Physical chemistry Homework for Chapter 6

1. Prove that for an ideal-gas reaction

2. At 400 K,

for

. Find

at 400 K for

(a) (b)

3. Consider the ideal-gas dissociation reaction

. For A and B, we have

0 = e + fT + gT 2 , where a, b, c, d, e, f, g are known and C P ,m , B

constants and these equations are valid over the temperature range from T1 to T2. Further, suppose that valid between and and . are known. Find an expression for

4. The

ideal-gas

reaction , , and

at

600K

has

. Estimate

the temperature at which

for this reaction. State approximations made.

Assuming that !Ho is constant.

5. Some vapor pressures of liquid are: T 80.0 100.0 120.0 P/torr (a) 0.08880 0.2729 0.7457

140.0 1.845

Find the average plot of versus 1/T

of vaporization over this temperature range from a

(b) (c)

Find the vapor pressure at 160

Estimate the normal boiling point of Hg.

6. Hydrogen sulfide dissociate according to the following reaction: 2 H2S (g) = 2 H2 (g) + S2 (g) Use the following thermochemical data to answer the following. substance -20.6 -----128.4 1). Evaluate standard state? Som (298K), J. mol-1K-1 205.8 130.7 228.2

for that reaction at 298 K. Is the reaction spontaneous in the

2). Evaluate

at 298 K is in this

3). If at 1400K and 1 bar pressure the degree of dissociation of 0.305, evaluate problem). (you can not use the temperature dependence of