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B GIO DC V O TO

THI TUYN SINH I HC, CAO NG NM 200

CHNH THC ( thi c 05 trang) : 90 pht.

Mn thi: HO HC, Kh Thi gian lm bi

M thi 182 H, tn th sinh:..................................................................... ..... S bo danh :....................................................................... ..... PHN CHUNG CHO TT C TH SINH (44 cu, t cu 1 n cu 44):

Cu 1: Cho 4,48 lt hn hp X ( ktc) gm 2 hirocacbon mch h li t t qua bnh cha 1,4 dung dch Br 0,5M. Sau khi phn ng hon ton, s mol Br gim mt na v khi lng bnh 2 2 tng thm 6,7 gam. Cng thc phn t c-a 2 hirocacbon l (cho H = 1, C = 12) A. C H v C H . B. C H v C H . C. C H v C H . D. C H v C H . 2 2 4 6 2 2 4 8 3 4 4 8 2 2 3 8

Cu 2: Ho tan hon ton hn hp gm 0,12 mol FeS v a mol Cu S vo axit HNO (va -), thu 2 2 3 c dung dch X (ch cha hai mui sunfat) v kh duy nht NO. Gi tr c-a a l A. 0,04. B. 0,075. C. 0,12. D. 0,06. Cu 3: Nh t t cho n d dung dch NaOH vo dung dch AlCl . Hin tng xy ra l 3

A. c kt t-a keo trng, sau kt t-a tan. B. ch c kt t-a keo t C. c kt t-a keo trng v c kh bay ln. D. khng c kt t-a, c Cu 4: Trong phng th nghim, iu ch mt lng nh kh X tinh khit, ngi ta un nng dch amoni nitrit bo ho. Kh X l A. NO. B. NO . C. N O. D. N . 2 2 2 + 2 2 6

Cu 5: Dy gm cc ion X , Y v nguyn t Z u c cu hnh electron 1s 2s 2p l: + + + + A. Na , Cl , Ar. B. Li , F , Ne. C. Na , F , Ne. D. K , Cl , Ar. Cu 6: Mnh khng ng l: A. CH CH COOCH=CH cng dy ng ng vi CH =CHCOOCH . 3 2 2 2 3 B. CH CH COOCH=CH tc dng vi dung dch NaOH thu c anehit v mui. 3 2 2 C. CH CH COOCH=CH tc dng c vi dung dch Br . 3 2 2 2

D. CH CH COOCH=CH c th trng hp to polime. 3 2 2 Cu 7: Dy cc ion xp theo chiu gim dn tnh oxi ho l (bit trong dy in ha, cp Fe3+ ng trc cp Ag+/Ag):

+ 2+ 3+ 2+ 3+ 2+ + 2+ A. Ag , Cu , Fe , Fe . B. Fe , Cu , Ag , Fe . + 3+ 2+ 2+ 3+ + 2+ 2+ C. Ag , Fe , Cu , Fe . D. Fe , Ag , Cu , Fe . Cu 8: Anion X2+ 2 6 v cation Y u c cu hnh electron lp ngoi cng 3p . V tr c-a cc nguyn t trong bng tun hon cc nguyn t ha hc l: A. X c s th t 17, chu k 4, nhm VIIA (phn nhm chnh nhm VII); Y c s th t 20, k 4, nhm IIA (phn nhm chnh nhm II). B. X c s th t 18, chu k 3, nhm VIA (phn nhm chnh nhm VI); Y c s th t 20, ch 4, nhm IIA (phn nhm chnh nhm II). C. X c s th t 17, chu k 3, nhm VIIA (phn nhm chnh nhm VII); Y c s th t 20, k 4, nhm IIA (phn nhm chnh nhm II). D. X c s th t 18, chu k 3, nhm VIIA (phn nhm chnh nhm VII); Y c s th t 20, k 3, nhm IIA (phn nhm chnh nhm II). Cu 9: Khi t chy hon ton mt amin n chc X, thu c 8,4 lt kh CO , 1,4 lt kh N ( 2 2

tch kh o ktc) v 10,125 gam H2O. Cng thc phn t c-a X l (cho H = 1, O = 16) A. C H N. B. C H N. C. C H N. D. C H N. 3 7 2 7 3 9 4 9 Cu 10: Cho 15,6 gam hn hp hai ancol (ru) n chc, k tip nhau trong dy ng ng tc vi 9,2 gam Na, thu c 24,5 gam cht rn. Hai ancol l (cho H = 1, C = 12, O = 16, Na = A. C H OH v C H OH. B. C H OH v C H OH. 3 5 4 7 2 5 3 7

C. C H OH v C H OH. H OH. 3 7 2 5

D. CH OH v C 4 9 3

Trang 1/5 - M thi 182 ----------------------- Page 2-----------------------

Cu 11: Cho t t dung dch cha a mol HCl vo dung dch cha b mol Na CO 2 3

ng thi khuy

u, thu c V lt kh ( ktc) v dung dch X. Khi cho d nc vi trong vo dung dch X th xut hin kt t-a. Biu thc lin h gia V vi a, b l: A. V = 22,4(a - b). B. V = 11,2(a - b). C. V = 11,2(a + b). D. V = 22,4(a + b). Cu 12: Thu phn hon ton 444 gam mt lipit thu c 46 gam glixerol (glixerin) v hai loi bo. Hai loi axit bo l (cho H = 1, C = 12, O = 16) A. C15H31COOH v C17H35COOH. B. C17H33COOH v C15H31COOH. C. C17H31COOH v C17H33COOH. D. C17H33COOH v C17H35COOH. Cu 13: Clo ho PVC thu c mt polime cha 63,96% clo v khi lng, trung bnh 1 phn t c phn ng vi k mt xch trong mch PVC. Gi tr c-a k l (cho H = 1, C = 12, Cl = 35,5) A. 3. B. 6. C. 4. D. 5. Cu 14: Ba hirocacbon X, Y, Z k tip nhau trong dy ng ng, trong khi lng phn t gp i khi lng phn t X. t chy 0,1 mol cht Y, sn phm kh hp th hon ton vo d dch Ca(OH) (d), thu c s gam kt t-a l (cho H = 1, C = 12, O = 16, Ca = 40) 2 B. 40. D. 10. Cu 15: Cho cc phn ng sau: a) FeO + HNO 3 (c, nng) c) Al O + HNO 2 3 3 (c, nng) Ni, t o A. 20. C. 30. b) FeS + H SO 2 4 (c, nng) 3 f) glucoz + AgNO 3 3 h) glixerol (glixerin) + Cu(OH) 2 (hoc Ag O)

d) Cu + dung dch FeCl

e) CH CHO + H trong dung dch NH 3 2 2 g) C H + Br 2 4 2

Dy gm cc phn ng u thuc loi phn ng oxi ha - kh l: A. a, b, d, e, f, h. B. a, b, d, e, f, g. C. a, b, c, d , e, h. D. a, b, c, d, e, g. Cu 16: Khi nung hn hp cc cht Fe(NO ) , Fe(OH) v FeCO trong khng kh n khi lng 3 2 3

3 khng i, thu c mt cht rn l A. Fe O . B. FeO. D. Fe O . 3 4 2 3 C. Fe.

Cu 17: Mt hirocacbon X cng hp vi axit HCl theo t l mol 1:1 to sn phm c thnh phn khi lng clo l 45,223%. Cng thc phn t c-a X l (cho H = 1, C = 12, Cl = 35,5) A. C H . B. C H . C. C H . D. C H . 3 6 3 4 2 4 4 8

Cu 18: Cho 6,6 gam mt anehit X n chc, mch h phn ng vi lng d AgNO (hoc Ag O) t 3 2

dung dch NH , un nng. Lng Ag sinh ra cho phn ng ht vi axit HNO long, thot ra 2,24 3 3 (sn phm kh duy nht, o ktc). Cng thc cu to thu gn c-a X l (cho H = 1, C = 12, O A. CH CHO. B. HCHO. C. CH CH CHO. D. CH = CHCHO. 3 3 2 2

Cu 19: Ha tan hon ton 12 gam hn hp Fe, Cu (t l mol 1:1) bng axit HNO3, thu c V l ktc) hn hp kh X (gm NO v NO2) v dung dch Y (ch cha hai mui v axit d). T khi ci vi H2 bng 19. Gi tr c-a V l (cho H = 1, N = 14, O = 16, Fe = 56, Cu = 64) A. 2,24. B. 4,48. C. 5,60. D. 3,36. Cu 20: Hirat ha 2 anken ch to thnh 2 ancol (ru). Hai anken l A. 2-metylpropen v but-1-en (hoc buten-1). B. propen v but-2en (hoc buten-2). C. eten v but-2-en (hoc buten-2). D. eten v but-1-en (hoc buten-1). Cu 21: Trn dung dch cha a mol AlCl3 vi dung dch cha b mol NaOH. thu c kt t-a th cn c t l A. a : b = 1 : 4. B. a : b < 1 : 4. C. a : b = 1 : 5. D. a : b > 1 : 4. Cu 22: Cho tng cht: Fe, FeO, Fe(OH) , Fe(OH) , Fe O , Fe O , Fe(NO ) , Fe(NO ) , Fe SO , Fe (SO ) , 2 3 3 4 2 3 3 2 3 3 4 2 4 3 FeCO ln lt phn ng vi HNO c, nng. S phn ng thuc loi phn ng oxi ho - kh l 3 3 B. 5. D. 6. Cu 23: Cho 0,1 mol anehit X tc dng vi lng d AgNO trong dung dch NH , 3 2 3 A. 8. C. 7.

(hoc A

un nng thu c 43,2 gam Ag. Hiro ho X thu c Y, bit 0,1 mol Y phn ng va - vi 4,6 gam Na. Cng thc cu to thu gn c-a X l (cho Na = 23, Ag = 108)

A. HCHO. D. CH CH(OH)CHO. 3

B. CH CHO. 3

C. OHC-CHO.

Cu 24: Hp th hon ton 2,688 lt kh CO ( ktc) vo 2,5 lt dung dch Ba(OH) nng a 2 2 thu c 15,76 gam kt t-a. Gi tr c-a a l (cho C = 12, O = 16, Ba = 137) A. 0,032. B. 0,048. C. 0,06. D. 0,04.

Trang 2/5 - M thi 182 ----------------------- Page 3-----------------------

Cu 25: nhn bit ba axit c, ngui: HCl, H SO , HNO ng ring bit trong ba l b mt 2 4 3 ta dng thuc th l A. Fe. D. Cu. Cu 26: Cho s HCl 2 C H (benzen) 6 6 Z. Fe, t Hai cht hu c Y, Z ln lt l: A. C H (OH) , C H Cl . H Cl . 6 6 6 6 6 6 2 6 4 2 C. C H OH, C H Cl. OH. 6 5 6 5 Cu 27: in phn dung dch CuCl vi in cc tr, sau mt thi gian thu c 0,32 gam Cu 2 6 5 6 5 t cao, p cao o X o Y B. CuO. Cl (t l mol 1:1) C. Al. NaOH c (d-) axit

B. C H (OH) , C 6 4 D. C H ONa, C H

v mt lng kh X ant. Hp th hon ton lng kh X trn vo 200 ml dung dch NaOH ( nh thng). Sau phn ng, nng NaOH cn li l 0,05M (gi thit th tch dung dch khng t i). Nng ban u c-a dung dch NaOH l (cho Cu = 64) A. 0,15M. B. 0,2M. C. 0,1M. D. 0,05M. Cu 28: Nilon6,6 l mt loi A. t axetat. B. t poliamit. C. polieste. D. t visco. Cu 29: Pht biu khng ng l:

A. Axit axetic phn ng vi dung dch NaOH, ly dung dch mui va to ra cho tc dng v CO li thu c axit axetic. 2

B. Phenol phn ng vi dung dch NaOH, ly mui va to ra cho tc dng vi dung dch HCl thu c phenol. C. Anilin phn ng vi dung dch HCl, ly mui va to ra cho tc dng vi dung dch NaOH thu c anilin. D. Dung dch natri phenolat phn ng vi kh CO2, ly kt t-a va to ra cho tc dng vi dch NaOH li thu c natri phenolat. Cu 30: Tng h s (cc s nguyn, ti gin) c-a tt c cc cht trong phng trnh phn ng Cu vi dung dch HNO c, nng l 3 A. 10.

B. 11. C. 8. D. 9. Cu 31: aminoxit X cha mt nhm -NH . Cho 10,3 gam X tc dng vi axit HCl (d), thu 2

13,95 gam mui khan. Cng thc cu to thu gn c-a X l (cho H = 1, C = 12, N = 14, O = 16, C 35,5) A. H NCH COOH. B. H NCH CH COO H. 2 2 2 2 2 C. CH CH CH(NH )COOH. H. 3 2 2 2 3 D. CH CH(NH )COO

Cu 32: Ho tan 5,6 gam Fe bng dung dch H SO long (d), thu c dung dch X. Dung dch X 2 4 phn ng va - vi V ml dung dch KMnO 0,5M. Gi tr c-a V l (cho Fe = 56) 4 A. 80.

B. 40. C. 20. D. 60. Cu 33: Cho m gam tinh bt ln men thnh ancol (ru) etylic vi hiu sut 81%. Ton b lng CO sinh ra c hp th hon ton vo dung dch Ca(OH) , thu c 550 gam kt t-a v dung d 2 2

X. un k dung dch X thu thm c 100 gam kt t-a. Gi tr c-a m l (cho H = 1, C = 12, O = Ca = 40) A. 550. B. 810. C. 650. D. 750. Cu 34: Cho dy cc cht: Ca(HCO ) , NH Cl, (NH ) CO , ZnSO , Al(OH) , Zn(OH) . S cht tron g 3 2 4 4 2 3 4 3 2

dy c tnh cht lng tnh l A. 3. B. 5. C. 2. D. 4. Cu 35: X phng ha 8,8 gam etyl axetat bng 200 ml dung dch NaOH 0,2M. Sau khi phn ng x

hon ton, c cn dung dch thu c cht rn khan c khi lng l (cho H = 1, C = 12, O = 1 A. 8,56 gam. B. 3,28 gam. C. 10,4 gam. D. 8,2 gam.

Cu 36: Hn hp X gm axit HCOOH v axit CH3COOH (t l mol 1:1). Ly 5,3 gam hn hp X tc dng vi 5,75 gam C H OH (c xc tc H SO c) thu c m gam hn hp este (hiu sut c-a c 2 5 2 4

phn ng este ho u bng 80%). Gi tr c-a m l (cho H = 1, C = 12, O = 16) A. 10,12. B. 6,48. C. 8,10. D. 16,20. Cu 37: t chy hon ton a mol axit hu c Y c 2a mol CO2 . Mt khc, trung ha a mol cn va - 2a mol NaOH. Cng thc cu to thu gn c-a Y l A. HOOC-CH -CH -COOH. B. C H -COOH. 2 2 2 5 C. CH -COOH. 3 Trang 3/5 - M thi 182 ----------------------- Page 4----------------------D. HOOC-COOH.

Cu 38: Cho hn hp X gm hai cht hu c c cng cng thc phn t C H NO tc dng va 2 7 2

vi dung dch NaOH v un nng, thu c dung dch Y v 4,48 lt hn hp Z ( ktc) gm hai k (u lm xanh giy qu m). T khi hi c-a Z i vi H2 bng 13,75. C cn dung dch Y thu khi lng mui khan l (cho H = 1, C = 12, N = 14, O = 16, Na = 23) A. 16,5 gam. B. 14,3 gam. C. 8,9 gam. D. 15,7 gam. Cu 39: Dung dch HCl v dung dch CH3COOH c cng nng mol/l, pH c-a hai dung dch tng ng l x v y. Quan h gia x v y l (gi thit, c 100 phn t CH3COOH th c 1 phn t i A. y = 100x. B. y = 2x. C. y = x - 2. D. y = x + 2. Cu 40: Cho m gam hn hp Mg, Al vo 250 ml dung dch X cha hn hp axit HCl 1M v axit H2SO4 0,5M, thu c 5,32 lt H2 ( ktc) v dung dch Y (coi th tch dung dch khng i) dch Y c pH l A. 1. B. 6. C. 7. D. 2. Cu 41: Cho lung kh H (d) qua hn hp cc oxit CuO, Fe O , ZnO, MgO nung nhit cao. 2 2 3

Sau phn ng hn hp rn cn li l: A. Cu, Fe, Zn, MgO. B. Cu, Fe, ZnO, MgO. C. Cu, Fe, Zn, Mg. D. Cu, FeO, ZnO, MgO. Cu 42: chng minh trong phn t c-a glucoz c nhiu nhm hiroxyl, ngi ta cho dung dc glucoz phn ng vi A. kim loi Na. B. AgNO (hoc Ag O) trong dung dch NH , un nng. 3 2 3 C. Cu(OH) trong NaOH, un nng. 2 D. Cu(OH)2 nhit thng. Cu 43: Trong phng th nghim, ngi ta thng iu ch clo bng cch

A. in phn nng chy NaCl. B. cho dung dch HCl c tc dng vi MnO , un nng. 2 C. in phn dung dch NaCl c mng ngn. D. cho F y Cl ra khi dung dch NaCl. 2 2

Cu 44: Khi tch nc t mt cht X c cng thc phn t C4H10O to thnh ba anken l ng ph c-a nhau (tnh c ng phn hnh hc). Cng thc cu to thu gn c-a X l A. (CH ) COH. B. CH OCH CH CH . 3 3 3 2 2 3 C. CH CH(OH)CH CH . OH. 3 3 2 2 3 3 D. CH CH(CH )CH

PHN RING: Th sinh ch c chn lm 1 trong 2 phn (Phn I hoc Phn II) Phn I. Theo chng trnh KHNG phn ban (6 cu, t cu 45 n cu 50): Cu 45: Ho tan hon ton 2,81 gam hn hp gm Fe O , MgO, ZnO trong 500 ml axit H SO 0,1M 2 3 2 4 (va -). Sau phn ng, hn hp mui sunfat khan thu c khi c cn dung dch c khi lng (cho H = 1, O = 16, Mg = 24, S = 32, Fe = 56, Zn = 65) A. 6,81 gam. B. 4,81 gam. C. 3,81 gam. D. 5,81 gam. Cu 46: Dy gm cc kim loi c iu ch trong cng nghip bng phng php in phn hp cht nng chy c-a chng, l: A. Na, Ca, Al. B. Na, Ca, Zn. C. Na, Cu, Al. D. Fe, Ca, Al. Cu 47: Dy gm cc cht u tc dng vi AgNO (hoc Ag O) trong dung dch NH , l: 3 2 3

A. anehit axetic, butin-1, etilen. B. anehit axetic, a xetilen, butin-2. C. axit fomic, vinylaxetilen, propin. D. anehit fomic, axetilen, etilen. Cu 48: Hn hp gm hirocacbon X v oxi c t l s mol tng ng l 1:10. t chy hon to hn hp trn thu c hn hp kh Y. Cho Y qua dung dch H SO c, thu c hn hp kh Z c 2 4 khi i vi hiro bng 19. Cng thc phn t c-a X l (cho H = 1, C = 12, O = 16) A. C H . B. C H . C. C H . D. C H . 3 8 3 6 4 8 3 4 Cu 49: Mnh khng ng l: 2+ A. Fe oxi ho c Cu. B. Fe kh c Cu2+ trong dung dch. C. Fe3+ c tnh oxi ha mnh hn Cu2+ .

2+ + D. Tnh oxi ha c-a cc ion tng theo th t: Fe Trang 4/5 - M thi 182 ----------------------- Page 5-----------------------

+ , H , Cu

2+ , Ag .

Cu 50: t chy hon ton mt lng cht hu c X thu c 3,36 lt kh CO , 0,56 lt kh N 2 2

kh o ktc) v 3,15 gam H2O. Khi X tc dng vi dung dch NaOH thu c sn phm c mui H N-CH -COONa. Cng thc cu to thu gn c-a X l (cho H = 1, C = 12, O = 16) 2 2 A. H N-CH -COO-C H . COO-CH . 2 2 2 3 C. H N-CH -CH -COOH. COO-C H . 2 2 2 2 2 5 Phn II. Theo chng trnh phn ban (6 cu, t cu 51 n cu 56): Cu 51: Khi thc hin phn ng este ho 1 mol CH COOH v 1 mol C H OH, lng este ln nht 3 2 5 B. H N-CH 3 7 2 D. H N-CH 2

thu c l 2/3 mol. t hiu sut cc i l 90% (tnh theo axit) khi tin hnh este ho CH COOH cn s mol C H OH l (bit cc phn ng este ho thc hin cng nhit ) 3 2 5 B. 2,925. C. 2,412. D. 0,456. Cu 52: Pht biu khng ng l: A. Hp cht Cr(II) c tnh kh c trng cn hp cht Cr(VI) c tnh oxi ho mnh. B. Cc hp cht Cr O , Cr(OH) , CrO, Cr(OH) u c tnh cht lng tnh. 2 3 3 2 C. Cc hp cht CrO, Cr(OH) tc dng c vi dung dch HCl cn CrO tc dng c vi 2 3 A. 0,342.

dung dch NaOH. D. Thm dung dch kim vo mui icromat, mui ny chuyn thnh mui cromat. Cu 53: thu ly Ag tinh khit t hn hp X (gm a mol Al O , b mol CuO, c mol Ag O), ngi 2 3 2

ho tan X bi dung dch cha (6a + 2b + 2c) mol HNO

c dung dch Y, sau thm (gi thi 3

hiu sut cc phn ng u l 100%) A. c mol bt Al vo Y. B. Y. C. 2c mol bt Al vo Y. D. Y. Cu 54: Cho cc cht: HCN, H , dung dch KMnO , dung dch vi 2 2 (CH ) CO l 3 2 A. 2.

c mol bt Cu vo 2c mol bt Cu vo Br . S cht phn 4

B. 4. C. 1. D. 3. Cu 55: C 4 dung dch mui ring bit: CuCl , ZnCl , FeCl , AlCl . Nu thm dung dch KOH ( 2 2 3 3

ri thm tip dung dch NH3 (d) vo 4 dung dch trn th s cht kt t-a thu c l A. 4. B. 1. C. 3. D. 2. Cu 56: Mt este c cng thc phn t l C H O , khi thu phn trong mi trng axit thu 4 6 2 axetanehit. Cng thc cu to thu gn c-a este l A. CH =CH-COO-CH . )=CH . 2 3 3 2 C. HCOO-CH=CH-CH . =CH . 3 2 --------------------------------------------------------------------------------------------------- HT ---------Trang 5/5 - M thi 182 B. HCOO-C(CH

D. CH COO-CH 3