0.317215 0.45169
348.815752 0.311729 0.44729
351.938848 0.305567 0.44234
355.448138 0.298642 0.43678
359.460019 0.290726 0.43042

15
16
17
18
19
20
21

0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21

0.3
0.25
0.2
0.15
0.1
0.05
0

0.7
0.75
0.8
0.85
0.9
0.95
1

ln 1C =

ln 2C =

0
3.325914
6.349758
9.110748
11.6416
13.96982
16.1187
18.10809
19.95504
21.67423
23.2784
24.77866
26.18473
27.50515
28.74747
29.91836
31.02379
32.06904
33.05887
33.99754
#DIV/0!

#DIV/0!
-63.2927
-57.2423
-51.7162
-46.6491
-41.9864
-37.6814
-33.6948
-29.9924
-26.545
-23.3273
-20.317
-17.4948
-14.8437
-12.3485
-9.99601
-7.77434
-5.67289
-3.68221
-1.7938
0

90.90962
96.24501
102.644
110.4878
120.3621
133.2719
150.9276

364.059617
369.39501
375.794034
383.637821
393.512137
406.421876
424.077612

0.28165
0.271123
0.258496
0.243019
0.223536
0.198063
0.163225

0.42313
0.41468
0.40454
0.39211
0.37647
0.35601
0.32803

X12=
X22=
X32=
X42=

0.333333
0
0.5
0.166667

11=
21=
31=
41=

PARTE RESIDUAL

X11=
X21=
X31=
X41=

0 TK
1
2
3
4
5
6
7

274.15
275.15
276.15
277.15
278.15
279.15
280.15

11=
1
1
1
1
1
1
1

21=
0.657869
0.658871
0.659868
0.660858
0.661843
0.662822
0.663796

31=
1.137668
1.137135
1.136606
1.136081
1.13556
1.135043
1.13453

0.5
0.5
0
0

41=
1
1
1
1
1
1
1

12=
0.4288634
0.430185
0.4315011
0.4328116
0.4341167
0.4354163
0.4367105

22=
1
1
1
1
1
1
1

32=
0.87104
0.87148
0.87192
0.87235
0.87277
0.8732
0.87362

8
9
10
11
12
13
14
15
16
17
18
19
20
21
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21

281.15
282.15
283.15
284.15
285.15
286.15
287.15
288.15
289.15
290.15
291.15
292.15
293.15
294.15

ln11=
0.40634075
0.40515263
0.40397105
0.40279597
0.40162733
0.40046508
0.39930918
0.39815958
0.39701623
0.39587909
0.3947481
0.39362322
0.39250441
0.39139161
0.39028479
0.3891839
0.3880889
0.38699973
0.38591637
0.38483876
0.38376686

1
1
1
1
1
1
1
1
1
1
1
1
1
1
ln21=
0.174644
0.174167
0.173693
0.173222
0.172753
0.172287
0.171823
0.171362
0.170904
0.170448
0.169994
0.169543
0.169095
0.168649
0.168206
0.167765
0.167326
0.16689
0.166456
0.166024
0.165595

0.664764
0.665727
0.666684
0.667636
0.668583
0.669524
0.67046
0.671391
0.672317
0.673237
0.674153
0.675063
0.675969
0.676869

1.13402
1.133515
1.133013
1.132516
1.132021
1.131531
1.131044
1.130561
1.130081
1.129605
1.129132
1.128663
1.128197
1.127735

ln31=
0.18873
0.187992
0.18726
0.186533
0.185812
0.185096
0.184385
0.18368
0.182979
0.182284
0.181595
0.18091
0.18023
0.179555
0.178886
0.178221
0.17756
0.176905
0.176254
0.175608
0.174967

ln41=
0.105419
0.10511
0.104804
0.104499
0.104196
0.103894
0.103594
0.103296
0.102999
0.102704
0.102411
0.102119
0.101829
0.10154
0.101253
0.100968
0.100683
0.100401
0.10012
0.09984
0.099562

ln12=
0.047218
0.047066
0.046915
0.046765
0.046615
0.046467
0.046319
0.046172
0.046027
0.045882
0.045738
0.045595
0.045452
0.045311
0.04517
0.045031
0.044892
0.044754
0.044617
0.04448
0.044345

0.4379993
0.4392827
0.4405608
0.4418335
0.443101
0.4443632
0.4456202
0.4468719
0.4481185
0.4493599
0.4505962
0.4518275
0.4530536
0.4542747

1
1
1
1
1
1
1
1
1
1
1
1
1
1

0.87404
0.87446
0.87487
0.87529
0.8757
0.8761
0.87651
0.87691
0.8773
0.8777
0.87809
0.87848
0.87887
0.87926

ln22=
1.2449908
1.2411917
1.2374155
1.2336618
1.2299306
1.2262216
1.2225347
1.2188695
1.2152261
1.2116041
1.2080033
1.2044236
1.2008649
1.1973268
1.1938093
1.1903122
1.1868353
1.1833784
1.1799413
1.1765239
1.1731261

ln32=
0.020887
0.020837
0.020787
0.020738
0.020689
0.02064
0.020591
0.020543
0.020494
0.020446
0.020398
0.02035
0.020302
0.020255
0.020208
0.020161
0.020114
0.020067
0.02002
0.019974
0.019928

ln42=
0.01225
0.01221
0.01217
0.01213
0.01209
0.01206
0.01202
0.01198
0.01194
0.0119
0.01187
0.01183
0.01179
0.01176
0.01172
0.01168
0.01165
0.01161
0.01158
0.01154
0.0115

lnk

COEFICIENTE DE ACTIVIDAD
X1
0.5

X2
0.5

X3
0

X4
0

1
0.32919255

2
0.670807

3
0

4
0

ln3
0.18873
0.187992
0.18726
0.186533
0.185812

ln4
0.105419
0.10511
0.104804
0.104499
0.104196

0 ln1
ln2
1 0.40634075 0.989974
2 0.40515263 0.987174
3 0.40397105
0.98439
4 0.40279597 0.981621
5 0.40162733 0.978866

1
1
1
1
1
1
1
1
1
1
1
1
1
1

Ln

R
1

0.815329
0.813007
0.810697
0.808399
0.806113

Ln

R
2

1.3149447
1.3105392
1.3061626
1.3018145
1.2974948

1 =

2.25992
62.7351
1287.5
20315.7
254667

6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21

0.40046508
0.39930918
0.39815958
0.39701623
0.39587909
0.3947481
0.39362322
0.39250441
0.39139161
0.39028479
0.3891839
0.3880889
0.38699973
0.38591637
0.38483876
0.38376686

0.976126
0.9734
0.970689
0.967992
0.965309
0.96264
0.959985
0.957344
0.954717
0.952104
0.949504
0.946917
0.944344
0.941784
0.939237
0.936704

0.185096
0.184385
0.18368
0.182979
0.182284
0.181595
0.18091
0.18023
0.179555
0.178886
0.178221
0.17756
0.176905
0.176254
0.175608
0.174967

0.103894
0.103594
0.103296
0.102999
0.102704
0.102411
0.102119
0.101829
0.10154
0.101253
0.100968
0.100683
0.100401
0.10012
0.09984
0.099562

datos experimentales
T(K)
x1
y1
329.08
0.9875
0.9989
329.65
0.9409
0.995
330.81
0.8826
0.99
332.4
0.8238
0.985
333.16
0.7998
0.9833
335.48
0.74
0.978
337.72
0.6856
0.9726
339.95
0.6357
0.9675
341.03
0.5998
0.965
343.39
0.543
0.9595
348.17
0.4538
0.945
350.85
0.4061
0.9353
356.81
0.3241
0.9092
368.15
0.2158
0.8437
373.52
0.1797
0.804
384.27
0.1176
0.7024
401.07
0.0525
0.4736
411.07
0.0258
0.2798
414.47
0.0186
0.2173
419.55
0.0085
0.1105

0.803839
0.801577
0.799327
0.797088
0.794861
0.792646
0.790442
0.788249
0.786068
0.783898
0.781739
0.779591
0.777454
0.775328
0.773213
0.771109

1.2932031
1.2889392
1.2847028
1.2804937
1.2763116
1.2721562
1.2680273
1.2639246
1.259848
1.2557971
1.2517717
1.2477716
1.2437965
1.2398463
1.2359206
1.2320194

2606865
2.2E+07
1.6E+08
1E+09
5.7E+09
2.8E+10
1.3E+11
5.2E+11
1.9E+12
6.7E+12
2.2E+13
6.5E+13
1.8E+14
4.9E+14
1.3E+15
#DIV/0!

1.2
1
0.8
0.6
0.4
0.2
0
1

11 13

GRUPOS FUNCIONALESSUB GRUPO

Methyl AcetateC3H6O2

CH3-COO CH3

Isopropylbenzene
C9H12

CH=CH

CH3

CH
tablas:

sub grupo
CH3
CH3-COO
CH=CH
CH
R1=
R2=
R3=
R4=

Rk

Qk

1
2
3
4

0.9011
1.9031
1.1167
0.4469

0.848
1.728
0.867
0.22

0.9011
1.9031
1.1167
0.4469

Q1=
Q2=
Q3=
Q4=

0.848
1.728
0.867
0.22

vk1 Methyl Acetate

vk2sopropylbenzene

1
1
0
0

2
0
3
1

v11=
v21=
v31=
v41=

1
1
0
0

v12=
v22=
v32=
v42=

2
0
3
1

PARAMETROS DE INTERACCION BINARIA ajk

tablas:
CH3
sub grupo
grupo principal
CH3
CH3-COO
CH=CH
CH

1
11
2
1

1
0
114.8
-35.36
0

a11=
a21=
a31=
a41=

0
114.8
-35.36
0

a12=
a22=
a32=
a42=

232.1
0
37.85
232.1

r1
2.8042
2.8042
2.8042
2.8042
2.8042
2.8042
2.8042
2.8042
2.8042
2.8042
2.8042
2.8042
2.8042
2.8042

r2
5.5992
5.5992
5.5992
5.5992
5.5992
5.5992
5.5992
5.5992
5.5992
5.5992
5.5992
5.5992
5.5992
5.5992

q1
2.576
2.576
2.576
2.576
2.576
2.576
2.576
2.576
2.576
2.576
2.576
2.576
2.576
2.576

q2
4.517
4.517
4.517
4.517
4.517
4.517
4.517
4.517
4.517
4.517
4.517
4.517
4.517
4.517

k
CH3-COO CH=CH
CH
11
2
1
232.1
86.02
0
0
132.1
114.8
37.85
0
-35.36
232.1
86.02
0
a13=
a23=
a33=
a43=

86.02
132.1
0
86.02

a14=
a24=
a34=
a44=

0
114.8
-35.36
0

PARMETROS
a12
a21
1.0438 -0.23275
1.0438 -0.23275
1.0438 -0.23275
1.0438 -0.23275
1.0438 -0.23275
1.0438 -0.23275
1.0438 -0.23275
1.0438 -0.23275
1.0438 -0.23275
1.0438 -0.23275
1.0438 -0.23275
1.0438 -0.23275
1.0438 -0.23275
1.0438 -0.23275

L1
34.313896
34.313896
34.313896
34.313896
34.313896
34.313896
34.313896
34.313896
34.313896
34.313896
34.313896
34.313896
34.313896
34.313896

L2
0.8118
0.8118
0.8118
0.8118
0.8118
0.8118
0.8118
0.8118
0.8118
0.8118
0.8118
0.8118
0.8118
0.8118

1
1
0.904903
0.818426
0.739447
0.667031
0.600394
0.53887
0.481891
0.428974
0.379697
0.333698
0.290661
0.250308
0.212396

2.8042
2.8042
2.8042
2.8042
2.8042
2.8042
2.8042

0.32919255
0.67080745
0
0

42=
0.4288634
0.43018502
0.43150109
0.43281165
0.43411672
0.43541633
0.43671052

5.5992
5.5992
5.5992
5.5992
5.5992
5.5992
5.5992

2.576
2.576
2.576
2.576
2.576
2.576
2.576

12=
22=
32=
42=

0.37547
0
0.575825
0.048705

13=
0.730687
0.731521
0.73235
0.733173
0.733992
0.734805
0.735614

23=
0.617638
0.61872
0.619797
0.620868
0.621933
0.622992
0.624045

4.517
4.517
4.517
4.517
4.517
4.517
4.517

1.0438
1.0438
1.0438
1.0438
1.0438
1.0438
1.0438

-0.23275
-0.23275
-0.23275
-0.23275
-0.23275
-0.23275
-0.23275

34.313896
34.313896
34.313896
34.313896
34.313896
34.313896
34.313896

0.8118
0.8118
0.8118
0.8118
0.8118
0.8118
0.8118

0.176709
0.143058
0.111273
0.081203
0.052713
0.025682
0

33=
1
1
1
1
1
1
1

43=
0.730687
0.731521
0.73235
0.733173
0.733992
0.734805
0.735614

14=
1
1
1
1
1
1
1

24=
0.6578694
0.6588714
0.6598676
0.6608581
0.661843
0.6628222
0.663796

34=
1.1376679
1.1371347
1.1366057
1.1360807
1.1355597
1.1350427
1.1345296

44=
1
1
1
1
1
1
1

0.4379993
0.43928271
0.44056078
0.44183353
0.44310099
0.44436319
0.44562016
0.44687192
0.4481185
0.44935994
0.45059625
0.45182746
0.4530536
0.4542747

2 =

0.736418
0.737217
0.738011
0.7388
0.739585
0.740365
0.741141
0.741912
0.742678
0.74344
0.744197
0.74495
0.745699
0.746443

0.625092
0.626134
0.62717
0.628201
0.629226
0.630245
0.631259
0.632268
0.633271
0.634269
0.635262
0.636249
0.637231
0.638208

1
1
1
1
1
1
1
1
1
1
1
1
1
1

0.736418
0.737217
0.738011
0.7388
0.739585
0.740365
0.741141
0.741912
0.742678
0.74344
0.744197
0.74495
0.745699
0.746443

PT
y1
y2
y1+y2
#DIV/0!
#DIV/0!
1.00057
0
1.00057
1.2064E-27 60.1361 0.998228 0.00181234
1.00004
5.0963E-25 1232.031 0.996508 0.00389559 1.000404
1.2745E-22 19386.44 0.993739 0.00629764 1.000037
2.0139E-20 242443.9 0.991386 0.00909797 1.000484

1
1
1
1
1
1
1
1
1
1
1
1
1
1

0.6647642
0.6657269
0.6666842
0.6676361
0.6685827
0.6695241
0.6704601
0.671391
0.6723167
0.6732373
0.6741528
0.6750633
0.6759688
0.6768693

1.1340204
1.133515
1.1330134
1.1325156
1.1320214
1.131531
1.1310441
1.1305609
1.1300812
1.129605
1.1291323
1.128663
1.1281971
1.1277345

1
1
1
1
1
1
1
1
1
1
1
1
1
1

2.1242E-18
1.5665E-16
8.404E-15
3.3929E-13
1.0615E-11
2.6398E-10
5.335E-09
8.9333E-08
1.2607E-06
1.5223E-05
0.00015938
0.00146403
0.01192526
0.08695471
0.5724212
3.42814524

2472545
21090071
1.53E+08
9.63E+08
5.32E+09
2.62E+10
1.16E+11
4.64E+11
1.7E+12
5.74E+12
1.78E+13
5.07E+13
1.31E+14
2.96E+14
5.04E+14
#DIV/0!

0.987713
0.984693
0.979285
0.974052
0.967522
0.958077
0.947367
0.933841
0.916946
0.893691
0.860347
0.813173
0.741661
0.624575
0.415851
0

0.01236558
0.01624799
0.02083231
0.0263843
0.03314719
0.04142395
0.05185793
0.065206
0.0827512
0.10628915
0.13878131
0.18598125
0.25813387
0.3757112
0.58465243
1.00002643

1.000079
1.000941
1.000117
1.000436
1.000669
0.999501
0.999224
0.999047
0.999698
0.99998
0.999128
0.999154
0.999795
1.000287
1.000504
1.000026

1.2
1
0.8
X

0.6

Y
0.4
0.2
0
11 13 15 17 19 21

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21

2
0
0.09509672
0.18157408
0.26055313
0.3329686
0.39960605
0.46113048
0.51810863
0.57102646
0.62030306
0.66630174
0.70933905
0.74969205
0.78760428

1
0.9155085
0.83693729
0.76368519
0.69522974
0.63111474
0.57094006
0.5143533
0.46104283
0.41073215
0.36317496
0.31815125
0.27546383
0.23493544

0
0.0844915
0.16306271
0.23631481
0.30477026
0.36888526
0.42905994
0.4856467
0.53895717
0.58926785
0.63682504
0.68184875
0.72453617
0.76506456

12 =

0.99683181
0.99684524
0.99685962
0.9968746
0.99689067
0.9969075
0.99692577
0.99694484
0.99696565
0.99698809
0.99701206
0.99703854
0.99706773
0.99710041

21 = pvp1

1.00070783
1.00070482
1.0007016
1.00069825
1.00069465
1.00069088
1.00068679
1.00068253
1.00067787
1.00067285
1.00066748
1.00066156
1.00065502
1.00064771

0.9608204
1.00902275
1.0632448
1.12266006
1.19000229
1.26463264
1.35082039
1.44673951
1.55892632
1.68924585
1.84003184
2.02162368
2.24185715
2.51576842

pvp2
y1
0.03253778 1.00056988
0.03480687 0.99822805
0.03740826 0.99650845
0.04031637 0.99373916
0.04368269 0.99138648
0.04749735
0.9877132
0.05200835 0.98469301
0.0571563 0.97928456
0.06334034 0.97405179
0.07073413
0.9675218
0.07955662
0.9580773
0.09054141 0.94736654
0.10435929 0.93384143
0.12225193 0.91694633

0.82329069
0.85694171
0.88872664
0.91879651
0.9472865
0.97431793
1

0.19640633
0.15973213
0.12478202
0.09143723
0.05958963
0.0291406
0

0.80359367
0.84026787
0.87521798
0.90856277
0.94041037
0.9708594
1

0.99713699
0.99717829
0.99722627
0.9972829
0.99735099
0.99743503
0.99754168

1.00063952
1.00063028
1.00061955
1.00060688
1.00059164
1.00057284
1.00054899

2.86062548
3.30467146
3.90434179
4.7479802
5.99762921
7.98661361
11.4636352

0.14580945
0.17769062
0.22324101
0.29162239
0.40087265
0.59097478
0.96029854

0.89369117
0.86034672
0.81317316
0.74166087
0.62457532
0.41585113
0

X
Y

21

y2
0
0.00181234
0.00389559
0.00629764
0.00909797
0.01236558
0.01624799
0.02083231
0.0263843
0.03314719
0.04142395
0.05185793
0.065206
0.0827512

y1+y2
1.00056988
1.0000404
1.00040403
1.00003681
1.00048445
1.00007879
1.000941
1.00011687
1.0004361
1.00066899
0.99950126
0.99922446
0.99904743
0.99969752

0.10628915
0.13878131
0.18598125
0.25813387
0.3757112
0.58465243
1.00002643

0.99998032
0.99912803
0.99915441
0.99979474
1.00028653
1.00050356
1.00002643

Alumna:

RODRIGUEZ GAMARRA MARITZA

Vapor-Liquid Equilibrium Data for
n-Butyraldehyde (l)/n-Heptane (2) at 70.00 "C

TC
PC
VpA
VpB
VpC
VpD
Volumen v
12
R

n-Butyraldehyde n-Heptane
545.4
540.3
53.096296
27.041608
-7.01403
-7.67468
0.12265
1.37068
-0.000073
-3.5362
-8.50911
-3.20243

0.15
0.08206

70
C

0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21

x1
0.0227
0.0575
0.0857
0.1195
0.1465
0.1893
0.2645
0.3074
0.3767
0.4755
0.5613
0.6416
0.7211
0.785
0.8376
0.8638
0.8902
0.9222
0.9533
0.9922
1

datos experimentales
P,mmHg P atm
303.93
0.39990789
333.49
0.43880263
371.28
0.48852632

343.15
K

x2
0.9773
0.9425
0.9143
0.8805
0.8535
0.8107
0.7355
0.6926
0.6233
0.5245
0.4387
0.3584
0.2789
0.215
0.1624
0.1362
0.1098
0.0778
0.0467
0.0078
0

x1
0
0.0227
0.0575

P mmHg
311.280371
323.359283
333.345452
344.980178
354.423984
369.396763
395.70267
410.690222
434.882217
469.255474
499.392587
527.116854
555.013438
577.152702
595.937771
605.127737
614.131114
625.136509
635.886202
649.433154
652.150239

y1
0
0.1065
0.2139

P atm
0.40957944
0.42547274
0.43861244
0.45392129
0.46634735
0.48604837
0.52066141
0.54038187
0.57221344
0.61744141
0.65709551
0.69357481
0.73028084
0.75941145
0.78412865
0.79622071
0.80806726
0.82254804
0.83669237
0.85451731
0.85809242

1.2
1

a1
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875

a2
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988

394.68
423.67
446.14
474.23
517.24
538.54
570.87
601.29
662.93
638.75
650.79
658.93
664.18
666.07
666.62
667.52
665.77
652.78
650.47

0.51931579
0.55746053
0.58702632
0.62398684
0.68057895
0.70860526
0.75114474
0.79117105
0.87227632
0.84046053
0.85630263
0.86701316
0.87392105
0.87640789
0.87713158
0.87831579
0.87601316
0.85892105
0.85588158

0.0857
0.1195
0.1465
0.1893
0.2645
0.3074
0.3767
0.4755
0.5613
0.6416
0.7211
0.785
0.8376
0.8638
0.8902
0.9222
0.9533
0.9922
1

0.2833
0.348
0.3974
0.4551
0.5241
0.5617
0.6079
0.6612
0.7038
0.7387
0.7772
0.8144
0.8492
0.8659
0.883
0.9154
0.9407
0.9894
1

1
0.8
0.6
0.4
0.2
0
1

11

13

15

1.2
1
0.8
0.6
0.4
0.2
0
1 2 3 4 5 6 7 8 9 10 11 12 13 14

12g12_g22

21g21_g11
parametros

12

1496.2
1496.2
1496.2
1496.2
1496.2
1496.2
1496.2
1496.2
1496.2
1496.2
1496.2
1496.2
1496.2
1496.2
1496.2
1496.2
1496.2
1496.2
1496.2
1496.2
1496.2

21 =

1550.1
1550.1
1550.1
1550.1
1550.1
1550.1
1550.1
1550.1
1550.1
1550.1
1550.1
1550.1
1550.1
1550.1
1550.1
1550.1
1550.1
1550.1
1550.1
1550.1
1550.1

12 =

21 =

53.1341986
53.1341986
53.1341986
53.1341986
53.1341986
53.1341986
53.1341986
53.1341986
53.1341986
53.1341986
53.1341986
53.1341986
53.1341986
53.1341986
53.1341986
53.1341986
53.1341986
53.1341986
53.1341986
53.1341986
53.1341986

55.0483366
55.0483366
55.0483366
55.0483366
55.0483366
55.0483366
55.0483366
55.0483366
55.0483366
55.0483366
55.0483366
55.0483366
55.0483366
55.0483366
55.0483366
55.0483366
55.0483366
55.0483366
55.0483366
55.0483366
55.0483366

1.2
1

G12 =
0.000345634
0.000345634
0.000345634
0.000345634
0.000345634
0.000345634
0.000345634
0.000345634
0.000345634
0.000345634
0.000345634
0.000345634
0.000345634
0.000345634
0.000345634
0.000345634
0.000345634
0.000345634
0.000345634
0.000345634
0.000345634

G21 =
0.000259371
0.000259371
0.000259371
0.000259371
0.000259371
0.000259371
0.000259371
0.000259371
0.000259371
0.000259371
0.000259371
0.000259371
0.000259371
0.000259371
0.000259371
0.000259371
0.000259371
0.000259371
0.000259371
0.000259371
0.000259371

1 =

1.025395255
1.019539232
1.018960495
1.01873693
1.018660093
1.018600676
1.018559141
1.018548054
1.018537171
1.018527536
1.018520436
1.018512716
1.018501843
1.018487828
1.018468297
1.018453025
1.018430334
1.01838237
1.018273523
1.016993463
1

1
0.8
Series1

0.6

Series2
0.4
0.2
0
15

17

19

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20

21

1.2
1
0.8
X

0.6

Y
P

0.4
0.2
0

13 14 15 16 17 18 19 20 21 22

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18

2 =

1.014062299
1.01425803
1.014300604
1.014325288
1.014336886
1.014348597
1.014360331
1.014364723
1.014370295
1.014377372
1.014385028
1.014396781
1.014420429
1.014463933
1.014549597
1.014637072
1.014800398
1.015277451
1.017029067
1.114626848
1.20806E+23

ln(Pvp/Pc)
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961

pvp1
0.858076142
0.858076142
0.858076142
0.858076142
0.858076142
0.858076142
0.858076142
0.858076142
0.858076142
0.858076142
0.858076142
0.858076142
0.858076142
0.858076142
0.858076142
0.858076142
0.858076142
0.858076142
0.858076142
0.858076142
0.858076142

ln(pvp/pc)
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435

pvp2
0.399050708
0.399050708
0.399050708
0.399050708
0.399050708
0.399050708
0.399050708
0.399050708
0.399050708
0.399050708
0.399050708
0.399050708
0.399050708
0.399050708
0.399050708
0.399050708
0.399050708
0.399050708
0.399050708
0.399050708
0.399050708

PT
0.41544943
0.431771244
0.445001093
0.460858926
0.473526657
0.493607522
0.528889922
0.549017753
0.581531793
0.627886032
0.668140127
0.705812472
0.74310705
0.773079832
0.79774693
0.810029909
0.822401824
0.837384567
0.851904817
0.869320479
0.858076142

y1
0.04807561
0.11650482
0.16838481
0.22666673
0.27042592
0.33519585
0.4370916
0.4893559
0.56614134
0.6618633
0.73421468
0.79445135
0.84807012
0.88741545
0.91758197
0.93192073
0.94593366
0.96235845
0.97775219
0.99600909
1

Series1
Series2

19 20 21

X
Y
P

18 19 20 21

y2
0.95192439
0.88349518
0.83161519
0.77333327
0.72957408
0.66480415
0.5629084
0.5106441
0.43385866
0.3381367
0.26578532
0.20554865
0.15192988
0.11258455
0.08241803
0.06807927
0.05406634
0.03764155
0.02224781
0.00399091
0

y1+y2
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

Alumna:

RODRIGUEZ GAMARRA MARITZA

Vapor-Liquid Equilibrium Data for
n-Butyraldehyde (l)/n-Heptane (2) at 70.00 "C
GRUPOS FUNCIONALES SUB GRUPO
n-Butyraldehyde
C4H8O
CH3
n-Heptane
C7H16
CH3

n-Butyraldehyde
n-Heptane

TC
545.4
540.3
PC
53.0963 27.041608
VpA
-7.014
-7.67468
VpB
0.12265
1.37068
VpC
-7E-05
-3.5362
VpD
-8.5091
-3.20243
Volumen v
12
0.15
R
0.08206
T

70
C
z=

sub grupo
CH3
CH2
CHO

R1=
R2=
R3=

343.15
K

10

0.9011
0.6744
0.998

tablas:
Rk
1
0.9011
2
0.6744
3
0.998

Q1=
Q2=
Q3=

0.848
0.54
0.948

PARAMETROS DE INTERACCION BINARIA ajk

tablas:
sub grupo grupo principal
CH3
CH2
CHO

a11=
a21=
a31=

0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18

x1
0.0227
0.0575
0.0857
0.1195
0.1465
0.1893
0.2645
0.3074
0.3767
0.4755
0.5613
0.6416
0.7211
0.785
0.8376
0.8638
0.8902
0.9222

x2
0.9773
0.9425
0.9143
0.8805
0.8535
0.8107
0.7355
0.6926
0.6233
0.5245
0.4387
0.3584
0.2789
0.215
0.1624
0.1362
0.1098
0.0778

P mmHg
311.2804
323.3593
333.3455
344.9802
354.424
369.3968
395.7027
410.6902
434.8822
469.2555
499.3926
527.1169
555.0134
577.1527
595.9378
605.1277
614.1311
625.1365

P atm
0.40958
0.42547
0.43861
0.45392
0.46635
0.48605
0.52066
0.54038
0.57221
0.61744
0.6571
0.69357
0.73028
0.75941
0.78413
0.79622
0.80807
0.82255

a1
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875

a2
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988

0
0
505.7

r1
3.2479
3.2479
3.2479
3.2479
3.2479
3.2479
3.2479
3.2479
3.2479
3.2479
3.2479
3.2479
3.2479
3.2479
3.2479
3.2479
3.2479
3.2479

1
1
10

a12=
a22=
a32=

r2
5.1742
5.1742
5.1742
5.1742
5.1742
5.1742
5.1742
5.1742
5.1742
5.1742
5.1742
5.1742
5.1742
5.1742
5.1742
5.1742
5.1742
5.1742

19
20
21

0.9533
0.9922
1

datos experimentales
P,mmHg P atm
303.93
0.3999
333.49
0.4388
371.28
0.4885
394.68
0.5193
423.67
0.5575
446.14
0.587
474.23
0.624
517.24
0.6806
538.54
0.7086
570.87
0.7511
601.29
0.7912
662.93
0.8723
638.75
0.8405
650.79
0.8563
658.93
0.867
664.18
0.8739
666.07
0.8764
666.62
0.8771
667.52
0.8783
665.77
0.876
652.78
0.8589
650.47
0.8559

0.0467
0.0078
0

x1
0
0.0227
0.0575
0.0857
0.1195
0.1465
0.1893
0.2645
0.3074
0.3767
0.4755
0.5613
0.6416
0.7211
0.785
0.8376
0.8638
0.8902
0.9222
0.9533
0.9922
1

635.8862
649.4332
652.1502

y1
0
0.1065
0.2139
0.2833
0.348
0.3974
0.4551
0.5241
0.5617
0.6079
0.6612
0.7038
0.7387
0.7772
0.8144
0.8492
0.8659
0.883
0.9154
0.9407
0.9894
1

0.83669
0.85452
0.85809

0.37082875 0.36488988
0.37082875 0.36488988
0.37082875 0.36488988

3.2479
3.2479
3.2479

5.1742
5.1742
5.1742

1.2
1
0.8
0.6
0.4
0.2
0
1

11

13

15

17

19

21

1.2
1
0.8
0.6
0.4
0.2
0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21

SUB GRUPO
CH2
CH2

Qk

CHO

vk1 n-Butyraldehyde
vk2 n-Heptane
0.848
1
2
0.54
2
5
0.948
1
0

v11=
v21=
v31=

1
2
1

CH3
1
0
0
505.7

CH2
1
0
0
505.7

v12=
v22=
v32=

2
5
0

BINARIA ajk
k

0
0
505.7

CHO
10
677
677
0

a13=
a23=
a33=

677
677
0
PARAMETROS

q1
2.876
2.876
2.876
2.876
2.876
2.876
2.876
2.876
2.876
2.876
2.876
2.876
2.876
2.876
2.876
2.876
2.876
2.876

q2
4.396
4.396
4.396
4.396
4.396
4.396
4.396
4.396
4.396
4.396
4.396
4.396
4.396
4.396
4.396
4.396
4.396
4.396

a12
-383.9
-383.9
-383.9
-383.9
-383.9
-383.9
-383.9
-383.9
-383.9
-383.9
-383.9
-383.9
-383.9
-383.9
-383.9
-383.9
-383.9
-383.9

a21
1458.4
1458.4
1458.4
1458.4
1458.4
1458.4
1458.4
1458.4
1458.4
1458.4
1458.4
1458.4
1458.4
1458.4
1458.4
1458.4
1458.4
1458.4

L1
-0.3884
-0.3884
-0.3884
-0.3884
-0.3884
-0.3884
-0.3884
-0.3884
-0.3884
-0.3884
-0.3884
-0.3884
-0.3884
-0.3884
-0.3884
-0.3884
-0.3884
-0.3884

L2
-0.2832
-0.2832
-0.2832
-0.2832
-0.2832
-0.2832
-0.2832
-0.2832
-0.2832
-0.2832
-0.2832
-0.2832
-0.2832
-0.2832
-0.2832
-0.2832
-0.2832
-0.2832

1
0.014370474
0.036882896
0.055567694
0.078503942
0.097264439
0.127834681
0.184164195
0.217894455
0.275029035
0.362679152
0.445409384
0.529126803
0.618750575
0.696221615
0.764011926
0.799238339
0.835773288
0.881524289

2.876
2.876
2.876

4.396
4.396
4.396

-383.9
-383.9
-383.9

1458.4
1458.4
1458.4

-0.3884
-0.3884
-0.3884

-0.2832
-0.2832
-0.2832

0.927607728
0.987631111
1

1.2
1
0.8
Series1

Series1

0.6

Series2

Series2
0.4
0.2
0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21

1.2
1
0.8
X

X
Y
P

0.6

Y
P

0.4
0.2
0

20 21 22

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21

2
0.9856295
0.9631171
0.9444323
0.9214961
0.9027356
0.8721653
0.8158358
0.7821055
0.724971
0.6373208
0.5545906
0.4708732
0.3812494
0.3037784
0.2359881
0.2007617
0.1642267
0.1184757

0.014968534
0.038381377
0.057779759
0.081550224
0.100958949
0.132519916
0.190463099
0.225028813
0.283356349
0.372297481
0.455653117
0.539423194
0.628463288
0.704901961
0.771391243
0.805796127
0.841374533
0.88577837

0.985031466
0.961618623
0.942220241
0.918449776
0.899041051
0.867480084
0.809536901
0.774971187
0.716643651
0.627702519
0.544346883
0.460576806
0.371536712
0.295098039
0.228608757
0.194203873
0.158625467
0.11422163

12 =

21 =

0.32668701
0.32668701
0.32668701
0.32668701
0.32668701
0.32668701
0.32668701
0.32668701
0.32668701
0.32668701
0.32668701
0.32668701
0.32668701
0.32668701
0.32668701
0.32668701
0.32668701
0.32668701

70.1079661
70.1079661
70.1079661
70.1079661
70.1079661
70.1079661
70.1079661
70.1079661
70.1079661
70.1079661
70.1079661
70.1079661
70.1079661
70.1079661
70.1079661
70.1079661
70.1079661
70.1079661

1 =

3.30218E-05
3.57306E-05
3.81915E-05
4.15087E-05
4.44934E-05
4.99573E-05
6.2433E-05
7.18154E-05
9.2195E-05
0.000140278
0.00021932
0.000368288
0.000709869
0.001413379
0.0029662
0.00469534
0.008153911
0.01902116

2 =

0.99942629
0.99611982
0.99100376
0.98158765
0.97117333
0.9486733
0.88814138
0.83960644
0.73678201
0.53738217
0.33041458
0.14971877
0.03598867
0.00426871
0.0001675
1.2046E-05
2.2779E-07
5.3998E-11

0.0723923
0.0123689
0

X
Y
P

0.930337864
0.988126555
1

0.069662136
0.011873445
0

0.32668701
0.32668701
0.32668701

70.1079661
70.1079661
70.1079661

0.059467193
0.64310384
1

9.4288E-19
1.729E-69
#DIV/0!

ln(Pvp/Pc)
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961

pvp1
0.85807614
0.85807614
0.85807614
0.85807614
0.85807614
0.85807614
0.85807614
0.85807614
0.85807614
0.85807614
0.85807614
0.85807614
0.85807614
0.85807614
0.85807614
0.85807614
0.85807614
0.85807614

ln(pvp/pc)
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435

pvp2
0.39905071
0.39905071
0.39905071
0.39905071
0.39905071
0.39905071
0.39905071
0.39905071
0.39905071
0.39905071
0.39905071
0.39905071
0.39905071
0.39905071
0.39905071
0.39905071
0.39905071
0.39905071

PT
0.38976916
0.3746477
0.36157257
0.34489897
0.3307773
0.3069138
0.26068526
0.23207149
0.18328834
0.11253245
0.05794918
0.0216155
0.00444461
0.00131828
0.00214274
0.00348087
0.00622845
0.01505178

y1
0.0475569
0.115963665
0.167658551
0.225898414
0.269559065
0.334192692
0.43590928
0.488122605
0.564889354
0.660816066
0.732980414
0.793774006
0.847288705
0.886989222
0.91659013
0.93090542
0.945291839
0.962032346

y2
0.95217734
0.88397036
0.83183246
0.77406405
0.73033498
0.66559303
0.56370953
0.5114578
0.43467749
0.33898292
0.26642024
0.2062067
0.15240061
0.11297684
0.08264694
0.06826086
0.05422292
0.03774387

-4.12516961 0.85807614
-4.12516961 0.85807614
-4.12516961 0.85807614

-4.2160435
-4.2160435
-4.2160435

0.39905071
0.39905071
0.39905071

0.0486444 0.977663971
0.54752777 0.996332245
#DIV/0!
0.999981031

0.02227302
0.00364252
0

y1+y2
0.99973424
0.99993402
0.99949101
0.99996246
0.99989404
0.99978572
0.99961881
0.9995804
0.99956685
0.99979899
0.99940066
0.99998071
0.99968931
0.99996606
0.99923707
0.99916628
0.99951476
0.99977621

0.99993699
0.99997476
0.99998103

Alumna:

RODRIGUEZ GAMARRA MARITZA

Vapor-Liquid Equilibrium Data for
n-Butyraldehyde (l)/n-Heptane (2) at 70.00 "C
n-Butyraldehyde

TC
PC
VpA
VpB
VpC
VpD
Volumen v
12
R

sub grupo
CH3
CH2
CHO

0.15
0.08206

70
C
z=

GRUPOS FUNCIONALES
n-Butyraldehyde
n-Heptane

n-Heptane
540.3
27.041608
-7.67468
1.37068
-3.5362
-3.20243

545.4
53.096296
-7.01403
0.12265
-0.000073
-8.50911

R1=
R2=
R3=

343.15
K

10

0.9011
0.6744
0.998

PARAMETROS DE INTERACCION BINARIA

tablas:

a11=
a21=
a31=

0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18

x1
0.0227
0.0575
0.0857
0.1195
0.1465
0.1893
0.2645
0.3074
0.3767
0.4755
0.5613
0.6416
0.7211
0.785
0.8376
0.8638
0.8902
0.9222

x2
0.9773
0.9425
0.9143
0.8805
0.8535
0.8107
0.7355
0.6926
0.6233
0.5245
0.4387
0.3584
0.2789
0.215
0.1624
0.1362
0.1098
0.0778

P mmHg
311.280371
323.359283
333.345452
344.980178
354.423984
369.396763
395.70267
410.690222
434.882217
469.255474
499.392587
527.116854
555.013438
577.152702
595.937771
605.127737
614.131114
625.136509

P atm
0.40957944
0.42547274
0.43861244
0.45392129
0.46634735
0.48604837
0.52066141
0.54038187
0.57221344
0.61744141
0.65709551
0.69357481
0.73028084
0.75941145
0.78412865
0.79622071
0.80806726
0.82254804

a1
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875
0.37082875

a2
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988
0.36488988

19
20
21

0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21

0.9533
0.9922
1

0.0467
0.0078
0

ln 1C =

-0.07845676
-0.07422534
-0.07083336
-0.0668145
-0.06364316
-0.05869234
-0.05024479
-0.04558585
-0.03833927
-0.02869724
-0.02110414
-0.01478238
-0.00940523
-0.00582288
-0.00343919
-0.00246181
-0.00162882
-0.00083594
-0.0003078
-8.8266E-06
0

635.886202
649.433154
652.150239

0.83669237
0.85451731
0.85809242

0.37082875
0.37082875
0.37082875

0.36488988
0.36488988
0.36488988

X12=
X22=
X32=

0.28571429
0.71428571
0

11=
21=
31=

0.12619048
0.16071429
0.14107143

ln 2C =

-3.20661E-05
-0.000209164
-0.000470948
-0.00093077
-0.001417451
-0.002417235
-0.004901611
-0.006768432
-0.010541069
-0.017719573
-0.025910094
-0.035469239
-0.046992594
-0.057935672
-0.068199274
-0.073770789
-0.079713317
-0.087381276
-0.095348779
-0.106075341

PARTE RESIDUAL

X11=
X21=
X31=

0.25
0.5
0.25

12=
1
22=
1
32= 0.22907644

1
11=
1
21=
31= 0.229076436
ln11=
ln21=
ln31=

0.663875892
0.422751158
-0.057176582

COEFICIENTE DE ACTIVIDAD
X1
0.28524647

X2
0.711478815

ln12=
ln22=
ln32=

lnk
X3
0.00327472

0
0
-1.13947191

13= 7.19148832
23= 7.19148832
33=
1

2
0.610622135

ln1 =
ln2 =
ln3 =

-8.03933E-06
-5.11939E-06
-1.13584311

Ln
Ln

0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21

R
1

R
2

-2.588063014

-4.16756E-05

1 =

0.06949366
0.06978834
0.07002546
0.07030745
0.07053077
0.07088082
0.07148213
0.07181594
0.07233825
0.07303911
0.07359581
0.07406254
0.07446186
0.07472909
0.07490743
0.07498068
0.07504316
0.07510269
0.07514236
0.07516483
0.07516549

datos experimentales
P,mmHg P atm
303.93
0.39990789
333.49
0.43880263
371.28
0.48852632
394.68
0.51931579
423.67
0.55746053
446.14
0.58702632
474.23
0.62398684
517.24
0.68057895
538.54
0.70860526
570.87
0.75114474
601.29
0.79117105
662.93
0.87227632
638.75
0.84046053
650.79
0.85630263
658.93
0.86701316

2 =

0.999926261
0.999749192
0.999487508
0.999028027
0.998541938
0.997544111
0.995068911
0.993213028
0.989473056
0.982395553
0.974382083
0.965112201
0.954054702
0.943671323
0.934035391
0.928845869
0.923342545
0.916289468
0.909017935
0.899319407
0.999958325

x1
0
0.0227
0.0575
0.0857
0.1195
0.1465
0.1893
0.2645
0.3074
0.3767
0.4755
0.5613
0.6416
0.7211
0.785

3
0.004934

PT
y1
y2
y1+y2
0.39131712
0.0475569 0.95217734 0.99973424
0.37945427 0.11596366 0.88397036 0.99993402
0.36981455 0.16765855 0.83183246 0.99949101
0.35823196 0.22589841 0.77406405 0.99996246
0.34895947 0.26955906 0.73033498 0.99989404
0.33422935 0.33419269 0.66559303 0.99978572
0.30827818 0.43590928 0.56370953 0.99961881
0.2934498
0.4881226
0.5114578
0.9995804
0.26949238 0.56488935 0.43467749 0.99956685
0.23541852 0.66081607 0.33898292 0.99979899
0.20602533 0.73298041 0.26642024 0.99940066
0.17880464 0.79377401
0.2062067 0.99998071
0.15225567 0.84728871 0.15240061 0.99968931
0.13129988 0.88698922 0.11297684 0.99996606
0.11436875 0.91659013 0.08264694 0.99923707
0.10605957 0.93090542 0.06826086 0.99916628
0.09777939 0.94529184 0.05422292 0.99951476
0.08787735 0.96203235 0.03774387 0.99977621
0.07840691 0.97766397 0.02227302 0.99993699
0.06679329 0.99633225 0.00364252 0.99997476
0.06449772 0.99998103
0 0.99998103

y1
0
0.1065
0.2139
0.2833
0.348
0.3974
0.4551
0.5241
0.5617
0.6079
0.6612
0.7038
0.7387
0.7772
0.8144

X VS Y
1.2
1
0.8
y

1
0.38444387

0.6
0.4
0.2
0
1 2 3 4 5 6 7 8 9 10

0
664.18
666.07
666.62
667.52
665.77
652.78
650.47

0.87392105
0.87640789
0.87713158
0.87831579
0.87601316
0.85892105
0.85588158

0.8376
0.8638
0.8902
0.9222
0.9533
0.9922
1

0.8492
0.8659
0.883
0.9154
0.9407
0.9894
1

1 2 3 4 5 6 7 8 9 10
x

1.2
1
0.8
0.6
0.4
0.2
0
1 2 3 4 5 6 7 8 9 10 11

RUPOS FUNCIONALES SUB GRUPO

C4H8O
CH3
CH2
C7H16
CH3
CH2
tablas:
Rk
Qk
1
0.9011
2
0.6744
3
0.998

Q1=
Q2=
Q3=

0.848
0.54
0.948

CHO

vk1 n-Butyraldehyde
vk2 n-Heptane
0.848
1
2
0.54
2
5
0.948
1
0

v11=
v21=
v31=

1
2
1

v12=
v22=
v32=

CH3
1
0
0
505.7

k
CH2
1
0
0
505.7

CHO
10
677
677
0

2
5
0

ETROS DE INTERACCION BINARIA ajk

sub grupo grupo principal

CH3
CH2
CHO

0
0
505.7

1
1
10

a12=
a22=
a32=

0
0
505.7

a13=
a23=
a33=

677
677
0
PARAMETROS

r1
3.2479
3.2479
3.2479
3.2479
3.2479
3.2479
3.2479
3.2479
3.2479
3.2479
3.2479
3.2479
3.2479
3.2479
3.2479
3.2479
3.2479
3.2479

r2
5.1742
5.1742
5.1742
5.1742
5.1742
5.1742
5.1742
5.1742
5.1742
5.1742
5.1742
5.1742
5.1742
5.1742
5.1742
5.1742
5.1742
5.1742

q1
2.876
2.876
2.876
2.876
2.876
2.876
2.876
2.876
2.876
2.876
2.876
2.876
2.876
2.876
2.876
2.876
2.876
2.876

q2
4.396
4.396
4.396
4.396
4.396
4.396
4.396
4.396
4.396
4.396
4.396
4.396
4.396
4.396
4.396
4.396
4.396
4.396

a12
-383.9
-383.9
-383.9
-383.9
-383.9
-383.9
-383.9
-383.9
-383.9
-383.9
-383.9
-383.9
-383.9
-383.9
-383.9
-383.9
-383.9
-383.9

a21
1458.4
1458.4
1458.4
1458.4
1458.4
1458.4
1458.4
1458.4
1458.4
1458.4
1458.4
1458.4
1458.4
1458.4
1458.4
1458.4
1458.4
1458.4

L1
-0.3884
-0.3884
-0.3884
-0.3884
-0.3884
-0.3884
-0.3884
-0.3884
-0.3884
-0.3884
-0.3884
-0.3884
-0.3884
-0.3884
-0.3884
-0.3884
-0.3884
-0.3884

L2
-0.2832
-0.2832
-0.2832
-0.2832
-0.2832
-0.2832
-0.2832
-0.2832
-0.2832
-0.2832
-0.2832
-0.2832
-0.2832
-0.2832
-0.2832
-0.2832
-0.2832
-0.2832

3.2479
3.2479
3.2479

12=
22=
32=

5.1742
5.1742
5.1742

0.38580528
0.61419472
0

2.876
2.876
2.876

4.396
4.396
4.396

-383.9
-383.9
-383.9

1458.4
1458.4
1458.4

-0.3884
-0.3884
-0.3884

-0.2832
-0.2832
-0.2832

X VS Y

X VS Y
1.2
1
0.8
y

Y
X

0.6
0.4

9 10 11 12 13 14 15 16 17 18 19 20 21 22

0.2

0.2

9 10 11 12 13 14 15 16 17 18 19 20 21 22
x

0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18

1.2
1
0.8
X
Y
P

0
1

0
1

0.6
0.4
0.2

10 11 12 13 14 15 16 17 18 19 20 21 22

0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18

1
0.01437047
0.0368829
0.05556769
0.07850394
0.09726444
0.12783468
0.18416419
0.21789446
0.27502903
0.36267915
0.44540938
0.5291268
0.61875058
0.69622162
0.76401193
0.79923834
0.83577329
0.88152429

2
0.98562953
0.9631171
0.94443231
0.92149606
0.90273556
0.87216532
0.81583581
0.78210554
0.72497097
0.63732085
0.55459062
0.4708732
0.38124942
0.30377838
0.23598807
0.20076166
0.16422671
0.11847571

0.01496853
0.03838138
0.05777976
0.08155022
0.10095895
0.13251992
0.1904631
0.22502881
0.28335635
0.37229748
0.45565312
0.53942319
0.62846329
0.70490196
0.77139124
0.80579613
0.84137453
0.88577837

0.98503147
0.96161862
0.94222024
0.91844978
0.89904105
0.86748008
0.8095369
0.77497119
0.71664365
0.62770252
0.54434688
0.46057681
0.37153671
0.29509804
0.22860876
0.19420387
0.15862547
0.11422163

12 =

21 =

0.32668701
0.32668701
0.32668701
0.32668701
0.32668701
0.32668701
0.32668701
0.32668701
0.32668701
0.32668701
0.32668701
0.32668701
0.32668701
0.32668701
0.32668701
0.32668701
0.32668701
0.32668701

70.1079661
70.1079661
70.1079661
70.1079661
70.1079661
70.1079661
70.1079661
70.1079661
70.1079661
70.1079661
70.1079661
70.1079661
70.1079661
70.1079661
70.1079661
70.1079661
70.1079661
70.1079661

1 =

3.3022E-05
3.5731E-05
3.8192E-05
4.1509E-05
4.4493E-05
4.9957E-05
6.2433E-05
7.1815E-05
9.2195E-05
0.00014028
0.00021932
0.00036829
0.00070987
0.00141338
0.0029662
0.00469534
0.00815391
0.01902116

2 =

0.99942629
0.99611982
0.99100376
0.98158765
0.97117333
0.9486733
0.88814138
0.83960644
0.73678201
0.53738217
0.33041458
0.14971877
0.03598867
0.00426871
0.0001675
1.2046E-05
2.2779E-07
5.3998E-11

0.92760773
0.98763111
1

0.07239227
0.01236889
0

0.93033786
0.98812655
1

0.06966214
0.01187345
0

0.32668701
0.32668701
0.32668701

70.1079661
70.1079661
70.1079661

0.05946719
0.64310384
1

9.4288E-19
1.729E-69
#DIV/0!

X
Y

17 18 19 20 21

X
Y
P

17 18 19 20 21

ln(Pvp/Pc)
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961
-4.12516961

pvp1
0.85807614
0.85807614
0.85807614
0.85807614
0.85807614
0.85807614
0.85807614
0.85807614
0.85807614
0.85807614
0.85807614
0.85807614
0.85807614
0.85807614
0.85807614
0.85807614
0.85807614
0.85807614

ln(pvp/pc)
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435
-4.2160435

pvp2
0.39905071
0.39905071
0.39905071
0.39905071
0.39905071
0.39905071
0.39905071
0.39905071
0.39905071
0.39905071
0.39905071
0.39905071
0.39905071
0.39905071
0.39905071
0.39905071
0.39905071
0.39905071

-4.12516961 0.85807614
-4.12516961 0.85807614
-4.12516961 0.85807614

-4.2160435
-4.2160435
-4.2160435

0.39905071
0.39905071
0.39905071