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HW 1 Key
HW 1 Key
Fall 2013
[CH 3CH 2COO ] [CH 3CH 2COOH ] [CH 3CH 2COO ] [CH 3CH 2COOH ]
3.00 = log
[CH 3CH 2COO ] [CH 3CH 2COOH ] [CH 3CH 2COO ] [CH 3CH 2COOH ]
[CH 3CH 2COO ] (0.1M )
1.0 x 103 =
b. 1.0 x 103 =
CHM 380
Fall 2013
B) Isobutylamine (
), pKa = 10.56
a. Acid:
+
3
b. pH = pKa + log
-2.70 = log
2.0 x 10-3 =
c. 2.0 x 10-3 =
[C4 H 9 NH 2] (0.1M )
C4H9NH2 =2.0 x 10-3 x 0.1 M = 2.0 x 10-4 M 2. Draw hydrogen bonding between the following pairs of molecules. Draw a dashed line from the hydrogen being donated and the hydrogen bond acceptor a. Two water molecules
HOH HOH
CHM 380
Fall 2013
c. Phenylacetic acid (
) and 1-propylamine (
)(Draw two
possible answers to this question; remember, a carboxylic acid can be a hydrogen bond donor OR acceptor)
H
O CH2
OH
OH
3. For the following pairs of compounds, draw the product formed by their acid catalyzed condensation. Identify the category of organic compound the product falls into:
A.
Ester
B. +
Amide (primary)
CHM 380
Fall 2013
C.
Amide (secondary)
D.
+ 1
Hemiacetal
CHM 380
Fall 2013
4.
A.
Sphingolipid Phospholipid
Steroid
C. D.
Phospholipid
Sphingolipid
E
Triglyceride
Fatty Acid
CHM 380
Fall 2013
5. Draw the structure of the a phosphatidylethanolamine containing oleic acid and lauric acid
oleic acid
lauric acid
H
ethanolamine
CH2 O
-
OH
P O-
O-
CH
OH
CH2
OH
Phosphate
Glycerol
CH2
O O
O O H2N OP O
CH CH2