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S IN LI I. in li - hng s in li (15 cu). Cu 1: Khi pha long dung dch CH3COOH 1M thnh dung dch CH3COOH 0,5M th A. in li tng B. in li gim C. in li khng i D. in li tng 2 ln Cu 2: Cn bng sau tn tai trong dung dch : CH3COOH CH3COO- + H+ . Trng hp nao sau y lam cho in li cua CH3COOH tng ? A. C cn dung dch B. Nho thm vai giot dd HCl vao C. Nho thm vao vai giot dd NaOH D. Nho thm vao vai giot dd NH4Cl Cu 3: Trong 500ml dung dch CH3COOH 0,02M c in li 4% c cha bao nhiu ht vi m ? A. 6,02 1021 B.1,204 1022 C. 6,26 1021 D. p n khc Cu 4: Dung dch axit fomic 0,05M c in li l 0,02%. pH ca dung dch l : A. 1 B. 3 C. 5 D. 2 Cu 5: Dung dch axit fomic 0,007M c pH = 3,0. Vy in li ca axit fomic trong dd bng: A. 12,48% B. 14,82% C. 18,42% D. 14,28% Cu 6: Cho cc axit sau: (1). H3PO4 (ka = 7,6.10-3) (2). HClO (ka = 5.10-8) (3). CH3COOH (ka = 1,8.10-5) (4). H2SO4 (ka = 10-2) Dy sp xp mnh ca cc axit theo th t tng dn ? A. (1) < (2) < (3) < (4) B. (4) < (2) < (3) <(1) C. (2) < (3)< (1) < (4) D. (3) < (2) < (1) < (4) Cu 7: Axit axetic c hng s phn li l 1,8.10-5. Tnh nng ca ion H+ trong dd CH3COOH 0,02M A. 6 10-4 B. 6 10-3 C. 1,34 10-4 D. 1,34 10-3 -4 Cu 8: Tnh pH ca dung dch HCOOH 0,1M c Ka = 1,6.10 ? A. 2,69 B. 1,2 C. 2 D. Kt qu khc Cu 9: Dung dch A cha: HF 0,1M; NaF 0,1M; Ka = 6,8.10-4. Dung dch A c pH ? A. 2,17 B. 3,17 C. 3,3 D. 4,2 Cu 10: Trong 100 ml dung dch HClO 0,01M c tng s: phn t HClO, ion H +, ClO- l 6,2.1020. Vy in li ca dung dch trn l (bit s Avogaro = 6,02.1023): A. 2,5% B. 0,3% C. 3,0% D. 4,3% Cu 11: Dung dch CH3COONa 0,04M, c kb = 2,564.10-5. Vy pH ca dung dch trn bng: A. 11 B. 11,465 C. 12,15 D. 12,45 Cu 12: Trong 2 lt dung dch axit flohirit c cha 4 gam HF nguyn cht. in li ca axit ny bng 8%. Vy hng s phn li ca axit flohirit bng: A. 5,96.10-4 B. 7,96.10-4 C. 6,96.10-4 D. 4,96.10-4 Cu 13: in li ca dd axit fomic 0,46% (d=1g/ml) c pH=3 l

= 1%. D. = 2%. C. Cu 14: Cho dd CH3COOH 0,1M. in li ca axit axetic gim mt na so vi ban u th khi lng CH3COOH cn phi cho vo 1 lit dd trn l (gi thit th tch dd vn l 1 lit) A. 9 gam. B. 18 gam. C. 12 gam. D. 24 gam. Cu 15: Dung dch CH3COONa 0,1 M (biet Kb cua CH3COO- bang 5,7.10-10). Vay nong o mol/l cua ion H+ trong dung dch tren bang: A. 1,32.10-9 M B. 1,23.10-9 M C. 2,13.10-9 M D. 3,21.10-9 M II. Ton hiroxit lng tnh (20 cu) Cu 1: Cho a mol NaAlO2 tc dng vi dung dch cha b mol HCl. thu c kt ta th cn c t l : A. a : b = 1 : 4 B. a : b > 1 : 4 C. a : b = 1 : 5 D. a : b < 1 : 4 Cu 2: Trn dd cha a mol AlCl3 vi dd cha b mol NaOH. thu c kt ta th cn c t l a : b nh th no ? A. a : b = 1: 5 B. a : b = 1 : 4 C. a : b < 1 : 4 D. a : b > 1 : 4 Cu 3: Cn thm bao nhiu ml dd NaOH 1M vo 100 ml dd cha Al 2(SO4)3 0,1M thu c lng kt ta ln nht: A. 60 B. 30 C. 80 D. 16

A. =1,5%.

B. = 0,5%.

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Cu 4: Cho 100ml dd hn hp gm FeCl 3 1M, AlCl3 1M v ZnCl2 0,5M tc dng vi dung dch NaOH d. Tch ly kt ta, nung trong khng kh n khi lng khng i thu c m gam cht rn. Tnh m. A. 16 g B. 8 g C. 7,2 g D. 12,5 g Cu 5: Thm dn dn Vml dd Ba(OH) 2 vo 150ml dd gm MgSO 4 0,1M v Al2(SO4)3 0,15M th thu c lng kt ta ln nht. Tch kt ta, nung n khi lng khng i thu c m gam cht rn. Tnh m. A. 22,1175g B. 24,4125g C. 2,895g D. 5,19g Cu 6: Cho 160 ml dd NaOH 0,2M vo 100 ml dd Al2(SO4)3 0,05M. Vy khi lng kt ta thu c s l : A. 0,624 B. 0,78 C. 0,39 D. 0,468 Cu 7: Cho 200ml dd KOH vo 200ml dd AlCl3 1M thu c 7,8 gam kt ta. Nng mol ca dd KOH dng: A. 1,5M hoc 3,5M B. 3M C. 1,5M D. 1,5M hoc 3M Cu 8: Cho V lit dd NaOH 0,1M vo cc cha 200 ml dd ZnCl 2 0,1M thu c 1,485 gam kt ta. Gi tr ln nht ca V l ? A. 0,7 lit B. 1 lit C. 0,5 lit D. 0,3 lit Cu 9: Cho V lit dd NaOH vo dd cha 0,1 mol Al 2(SO4)3 v 0,1 mol H2SO4 n phn ng xy ra hon ton thu c 7,8 gam kt ta. Gi tr ln nht ca V thu c lng kt ta trn l: A. 0,25 B. 0,35 C. 0,45 D. 0,05 Cu 10: Cho dd A cha 0,05 mol NaAlO2 v 0,1 mol NaOH tc dng vi dd HCl 2M. Th tch dung dch HCl 2M ln nht cn cho vo dd A xut hin 1,56 gam kt ta l? A. 0,18 lit B. 0,12 lit C. 0,06 lit D. 0,08 lit Cu 11: Thm dd HCl vo dd hn hp gm 0,1 mol NaOH v 0,1 mol NaAlO 2 thu c 0,08 mol cht kt ta. S mol HCl thm vo l: A. 0,08 hoc 0,16 mol B. 0,16 mol C. 0,18 hoc 0,26 mol D. 0,26 mol Cu 12: Ho tan 0,24 mol FeCl3 v 0,16 mol Al2(SO4)3 vo dd cha 0,4 mol H2SO4 c dd A. Thm 2,6 mol NaOH vo dd A thy xut hin m gam kt ta. Tnh m. A. 15,6g B. 41,28g C. 0,64g D. 25,68g Cu 13: Cho dung dch NH3 n d vo dung dch cha 0,1 mol Al 2(SO4)3 , 0,1 mol CuSO4 v 0,15 mol Fe2SO4 khi phn ng hon ton, thu c m gam kt ta. Gi tr m l A. 15,6 B. 47,7 C. 23,85. D. 63,8 Cu 14: Ho tan hon ton m gam hn hp X gm Na2O v Al2O3 vo H2O thu c 200 ml dung dch Y ch cha cht tan duy nht c nng 0,5M. Thi kh CO2 (d) vo Y thu c a gam kt ta. Gi tr ca m v a ln lt l A. 8,2 v 7,8. B. 13,3 v 3,9. C. 8,3 v 7,2. D. 11,3 v 7,8. Cu 15: Ho tan hon ton 47,4 gam phn chua KAl(SO4)2.12H2O vo nc, thu c dung dch X. Cho ton b X tc dng vi 200 ml dd Ba(OH)2 1M, sau phn ng thu c m gam kt ta. Gi tr ca m l A. 54,4. B. 62,2. C. 7,8. D. 46,6. Cu 16: Nh t t 0,25 lt dung dch NaOH 1,04M vo dung dch gm 0,024 mol FeCl 3; 0,016 mol Al2(SO4)3 v 0,04 mol H2SO4 thu c m gam kt ta. Gi tr ca m l A. 1,560. B. 5,064. C. 4,128. D. 2,568 Cu 17: Dung dch A cha m gam KOH v 29,4 gam KAlO 2. Cho 500 ml dd HCl 2M vo dd A thu c 15,6 gam kt ta. Gi tr ca m l? A. Kt qu khc B. 8g hoc 22,4g C. 44,8g D. 22,4g hoc 44,8g Cu 18: Ho tan 3,9 gam Al(OH)3 bng 50 ml dd NaOH 3M thu c dd A. Cn t nht bao nhiu lit HCl 2M khi cho vo dd A ta thu c 1,56 gam kt ta? A. 0,36 lit B. 0,03 lit C. 0,24 lit D. 0,06 lit Cu 19: Cho m gam hn hp X gm Na2O v Al2O3 lc vi nc n khi phn ng hon ton thu c 300ml dd A ch cha mt cht tan duy nht c nng 0,5M. Thi CO 2 d vo dd A thu c a gam kt ta. Gi tr ca m v a ln lt l: A. 12,3g; 23,4g B. 6,15g; 23,4g C. 6,15g; 11,7g D. 12,3g; 11,7g Cu 20: Ho tan hon ton m gam hn hp K 2O, Al2O3 vo nc c dd A ch cha mt cht tan duy nht. Cho t t 275ml dd HCl 2M vo dd A thy to ra 11,7 gam kt ta. Tnh m A. 14,7 gam B. 29,4 gam C. 24,5 gam D. 49 gam III. Ton pH trong dung dch (15 cu) Cu 1: Mt dd c nng H+ bng 0,001M th pH v [OH-] ca dd ny l A. pH = 2; [OH-] =10-10 M. B. pH = 3; [OH-] =10-10 M.
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C. pH = 10-3; [OH-] =10-11 M. D. pH = 3; [OH-] =10-11 M. Cu 2: Dn 4,48 lt kh HCl (ktc) vo 2 lt nc thu c 2 lit dd c pH l A. 2. B. 1,5. C. 1. D. 3 . Cu 3: Dung dch NaOH 0,001M c pH l A. 11. B. 12. C. 13. D. 14. Cu 4: Pha long 200ml dd Ba(OH)2 vi 1,3 lit nc thu c 1,5 lit dd c pH=12. Nng mol ca dd Ba(OH) 2 ban u l A. 0,375M. B. 0,075M. C. 0,0375M. D. 0,05M. Cu 5: C 10 ml dung dch HCl pH = 1. Thm vo x ml nc ct v khuy u th thu c dung dch c pH = 2. Gi tr ca x la : A. 10 ml B. 90 ml C. 100 ml D. 40 ml Cu 6: Dung dch NaOH c pH = 11. thu c dung dch NaOH c pH = 9 cn pha long dung dch NaOH ban u (bng nc) A. 1000 ln. B. 10 ln. C. 20 ln. D. 100 ln Cu 7: Trn V1 lit dung dch Ba(OH)2 c pH = 12 vi V2 lit dung dch HNO3 c pH = 2 thu c (V1+V2) lit dung dch c pH = 10. T l V1:V2 bng A. 11:9. B. 101:99. C. 12:7. D. 5:3. Cu 8: Trn V1 lit dung dch baz c pH=13 vi V 2 lit dung dch axit c pH=3 thu c (V 1+V2) lit dung dch c pH = 4. T l V1:V2 bng A. 2:9. B. 8:9. C. 11:99. D. 3:4. Cu 9: Trn 100 ml dung dch hn hp gm H2SO4 0,05M v HCl 0,1M vi 100 ml dung dch hn hp gm NaOH 0,2M v Ba(OH)2 0,1M, thu c dung dch X. Dung dch X c pH l A. 13,0. B. 1,0. C. 12,8. D. 1,2. 2 + Cu 10: Dung dich X co cha: 0,07 mol Na ; 0,02 mol SO4 va x mol OH . Dung dich Y co cha ClO 4 , NO3 va y
mol H+; tng s mol ClO 4 va NO3 la 0,04. Trn X va Y c 100 ml dung dich Z. Dung dich Z co pH (bo qua s in li cua H2O) la A. 1 B. 2 C. 12D. 13 o Cu 11: Cho dung dch X cha hn hp gm CH3COOH 0,1M v CH3COONa 0,1M. Bit 25 C, Ka ca -5 o CH3COOH l 1,75.10 v b qua s phn li ca nc. Gi tr pH ca dung dch X 25 C l A. 4,24. B. 2,88. C. 4,76. D. 1,00. Cu 12: Cho m gam hn hp Mg, Al vo 250 ml dd X cha hn hp axit HCl 1M v axit H2SO4 0,5M, thu c 5,32 lt H2 ( ktc) v dd Y (coi th tch dung dch khng i). Dung dch Y c pH l A. 1. B. 6. C. 7. D. 2. Cu 13: Trn ln V ml dung dch NaOH 0,01M vi V ml dung dch HCl 0,03 M c 2V ml dung dch Y. Dung dch Y c pH l A. 4. B. 2. C. 3. D. 1. Cu 14: Cho cc dd c nh s th t nh sau: (1) KCl ; (2) Na2CO3 ; (3) CuSO4 ; (4) CH3COONa 5. Al2(SO4)3 6. NH4Cl 7. NaBr 8. K2S. Dung dch c pH < 7 l: A. 1, 2, 3 B. 2, 4, 6 C. 6, 7 , 8 D. 3, 5, 6 Cu 15: Cho: NH4NO3 (1), CH3COONa (2), Na2SO4 (3), Na2CO3 (4). Hy chon ap an ung. A. (4), (3) co pH =7 B. (4), (2) co pH>7 C. (1), (3) co pH=7 D. (1), (3) co pH<7 IV. Phn ng ion trong dung dch-tnh cht ca axit-baz-mui (20 cu) Cu 1: Mt dung dch cha 0,02 mol Cu 2+, 0,03 mol K+, x mol Cl- v y mol SO42 . Tng khi lng cc mui tan c trong dung dch l 5,435 gam. Gi tr ca x v y ln lt l: A. 0,01 v 0,03. B. 0,03 v 0,02. C. 0,05 v 0,01. D. 0,02 v 0,05. + 2+ Cu 2: Cho dung dich X gm: 0,007 mol Na ; 0,003 mol Ca ; 0,006 mol Cl-; 0,006 HCO3 va 0,001 mol NO3 . loai bo ht Ca2+ trong X cn mt lng va u dung dich cha a gam Ca(OH)2 Gia tri cua a la A. 0,222 B. 0,120 C. 0,444 D. 0,180 Cu 3: Cho dung dch Ba(HCO3)2 ln lt vo cc dung dch: CaCl 2, Ca(NO3)2, NaOH, Na2CO3, KHSO4, Na2SO4, Ca(OH)2, H2SO4, HCl. S trng hp c to ra kt ta l A. 4. B. 7. C. 5. D. 6. Cu 4: Dung dch X cha hn hp gm Na2CO3 1,5M v KHCO3 1M. Nh t t tng git cho n ht 200 ml dung dch HCl 1M vo 100 ml dung dch X, sinh ra V lt kh ( ktc). Gi tr ca V l A. 4,48. B. 3,36. C. 2,24. D. 1,12.

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Cu 5: Cho cac cht: NaHCO3, CO, Al(OH)3, Fe(OH)3, HF, Cl2, NH4Cl. S cht tac dung c vi dung dich NaOH loang nhit thng la A. 4 B. 5 C. 3 D. 6 Cu 6: Cho 32 gam hn hp gm MgO, Fe2O3, CuO tc dng va vi 300ml dung dch H2SO4 2M. Khi lng mui thu c l A. 60 gam. B. 80 gam. C. 85 gam. D. 90 gam. Cu 6: Ho tan 5,6 gam Fe bng dung dch H2SO4 long (d), thu c dung dch X. Dung dch X phn ng va vi V ml dung dch KMnO4 0,5M. Gi tr ca V l A. 80. B. 20. C. 40. D. 60. Cu 7. Ho tan hon ton 24,4 gam hn hp gm FeCl 2 v NaCl (c t l s mol tng ng l 1:2) vo mt lng nc (d), thu c dung dch X. Cho dung dch AgNO3 (d) vo dung dch X, sau khi phn ng xy ra hon ton sinh ra m gam cht rn. Gi tr ca m l A. 10,8. B. 28,7. C. 57,4. D. 68,2. Cu 8: 1l dung dch X c cha 0,2mol Fe2+ ; 0,3mol Mg2+ v 2anion Cl-,NO3-.C cn cn thn dung dch thu c 69,8g cht rn.Tnh nng mol ln lt ca 2 anion trn A. 0,5M; 0,5M B. 0,4M; 0,6M C. 0,6M; 0,4M D. 0,2M; 0,8M Cu 9: Dung dch A cha cc ion Cu2+;Fe3+,Cl-. kt ta ht ion Cl- trong 10ml dung dch A phi dng ht 70ml dung dch AgNO3 1M.C cn 100ml dung dch A thu c 43,25g hn hp mui khan.Tnh nng mol cc ion Cu2+,Fe3+,ClA. 2M,1M,7M B. 2M,1M,0,7M C. 0,2M;0,1M;7M D. 0,2M;0,1M;0,7M Cu 10: 100ml dung dch A cha HCl 2M v HNO 3 1,5M tc dng va vi 0,1 lt dung dch B cha NaOH 0,5M v KOH a M.Tm a? A. 1 B. 2 C. 3 D. 4 Cu 11: Trn 250 ml dd hn hp gm HCl 0,08M v H 2SO4 0,01M vi 250 ml dd Ba(OH)2 nng x mol/l thu c m gam kt ta v 500 ml dd c pH=12 . Gi tr ca m v x tng ng l A. 0,5825 gam; 0,06M. B. 3,495 gam; 0,06M. C. 0,5825 gam; 0,12M. D. 3,495 gam; 0,12M. Cu 12: Hoa tan hoan toan 7,8 gam hn hp 2 kim loai Mg, Al vao dung dich HCl d, sau phan ng khi lng dung dich axit tng thm 7 gam. Vy khi lng cua Al trong hn hp ban u la: A. 2,7 gam B. 4,05 gam C. 5,4 gam D. 8,1 gam 0 Cu 13: tan ca KCl 0 C l 27,6. Vy nng phn trm ca dung dch bo ha nhit l: A. 21,6% B. 20,5% C. 15,8% D. 23,5% Cu 14: Ha tan 125 gam mui ngm nc CuSO4.5H2O vo mt lng nc va c 500 ml dd X. Vy th tch dd KOH 1M cn dng kt ta ht ion Cu 2 + trong 100 ml dd X l: A. 0,01 lt B. 0,1 lt C. 0,2 lt D. 0,02 lt Cu 15. Cho dd NH3 n d vo dd X c cha AlCl 3 v ZnCl2 thu c kt ta Y. Nung Y n khi lng khng i thu c cht rn Z. Cho kh hiro d i qua rn Z nung nng s thu c cht rn cha: A. Zn v Al2O3 B. ZnO v Al2O3 C. ZnO v Al D. Al2O3 Cu 16: Cho 3,87 gam Mg v Al vo 200ml dung dch X gm HCl 1M v H 2SO4 0,5M thu c dung dch B v 4,368 lt H2 ktc. Phn trm khi lng ca Mg v Al trong hn hp ln lt l A. 72,09% v 27,91%. B. 62,79% v 37,21%. C. 27,91% v 72,09%. D. 37,21% v 62,79%. Cu 17: Ho tan hon ton 104,25 gam hn hp X gm NaCl v NaI vo nc c dung dch A. Sc kh Cl2 d vo dung dch A. Kt thc th nghim, c cn dung dch thu c 58,5g mui khan. Khi lng NaCl c trong hn hp X l A. 29,25 gam. B. 58,5 gam. C. 17,55 gam. D. 23,4 gam. Cu 18: Khi ha tan hiroxit kim loi M(OH)2 bng mt lng va dung dch H2SO4 20% thu c dung dch mui trung ho c nng 27,21%. Kim loi M l A. Cu. B. Zn. C. Fe. D. Mg. 3+ 2+ Cu 19: Dung dch X cha cc ion: Fe , SO4 , NH4 , Cl . Chia dd X thnh hai phn bng nhau: - Phn mt tc dng vi lng d dd NaOH, un nng thu c 0,672 lt kh ( ktc) v 1,07 gam kt ta; - Phn hai tc dng vi lng d dung dch BaCl2, thu c 4,66 gam kt ta. Tng khi lng cc mui khan thu c khi c cn dung dch X l (qu trnh c cn ch c nc bay hi) A. 3,73 gam. B. 7,04 gam. C. 7,46 gam. D. 3,52 gam.

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Cu 20: Hoa tan hoan toan 10 gam hn hp gm Fe va Fe 2O3 dung dich HCl (va u) thu c 1,12 lit khi H2 ( ktc) va dung dich A. Cho dung dich NaOH n d vao dung dich A, loc ly ht tua nung trong khng khi n khi lng khng i thu c m gam cht rn. Vy gia tri cua m la: A. 12 gam B. 16 gam C. 11,2 gam D. 12,2 gam V. Mui tc dng vi kim loi (20 cu) Cu 1: Mt tm kim loai bng vang bi bam kim loai Fe ngoai b mt, ta co th ra kim loai Fe trn b mt bng dung dich nao sau y: A. Dd CuSO4 d B. Dd FeSO4 d C. Dd FeCl3 d D. Dd AgNO3 d Cu 2: Nhung mt thanh Cu d vao 200 ml dung dich AgNO3 1M, khi phan ng xay ra hoan toan, toan b Ag tao thanh u bam vao thanh kim loai Cu, Vy khi lng thanh Cu sau phan ng la: A. Tng 21,6 gam B. Tng 15,2 gam C. Tng 4,4 gam D. Giam 6,4 gam Cu 3: Cho mt l st (d) vo dung dch CuSO 4 . Sau mt thi gian vt l st ra ra sch lm kh thy khi lng l st tng 1,6g . Khi lng ng sinh ra bm ln l st l A : 12,8g B : 6,4g C : 3,2g D : 9,6g Cu 4: Ho tan 58 gam CuSO4.5H2O vo nc c 500ml dung dch CuSO4. Cho dn dn mt st vo 50 ml dung dch trn, khuy nh cho ti khi dung dch ht mu xanh th lng mt st dng l: A. 0,65g. B. 1,2992g. C. 1,36g. D. 12,99g Cu 5: Ngm l km trong dung dch cha 0,1 mol CuSO4. Phn ng xong thy khi lng l km: A. tng 0,1 gam. B. tng 0,01 gam. C. gim 0,1 gam. D. khng thay i. Cu 6: Ho tan hon ton 28 gam bt Fe vo dung dch AgNO3 d th khi lng cht rn thu c l A. 108 gam. B. 162 gam. C. 216 gam. D. 154 gam. Cu 7: Ngm 1 l km trong 100 ml dd AgNO3 0,1M. Khi phn ng kt thc, khi lng l km tng thm A. 0,65 gam. B. 1,51 gam. C. 0,755 gam. D. 1,3 gam. Cu 8: Cho 2,24 gam bt st vo 200 ml dung dch cha hn hp gm AgNO3 0,1M v Cu(NO3)2 0,5M. Sau khi cc phn ng xy ra hon ton, thu c dung dch X v m gam cht rn Y. Gi tr ca m l A. 4,08. B. 0,64. C. 2,16. D. 2,80. Cu 9: Nhng mt thanh st nng 100 gam vo 100 ml dung dch hn hp gm Cu(NO3)2 0,2M v AgNO3 0,2M. Sau mt thi gian ly thanh kim loi ra, ra sch lm kh cn c 101,72 gam (gi thit cc kim loi to thnh u bm ht vo thanh st). Khi lng st phn ng l A. 2,16 gam. B. 1,40 gam. C. 0,84 gam. D. 1,72 gam. Cu 10: Cho 14 gam bt st vo 400 ml dd (Z) gm AgNO 3 0,5M v Cu(NO3)2 aM . Khuy nh cho n khi phn ng kt thc thu c dd (Y) v 30,4 gam cht rn (X). Vy tr s a c gi tr l: A. 0,15M B. 0,1M C. 0,125M D. 0,2M Cu 11: Nhng mt l nhm vo dung dch CuSO4. Sau mt thi gian ly l nhm ra khi dung dch th thy khi lng dung dch gim 1,38 gam. Khi lng ca nhm tham gia phn ng l. A. 0,27 gam B. 0,81 gam C. 0,54 gam D. 1,08 gam Cu 12: Cho m gam Mg vo dung dch cha 0,12 mol FeCl3. Sau khi phn ng xy ra hon ton thu c 3,36 gam cht rn. Gi tr ca m l A. 2,16. B. 5,04. C. 4,32. D. 2,88. Cu 13: Cho 2,24 gam bt st vo 200 ml dung dch cha hn hp gm AgNO3 0,1M v Cu(NO3)2 0,5M. Sau khi cc phn ng xy ra hon ton, thu c dd X v m gam cht rn Y. Gi tr ca m l A. 4,08. B. 0,64. C. 2,16. D. 2,80. Cu 14: Cho m1 gam Al vo 100 ml dung dch gm Cu(NO3)2 0,3M v AgNO3 0,3M. Sau khi cc phn ng xy ra hon ton th thu c m2 gam cht rn X. Nu cho m2 gam X tc dng vi lng d dung dch HCl th thu c 0,336 lt kh ( ktc). Gi tr ca m1 v m2 ln lt l A. 8,10 v 5,43. B. 1,08 v 5,43. C. 0,54 v 5,16. D. 1,08 v 5,16. Cu 15. Cho 0,81 gam Al v 2,8 gam Fe tc dng vi 200 ml dung dch X cha AgNO 3 v Cu(NO3)2. Sau khi phn ng xy ra hon ton thu c dung dch Y v 8,12 gam hn hp 3 kim loi. Cho 8,12 gam hn hp 3 kim loi ny tc dng vi dung dch HCl d, kt thc phn ng thy thot ra 0,672 lt H 2 (ktc). Nng mol ca AgNO3 v Cu(NO3)2 ln lt l A. 0,15M v 0,25M. B. 0,10M v 0,20M. C. 0,25M v 0,15M. D. 0,25M v 0,25M. VI. Baz tc dng vi oxit axit (20 cu)
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Cu 1. Cho 112 ml khi CO 2 ( ktc) hp thu hoan toan bi 200 ml dd Ca(OH) 2 thu c 0,1 gam tua. Vy nng mol/l cua dd Ca(OH)2 ban u bng: A. 0,5M B. 0,05M C. 0,015M D. 0,02M Cu 2. Suc 1,12 lit CO2 ( ktc) vao 200 ml dd Ba(OH)2 0,2M. Khi lng kt tua thu c la: A. 78,8 gam B. 98,5 gam C. 5,91 gam D. 19,7 gam Cu 3. Cho V lit CO2 ( ktc) hp thu hoan toan vao 500 ml dd Ba(OH)2 1M. Sau khi kt thuc phan ng thu c 59,1 gam kt tua. V co gia tri la: A. 6,72 lit hoc 10,08 lit B. 2,24 lit hoc 6,72 lit C. 4,48 lit hoc 15,68 lit D. 6,72 lit hoc 15,68 lit. Cu 4. Suc V lit CO2 ( ktc) vao dd Ba(OH)2 thu c 9,85 gam kt tua. Loc bo kt tua ri cho dd H2SO4 d vao dd nc loc thu c 1,65 gam kt tua na. Vy V co gia tri la: A. 11,2 lit va 2,24 lit B. 3,36 lit v 6,72 lt C. 3,36 lit va 1,12 lit D. 1,12 lit v 4,48 lt L thuyt: I, Dng 1: i cng v s in li-phn loi cht in li Cu I-1: S in li l A. S phn li cc cht thnh cc phn t nh hnC. S phn li cc cht thnh cc nguyn t cu to n B. S phn li cc cht thnh ion trong nc D. S phn li cc cht thnh cc cht n gin Cu I-2: Cht in li l: A. Cht tan trong nc B. Cht dn in C. Cht phn li trong nc thnh cc ion D. Cht khng tan trong nc Cu I-3: Dung dch no dn in c A. NaCl B. C2H5OH C. HCHO D. C6H12O6 Cu I-4: Cht no khng l cht in li A. CH3COOH B. CH3COONa C. CH3COONH4 D. CH3OH Cu I-5:Cho cc cht: NaOH, Na2CO3, Ca(OH)2, CaCO3, CH3COONa, C2H5OH,C2H5ONa, HCl, H2SO4, BaCl2 S cc cht khi cho thm nc to thnh dung dch dn in l: A. 11 B. 8 C. 9 D. 10 Cu I-6: Cho cc cht :NaCl (dd), KCl (rn), Pb(NO3)2 (dd), PbSO4 (rn), Fe (rn), C6H12O6 (dd), nc ct. a, S cht dn in l: A. 7 B. 4 C. 4 D. 6 b, S cht khi thm H2O c dd dn in l: A. 3 B. 4 C. 2 D. 5 Cu I-7: Cht no sao y dn in A. NaCl nng chy B. CaCO3 nng chy C. AlCl3 nng chy D. 2 trong 3 cht cho Cu I-8: Cht no sau y dn in A. dd NaCl B. NaOH rn C. NaCl nng chy D. C A v C Cu I-9: Phng trnh in li no ng? A. NaCl Na2+ + ClB. Ca(OH)2 Ca2+ + 2 OHC. C2H5OH C2H5+ + OHD. C A, B, C Cu I-10: Dung dch mui, axit, baz l nhng cht in li v: A. Chng c kh nng phn li thnh ion trong dd B. Dung dch ca chng dn in C. Cc ion thnh phn c tnh dn in D. C A,B,C Cu I-11: Chn cu ng A. Mi cht tan u l cht in li B. Mi axit mnh u l cht in li C. Mi axit u l cht in li D. C ba cu u sai Cu I-12: Cng thc tnh in li l: A. = m cht tan / m dd B. =n in li / n cht tan C. = n in li / mdd D. =ncht tan /n in li Cu I-13: Cho cc gi tr (1) = 0 (2) = 1 (3) 0 < < 1 (4) 0 < 1 (5) 0 < 1 a, Cc cht in li mnh c gi tr no ? A. (2) B. (3) C. (4) D. (5) b, Cc cht in li yu c gi tr no? A. (1) B. (3) C. (4) D. (5) c, Cht khng in li c gi tr no ? A. (1) B. (3) C. (4) D. p n khc Cu I-14: Trong cc yu t sau: (1) Nhit , (2) p sut , (3) Xc tc, (4) Nng cht tan, (5) Din tch tip xc, (6) Bn cht cht in li
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a, Yu t no nh hng n in li ? A. (1), (4),(6) B. (1),(3),(4),(6) C. (1),(2),(3),(5) D. (2),(4),(5),(6) b,Yu t no nh hng n hng s in li? A. (1),(2),(6) B. (1), (6) C. (1),(4),(6) D. (1),(2),(3),(4),(5),(6) Cu I-15: Cho cc cht sau: NaCl, HCl, HF, NaOH, Ca(OH)2, C2H5OH, CH3COOH, KBr, Fe2O3, BaCl2, H2O a, S cht in li mnh l A. 5 B. C. 6 D. 7 b, S cht in li yu l A. 3 B. 4 C. 5 D. 6 c, S cht khng in li l A. 2 B. 3 C. 1 D. 4 + Cu I-16: Cho dung dch CH3COOH c cn bng CH3COOH CH3COO + H a, Dung dch cha nhng ion no? A. CH3COOH, H+, CH3COOB. H+, CH3COOH C. H+, CH3COOD. H2O, CH3COOH b, Khi cho thm HCl vo dung dch th in li thay i nh th no? A. Tng B. Gim C. Khng i D. Tng gim tu thuc vo nng HCl Cu I-17: Khi pha long dung dch CH3COOH 1M thnh dung dch CH3COOH 0,5M th A. in li tng B. in li gim C. in li khng i D. in li tng 2 ln Cu I-18: Ion kali hirat K+.nH2O c hnh thnh khi: A. Ho tan mui KCl vo nc. B. C cn dung dch KCl. C. Ha tan mui KCl vo nc c pha axit v c long. D. C cn dung dch KOH. Cu I-19: Cac dd sau y co cung nng 1M, dung dch nao dn in tt nht A. NH4NO3 B. H2SO4 C. Ba(OH)2 D. Al2(SO4)3 Cu I-20: Chn cu pht biu ng: A. Ch c hp cht ion mi b in li khi ha vo nc B. in li ch ph thuc vo bn cht ca cht in li C. Vi cht in li yu, in li gim khi nng tng D. in li ca cht in li yu c th bng 1 - Kl tc dng vi phi kim. Cu 11. Ho tan hon ton 2,81 gam hn hp gm Fe2O3, MgO, ZnO trong 500 ml axit H2SO4 0,1M (va ). Sau phn ng, hn hp mui sunfat khan thu c khi c cn dung dch c khi lng l A. 3,81 gam. B. 4,81 gam. C. 5,81 gam. D. 6,81 gam. Cu 12. Cho 2,13 gam hn hp X gm ba kim loi Mg, Cu v Al dng bt tc dng hon ton vi oxi thu c hn hp Y gm cc oxit c khi lng 3,33 gam. Th tch dung dch HCl 2M va phn ng ht vi Y l A. 75 ml. B. 57 ml. C. 50 ml. D. 90 ml. Cu 13. Nung nng 16,8 gam hn hp gm Au, Ag, Cu, Fe, Zn vi mt lng d kh O2, n khi cc phn ng xy ra hon ton, thu c 23,2 gam cht rn X. Th tch dung dch HCl 2M va phn ng vi cht rn X l A. 200 ml. B. 400 ml. C. 600 ml. D. 800 ml. Cu 14. ho tan hon ton 2,32 gam hn hp gm FeO, Fe 3O4 v Fe2O3 (trong s mol FeO bng s mol Fe2O3), cn dng va V lt dung dch HCl 1M. Gi tr ca V l A. 0,23. B. 0,18. C. 0,08. D. 0,16. Cu 15. Cho 9,12 gam hn hp gm FeO, Fe 2O3, Fe3O4 tc dng vi dung dch HCl (d). Sau khi cc phn ng xy ra hon ton, c dung dch Y; c cn Y thu c 7,62 gam FeCl2 v m gam FeCl3. Gi tr ca m l A. 9,75. B. 8,75. C. 6,50. D. 7,80. Cu 16. Cho 11,36 gam hn hp gm Fe, FeO, Fe2O3, Fe3O4 phn ng ht vi dung dch HNO3 long (d), thu c 1,344 lt kh NO (sn phm kh duy nht, ktc) v dung dch X. C cn dung dch X thu c m gam mui khan. Gi tr ca m l A. 35,50. B. 38,72. C. 49,09. D. 34,36. Cu 17. t chy hon ton 7,2 gam kim loi M (c ho tr hai khng i trong hp cht) trong hn hp kh Cl2 v O2. Sau phn ng thu c 23,0 gam cht rn v th tch hn hp kh phn ng l 5,6 lt ( ktc). Kim loi M l A. Be. B. Cu. C. Ca. D. Mg.

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Cu 18. Trn 5,6 gam bt st vi 2,4 gam bt lu hunh ri nung nng (trong iu kin khng c khng kh), thu c hn hp rn M. Cho M tc dng vi lng d dung dch HCl, gii phng hn hp kh X v cn li mt phn khng tan G. t chy hon ton X v G cn va V lt kh O2 (ktc). Gi tr ca V l A. 4,48. B. 2,80. C. 3,08. D. 3,36. - Tc ha hc, s phn ng. Cu 30. Cho dy cc cht: NH4Cl, (NH4)2SO4, NaCl, MgCl2, FeCl2, AlCl3. S cht trong dy tc dng vi lng d dung dch Ba(OH)2 to thnh kt ta l A. 3. B. 5. C. 4. D. 1. Cu 31. Cho s phn ng: NaCl (X) NaHCO3 (Y) NaNO3. X v Y c th l A. NaOH v NaClO. B. NaClO3 v Na2CO3.C. NaOH v Na2CO3. D. Na2CO3 v NaClO. Cu 32. T hai mui X v Y thc hin cc phn ng sau: to X X1 + H2O X2. X1 + CO2 X2 + Y X + Y1 + H2O X2 + 2Y X + Y2 + 2H2O. Hai mui X, Y tng ng l A. CaCO3, NaHCO3. B. MgCO3, NaHCO3. C. CaCO3, NaHSO4. D. BaCO3, Na2CO3 . - Kl tc dng vi nc, axit, baz, mui. Cu 35. Cho mt mu hp kim Na-Ba tc dng vi nc (d), thu c dung dch X v 3,36 lt H 2 (ktc). Th tch dung dch axit H2SO4 2M cn dng trung ho dung dch X l A. 30ml. B. 60ml. C. 75ml. D. 150ml. Cu 36. Khi cho 100ml dung dch KOH 1M vo 100ml dung dch HCl thu c dung dch c cha 6,525 gam cht tan. Nng mol (hoc mol/l) ca HCl trong dung dch dng l A. 0,5M. B. 1M. C. 0,75M. D. 0,25M. Cu 37. Chia m gam Al thnh hai phn bng nhau: - Phn mt tc dng vi lng d dung dch NaOH, sinh ra x mol kh H2;. - Phn hai tc dng vi lng d dung dch HNO 3 long, sinh ra y mol kh N 2O (sn phm kh duy nht). Quan h gia x v y l A. x = 4y. B. x = y. C. x = 2y. D. y = 2x. Cu 38. Cho hn hp gm Na v Al c t l s mol tng ng l 1 : 2 vo nc (d). Sau khi cc phn ng xy ra hon ton, thu c 8,96 lt kh H2 ( ktc) v m gam cht rn khng tan. Gi tr ca m l A. 5,4. B. 43,2. C. 7,8. D. 10,8. Cu 39. Hn hp X gm Na v Al. Cho m gam X vo mt lng d nc th thot ra V lt kh. Nu cng cho m gam X vo dung dch NaOH (d) th c 1,75V lt kh. Thnh phn phn trm theo khi lng ca Na trong X l (bit cc th tch kh o trong cng iu kin). A. 29,87%. B. 39,87%. C. 77,31%. D. 49,87%. Cu 40. Ho tan hon ton 2,9 gam hn hp gm kim loi M v oxit ca n vo nc, thu c 500 ml dung dch cha mt cht tan c nng 0,04M v 0,224 lt kh H2 ( ktc). Kim loi M l A. Ba. B. Na. C. Ca. D. K. Cu 41. Ho tan hon ton 0,3 mol hn hp gm Al v Al4C3 vo dung dch KOH (d), thu c a mol hn hp kh v dung dch X. Sc kh CO2 (d) vo dung dch X, lng kt ta thu c l 46,8 gam. Gi tr ca a l A. 0,40. B. 0,45. C. 0,60. D. 0,55. - CO2, SO2, P2O5 td dung dch kim. Cu 42. Nung 13,4 gam hn hp 2 mui cacbonat ca 2 kim loi ha tr 2, thu c 6,8 gam cht rn v kh X. Lng kh X sinh ra cho hp th vo 75 ml dung dch NaOH 1M, khi lng mui khan thu c sau phn ng l A. 6,5 gam. B. 5,8 gam. C. 6,3 gam. D. 4,2 gam. Cu 43. Hp th hon ton 4,48 lt kh CO2 (ktc) vo 500 ml dung dch hn hp gm NaOH 0,1M v Ba(OH) 2 0,2M, sinh ra m gam kt ta. Gi tr ca m l A. 11,82. B. 19,70. C. 9,85. D. 17,73. Cu 44. Cho 0,448 lt kh CO2 ( ktc) hp th ht vo 100 ml dung dch cha hn hp NaOH 0,06M v Ba(OH)2 0,12M, thu c m gam kt ta. Gi tr ca m l
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A. 1,182. B. 2,364. C. 3,940. D. 1,970. Cu 45. Hp th hon ton 2,688 lt kh CO2(ktc) vo 2,5 lt dung dch Ba(OH)2 nng a mol/l, thu c 15,76 gam kt ta. Gi tr ca a l A. 0,048. B. 0,06. C. 0,04. D. 0,032. Cu 46. Cho 100 ml dung dch KOH 1,5M vo 200 ml dung dch H3PO4 0,5M, thu c dung dch X. C cn dung dch X, thu c hn hp gm cc cht l A. KH2PO4 v K3PO4. B. KH2PO4 v H3PO4. C. KH2PO4 v K2HPO4. D. K3PO4 v KOH. Cu 47. Cho 0,1 mol P2O5 vo dung dch cha 0,35 mol KOH. Dung dch thu c c cc cht: A. K3PO4, K2HPO4. B. K2HPO4, KH2PO4. C. H3PO4, KH2PO4. D. K3PO4, KOH. - CO3 tc dng H+. Cu 48. Cho t t dung dch cha a mol HCl vo dung dch cha b mol Na 2CO3 ng thi khuy u, thu c V lt kh ( ktc) v dung dch X. Khi cho d nc vi trong vo dung dch X thy c xut hin kt ta. Biu thc lin h gia V vi a, b l: A. V = 11,2(a - b). B. V = 22,4(a - b). C. V = 22,4(a + b). D. V = 11,2(a + b). Cu 49. Dung dch X cha hn hp gm Na2CO3 1,5M v KHCO3 1M. Nh t t tng git cho n ht 200 ml dung dch HCl 1M vo 100 ml dung dch X, sinh ra V lt kh ( ktc). Gi tr ca V l A. 3,36. B. 2,24. C. 4,48. D. 1,12. Cu 50. Cho 1,9 gam hn hp mui cacbonat v hirocacbonat ca kim loi kim M tc dng ht vi dung dch HCl (d), sinh ra 0,448 lt kh ( ktc). Kim loi M l A. Li. B. Rb. C. Na. D. K. Cu 51. Nhit phn hon ton 40 gam mt loi qung lmit c ln tp cht tr sinh ra 8,96 lt kh CO 2(ktc). Thnh phn phn trm v khi lng ca CaCO3.MgCO3 trong loi qung nu trn l A. 84%. B. 50%. C. 92%. D. 40%. - Tnh lng tnh ca Al(OH)3, Zn(OH)2. Cu 52. Nh t t cho n d dung dch NaOH vo dung dch AlCl3. Hin tng xy ra l A. ch c kt ta keo trng. B. c kt ta keo trng, sau kt ta tan. C. khng c kt ta, c kh bay ln. D. c kt ta keo trng v c kh bay ln. Cu 53. Nh t t 0,25 lt dung dch NaOH 1,04M vo dung dch gm 0,024 mol FeCl3; 0,016 mol Al2(SO4)3 v 0,04 mol H2SO4 thu c m gam kt ta. Gi tr ca m l A. 1,560. B. 5,064. C. 4,128. D. 2,568. Cu 54. Ho tan hon ton 47,4 gam phn chua KAl(SO4)2.12H2O vo nc, thu c dung dch X. Cho ton b X tc dng vi 200 ml dung dch Ba(OH)2 1M, sau phn ng thu c m gam kt ta. Gi tr ca m l A. 54,4. B. 62,2. C. 7,8. D. 46,6. Cu 55. Trn dung dch cha a mol AlCl3 vi dung dch cha b mol NaOH. thu c kt ta th cn c t l. A. a : b > 1 : 4. B. a : b < 1 : 4. C. a : b = 1 : 4. D. a : b = 1 : 5. Cu 56. Cho 200 ml dung dch AlCl3 1,5M tc dng vi V lt dung dch NaOH 0,5M, lng kt ta thu c l 15,6 gam. Gi tr ln nht ca V l A. 2. B. 1,2. C. 1,8. D. 2,4. Cu 57. Cho V lt dung dch NaOH 2M vo dung dch cha 0,1 mol Al 2(SO4)3 v 0,1 mol H2SO4 n khi phn ng hon ton, thu c 7,8 gam kt ta. Gi tr ln nht ca V thu c lng kt ta trn l A. 0,35. B. 0,45. C. 0,25. D. 0,05. Cu 58. Thm m gam kali vo 300ml dung dch cha Ba(OH) 2 0,1M v NaOH 0,1M thu c dung dch X. Cho t t dung dch X vo 200ml dung dch Al2(SO4)3 0,1M thu c kt ta Y. thu c lng kt ta Y ln nht th gi tr ca m l A. 1,95. B. 1,71. C. 1,59. D. 1,17. Cu 59. Ho tan ht m gam ZnSO4 vo nc c dung dch X. Cho 110 ml dung dch KOH 2M vo X, thu c a gam kt ta. Mt khc, nu cho 140 ml dung dch KOH 2M vo X th cng thu c a gam kt ta. Gi tr ca m l A. 12,375. B. 22,540. C. 20,125. D. 17,710.
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Cu 60. Ho tan hon ton m gam hn hp X gm Na2O v Al2O3 vo H2O thu c 200 ml dung dch Y ch cha cht tan duy nht c nng 0,5M. Thi kh CO2 (d) vo Y thu c a gam kt ta. Gi tr ca m v a ln lt l A. 8,2 v 7,8. B. 13,3 v 3,9. C. 8,3 v 7,2. D. 11,3 v 7,8. S in li: 2 + 0,5. Cu 178. Dung dch HCl v dung dch CH3COOH c cng nng mol/l, pH ca hai dung dch tng ng l x v y. Quan h gia x v y l (gi thit, c 100 phn t CH3COOH th c 1 phn t in li). A. y = 2x. B. y = x + 2. C. y = x - 2. D. y = 100x. Cu 179. Cho dung dch X cha hn hp gm CH3COOH 0,1M v CH3COONa 0,1M. Bit 25 oC, Ka ca CH3COOH l 1,75.10-5 v b qua s phn li ca nc. Gi tr pH ca dung dch X 25 oC l A. 2,88. B. 4,76. C. 1,00. D. 4,24. Cu 180. Cho dy cc cht: KAl(SO4)2.12H2O, C2H5OH, C12H22O11 (saccaroz), CH3COOH, Ca(OH)2, CH3COONH4. S cht in li l A. 5. B. 4. C. 2. D. 3. Cu 181. Cho dy cc cht: Ca(HCO3)2, NH4Cl, (NH4)2CO3, ZnSO4, Al(OH)3, Zn(OH)2. S cht trong dy c tnh cht lng tnh l A. 3. B. 5. C. 4. D. 2. Cu 182. Cho dy cc cht: Cr(OH)3, Al2(SO4)3, Mg(OH)2, Zn(OH)2, MgO, CrO3. S cht trong dyc tnh cht lng tnh l A. 4. B. 5. C. 3. D. 2. Cu 183. Cc hp cht trong dy cht no di y u c tnh lng tnh? A. Cr(OH)3, Fe(OH)2, Mg(OH)2 B. Cr(OH)3, Zn(OH)2, Mg(OH)2 C. Cr(OH)3, Pb(OH)2, Mg(OH)2. D. Cr(OH)3, Zn(OH)2, Pb(OH)2. Cu 184. Cho cc cht: Al, Al2O3, Al2(SO4)3, Zn(OH)2, NaHS, K2SO3, (NH4)2CO3. S cht u phn ng c vi dung dch HCl, dung dch NaOH l A. 5. B. 7. C. 4. D. 6. Cu 185. Dy gm cc cht va tan trong dung dch HCl, va tan trong dung dch NaOH l: A. NaHCO3, MgO, Ca(HCO3)2. B. NaHCO3, ZnO, Mg(OH)2. C. Mg(OH)2, Al2O3, Ca(HCO3)2. D. NaHCO3, Ca(HCO3)2, Al2O3. Cu 186. Trong s cc dung dch: Na2CO3, KCl, CH3COONa, NH4Cl, NaHSO4, C6H5ONa, nhng dung dch c pH > 7 l A. KCl, C6H5ONa, CH3COONa. B. NH4Cl, CH3COONa, NaHSO4. C. Na2CO3, NH4Cl, KCl. D. Na2CO3, C6H5ONa, CH3COONa. Cu 187. Cho cc dung dch c cng nng : Na2CO3 (1), H2SO4 (2), HCl (3), KNO3 (4). Gi tr pH ca cc dung dch c sp xp theo chiu tng t tri sang phi l: A. (2), (3), (4), (1). B. (1), (2), (3), (4). C. (3), (2), (4), (1). D. (4), (1), (2), (3). - Hn hp axit td hn hp baz. Pt ion thu gn. Bt in tch. Cu 188. Cho 4 phn ng: (1) Fe + 2HCl FeCl2 + H2. (2) 2NaOH + (NH4)2SO4 Na2SO4 + 2NH3 + 2H2O. (3) BaCl2 + Na2CO3 BaCO3 + 2NaCl. (4) 2NH3 + 2H2O + FeSO4 Fe(OH)2 + (NH4)2SO4. Cc phn ng thuc loi phn ng axit - baz l A. (2), (4). B. (1), (2). C. (3), (4). D. (2), (3). Cu 189. Cho cc phn ng ha hc sau: (1) (NH4)2SO4 + BaCl2 (2) CuSO4 + Ba(NO3)2 . (3) Na2SO4 + BaCl2 (4) H2SO4 + BaSO3 . (5) (NH4)2SO4 + Ba(OH)2 (6) Fe2(SO4)3 + Ba(NO3)2 . Cc phn ng u c cng mt phng trnh ion rt gn l: A. (1), (2), (3), (6). B. (3), (4), (5), (6). C. (1), (3), (5), (6). D. (2), (3), (4), (6). Cu 190. Trn ln V ml dung dch NaOH 0,01M vi V ml dung dch HCl 0,03 M c 2V ml dung dch Y. Dung dch Y c pH l A. 3. B. 1. C. 2. D. 4. Cu 191. Trn 100 ml dung dch (gm Ba(OH)2 0,1M v NaOH 0,1M) vi 400 ml dung dch (gm H2SO4 0,0375M v HCl 0,0125M), thu c dung dch X. Gi tr pH ca dung dch X l
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A. 2. B. 6. C. 1. D. 7. Cu 192. Trn 100 ml dung dch hn hp gm H2SO4 0,05M v HCl 0,1M vi 100 ml dung dch hn hp gm NaOH 0,2M v Ba(OH)2 0,1M, thu c dung dch X. Dung dch X c pH l A. 1,0. B. 12,8. C. 1,2. D. 13,0. Cu 193. Trn 100 ml dung dch c pH = 1 gm HCl v HNO3 vi 100 ml dung dch NaOH nng a (mol/l) thu c 200 ml dung dch c pH = 12. Gi tr ca a l A. 0,12. B. 0,15. C. 0,03. D. 0,30. Cu 194. Cho dung dch cha 0,1 mol (NH4)2CO3 tc dng vi dung dch cha 34,2 gam Ba(OH)2. Sau phn ng thu c m gam kt ta. Gi tr ca m l A. 17,1. B. 19,7. C. 15,5. D. 39,4. 22+ + Cu 195. Mt dung dch cha 0,02 mol Cu , 0,03 mol K , x mol Cl v y mol SO 4 . Tng khi lng cc mui tan c trong dung dch l 5,435 gam. Gi tr ca x v y ln lt l: A. 0,01 v 0,03. B. 0,03 v 0,02. C. 0,05 v 0,01. D. 0,02 v 0,05. Cu 196. Ho tan hon ton hn hp gm 0,12 mol FeS2 v a mol Cu2S vo axit HNO3 (va ), thu c dung dch X (ch cha hai mui sunfat) v kh duy nht NO. Gi tr ca a l A. 0,075. B. 0,12. C. 0,06. D. 0,04. Cu 197. Hn hp X cha Na2O, NH4Cl, NaHCO3 v BaCl2 c s mol mi cht u bng nhau. Cho hn hp X vo H2O (d), un nng, dung dch thu c cha. A. NaCl, NaHCO3, NH4Cl, BaCl2. B. NaCl. C. NaCl, NaOH. D. NaCl, NaOH, BaCl2. Cu 198. Trong cc dung dch: HNO3, NaCl, Na2SO4, Ca(OH)2, KHSO4, Mg(NO3)2, dy gm cc cht u tc dng c vi dung dch Ba(HCO3)2 l: A. HNO3, Ca(OH)2, KHSO4, Mg(NO3)2. B. NaCl, Na2SO4, Ca(OH)2. C. HNO3, Ca(OH)2, KHSO4, Na2SO4. D. HNO3, NaCl, Na2SO4. Cu 199. Dung dch X cha cc ion: Fe3+, SO42-, NH4+, Cl-. Chia dung dch X thnh hai phn bng nhau: - Phn mt tc dng vi lng d dung dch NaOH, un nng thu c 0,672 lt kh ( ktc) v 1,07 gam kt ta;. - Phn hai tc dng vi lng d dung dch BaCl2, thu c 4,66 gam kt ta. Tng khi lng cc mui khan thu c khi c cn dung dch X l (qu trnh c cn ch c nc bay hi). A. 7,04 gam. B. 3,73 gam. C. 3,52 gam. D. 7,46 gam. Cu 200. Khi ha tan hiroxit kim loi M(OH)2 bng mt lng va dung dch H2SO4 20% thu c dung dch mui trung ho c nng 27,21%. Kim loi M l A. Fe. B. Mg. C. Zn. D. Cu. CC BI T LUN NNG CAO (T LM) Bi 1. H2O , SO2 , Br2 , H2CO3 ,C2H6 , Ca(HCO3)2 , H2SO4 , NaClO , Mg(OH)2 , CuSO4 , C6H6 , C2H5OH , CH3COOH , C6H12O6 , CaO , CH3COONa. Nhng cht no l cht in li. Bi 2. Cho cc cht : HCl, HClO4, HNO3, H2SO4, H2CO3, H2S, CH3COOH, HClO, HF, H2SO3, HNO2, HI, NaOH, Bi(OH)3, KOH, Sr(OH)2, RbOH, Ba(OH)2, NaCl, Na3PO4, NaHCO3, CaCl2, KHSO4, KClO3, CuSO4, Mg(OH)2, CH3COONa. a) Cht no l cht in li mnh ? Vit phng trnh in li. b) Cht no l cht in li yu ? Vit phng trnh in in li Bi 3. Vit phng trnh in li trong nc: a) Cc hiroxit lng tnh : Al(OH)3 , Zn(OH)2 , Pb(OH)2 , Sn(OH)2 , Cr(OH)3 , Cu(OH)2. b) Cc mui: NaCl.KCl , K 2SO4.Al2(SO4)3.24H2O , KCl.MgCl2.6H2O, NaHCO3, Na2HPO4, NaH2PO3, Na2HPO3 , NaH2PO2 , [Ag(NH3)2]Cl , [Cu(NH3)4]SO4 , [Zn(NH3)4](NO3)2 . Bi 4. Trong s cc mui sau, mui no l mui axit ? mui no l mui trung ho ? (NH4)2SO4 , K2SO4 , NaHCO3 , CH3COONa , Na2HPO4 , NaHSO4 , Na2HPO3 , Na3PO4 ,NaHS, NaClO. Bi 5. C bn dung dch : Kali clorua, ru etylic, axit axetic, kali sunfat, u c nng 0,01 mol/l. Hy so snh kh nng dn in ca cc dung dch . Gii thch ngn gn.

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Bi 6. Cho mt dung dch axit axetic CH 3COOH ( cht in li yu). Nu ho tan vo dung dch mt t tinh th natri axetat CH3COONa ( cht in li mnh) , th nng ion H + c thay i khng ? nu c th thay i nh th no ? Gii thch. Bi 7. Cho mt dung dch amonic, nu ha tan vo dung dch ny mt t tinh th amoni clorua NH 4Cl (cht in li mnh) th nng OH- c thay i khng ? Nu c th thay i nh th no? Gii thch. Bi 8. Vit biu thc hng s phn li axit Ka hoc hng s phn li baz Kb cho cc trng hp sau : 2NH + 4 , NO 2 , HClO , CH3COO , S , H2CO3 . Bi 9. Vit cng thc ca cc cht m khi in li to ra cc ion sau : a) K+ v PO 3 b) Al3+ v NO 3 c) Fe3+ v SO 2 d) K+ v MnO 2 4 4 4 e) Na+ v CrO 2 f) Cu2+ v SO 2 g) Rb+ v Clh) CH3COO- v Na+. 4 4 Bi 10. Trong mt dung dch cha ng thi cc ion : Na+ , Al3+ , Cu2+, Cl- , SO 2 4 , NO 3 . Khi c cn dung dch ta c th thu c ti a my mui ? Vit cng thc phn t ca cc mui . Bi 11. C 3 ng nghim, mi ng nghim cha 2 cation v 2 anion (khng trng lp gia cc ng nghim) trong 2 3 + + 2+ s cc cation v anion sau : NH + , Mg2+, Al3+ v Cl- , Br- , NO 3 , SO 2 . Hy 4 , Na , Ag , Ba 4 , PO 4 , CO 3 xc nh cc cation v anion sau trong tng ng nghim. Bi 12. C th pha ch dung dch ng thi cha cc ion sau khng ? V sao? a) Na+, Ag+, Clb) Ba2+, K+, SO 2 c) Mg2+, H+, SO 2 4 4 , NO 3 2 2 d) Mg2+, Na+, SO 2 e) H+, Na+, NO 3 , CO 3 f) H+, NO 3 , OH-, Ba2+. 4 , CO 3 + 2+ g) Br-, NH + h) OH-, HCO 3 , Na+, Ba2+ i) HCO 3 , H+, K+, Ca2+. 4 , Ag , Ca Bi 13. Trong mt dung dch c cha cc ion : Ca2+, Na+, Mg2+, HCO 3 , Cl-. Hy nu v gii thch: - Trong dung dch c th c nhng mui no ? - Khi c cn dung dch c th thu c nhng mui no ? - Khi nung hn hp cht rn sau khi c cn c th thu c nhng cht g ? Bi 14. Mt dung dch cha a mol Na+, b mol Ca2+, c mol HCO 3 v d mol Cl- . Lp biu thc lin h gia a, b, c, d v cng thc tng khi lng mui trong dung dch. Bi 15. Trong mt dung dch c cha a mol Ca2+, b mol Mg2+, c mol Cl-, d mol SO 2 4 . a) Lp biu thc lin h gia a, b, c, d. b) Nu a = 0,1 ; c = 0,1 ; d = 0,3 th b bng bao nhiu ? T kt qu ny hy tnh tng khi lng cc mui c trong dung dch. Bi 16. Mt dung dch c cha 2 loi cation Fe2+(0,1 mol) v Al3+(0,2 mol) cng 2 loi anion l Cl-(x mol) v SO 2 4 (y mol) . Tnh x ,y . Bit rng khi c cn dung dch v lm khan thu c 46,9 gam cht kt ta. Bi 17. C hai dung dch , dung dch A v dung dch B. Mi dung dch ch cha 2 loi cation v 2 loi anion trong 2 + s cc ion sau : K+(0,15 mol) ; Mg2+(0,1 mol) ; NH + 4 (0,25 mol) ; H (0,2 mol) ; Cl (0,1 mol); SO 4 (0.075 mol) ; 2 NO 3 (0,25 mol) ; CO 3 (0,15 mol). Xc nh dung dch A v dung dch B. 2 + Bi 18. Dung dch A cha a mol K+ , b mol NH + 4 , c mol HCO 3 , d mol SO 4 (khng k ion H v OH ca nc). Cho thm (c+d+e) mol Ba(OH)2 vo dung dch A thu c dung dch X , kh Y vag kt ta Z. Coi Ba(OH) 2 in li hon ton. Tm biu thc lin h a, b, c, d, e trong dung dch A v dung dch X. Bi 19. Mt dung dch cha a mol NaHCO3 v b mol Na2CO3 . a) Khi thm (a+b) mol BaCl 2 hoc (a +b) mol Ba(OH)2 vo dung dch trn th khi lng kt ta thu c trong hai trng hp c bng nhau khng ? Gii thch . Coi Ba(OH)2 in li hon ton. b) Tnh khi lng kt ta thu c trong trng hp a = 0,1 mol v b = 0,2 mol. 2 2 Bi 20. Hy xc nh tng khi lng ca cc mui c trong dung dch A cha cc ion Na +, NH + . 4 , SO 4 , CO 3 Bit rng - Khi cho dung dch A tc dng vi dung dch Ba(OH) 2 d v un nng thu c 0,34 gam kh c th lm xanh giy qu m v 4,3 gam kt ta. - Khi cho dung dch A tc dng vi dung dch H2SO4 d th thu c 0,224 lt kh (ddktc). 2 2 Bi 21. Dung dch A cha cc ion Na+, NH + 4 , SO 4 , CO 3 .
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a) Dung dch A trn c th iu ch t hai mui trung ho no ? b) Chia dung dch A lm hai phn bng nhau : - Phn th nht cho tc dng vi dung dch Ba(OH) 2 d ,un nng ta thu c 4,3 gam kt ta X v 470,4 ml kh Y 13,5oC v 1 atm. - Phn th hai cho tc dng vi dung dch HCl d thu c 235,2 ml kh 13,5oC v 1 atm. Tnh tng khi lng cc mui trong dung dch A. Bi 22. Mt dung dch cha x mol Cu 2+, y mol K+; 0,03 mol Cl- v 0,02 mol SO 2 4 . Tng khi lng cc mui tan c trong dung dch l 5,435 gam. Hy xc nh gi tr x v y. Bi 23. a) Mt dung dch A cha 0,03 mol Ca 2+; 0,06 mol Al3+; 0,06 mol NO 3 ; 0.09 mol SO 2 4 . Mui c trong dung dch ny th phi ho tan hai mui no vo nc ? Gii thch. b) Kt qu xc nh nng mol ca cc ion trong dung dch sau: [Na+] = 0,05 ; [Ca2+] = 0,01 ; [NO 3 ] = 0,01 ; [Cl-] = 0,04 ; [HCO 3 ] = 0,025. Kt qu trn ng hay sai ? V sao. Bi 24. Trong 1 ml dung dch axit nitr nht nht nh c 5,64.1019 phn t HNO2 ; c 3,60.1018 ion NO 3 . a) Tnh in li ca axit nitr trong dung dch nhit . b) Tnh nng mol ca dung dch ni trn. Bi 25. Trong 500 ml dd CH3COOH 0,01 M, = 4% c bao nhiu ht vi m ( phn t , ion). Khng tnh nc. Bi 26. Dung dch axit axetic 0,6% c khi lng ring xp x 1 g/ml. in li ca axit axetic trong iu kin ny l 1,0% . Tnh nng mol ca ion H+ trong dung dch ( b qua s in li ca nc). Bi 27. Tnh in li ca axit fomic HCOOH, nu dung dch 0,46% (d = 1,0g/ml) ca axit fomic c pH = 3. Bi 28. Dung dch CH3COOH 0,1M c in li = 1% . Vit phng trnh in li CH 3COOH v xc nh pH ca dung dch ny. 2 + Bi 29. Theo nh ngha axit baz ca Bron-stt cc ion : Na +, NH + , CH3COO- , HCO 3 , HSO 4 , CO 3 4 , K , Cl- , Cu2+, SO 2 l axit , baz, lng tnh hay trung tnh ? Ti sao? 4 Trn c s , hy d on cc dung dch ca tng cht cho di y c pH ln hn , nh hn, hay bng 7. Na2CO3, KCl, CH3COONa, Na2SO4, CuSO4, NH4Cl, NH4HSO4. Bi 30. Mt dung dch c cha 3 gam axit CH 3COOH trong 250 ml dung dch. Cho bit in li ca axit CH3COOH l = 0,01. a) Tnh nng mol/l ca phn t v ion c trong dung dch axit . b) Tnh pH ca dung dch axit trn. Bi 31. Dung dch A c cha ng thi hai mui natri clorua (0,3mol/l) v kali photphat (0,1mol/l). a) C th pha ch dd A bng cch ho tan vo nc hai mui kali clorua v natri photphat c khng ? b) Nu c th c, pha ch 2 lt dd A cn bao nhiu mol kali clorua v bao nhiu mol natri photphat ? Bi 32. Dung dch A c cha ng thi ba mui : Na2SO4 0,05M ; KCl 0,1M v NaCl 0,5M. a) C th pha ch dung dch A c hay khng nu ch ho tan vo nc hai mui sau y ? * NaCl v K2SO4 * KCl v Na2SO4. b) Nu c th c, chun b 200 ml dung dch A cn ho tan vo nc bao nhiu gam mi mui? Bi 33. imetyl amin (CH3)2NH l mt baz mnh hn amonic . imetyl amin trong nc c phn ng thu phn sau: (CH3)2NH + H2O (CH3)2NH + 2 + OH a) Vit biu thc tnh hng s phn li baz Kb ca imetyl amin. b) Nu thm mt t mui khan (CH3)2NH2Cl vo dd trn th nng OH- thay i nh th no ? V sao ? c) Tnh pH ca dung dch imetyl amin 1,5M. Bit rng Kb = 5,9.10-4. Bi 34. a) Dung dch axit fomic HCOOH c pH = 3,0. Tnh in li ca axit fomic. b) Tnh nng H + v ion axetat CH3COO- trong dung dch axit CH3COOH 0,1M, bit in li ca dung dch bng 1,3% Bi 35. a) Tnh pH ca dung dch CH3COOH 0,1 M (Bit Ka = 1,75.10-5) b) Tnh nng mol/l ca ion H+ trong dung dch NH4Cl 0,1M. Bit Kb ca NH3 bng 1,8.10-5. c) Tnh nng mol/l ca ion H+ trong dung dch NH3 0,01M ( Bit Kb = 1,8.10-5 ).
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d) Tnh nng mol/l ion H+ ca dung dch CH3COOH 0,1M ( Bit Kb ca CH3COO- l 5,71.10-10). Bi 36. So snh pH ca cc dung dch sau c cng nng v iu kin . Gii thch . a) Cc dung dch : HCl ; H2SO4 ; CH3COOH. b) Cc dung dch : NaOH ; Ba(OH)2 ; dung dch NH3. Bi 37. Cho dung dch H2S 0,1M . Bit axit ny c th phn li 2 nc : H2S H+ + HS- ; Ka1 = 1,0.10-7 HS- H+ + S2- ; Ka2 = 1,3.10-13 a) Tnh nng mol/l ca ion H+ v pH ca dung dch. b) Tnh nng mol/l ca cc ion HS- v S2- trong dung dch. Bi 38. Trong hai dung dch cc th d sau y, dung dch no c pH ln hn ? a) Dung dch 0,1M ca mt axit mt nc c K = 1,0.10-4 v dung dch 0,1M ca mt axit mt nc c K = 4,0.10-5. b) Dung dch HCl 0,1M v dung dch HCl 0,01M c) Dung dch CH3COOH 0,1M v dung dch HCl 0,1M. d) Dung dch HCl 0,01M v dung dch H2SO4 0,01M. Gii thch vn tt cho mi trng hp. Bi 39. Dung dch axit fomic 0,007M c pH = 3,0. a) Tnh in li ca axit fomic trong dung dch . b) Nu ho tan thm 0,001 mol HCl vo 1 lit dd th in li ca axit fomic tng hay gim ? Gii thch. Bi 40. Tnh pH ca cc dung dch sau: a) Dung dch HCl 0,001M. b) Dung dch H2SO4 0,0001M. Coi H2SO4 phn li hon ton 2 nc. c) Dung dch NaOH 0.01M . d) Dung dch Ba(OH)2 0,0001M. Coi Ba(OH)2 phn li hon ton. Bi 41. Tnh pH ca dung dch thu c khi cho 100 ml H 2SO4 0,1M vo 400 ml dung dch NH 3 0,05M . Coi -10 Ka(NH + 4 ) = 5,6.10 . Coi H2SO4 phn li hon ton 2 nc. Bi 42. Thm 100 ml dung dch CH3COOH 0,1M vo 200 ml dung dch NaOH 0,05M. Tnh pH ca dung dch thu c . Cho Kb(CH3COO-) = 5,71.10-10 . Bi 43.a) Cho m gam Na vo nc, ta thu c 2 lit dung dch c pH = 13. Tnh m(g). b) Ho tan a gam kim loi Ba vo nc thu c 1,5 lit dung dch X c pH = 12. Tnh a (g). c) Dn V(lit) HCl (ktc) vo nc ta thu c 2 lt dung dch Y c pH = 1. Xc nh V (lit). d) Dn V(l) SO3 (ktc) vo nc ta thu c 5 lt dung dch C c pH = 2. Tnh V(l). Coi H 2SO4 phn li hon ton 2 nc. Bi 44. Tnh pH ca dd gm NH4Cl 0,2M v NH3 0,1M. Bit hng s phn li axit ca NH 4 l KNH 4 = 5,0.10-10 . Bi 45. Hon thnh cc phng trnh ion rt gn di y v vit phng trnh phn t ca cc phn ng tng ng di y. a) Cr3+ + Cr(OH)3 b) Pb2+ + PbS + c) Ag + AgCl d) Ca2+ + Ca3(PO4)2 e) S2- + H2S f) CH3COO- + CH3COOH g) H+ + H2O h) OH- + AlO 2 + 2 + 3+ i) H + Al + . k) OH + CO 3 + Bi 46. Vit phng trnh trao i ion cc dung dch sau y (dng phn t v ion rt gn) : a) CaCl2 v AgNO3 b) Pb(NO3)2 v Al2(SO4)3 c) FeSO4 v NaOH d) NaNO3 v CuSO4 e) Fe2(SO4)3 v NaOH f) CH3COOH v HCl g) (NH4)2SO4 v Ba(OH)2 h) NH4Cl v Ba(OH)2 i) Ba(NO3)2 v CuSO4 j) KCl v Na2SO4 k) Pb(OH)2 (r) v HCl l) Pb(OH)2 (r) v NaOH. Bi 47. Hy dn ra phn ng gia dung dch cc cht in li to ra : a) Hai cht kt ta . b) Mt cht kt ta v mt cht kh. c) Mt cht kt ta, mt cht kh v mt cht in li yu. d) Mt cht kh, mt cht in li yu v mt cht in li mnh. e) Mt cht in li yu v mt cht in li mnh. Bi 48. Cho cc mui : NH4Cl, K2SO4, Ba(NO3)2, CH3COOONa, Na2CO3, KHSO3, Na2HPO4, CuSO4, NaCl, Al2(SO4)3, (CH3COO)2Pb, (NH4)2CO3 .
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Mui no trong s mui trn b thu phn kh ho tan vo nc. Vit phng trnh minh ho. Bi 49.a) Cho cc dung dch NaCl, Na2CO3, C6H5OH, NH4Cl c mi trng axit , kim hay trung tnh ? Gii thch . b) Cho qu tm vo cc dung dch sau y : NH 4Cl , CH3COOK , Ba(NO3)2 , Na2CO3 . Qu tm i mu g ? Gii thch . c) C th dng qu tm phn bit 2 dung dch NaOH v Na2CO3 c khng ? Ti sao ? d) C th dng qu tm phn bit 2 dung dch HCl v dung dch NH4Cl c khng ? Ti sao ? e) V sao NH 3 khng tn ti trong mi trng axit ? V sao Zn(OH) 2 khng tn ti trong mi trng axit cng nh trong mi trng kim ? Bi 50. Hy ghi ng s thay i mu ca qu , qu xanh, qu tm khi nhng ln lt chng vo tng dd sau : Dung dch KCl FeCl3 NaNO3 K2S Zn(NO3)2 Na2CO3 Qu Qu xanh Qu tm Bi 51. C bn bnh mt nhn, mi bnh cha mt trong cc dung dch sau : Na 2SO4, Na2CO3 , BaCl2, KNO3 vi nng khong 0,1M. Ch dng thm qu tm, hy nu cch phn bit cc dung dch trn. Vit cc phng trnh phn ng minh ho. Bi 52 y ng ring bit trong cc bnh khng c nhn : NH4Cl,(NH4)2SO4,BaCl2, NaOH , Na2CO3 . Bi 53. C 3 l ho cht mt nhn, mi l ng mt trong cc dung dch NaCl , Na 2CO3 v HCl . Khng c dng thm bt k ho cht no (k c qu tm), lm th no nhn ra cc dung dch ny. Vit phng trnh ho hc ca cc phn ng xy ra di dng phn t v ion. Bi 54. Ch dng thm mt ho cht hy phn bit cc dung dch sau : Na2CO3,Na2SO3,Na2SO4,Na2SiO3 v Na2S. Bi 55. Hy phn bit cc cht bt sau : NaCl,Na2CO3,Na2SO4, BaCO3, BaSO4(Ch dng thm 1 ho cht v nc). Bi 56. C 4 bnh mt nhn, mi bnh cha mt hn hp dung dch sau y : K 2CO3 v Na2SO4 ; KHCO3 v Na2CO3 ; KHCO3 v Na2SO4 ; Na2SO4 v K2SO4. Trnh by phng php ho hc nhn bit 4 bnh ny m ch dng thm dung dch NaCl v dung dch Ba(NO3)2. Bi 57. Bng phng php ho hc, hy nhn bit cc dung dch ng trong cc l mt nhn sau : Ba(OH)2 , H2SO4 , FeCl3 , FeCl2 , AlCl3 , CuCl2 , NaCl , Na2CO3 , NH4Cl , (NH4)2SO4. (Ch dng thm qu tm) Bi 58. Trn 250 ml dung dch hn hp HCl 0,08 mol/l v H 2SO4 0,01 mol/l vi 250 ml dung dch Ba(OH) 2 c nng x mol/l thu c m gam kt ta v 500 ml dung dch c pH = 12. Hy tnh m v x. Coi Ba(OH) 2 in li hon ton c hai nc. Bi 59. Tr 300 ml dung dch c cha NaOH 0,1mol/l v Ba(OH) 2 0,025 mol/l vi 200 ml dung dch H2SO4 nng x mol/l, thu c m gam kt ta v 500 ml dung dch c pH = 2. Hy tnh m v x. Coi Ba(OH) 2 v H2SO4 phn li hon ton 2 nc. Bi 60. Thm t t 400 ml dung dch H 2SO4 49% vo nc v iu chnh lng nc thu c ng 2 lt dung dch A . Coi H2SO4 phn li hon ton 2 nc. a) Tnh nng mol ca ion H+ trong dung dch A . b) Tnh th tch dung dch NaOH 1,8M cn thm vo 0,5 lt dung dch A thu c * dung dch c pH = 1. * dung dch c pH = 13. Bi 61. X l dung dch H2SO4 0,02M, Y l dung dch NaOH 0,035M . Khi trn ln dung dch X vi dung dch Y ta thu c dung dch Z c th tch bng tng th tch hai dung dch mang trn v c pH = 2. Coi H 2SO4 phn li hon ton 2 nc.Hy tnh t l th tch gia dung dch X v dung dch Y . Bi 62. Cho 40 ml dung dch H2SO4 0,375M vo 160 ml dung dch cha ng thi NaOH 0,16M v KOH 0,04M. Tnh pH ca dung dch thu c. Coi H2SO4 phn li hon ton 2 nc. Bi 63. Trn 3 dung dch H2SO4 0,1M ; HNO3 0,2M ; HCl 0,3M vi th tch bng nhau thu c dung dch A . Ly 300 ml dung dch A tc dng vi dung dch B gm NaOH 0,2M v Ba(OH) 2 0,1M. Tnh th tch dung dch B cn dng sau khi phn ng kt thc thu c dung dch c pH = 1. Coi Ba(OH)2 v H2SO4 phn li hon ton 2 nc. Bi 64. A l dung dch H2SO4, B l dung dch NaOH . Tin hnh cc th nghim sau : - Trn 0,2 lt A v 0,3 lt B thu c 0,5 lt dung dch C. trung ho 20 ml dd C cn 40 ml dd HCl 0,5M. - Trn 0,3 lt A vi 0,2 lt B thu c 0,5 lt dd D. trung ho 20 ml dd D cn 80 ml dd NaOH 0,1M. Tnh nng mol ca H2SO4 v NaOH trong dung dch A, B. Coi H2SO4 phn li hon ton 2 nc.
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Trac nghiem chuong Su Dien Li

GV: Tran Thi Lien Huong

Bi 65.a) Tnh th tch dung dch NaOH 0,01M cn trung ho 200 ml dung dch H 2SO4 c pH = 3. Coi H2SO4 phn li hon ton 2 nc. b) Pha long 10 ml dung dch HCl vi nc thnh 250 ml, dung dch thu c c pH = 3. Hy tnh nng mol ca dung dch HCl trc khi pha long v pH ca dung dch . Bi 66.a) Tnh pH ca dung dch thu c khi ho tan 0,4 gam NaOH vo 100 ml dung dch Ba(OH) 2 0,05M. Coi Ba(OH)2 in li hon ton c hai nc. b) Tnh th tch dung dch HCl 0,1M cn trung ho 200 ml dung dch Ba(OH) 2 c pH = 13. Coi Ba(OH) 2 in li hon ton c hai nc. c) Pha long 200 ml dung dch Ba(OH) 2 vi 1,5 lt nc c dung dch c pH = 12. Tnh nng dung dch Ba(OH)2 trc khi pha long. Coi Ba(OH)2 in li hon ton c hai nc. Bi 67.a) Tnh pH ca dung dch thu c khi cho 1lit dd H2SO4 0,005M tc dng vi 4 lt dd NaOH 0,005M. b) Trn 300 ml dung dch HCl 0,05M vi 200 ml dd Ba(OH) 2 a mol/l c 500 ml dd c pH = 12. Tnh a. Coi Ba(OH)2 in li hon ton c hai nc. Bi 68.a) Cho dung dch NaOH c pH = 12 (dd A). Cn pha long hay c cn dung dch A bao nhiu ln c dung dch NaOH c pH = 11. b) Cho dung dch NaOH c pH = 10 (dd B). Cn pha long hay c cn dung dch B bao nhiu ln c dung dch NaOH c pH = 12. c) Cho dung dch HCl c pH = 2 (dd C). Cn pha long hay c cn dung dch C bao nhiu ln c dung dch HCl c pH = 4. d) Cho dung dch HCl c pH = 4 (dd D). Cn pha long hay c cn dung dch D bao nhiu ln c dung dch HCl c pH = 3. Bi 69. A l dung dch H2SO4 0,5M, B l dung dch NaOH 0,5M. Cn trn VA vi VB theo t l no c : * dung dch c pH = 2 ; * dung dch c pH = 13. ( Coi cc cht phn li hon ton) Bi 70. Trn V1 lt dung dch HCl 0,6M v V2 lt dung dch NaOH 0,4M thu c 0,6 lt dung dch A. Tnh V 1 , V2. Bit rng 0,6 lt dung dch A c th ho tan ht 1,02 gam Al2O3. Bi 71. Nh t t dung dch NaOH 2M vo 100 ml dung dch Y cha cc ion Zn 2+, Fe3+, SO 2 4 cho n khi kt ta ht cc ion Zn2+, Fe3+ th thy th tch dung dch NaOH dng l 350 ml. Tip tc thm 200 ml dung dch NaOH 2M vo h trn th mt cht kt ta va tan ht. Tnh nng mol/l ca cc ion c trong dung dch Y . Bi 72. Ly 100 ml dung dch A cha HCl 2M v HNO 3 1,5M cho tc dng vi 400 ml dung dch B cha NaOH 0,5M v KOH nng a mol/l thu c 500 ml dung dch C trung tnh. Tnh a v nng mol/l ca cc ion trong dung dch. Bi 73. Cho 100 ml dung dch A cha Na 2SO4 0,1M v Na2CO3 0,1M tc dng va vi 100 ml dung dch B cha Ba(NO3)2 0,05M v Pb(NO3)2 aM to kt ta . Tnh nng mol/l ca Pb(NO 3)2 v khi lng chung ca cc kt ta. Bi 74. C 1lt dung dch hn hp Na2CO3 0,1M v (NH4)2CO3 0,25M. Cho 43 gam hn hp BaCl2 v CaCl2 vo dung dch . Sau khi phn ng kt thc thu c 39,7 gam kt ta A v dung dch B.Tnh %m cc cht trong A. Bi 75. Tnh pH ca dung dch : 2 a) Na2CO3 0,1M bit : CO 3 + H2O HCO 3 + OH- ; Kb = 1,6.10-4. b) NaHCO3 2.10-2M, bit : H2CO3 H+ + HCO 3 ; Ka1 = 4,5.10-7 2 HCO 3 H+ + CO 3 ; Ka2 = 4,8.10-11

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