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Homework 5 for Organic Chemistry 201 Due: Thursday 10th October Name:

Score

Question 1

Draw the following alkene, (E)-2-Fluoro-3-methylhex-2-ene:(3 pts)

Name this compound:(3 pts)

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Question 2

Propose a line angle formula for a compound with a molar mass of 94 g? Show ALL work! (4 pts)

Homework 5 for Organic Chemistry 201 Due: Thursday 10th October Question 3 Show the mechanism for the following addition reaction. Used labeling for any formal charge and the nucleophile, electrophile and carbocation of the mechanism. (4 pts)

Br

H-Br
H

Homework 5 for Organic Chemistry 201 Due: Thursday 10th October Question 4 Show the mechanism for the following addition reaction. Used labeling for any formal charge and the nucleophile, electrophile and carbocation of the mechanism. (4 pts)

Cl-Cl

Homework 5 for Organic Chemistry 201 Due: Thursday 10th October Question 5: Hammond Postulate

A student carried out an alkene addition with HBr (compound A). The energy diagram for this reaction is shown below (full line)-

The student carried out a second reaction using a different alkene. The energy diagram is added above as a broken line. Use the Hammond postulate to explain which of the following three compounds (B,C or D) is responsible for the second line on the diagram and EXPLAIN in terms of energy and structure of the intermediate and transition state?

(2 pts)

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