TRNG I HC M - A CHT

B mn: Lc Ha - Du

BI TP LN MN
TIN HC NG DNG TRONG CNHH

bi:
M phng gi nh h thng chng ct du th ca nh my lc
du Dung Qut khi s dng nguyn liu du th hn hp (85% du th
Bch H v 15% du th Dubai).

Sinh vin thc hin:

L Vn Bc MSSV 0964040006
Trn Danh Bnh MSSV 0964040008

Bi tp ln
Chin

GVGD: L nh

Bi S Hong MSSV 0964040023

Mai Vn Nam MSSV 0964040037
L Th Tuyt MSSV 0964040070
L Quang Vng MSSV 0964040071
Lp: Lc Ha Du A - K54TH

Thanh Ha - 2013

LHD A-K54TH

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GVGD: L nh Chin

Mc lc
Mc lc.................................................................................................................. 3
TNG QUAN........................................................................................................... 4
Chng 1: Tng quan v nh my lc du Dung Qut.......................................6
1.1. Tng quan nh my..................................................................................6
1.2 Tng quan phn xng chng ct.............................................................7
Chng 2: Tng quan v nguyn liu v qu trnh chng ct.............................8
2.1 Tnh cht du th Bch H........................................................................8
2.2 Tnh cht du th Dubai ...........................................................................9
2.3 Miu t qu trnh chng ct.....................................................................10
Chng 3: Tin hnh m phng........................................................................12
3.1 i n v................................................................................................ 12
3.2 Nhp dng du th Bch H v Dubai.....................................................13
3.3 Nhp cc thng s dng v thit b.........................................................21
3.3 Nhp thm cc gi tr c th...................................................................28
3.4 Chy thp chng ct............................................................................... 29
Chng 4: Kt qu m phng...........................................................................31
4.2 Thp chng ct........................................................................................ 31
4.3 nh gi.................................................................................................. 33
Ti liu tham kho............................................................................................... 34

LHD A-K54TH

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TNG QUAN
Hin nay, du v kh cng nh cc sn phm ca chng c s dng rng ri
trong tt c cc nghnh kinh t th gii. ngha ca du v sn phm ca du c bit
tng nhanh vo nhng nm gn y, nht l sau cuc khng hong nng lng xy ra
ti nhiu nc pht trin.

Nc ta l mt trong nhng nc c tr lng du kh kh ln. Ngun ti

nguyn ny bc u c pht hin ti cc m c tr lng ln nh: i Hng, Bch
H, Rng ng... v cng c xem l cha nh gi ht tin nng ca ngun du m
ti vng bin ng rng ln ca t nc ta. Nhng mt iu ng tic ca ngnh
nng lng nc nh l chng ta ch mi dng li giai on khai thc v xut
khu du th trong khi vn phi nhp mt lng ngy cng ln cc sn phm du
m thng phm t nc ngoi gy tht thu mt ngun li ngoi t ln. Trc tnh
LHD A-K54TH

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hnh nh vy nm 2006 nh nc ta quyt nh xy dng nh my lc du du tin

nh my lc du Dung Qut. Nh my lc du Dung Qut ch tp trung sn xut nhin
liu, quy m cng sut 6.5 triu tn du th/nm v p ng 30% nhu cu trong nc.
Nh my Lc du Dung Qut, chn du th Bch H lm nguyn liu c s, khi
thit k tnh ton cho 2 trng hp: vn hnh vi 100% du th Bch H v vn hnh
vi du hn hp (85% du th Bch H v 15% Du chua Dubai). Du th Bch
H,nguyn liu cho NMLD Dung Qut, c sn lng khai thc gim dn hng nm.
Nm:

D kin:

- 2009: 5.4 triu tn/nm

- 2010: 4.82 triu tn/nm
- 2011: 4.26 triu tn/nm
- 2012: 3.81 triu tn/nm
- 2013: 3.43 triu tn/nm
- 2014: 3.11 triu tn/nm
- 2015: 2.78 triu tn/nm.

Trong tng lai khng xa, ngun du th Bch H khng p ng nhu cu

nguyn liu ca nh my. Do , vic tm kim v la chn du thay th du th Bch
H c ngha quan trng i vi hot ng ca nh my trong tng lai. Tuy nhin
du th Bch h l du th thuc loi c bit (l loi du siu ngt ch c hm lng
lu hunh l 0.3%), nu theo bng xp hng th dng hng 2/9. Coi nh loi tt hng
u v loi s 1 c trong phn loi xp hng nhng t c trn th trng th gii. Chnh
do tnh c bit (siu ngt) ny ca du th Bch h m vic la chn du th thay th
n i vi nh my Lc du Dung Qut hin nay l rt kh khn. Kt qu nghin cu
ca PVPro (Vin du kh Vit Nam) nhm tm kim ngun du th thay th du th
Bch H lm nguyn liu cho nh my Lc du Dung Qut cho thy:
Ch c 7 mu du (trong s 3068 mu du trn th gii c thng tin v cht
lng) v du th Vit Nam nh du th thuc m C Ng Vng, S T Vng c
iu kin lm nguyn liu cho nh my lc du Dung Qut.
Hin nay nh my lc du Dung Qut ang tin hng c phn ha thu ht vn
nng cp, m rng cng sut nh my t 6.5 triu tn du th/nm ln cng sut l
10 triu tn du th/nm. V vy song song vi vic tm kim ngun du t nc
ngoi, ngun du trong nc cn c nh gi mc ph hp v mt k thut v
hiu qu kinh t khi x l ti NMLD Dung Qut nhm a ra c k hoch cung cp
nguyn liu di hn cho NMLD Dung Qut. Cng vic ny gp phn n nh hot
ng ca nh my trong tng lai.
Mt khc trong 5 nm ti, s c thm vi NMLD na c hnh thnh v i
vo sn xut. Dung Qut buc phi cnh tranh vi cc NMLD khc. gia tng tnh
cnh tranh ca NMLD phi tng hiu qu sn xut v ti u ha nn tng cng sut v
LHD A-K54TH

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GVGD: L nh Chin

m rng l bt buc pht trin ha du, tm v s dng cc ngun du th khc

gi tr u vo thp hn du t m Bch H (cc ngun du th khc r hn du Bch
H t 15% - 30%).
V vy vic cp thit l phi tm ngun du phi trn vi du th Bch H
nhm p ng nguyn liu cho nh my. Nhng khi s dng du phi trn th phi
m bo mc ph hp v mt k thut v hiu qu kinh t. T nhng phn tch
trn, ti quyt nh chn ti: M phng gi nh h thng chng ct du th ca
nh my lc du Dung Qut khi s dng nguyn liu du th hn hp (85% du th
Bch H v 15% du th Dubai). xem xt tng quan nh hng ca nguyn liu
hn hp du th (85% du th Bch H +15% du th Dubai) v 100% du th Bch
H i lu lng sn phm ca nh my lc du Dung Qut nh th no.

Chng 1: Tng quan v nh my lc du Dung Qut

1.1. Tng quan nh my.
Nh my lc du Dung Qut t ti huyn Bnh Sn, tnh Qung Ngi. Mt
bng d n gm c 4 khu vc chnh: cc phn xng cng ngh v ph tr, khu b
cha sn phm, cng xut sn phm v phao rt du khng bn, h thng ly v x
nc bin. Nhng khu vc ny c ni vi nhau bng h thng ng vi ng ph
lin k. Cng sut thit k l 6.5 triu tn du th/nm (148000 BPSD). Nguyn liu
ca nh my l 100% du th Bch H hoc 85% du th Bch H v 15% du chua
Dubai.
Sn phm lc du ca nh my gm c:
Kh du m ha lng LPG (cho th trng ni a)
Propylene
Xng Mogas 92/95
Du ha
Nhin liu phn lc Jet A1
Diesel t
Du t (FO).
LHD A-K54TH

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1.2 Tng quan phn xng chng ct.

Phn xng CDU c th xem l phn xng ca ng ca nh my lc du
vi nhim v phn tch du th thnh nhng phn on nh hn theo nhng khong
nhit si khc nhau. Qu trnh chng ct p sut thng hay chng ct p sut
kh quyn vi mc ch thu nhn cc phn on nhin liu nh xng (light
naphtha v heavy naphtha), kerosene (du ha dn dng) v nhin liu phn lc
(jetfuel), diesel (light diesel v heavy diesel) v cn kh quyn (hay gi l phn on
mazut). Hiu sut ca cc phn on sn phm khi chng ct du m ph thuc vo
bn cht du th, nhit ct phn on v mc i hi cht lng sn phm thu
c. Phn xng CDU ca nh my lc du Dung Qut c thit k vi cng sut
6.5 triu tn du th/nm .

LHD A-K54TH

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M hnh 3D ca phn xng CDU nh my lc du Dung Qut theo hng ng Nam

M hnh 3D ca phn xng CDU nh my lc du Dung Qut theo hng Ty Nam

Chng 2: Tng quan v nguyn liu v qu trnh chng ct

2.1 Tnh cht du th Bch H.
T trng
LHD A-K54TH

36.9 0API
Page 8

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GVGD: L nh Chin

H s KUOP
-

12.39

ng cong TBP ca du th Bch H.

Nhit si(C)

% khi lng

94.00

5.00

125.00

10.00

195.00

20.00

253.00

30.00

303.00

40.00

356.00

50.00

403.00

60.00

446.00

70.00

505.00

80.00

Thnh phn phn nh (lights end) ca du th Bch H

Cu t
% th tch

% khi lng

CH4

0.0009

0.0006

C2H6

0.0119

0.0078

C3H8

0.057

0.0401

i-C4H10

0.034

0.0228

n-C4H10

0.0658

0.0457

Neo-C5H12

0.0003

0.0002

i-C5H12

0.028

0.0208

n-C5H12

0.034

0.0256

n-C6H14

0.0107

0.1719

2.2 Tnh cht du th Dubai

LHD A-K54TH

T trng

30.4

H s KUOP

11.78

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ng cong TBP ca du th Dubai.

Nhit (0C)
% th tch

% khi lng

15

1.86

1.4

149

19.2

15.6

232

33.76

28.85

342

53.85

48.55

362

58.53

53.35

509

78.27

74.35

550

82.71

79.25

Thnh phn phn nh ca du th Dubai.

% th tch

% khi lng

Ethanal

0.05

0.02

Propane

0.5

0.29

i-butane

0.36

0.23

n-butan

1.29

0.86

2.3 Miu t qu trnh chng ct.

Blend Crude Oil

Nhit (0C)

233

p sut (psi)

75

Lu lng th tch (bbl/day)

148000

Furnace
Nhit (oC)

350

gim p sut(psia)

10

LHD A-K54TH

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GVGD: L nh Chin

DieselSteam

AGOSteam

MainSteam

Nhit (oC)

150

150

200

p sut(psia)

50

50

150

Lu lng khi
lng(lb/hr)

3000

3000

7500

S PFD thu gn

Chi tit thp chng ct.

LHD A-K54TH

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Chng 3: Tin hnh m phng

3.1 i n v.
Trc tin chng ta tin hnh i n v
Chn SI trong mc Available Unit Sets Tab Clone
i tn trong mc Unit Set Name: Dung Quat Refinery
Display Units : p sut l psia, nhit oC.

LHD A-K54TH

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3.2 Nhp dng du th Bch H v Dubai.

- La chn cu t:
H2O, CH4, C2H6, C3H8, i-C4H10,n-C4H10, Neo-C5H12, i-C5H12, n-C5H12, nC6H14.

Chn gi cht lu.

V yu cu ca bi l chng ct du th p sut kh quyn nn ta la chn gi

cht lu l Peng-Robinson.

LHD A-K54TH

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Vo mi trng c trng du m.

Sau khi nhp cc thng s c trng du m ca 2 loi du ta c

-

Thnh phn nh ca du th Bch H.

LHD A-K54TH

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Thnh phn nh ca du th Dubai.

S liu ca ng cong lm vic ca du th Bch H

LHD A-K54TH

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S liu ca ng cong lm vic ca du th Dubai

LHD A-K54TH

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GVGD: L nh Chin

ng cong chng ct ca du th Bch H.

LHD A-K54TH

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ng cong chng ct ca du th Dubai.

Trong mc Cut/blend

Phn Cut Opinion Selection chng ta c 3 s la chn.

Auto Cut
User Points
User Ranges
Ta chn Auto Cut: Hysys s chia du m da trn cc gi tr bn trong

Khong

S phn on

37.78-4250C (100-8000F)

28 (4 phn on trn mi khong

37.780C/1000F)

425-6500C (800-12000F)

8 (2 phn on trn mi khong

37.780C/1000F)

650-7800C (1200-16000F)

4 (1 phn on trn mi khong

LHD A-K54TH

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37.780C/1000F)
-

Khi phi trn hn hp du th ( Bch H + Dubai).

Sau khi xong chng ta c bng tnh cht ca cc cu t gi ca hn hp du

th.

V chng ta c cc phn phn on ca hn hp du th.

LHD A-K54TH

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Ta c tng quan so snh gia 3 ng cong chng ct gia ca du th Bch

H, du th Dubai v hn hp du th Bch H + Dubai.

LHD A-K54TH

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3.3 Nhp cc thng s dng v thit b

-

Hn hp du th.
Blend Crude Oil
Nhit (0C)

233

p sut (psi)

75

Lu lng th tch (bbl/day)

148000

Thit b PreFlash.

Thit b tin phn tch c tc dng loi bt phn nh ( nhit si nh hn 350

C) trong hn hp du th to iu kin hot ng d dng cho l gia nhit, nh trnh
c dng hi qu ln v khi lng du gim khong 10% khi qua thp PreFlash.
0

L t.

un nng dng sn phm lng ra t thp PreFlash n 350 0C vo thp

chng ct.
Furnace
Nhit (oC)
LHD A-K54TH

350
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gim p sut(psia)

10

Thit b phi trn Mix 100.

Trn cc dng nguyn liu cho vo tho chng ct

Chn Set Outlet to Lowest Inlet

Dng qu trnh
DieselSteam

AGOSteam

MainSteam

Nhit (oC)

150

150

200

p sut(psia)

50

50

150

Lu lng khi
lng(lb/hr)

3000

3000

7500

Thp chng ct

LHD A-K54TH

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Thng s thp

p sut

Nhit

Condenser Pressure

19.7 psia

Condenser

38 0C

Condenser Pressure Drop

9 psia

1_Main TS

122 0C

Bottom Stage Pressure

32.7 psia

29_Main TS

372 0C

Nhp Side Strippers v Pump Arounds

Side Strippers: (Thit b bay hi cnh sn) c thm vo bn cnh thp

nhm ci thin cht lng ca ba sn phm chnh: Kerosene, Diesel, AGO. C hai loi
thit b Stripped c sn trong Hysys: Reboiled v Steam Stripped. Ci t mt
Reboiler bc hi cnh sn v hai thit b Steam Stripped.
Pump Arounds: (bm tun hon) gip ci thin kh nng phn tch ca thp.
Dng lng t mt a c lm lnh v bm vo a cao hn. Trn thc t, qu trnh
ny l s hi lu gia hai a.

LHD A-K54TH

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- Ci t cc thp Stripping sn.

Chng ta s ci t cc thp stripping sn trn mc Side Ops. Trn mc
ny, chng ta c th ci t, hin th, s dng hoc xa tt c cc dng ca thit
b ph tr.
u tin chng ta s ci th thp Kero_SS. y l mt thit b stripping
ti un 3 a l thuyt vi t s un si bay hi l 0.75, nn chn Reboiled trong
nhm Configuration v t s si bay hi l mc nh.
D liu phn b sn phm ct trc tip c tnh ton trong qu trnh
c trng du m.

LHD A-K54TH

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T y ta c th tnh c lng sn phm cc phn on ca du m.

Nh phn th tch lng Kerosene l 0.11. m lng nguyn liu tiu th trong
mt ngy ca thp chng ct l 148000 bbl/day, v vy ta c lng sn phm
Kerosene thu c l 0.11*148000 = 16300 bbl/day. Tng t ta c bng sau:

Sn phm

Phn th tch

Lng sn phm

Kerosene

0.11

16300 bbl/day

Diesel

0.205

31000 bbl/day

AGO

0.062

9200 bbl/day

Ta c

LHD A-K54TH

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Tng t nh vy, chng ta c th ci t hai thit b stripping sn cn li

Diesel_SS v AGO_SS. Chng u l nhng thit b stripping bng hi nc, nn
chng ta phi la chn Steam Stripper trong nhm Configuration.

LHD A-K54TH

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Ci t bm hi lu

Mi bm hi lu lm lnh c 2 thng s k thut lin quan n n. Cc thng

s mc nh l lu lng lu thng v gim nhit (Dt) gia lng ly ra v lng
quay li.Vi v d ny, thng s Dt c thay i thnh mt thng s k thut l cng
sut lm lnh ca bm hi lu.
Bm hi lu

Lu lng

PA_1_Rate(PA)

5e+4 bbl/day

PA_1_Duty(PA)
PA_2_Rate(PA)

-5.5e+7 Btu/day
3e+4 bbl/day

PA_2_Duty(PA)
PA_3_Rate(PA)
PA_3_Duty(PA)

LHD A-K54TH

Cng sut

-3.5e+7 Btu/day
3e+4 bbl/day
-3.5e+7 Btu/day

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Nhp cc thng s k thut ca thp.

3.3 Nhp thm cc gi tr c th.

-

La chn trang Monitor ca ca s tnh cht thp.

t do by gi l khng , ngha l thp sn sng chy. Tuy nhin, trc

khi chy thp chng ta s phi thay th 2 thng s k thut c kch hot, lu
lng WasterH2O v t s Kero_SSBoiUp, vi cc thng s mi nh sau:
-

Thng s k thut Overflash cho a np liu (dng lng thc hin trn a np
liu)

Thng s k thut cng sut ni ti un ca thp stripping Kerosene.

Khong thng thng cho lu lng hi l 3-5% tng lu lng np liu vo
thp. Trong trng hp ny, lu lng ca dng nguyn liu 148000 bbl/day.

LHD A-K54TH

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Nn lu lng hi 3.5% hay 5200 bbl/day. Do vy, ta nhp gi tr cho thng s

Overflash l 5200 bbl/day.
Gi tr cho thng s cng sut ni ti un (Kero Reb Duty) l 7.5e6 Btu/hr

3.4 Chy thp chng ct.

La chn trang Monitor hin th bng Specification. t do by gi l
khng, nn thp sn sng c tnh ton, tuy nhin mt gi trn cho tc dng sn
phm ct (Naphtha) phi c cung cp trc. thm vo , c mt vi thng s k
thut m ang c kch hot, nhng chng ta li ch mun s dng lm gi tr c
tnh m thi.
To thay i cho cc thng s k thut nh sau.
1. Trong Specified Value cho distillate Rate ,nhp 2e4 bbl/day
2. Kch hot cc thng s: Overflash, Kero Reb duty, Vapour Prod Rate.
3. B kch hot cc thng s: Reflux Ratio, WasterH2O Rate, Kero_SSBoilUp
4. Kch vo nt Run bt u qu trnh tnh ton. Thng s hin th trn
trang ny c cp nhp sau tng vng lp. Thp s hi t nh hnh sau:
LHD A-K54TH

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LHD A-K54TH

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Chng 4: Kt qu m phng.
4.1 Phn xng chng ct.

4.2 Thp chng ct.

LHD A-K54TH

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LHD A-K54TH

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4.3 nh gi.
c ci nhn tng quan hn v vic thay i nguyn liu ca thp chng ct
c nh hng n lu lng sn phm ca thp chng ct hay khng? By gi ta s
ly kt qu m phng thp chng ct hot vi 100% nguyn liu du th Bch H
so snh. Cng tng t ta c cc phn phn on du th Bch H.

Ta c bng so snh tng quan sn phm ca nh my loc du Dung Qut khi

s dng blend Oil ( 85%du bch H+15%du Dubai) v 100% du Bch H.

Blend Oil

Bch H Oil

Fraction

Volumn in
148000 bbl/day

Fraction

Volumn in
148000
bbl/day

Naphtha

0.164

25000

0.166

25000

Kerosene

0.11

16300

0.111

16300

Light Diesel

0.104

16000

0.106

16000

Heavy Diesel

0.101

15000

0.101

15000

AGO

0.062

9200

0.061

9200

Residue

0.448

67000

0.455

68000

Ta thy sn phm ca thp chng ct khng thay i khi s dng thay th du

Bch H bng hn hp du th (blend Oil).
LHD A-K54TH

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Ngy nay khi m tr lng khai thc du th Bch H ang giam dn, cng
nh nhu cu phi nng cp v m rng nh my th vic tm kim ngun du th thay
th cng nh phi trn vi du th Bch H l yu cu tt yu. Nhng khi phi
trn th chng ta cn phi m bo yu cu v t l gia 2 loi du phi trn m
bo yu cu k thut, cng nh li nhun cho nh my. Vi bi m phng ny th
phn xng chng ct ca nh my lc du Dung Qut s dng nguyn liu hn hp
du th Bch H v du chua Dubai (t l phi trn l 85% du th Bch H + 15%
du chua Dubai). Kt qu thu c th vi t l phi trn ny th phn xng chng
ct ca nh my lc du Dung Qut vn cho lng sn phm tng ng vi lng
sn phm thu c khi phn xng s dng 100% nguyn liu l du th Bch H.
y l nhng m phng gi nh nhng khi chng ta mun tng t l phi trn
gim lng du th Bch h, cng nh thay th hon ton du th Bch H th cn
phi c nhng nh gi k lng v chuyn su hn na.

Ti liu tham kho

1. Prosses simulation use Hysys
2. Hysys Turial
3. Advanced Hysys course -2008
4. Advanced Hysys course - 2010

LHD A-K54TH

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