:

2+
2 C u a q+ S O 4a q
C u 2 + a q

F e2 + a q
1
2
3
4

Oxydation
:
Fe s
F e2 + a q 2 + e

Rduction
:
C u 2+aq 2 + e
C u s

le
reducteur

:
Fe s
.

loxydant

:
C u 2+aq
/ . _ 2

Ox / Red

H3 O a q+ N O 3a q
) (
1
2
C u s 3
2+
C u s4 C u a q /
1-

- 1 -kichah ahmed batna

187853101.docPage 1 sur 16

 5

6
_ /

2+

/ C u a q / C u s

+ + ne

_ /
n

++ ne

n + + ne

Cr2 O- 2 7 a q /Cr+3 a q _

1
2
3
4
+ H
+ H3 O
5
_ 3

1
_ 2

_
/ _


/ 1 1
/ 2 2
+ 1 = 2 + 2 1

)( n2
)( n1

Ox1 + n1 e- = Red1
Ox2 + n2 e- = Red2

Ox1 / Red1 :
Ox2 / Red2:

n2Ox1 + n1 Re d 2
n1Ox2 + n2 Re d1

- 2 -kichah ahmed batna

187853101.docPage 2 sur 16

 : -2- 2-

1
2
: Ox / Red 2
3
4
3
g5 c m 15 0.4mo L / L100

P V = n RT
0

(T T ) K+273 = ( T0 ) C
8.31 J / mo L 0 K
R
3
m
V
atm =101325 Pa 1Pa = N.m-2- 1
P a

P
5
1ba r=10 Pa
n n =Vg / Vm Vm

1 m c 20 = V2 3 C 2 C 0 25
m c 200 = V1 3 L / g 0.76 = m C C 2
2 V1
m L o m / 3

V1

V1 10 0.76 = G

3
K
2
L o m/ m s m 7.6 = - l C

m s m 7.4 = +

G=I / V

3-

L o m/
+

X ] = ]+ X + [

K= S / L . G= K

- 3 -kichah ahmed batna

187853101.docPage 3 sur 16

 : 1
12 13

:

:
:
: 2
:

:

:
1 :

:
2 :
P V = n RT

n =Vg / Vm Vm

[ + pH H3 ]

X ] = ]+ X + [+
]
G=I / V



:







4

- 4 -kichah ahmed batna

187853101.docPage 4 sur 16

. . .
.
:
- I

(1

/ :
- ) ( (K+(aq) + I- (aq

C1=0.1mol.L-1

( H2O2(aq 0.5 )(C2 = 0.044mol.L-1 3mol.L-1 ) ((2Na+(aq)+S2O32-(aq C3=0.1mol.L-1 ) ( . - / :

) ( 50mL - 200mL-

10 100mL

25mL * : )( 10mL * 2mL* 1mL 5

- 5 -kichah ahmed batna

187853101.docPage 5 sur 16

(2
(2
(2
(2
(2
(2
(2
(2
(2
(2
(2
(2
(2
(2
(2
(2
(2
(2

-1

V1=50mL V2=50mL 2mL - . 3mol.L-1

- 6 -kichah ahmed batna

187853101.docPage 6 sur 16

 .
-2

-3

t 10mL
50mL
1mL
.

-4

VE :

60

50

40

30

20

16

12

- 7 -kichah ahmed batna

t(min
(

187853101.docPage 7 sur 16

VE(m
(L
:
. 100mL 100mL 20 .
-II

- 1( .
( .
( x t (n(I2
.
- 2( .
( ( n'(I2 t
VE .
C3
-3( (n(I2 t
C3 .VE
( :

12 16 20 30 40 50 60

t(min

)n(I2
mmol

mmol

-5

(x=f (t

-6

:
(1 ) ( .
(2 .

- 8 -kichah ahmed batna

187853101.docPage 8 sur 16

-7

t1=4min t2 = 16min t3 = :
. 40min

) (
40 50 60

30

20

16

12

3.4

2.8

2.4

2.3

2.5

2.8

3.2

1 2.3

t(min
(

VE(m
(L

) (
60

50

40

30

20

16

12

3.2

3.2

3.0

2.8

2.4

2.3

2.1

0.9 1.8

t(min
(

VE(m
(L

1
L m 100.0 q-a I+ q+aK L / L o m 0.40 =1 C
L m 100.0 q a2-8 O 2 S + q+a K2 L / L o m 0.036= 2 C
20 L m 10.0
I 2 t
q a2-3O 2 S + +q a a N2 L / L o m 0.02 = 3 C
t L m 50.0


I 2 I 2

1 d Re / Ox
22. q -a I / q a 2 I
q a 4 O S / q a 8 O 2 S
22. q -a I / q a 2 I
q a 3O 2 S / q a 6O 4 S

2
3
nimt
0
3
6
9 12
16
20
30
40
50
60
LmV
0.0 2.5 5.1
7.1 8.4 10.6 11.4 14.1 15.6 16.1 16.4

4 t
5 q-a I+ q+aK q a2-8 O 2 S + q+aK2
9

- 9 -kichah ahmed batna

187853101.docPage 9 sur 16



X
X


7
n i m 60
8

1 :

I + q a2-4 O S 2 = q-a I 2 + q a2-8 O 2 S

I 2 + q a2-6O 4 S = q a2-3O 2 S 2 + g 2 I

g 2
qa

2
3
qa

2q a 6

I2
0
X2
x a m X2

O4S
0
X
xam X

X- 1n=0
x a m X 2 - 2n = 0
4
xam

60
32.8

50
32.2

2q a 3

40
31.2

O 2 S2
n2
X 2- 2 n
0

g 2

n1
X- 1n
0

X=1n
x a m X = 2 / 2n = 1 n
xam

20
22.8

30
28.2

9
12
14. 16.8
2

16
21.2

6
10.
2

0
0.0

3
5

nimt
10 . (2 I) n

4-

L om

5
I
0
X
xam X
g 2

O S2
0
X2
x a m X2

2-

q a 4

qa

I2
n2
X 2- 2 n
x a m X 2 - 2n

O2S
n1
X- 1n
xam X - 1 n

X = 1 n = L o m 3 - 10 .3.6
x a m X - 1 n = 0
x a m X 2 - 2n = 0
x a m X = 2 / 2n = L o m 0.02

)X= n 2
) I
10

2q a 8

xam

- 10 -kichah ahmed batna

187853101.docPage 10 sur 16


nimt
L o m 10 . X
4-

0
0.0

3
5

6
10.
2

9
12
14. 16.8
2

16
21.2

20
22.8

30
28.2

40
31.2

50
32.2

60
32.8

X L o m 4- 10 .

4
nimt

yn

2
8

n( S 2 O

5
)

n( S 2 O82 )

imt

0
3
L o m 3- 10 3.6 3.1
n( S 2 O82 )

6
2.5
8

9
2.1
8

12
16
1.9 1.48
2

20
1.32

= X- 1n
= X - 3 - .10 .3.6
30
40
50
0.78 0.48 0.38

60
0.3
2

L o m 3- 10

0,4
187853101.docPage 11 sur 16

- 11 -kichah ahmed batna

11

nimt

7

x a m X
8
t 2/1
xam X
=X
t = t 2/1
2


X - 2X1
X
V
=
=
1 :
m
t - 2 t1
t
2 :
m V lim = V
t
0 X
lim = V
t

0

X t


1

t
dX
dt

= V

1 X- 2X1
=
V t - 2 t1
[]X

VV

VV

=
2 t

1
dX
= V V V
V dt

m

[d]X

V V = dt
12

- 12 -kichah ahmed batna

187853101.docPage 12 sur 16

:

D d + cC
Bb + A a

][ X

1 D C
n

dn
dt

= V

D C t

t0

2 A B

n A B

dn

V = - dt

t0

1
n i m 5 n i m 5 4


[ X ]

t 2/1
13

- 13 -kichah ahmed batna

187853101.docPage 13 sur 16

V
V 1
V
V1
V
nimt
L o m 4- 10 . X

0
0.0

3
5

6
10.2

[ L o m 4- 10 . [X

0.0

25

51

9
14.
2
71

4 -

nim . L om
10 1.5 = n i m 5
1n i m . L o m 4 - 100.07= n i m 5 4
- L 1 - n i m . L o m 4 - 10 7.5 = n i m 5
1L 1 - n i m . L o m 4 - 10 0.35= n i m 5 4
- n i m . L o m 4 - 10 0.17 = n i m 5
1n i m . L o m 7 - 10 7.2 = n i m 5 4

12
16
20
30
40
50 60
16. 21.2 22.8 28.2 31.2 32.2 32.
8
8
84 106
114
141 156 161 164

[ L o m 4- 10 . [X

20
187853101.docPage 14 sur 16

- 14 -kichah ahmed batna

14

nimt

1-

- L V 1

n i m . L o m 4 - 10 8 = n i m 5
1V
L 1 - n i m . L o m 4 - 10 0.37 = n i m 5 4
: 3
:
:

:
:
:

1 :
2 :
3 :
:

2
L m 500=V L m 200=V
L / L o m 0.1 = C g 0.9
C 0 20 d Re / Ox
2+
+
s Mg aq / Mg . g H aq / H2
1
2
5
3 a P 10 9 1.00 = tm a P P
H P + tm a P = P 2 H P 2

)s) t
0
18
52
71
90
115
144 160 174
5
a P 10 P 1.009 1.03 1.097 1.127 1.159
1.198 1.239 1.260 1.27
4
3
238
266
290
1.297
1.297
1.297
X H P 2
4


15

212
1.297

193
1.294

- 15 -kichah ahmed batna

)s) t
10 P a

187853101.docPage 15 sur 16

 s 180 = t
5 H aq
s 180 = t
2+
6 s 180 = t Mg aq

7
8
9 s 180 = t . s 115 = t . s 52 = t

0
10 C 20

0
mo L K / J 8.31 = R
mo L . g 24.3 = (Mg) M - 1
L 24 = Vm
)T 0 ) K+273 = ( T0 ) C
:
-1
.
-2
.
+

-4 :
-1 :
/1 .
/2 .
/3 : .
-2 :
.
-3 :
/1 .
/2 .
/3 .

16

- 16 -kichah ahmed batna

187853101.docPage 16 sur 16