Ti liu n thi H 2013 2014

Anken

Chuyn anken
1. Bi tp v ng phn ca anken
Cu 1: Anken X c cng thc cu to: CH3 CH2 C(CH3)=CHCH3. Tn ca X l A. isohexan B. 3-metylpent-3-en. C. 3-metylpent-2-en. D. 2-etylbut-2-en. Cu 2: S ng phn ca C4H8 l: A. 7. B. 4. C. 6. D. 5. Cu 3: Hp cht C5H10 mch h c bao nhiu ng phn cu to? A. 4. B. 5. C. 6. D. 10. Cu 4: Hp cht C5H10 c bao nhiu ng phn anken? A. 4. B. 5. C. 6. D. 7. Cu 5: Hp cht C5H10 c bao nhiu ng phn cu to? A. 4. B. 5. C. 6. D. 10. Cu 6: iu kin anken c ng phn hnh hc l: A. Mi nguyn t cacbon lin kt i lin kt vi 2 nguyn t hoc nhm nguyn t bt k B. Mi nguyn t cacbon lin kt i lin kt vi 2 nguyn t hoc nhm nguyn t khc nhau C. Mi nguyn t cacbon lin kt i lin kt vi 2 nguyn t hoc nhm nguyn t ging nhau D. 4 nguyn t hoc nhm nguyn t 2 nguyn t cacbon mang ni i phi khc nhau Cu 7: Cho cc cht sau: 2-metylbut-1-en (1); 3,3-imetylbut-1-en (2); 3-metylpent-1-en (3); 3metylpent-2-en (4). Nhng cht no l ng phn ca nhau? A. (3) v (4). B. (1),(2) v (3). C. (1) v (2). D. (2),(3) v (4). Cu 8: Hp cht no sau y c ng phn hnh hc? A. 2-metylbut-2-en. B. 2-clo-but-1-en. C. 2,3- iclobut-2-en. D. 2,3 imetylpent-2-en. Cu 9: Nhng hp cht no sau y c ng phn hnh hc (cis-trans)? CH3CH = CH2 (I); CH3CH = CHCl (II); CH3CH = C(CH3)2 (III); C2H5C(CH3)=C(CH3)C2H5(IV); C2H5C(CH3)=CClCH3(V). A. (I), (IV), (V). B. (II), (IV), (V). C. (III), (IV). D. (II), III, (IV), (V). Cu 10:S ng phn cu to ca C5H10 phn ng c vi dung dch brom l A.8. B. 7. C. 9. D. 5. Cu 11: Cho cc cht sau: CH2 =CH CH2 CH2 CH=CH2; CH2=CH CH=CH CH2 CH3; CH3 C(CH3)=CH CH2; CH2=CH CH2 CH=CH2; CH3 CH2 CH = CH CH2 CH3; CH3 C(CH3) = CH CH2 CH3; CH3 CH2 C(CH3) = C(C2H5) CH(CH3)2; CH3-CH=CH-CH3.S cht c ng phn hnh hc l A. 4. B. 1. C. 2. D. 3. Cu 12: Cho cc anken c cng thc cu to di y :
CH3CH CH=CHCH2CH3 CH3 CH3CH2CH=CCH3 CH3 CH3CH CH=CHCH3

(X) (Z)

CH3 CH3

(Y) (T)

CH3CH2C=CHCH3

GV: Cao Vit Chung

Email: mrcaochung@gmail.com

ST: 0982 917 136

Ti liu n thi H 2013 2014

Anken

Anken khng c ng phn hnh hc l A. X. B. Y. C. Z D. T. Cu 13: Cho cc cht sau: CH2=CH-CH2-CH2-CH=CH2, CH2=CH-CH=CH-CH2-CH3, CH3-C(CH3)=CH-CH3,CH2=CH-CH2-CH=CH2. S cht c ng phn hnh hc l A.2. B. 3. C. 1. D. 4. Cu 14: Anken X c t khi hi so vi nit bng 2,5. Kt lun no sau y l ng? A. X c ng phn hnh hc B. C 5 anken ng phn cu to ng vi CTPT ca X C. C 3 ng phn hnh hc c cng CTPT vi X D. Khi X tc dng vi HBr to ra 1 sn phm duy nht Cu 15: Cht hu c mch h no sau y khng c ng phn cis trans? A. 2-clobut-2-en B. pent-2-en C. 3-metylbut-1-en D. but-2-en Cu 16: Theo chiu tng s nguyn t cacbon trong phn t, phn trm khi lng cacbon trong phn t ca cc ng ng anken: A. tng dn. B. gim dn. C. khng i. D. bin i khng theo quy lut. Cu 17: Anken l nhng hirocacbon A. khng no, mch h, phn t c t nht mt lin kt i C=C. B. khng no, mch vng, phn t c mt lin kt i C=C. C. khng no, mch h, phn t c mt lin kt i C=C. D. khng no, mch h, phn t c mt hoc hai lin kt i C=C. Cu 18: Cng thc phn t ca cc anken c dng A. CnH2n+2, n 2. B. CnH2n, n 3. C. CnH2n, n 2. D. CnH2n2, n 3. Cu 19: ng phn hnh hc l nhng cht c cng cng thc cu to, nhng A. khc nhau v ln ca mch chnh. B. khc nhau v s phn b trong khng gian ca mch chnh xung quanh lin kt i C=C. C. khc nhau v ln ca mch chnh nhng ging nhau v s phn b trong khng gian ca mch chnh xung quanh lin kt i C=C. D. khc nhau v tnh cht ho hc. Cu 20: Cng thc no di y l ca cispent2en ?
CH3CH2 C=CH

CH3CH2 C=C
CH3

CH3 H

A.
CH3CH2 C=C

B.

H CH3

H CH3CH2 C=C CH3 H

H C. D. Cu 21: C bao nhiu anken ng phn cu to ca nhau khi cng hiro u to thnh 2 metylbutan A. 1. B. 2. C. 3. D. 4. Cu 22: ng vi cng thc phn t C4H8 c bao nhiu ng phn cu to u tc dng c vi hiro ? A. Hai. B. Ba. C. Nm. D. Su. Cu 23: Cc anken ng phn hnh hc ca nhau th?

GV: Cao Vit Chung

Email: mrcaochung@gmail.com

ST: 0982 917 136

Ti liu n thi H 2013 2014 A. ging nhau v tnh cht ho hc, khc nhau v mt vi tnh cht vt l. B. ging nhau v tnh cht vt l, khc nhau v mt vi tnh cht ho hc. C. khc nhau v tnh cht ho hc v mt vi tnh cht vt l. D. ging nhau v tnh cht ho hc v tnh cht vt l.

Anken

2. Bi tp v danh php ca anken

Cu 24: Cho anken X c cng thc cu to sau :
CH3 C=C H H CH2CH3

Tn y ca X l A. cispent2en. B. transpent2en. C. transpent3en. D. cispent3en. Cu 25: Anken CH3CH=CHCH2CH3 c tn l A. metylbut2-en. B. pent3-en. C. pent2en. D. pent3en. Cu 26: Anken 3metylpent2en c cng thc cu to no di y ?
CH3CH CH=CHCH2CH3 CH3CH CH=CHCH3

A. C.

CH3 CH3CH2CH=CCH3 CH3

B.

CH3 CH3CH2C=CHCH3 CH3

D.

3. Phn ng cng ca anken

Cu 27: 4,48 lt hn hp X gm propilen v xiclopropan (ktc) c th tc dng ht bao nhiu lt dung dch brom 0,10M ? A. 2,0 lt. B. 1,0 lt. C. 1,5 lt. D. 2,5 lt. Cu 28: Anken X c t khi so vi nit bng 2,00. Khi X tc dng vi nc (xc tc axit) to ra hn hp 2 ancol ng phn ca nhau. Tn gi ca X l A. isobuten. B. but1en. C. but2en. D. pent1en. Cu 29: Khi but2en tc dng vi HBr c xc tc axit thu c A. mt sn phm cu to duy nht cha mt nguyn t brom trong phn t. B. hn hp hai sn phm ng phn cu to cha mt nguyn t brom trong phn t. C. sn phm th brom. D. sn phm cha hai nguyn t brom trong phn t. Cu 30: Anken X tc dng vi HBr c cht Y; Y c t khi so vi X bng 2,446. CTPT ca X l A. C3H6. B. C4H8. C. C4H10. D. C5H10. Cu 31: Cho 2,24 lt anken X (ktc) tc dng vi brom d (trong dung dch) thu c sn phm c khi lng ln hn khi lng anken l A. 8,0 g. B. 10,0 g. C. 12,0 g. D. 16,0 g. Cu 32: Anken Y tc dng vi brom to thnh dn xut ibrom trong phn trm khi lng cacbon bng 17,82%. Cng thc phn t ca Y l A. C3H6. B. C4H8. C. C4H10. D. C5H10.

GV: Cao Vit Chung

Email: mrcaochung@gmail.com

ST: 0982 917 136

Ti liu n thi H 2013 2014

Anken

Cu 33: Dn t t 5,60 lt hn hp Y gm C2H4 v C2H6 i vo dung dch brom thy dung dch brom nht mu v cn 4,48 lt kh thot ra. Cc th tch kh o iu kin tiu chun. Phn trm th tch ca etilen trong hn hp Y bng A. 20%. B. 25%. C. 75%. D. 50%. Cu 34: Cho V lt mt anken A kc qua bnh ng nc brom d, c 8 g Br2 phn ng ng thi khi lng bnh tng 2,8g. Mt khc khi cho A phn ng vi HBr ch thu c 1 sn phm . Gi tr ca V v tn ca A l: A. 2,24lt; propen B. 2,24 l; etilen C. 1,12l; but-1-en D. 1,12l; but-2-en Cu 35: Cho 5,1g hn hp X gm CH4 v 2 anken ng ng 4hem tip qua dung dch brom d thy khi lng bnh tng 2,5g, ng thi th tch hn hp X gim mt na. Hai anken c cng thc phn t l: A. C2H4, C3H6 B. C3H6, C4H8 C. C4H8, C5H10 D. C5H10, C6H12 Cu 36: Mt anken X mch h c CTPT C4H8 khi tc dng vi HBr cho 1 sn phm duy nht. CTCT ca X l A. CH2=CH-CH2-CH3 B. CH3 CH = CH- CH3 C. CH2 = C (CH3)2 D. CH3-CH=C(CH3)2 Cu 37: Cho hn hp 2 anken 4hem tip trong dy ng ng i qua dung dch Br2, thy c 80g Br2 phn ng v khi lng bnh Br2 tng 19,6g. a. Hai anken l: A. C3H6; C4H8 B. C4H8, C5H10 C. C2H4; C3H6 D. C5H10, C6H12 b. %th tch ca mi anken trong hn hp l: A. 20%, 80% B. 25%, 75% C. 40%, 60% D. 50%, 50% Cu 38: Cho 10g hn hp kh X gm etilen v etan qua dung dch Br2 25% c 160g dd Br2 phn ng. % khi lng ca etilen trong hn hp l: A. 70% B. 30% C. 35,5% D. 64,5% Cu 39: Hirocacbon X c cng thc phn t C6H12, bit X khng lm mt mu dung dch brom, cn khi tc dng vi bron khan ch thu c 1 dn xut monobrom duy nht. X l cht no di y? Chn mt p n di y A. 3-metylpentan B. 1,2-imetylxiclobutan C. 1,3-imetylxiclobutan D. xiclohexan Cu 40: Cho buta-1,3-ien phn ng cng vi Br2 theo t l mol 1:1. S dn xut ibrom (ng phn cu to v ng phn hnh hc) thu c l A. 2. B. 3. C. 4. D. 1. Cu 41: Anken X hp nc to thnh 3-etylpentan-3-ol. Tn ca X l A.3-etylpent-3-en. B. 2-etylpent-2-en. C. 3-etylpent-2-en. D. 3-etylpent-1en. Cu 42: Cho iso-pentan tc dng vi Cl2 theo t l s mol 1 : 1, s sn phm monoclo ti a thu c l A.2. B. 3. C. 5. D. 4. Cu 43: Cho 4,48 lt hn hp X ( ktc) gm 2 hirocacbon mch h li t t qua bnh cha 1,4 lt dung dch Br2 0,5M. Sau khi phn ng hon ton, s mol Br2 gim i mt na v khi lng bnh tng thm 6,7 gam. Cng thc phn t ca 2 hirocacbon l (cho H = 1, C = 12) A.C2H2 v C4H6. B. C2H2 v C4H8. C. C3H4 v C4H8. D. C2H2 v C3H8. Cu 44: Mt hirocacbon X cng hp vi axit HCl theo t l mol 1:1 to sn phm c thnh phn khi lng clo l 45,223%. Cng thc phn t ca X l (cho H = 1, C = 12, Cl = 35,5) GV: Cao Vit Chung ST: 0982 917 136

Email: mrcaochung@gmail.com

Ti liu n thi H 2013 2014

Anken

A.C3H6. B. C3H4. C. C2H4. D. C4H8. Cu 45: Hirat ha 2 anken ch to thnh 2 ancol (ru). Hai anken l A. 2-metylpropen v but-1-en (hoc buten-1). B. propen v but-2-en (hoc buten-2). C. eten v but-2-en (hoc buten-2). D. eten v but-1-en (hoc buten-1). Cu 46: Cho cc cht: xiclobutan, 2-metylpropen, but-1-en, cis-but-2-en, 2-metylbut-2-en. Dy gm cc cht sau khi phn ng vi H2 (d, xc tc Ni, to), cho cng mt sn phm l: A. xiclobutan, cis-but-2-en v but-1-en. B. but-1-en, 2-metylpropen v cis-but-2-en. C. xiclobutan, 2-metylbut-2-en v but-1-en. D. 2-metylpropen, cis-but-2-en v xiclobutan. Cu 47: Cho hirocacbon X phn ng vi brom (trong dung dch) theo t l mol 1 : 1, thu c cht hu c Y (cha 74,08% Br v khi lng). Khi X phn ng vi HBr th thu c hai sn phm hu c khc nhau. Tn gi ca X l A. but-1-en. B. xiclopropan. C. but-2-en. D. propilen. Cu 48: Hirat ha 2-metylbut-2-en (iu kin nhit , xc tc thch hp) thu c sn phm chnh l A. 2-metylbutan-2-ol. B. 3-metylbutan-2-ol. C. 3-metylbutan-1-ol. D. 2-metylbutan-3-ol. Cu 49: Hn hp X gm H2 v C2H4 c t khi so vi H2 l 7,5. Dn X qua Ni nung nng, thu c hn hp Y c t khi so vi H2 l 12,5. Hiu sut ca phn ng hiro ha l A. 70%. B. 60%. C. 50%. D. 80%. Cu 50: Cho 1 lng anken X tc dng vi H2O( c xc tc H2SO4) c cht hu c Y, thy khi lng bnh ng nc ban u tng 4,2g. Nu cho 1 lng X nh trn tc dng vi HBr, thu c cht Z, thy khi lng Y, Z thu c khc nhau 9,45g. Tm CTPT, gi tn ca X, gi s cc phn ng xy ra hon ton. Cu 51: Cho 0,896 lt (ktc) hn hp 2 anken l ng ng 5hem tip li qua dung dch brom d. Sau phn ng thy bnh ng dung dch brom tng 5hem 2,0 gam. Cng thc phn t ca 2 anken l: A. C2H4, C3H6 B. C3H6, C4H8 C. C4H8, C5H10 D. C5H10, C6H12 Cu 52: Hn hp kh X gm 1 ankan v 1 anken. Cho 1680ml kh X cho qua dung dch brom lm mt mu va dung dch cha 4g brom v cn li 1120ml kh. Mt khc nu t chy hon ton 1680ml kh X ri cho sn phm chy i qua bnh ng dung dch nc vi trong d thu c 12,5g kt ta. Cng thc phn t ca cc hirocacbon ln lt l: A. CH4, C2H4 B. CH4, C2H6 C. CH4, C4H8 D. C2H6, C3H6

4. Phn ng chy ca aken

Cu 53: t chy hon ton 4,48 lt hn hp X gm propan v xiclopropan thu c bao nhiu lt kh CO2 (cc th tch kh o ktc) ? A. 4,48 lt. B. 8,96 lt. C. 13,44 lt. D. 15,92 lt. Cu 54: t chy hon ton 1,12 lt mt anken X (ktc) thu c 5,60 lt kh CO2 (ktc). CTPT ca X l A. C3H6. B. C4H8. C. C4H10. D. C5H10. Cu 55: t chy hon ton 2,24 lt hn hp hai anken X v Y (ktc) k tip nhau trong dy ng ng thu c 5,60 lt kh CO2 (ktc). Cng thc phn t ca X v Y l A. C2H4 v C3H6. B. C3H6 v C4H8. C. C2H4 v C4H10. D. C3H6 v C5H10. GV: Cao Vit Chung ST: 0982 917 136

Email: mrcaochung@gmail.com

Ti liu n thi H 2013 2014

Anken

t chy hon ton mt th tch hn hp gm anken X v hirocacbon Y thu c 5,60 lt kh CO2 (ktc) v 5,40 gam nc.Y thuc loi hirocacbon c cng thc phn t dng A. CnH2n. B. CnH2n2. C. CnH2n+2. D. CnH2n4. Cu 56: tch ring metan khi hn hp vi etilen v kh SO2 c th dn hn hp sc vo A. dung dch natri hiroxit. B. dung dch axit H2SO4. C. dung dch brom. D. dung dch HCl. Cu 57: Cho 4,48 lt hn hp etilen v propilen (ktc) tc dng vi oxi d thu c 22,0 gam kh CO2. Phn trm th tch ca etilen trong hn hp bng A. 25%. B. 40%. C. 75%. D. 50%. Cu 58: Cho mt th tch kh anken X (ktc) tc dng vi nc (xc tc axit) c 4,60 gam ancol Y; nu cho lng anken X trn tc dng vi HBr c 10,90 gam cht Z. Cng thc phn t ca anken X l A. C2H4. B. C3H6. C. C4H8. D. C5H10. Cu 59: Trong phng th nghim c th iu ch mt lng nh kh etilen theo cch no sau y ? A. hiro ho etan. B. un si hn hp gm etanol vi axit H2SO4. C. Cho axetilen tc dng vi hiro c xc tc l Pd/PbCO3. D. Crackinh butan. Cu 60: t chy 2,24 lt hn hp gm propilen v xiclopropan (ktc) cn bao nhiu lt kh oxi (ktc) ? A. 6,72 lt. B. 8,96 lt. C. 10,08 lt. D. 11,20 lt. Cu 61. Trong phn t cc anken, theo chiu tng s nguyn t C, phn trm khi lng ca C A. tng dn B. gim dn C. khng i D. khng theo qui lut no 5. t chy hon ton 3 hirocacbon X. Y, Z ngi ta thu c t l nH2O : nCO2 ln lt bng 0,5; 1; 1,5. X, Y, Z c CTPT l: A. CH4, C2H4, C2H6 B. C2H4, C4H4, C3H4 C. C2H2, C3H6, C2H6 D.C6H6, C4H6, C3H6 Cu 62: Hn hp A gm 2 anken ng ng 6hem tip. t chy hon ton V lt A thu c 13,44 lt CO2 kc. Mt khc A lm mt mu va ht 40g nc Br2. CTPT ca 2 anken l: A. C2H4, C3H6 B. C2H4, C4H8 C. C3H6, C4H8 D. C4H8, C5H10 Cu 63: Anken A phn ng hon ton vi dung dch KmnO4 c cht hu c B c MB= 1,81MA. CTPT ca A l: A. C2H4 B. C3H6 C. C4H8 D. C5H10 Cu 64: Hn hp no sau y cha cc cht u khng lm mt mu dung dch Br2? A. CO2, C2H2, H2 B. H2, C2H6, CO2 C. C2H4, SO2, CO2 D. CH4, SO2, H2S Cu 65: iu no sau y khng ng khi ni v anken? A. l cht k nc B. l cht k du m C. C ts, tnc tng theo phn t khi D. Cc anken u nh hn nc v khng mu Cu 66: phn bit 2 cht lng hex-2-en v xiclohexan, ngi ta c th 6hem: A. dd Ag2O/NH3 B. dd KmnO4 C. dd Br2 D. C B v C u ng Cu 67: Hn hp A gm 1 ankan v 1 anken. S nguyn t H trong ankan bng s nguyn t C trong anken. t chy 3 g hn hp A thu c 5,4g H2O. CTPT v % khi lng cc cht trong A l:

GV: Cao Vit Chung

Email: mrcaochung@gmail.com

ST: 0982 917 136

Ti liu n thi H 2013 2014

Anken

A. CH4: 46,67%; C4H8 : 53,33% B. CH4: 53,33%; C4H8: 46,67% C. C2H6: 33,33%; C6H12: 66,67% D. C2H6: 66,67%; C6H12: 33,33% Cu 68: Chia hn hp 3 anken: C2H4, C3H6, C4H8 thnh 2 phn bng nhau: - t chy phn 1 sinh ra 6,72 lt CO2 (ktc) - Phn 2 cho tc dng vi hiro (c Ni xc tc), t chy sn phm sau phn ng ri dn sn phm chy vo bnh ng nc vi trong d th khi lng kt ta thu c l: A. 29g B. 30g C. 31g D. 32g Cu 69: X l hn hp kh gm hai hirocacbon. t chy 0,5 lt hn hp X cho 0,75 lt CO2 v 0,75 lt hi nc (cc th tch o cng iu kin). Hai hirocabon c cng thc phn t l: A. CH4, C2H2 B. C2H4, C2H2 C.CH4, C2H4 D. C3H8, C3H4 Cu 70: t chy hon ton mt th tch hn hp 2 hirocacbon ng ng 7hem tip thu c 2,24 lt CO2 (ktc) v 2,52g H2O. Hai hirocacbon c cng thc phn t l: A. CH4, C2H6 B. C2H6, C3H8 C. C2H4, C3H6 D. C3H8, C4H10 Cu 71: Mt hn hp gm mt ankan X v mt anke Y c cng s nguyn t cacbon trong phn t v s mol. M gam hn hp ny lm mt mu va 80g dung dch brom 20%. t chy hon ton m gam hn hp trn thu c 0,6 mol CO2 X v Y c cng thc phn t l: A. C2H4, C2H6 B. C3H6, C3H8 C. C5H10, C5H12 D. C4H8, C4H10 Cu 72: t chy s mol nh nhau ca 2 hirocacbon X v Y mch h thu c s mol CO2 nh nhau, cn t l s mol H2O v CO2 ca chng l 1 v 1,5. X v Y c cng thc phn t ln lt l: A. C2H6, C2H4 B. C3H8, C3H6 C. C4H10, C4H8 D. C5H12, C5H10 Cu 73. Clo ho PVC thu c mt polime cha 63,96% clo v khi lng, trung bnh 1 phn t clo phn ng vi k mt xch trong mch PVC. Gi tr ca k l (cho H = 1, C = 12, Cl = 35,5) A.3. B. 6. C. 4. D. 5. Cu 74. Ba hirocacbon X, Y, Z k tip nhau trong dy ng ng, trong khi lng phn t Z gp i khi lng phn t X. t chy 0,1 mol cht Y, sn phm kh hp th hon ton vo dung dch Ca(OH)2 (d), thu c s gam kt ta l (cho H = 1, C = 12, O = 16, Ca = 40) A.20. B. 40. C. 30. D. 10. Cu 75. Hn hp gm hirocacbon X v oxi c t l s mol tng ng l 1:10. t chy hon ton hn hp trn thu c hn hp kh Y. Cho Y qua dung dch H2SO4 c, thu c hn hp kh Z c t khi i vi hiro bng 19. Cng thc phn t ca X l (cho H = 1, C = 12, O = 16) A.C3H8. B. C3H6. C. C4H8. D. C3H4. Cu 76. Cht no sau y c ng phn hnh hc? A. CH2=CH-CH=CH2. B. CH3-CH=C(CH3)2. C. CH3-CH=CH-CH=CH2. D. CH2=CH-CH2-CH3. Cu 77. Hn hp kh X gm H2 v C2H4 c t khi so vi He l 3,75. Dn X qua Ni nung nng, thu c hn hp kh Y c t khi so vi He l 5. Hiu sut ca phn ng hiro ho l A.20%. B. 25%. C. 50%. D. 40%. Cu 78. Cho cc cht: CH2=CHCH=CH2; CH3CH2CH=C(CH3)2; CH3CH=CHCH=CH2; CH3CH=CH2; CH3CH=CHCOOH. S cht c ng phn hnh hc l A.4. B. 3. C. 2. D. 1. Cu 79. t chy hon ton 20,0 ml hn hp X gm C3H6, CH4, CO (th tch CO gp hai ln th tch CH4), thu c 24,0 ml CO2 (cc th tch kh o cng iu kin nhit v p sut). T khi ca X so vi kh hiro l A.12,9. B. 25,8. C. 22,2. D. 11,1.

GV: Cao Vit Chung

Email: mrcaochung@gmail.com

ST: 0982 917 136

Ti liu n thi H 2013 2014

Anken

Cu 80. Cho hn hp hai anken ng ng k tip nhau tc dng vi nc (c H2SO4 lm xc tc) thu c hn hp Z gm hai ru (ancol) X v Y. t chy hon ton 1,06 gam hn hp Z sau hp th ton b sn phm chy vo 2 lt dung dch NaOH 0,1M thu c dung dch T trong nng ca NaOH bng 0,05M. Cng thc cu to thu gn ca X v Y l (Cho: H = 1; C = 12; O = 16; th tch dung dch thay i khng ng k) A. C2H5OH v C3H7OH. B. C3H7OH v C4H9OH. C. C2H5OH v C4H9OH. D. C4H9OH v C5H11OH. Cu 81. Cho phn ng: C6H5-CH=CH2 + KMnO4 C6H5-COOK + K2CO3 + MnO2 + KOH + H2O. Tng h s (nguyn, ti gin) tt c cc cht trong phng trnh ho hc ca phn ng trn l A.27. B. 24. C. 34. D. 31. Cu 82. Hn hp kh X gm mt ankan v mt anken. T khi ca X so vi H2 bng 11,25. t chy hon ton 4,48 lt X, thu c 6,72 lt CO2 (cc th tch kh o ktc). Cng thc ca ankan v anken ln lt l A.CH4 v C2H4. B. C2H6 v C2H4. C. CH4 v C3H6. D. CH4 v C4H8. Cu 83. Dn 1,68 lt hn hp kh X gm hai hirocacbon vo bnh ng dung dch brom (d). Sau khi phn ng xy ra hon ton, c 4 gam brom phn ng v cn li 1,12 lt kh. Nu t chy hon ton 1,68 lt X th sinh ra 2,8 lt kh CO2. Cng thc phn t ca hai hirocacbon l (bit cc th tch kh u o ktc) A. CH4 v C2H4. B. CH4 v C3H4. C. CH4 v C3H6. D. C2H6 v C3H6 Cu 84. Ba hirocacbon X, Y, Z l ng ng k tip, khi lng phn t ca Z bng 2 ln khi lng phn t ca X. Cc cht X, Y, Z thuc dy ng ng A. ankan. B. ankaien. C. anken. D. ankin. Cu 85. Hiro ha hon ton hirocacbon mch h X thu c isopentan. S cng thc cu to c th c ca X l A. 6. B. 5. C. 7. D. 4. Cu 86. t chy hon ton 3 lt hn hp X gm 2 anken kt tip nhau trong dy ng ng cn va 10,5 lt O2 (cc th tch kh o trong cng iu kin nhit , p sut). Hirat ha hon ton X trong iu kin thch hp thu c hn hp ancol Y, trong khi lng ancol bc hai bng 6/13 ln tng khi lng cc ancol bc mt. Phn trm khi lng ca ancol bc mt (c s nguyn t cacbon ln hn) trong Y l A. 46,43%. B. 31,58%. C. 10,88%. D. 7,89%. Cu 87. Khi t 1 th tch hirocacbon A mch h cn 30 th tch khng kh, sinh ra 4 th tch CO2. A tc dng vi H2 xc tc Ni, to thnh hirocacbon no mch nhnh. Xc nh CTPT, CTCT ca A, bit trong khng kh oxi chim 20% th tch khng kh, cc th tch kh o cng iu kin. Cu 88. t chy hon ton 2,24 lt kc 1 hirocacbon X mch h, sau dn sn phm chy ln lt qua dung dch H2SO4 v dung dch Ca(OH)2 d. Sau th nghim thy khi lng bnh ng dung dch axit tng 5,4g, bnh ng dung dch Ca(OH)2 c 30g kt ta. Tm CTPT ca X. Cu 89. Mt hirocacbon A cha 14,28% H. t chy hon ton 0,224 lt A (kc), cho ton b sn phm chy sinh ra vo bnh ng nc vi d, thy thu c 4 gam kt ta v khi lng dung dch trong bnh nc vi thay i a gam. a. Xc nh CTPT , vit cc CTCT thu gon c th c ca A v gi tn a. Xc nh CTCT ng ca A bit A c ng phn hnh hc. Biu th cc ng phn hnh hc ca A.

GV: Cao Vit Chung

Email: mrcaochung@gmail.com

ST: 0982 917 136

Ti liu n thi H 2013 2014

Anken

b. Cho bit khi lng dung dch trong bnh nc vi tng hay gim? Tnh a? - Tnh khi lng ru thu c khi cho 4,48 lt A (kc) tc dng ht vi H2O khi c xc tc H2SO4, bit hiu sut ca phn ng l 80%. Cu 90. Cho mt hn hp kh X gm ankan A , mt anken B. Khi dn 1,12 lt hn hp A qua dung dch Br2 d thy th tch hn hp gim cn 0,448 lt, khi lng bnh Br2 tng 1,68gam. Kh thot ra em t chy hon ton thu c 1,344 lt kh CO2. Cho th tch cc kh u o kc. a. Xc nh CTPT ca A, B v vit tt c cc CTCT ph hp b. Bit B khi tc dng vi H2O ch to mt ru duy nht . Xc nh CTCT ng ca B. Cu 91. A l hirocacbon mch h. Khi phn tch hirocacbon A ngi ta nhn thy mC = 8mH . Mt khc khi t chy 0,1molA trong kh O2 th thu c 17,6gam CO2 a. Tm CTPT ca A. Vit CTCT ca A c th c v gi tn tng ng. b. Khi hiro ha A c xc tc Pd th thu c kh B. B c ng phn hnh hc. Xc nh CTCT ng ca B. Vit PTP c lin quan. Cu 92. a) Cho 6,72l(kc) hn hp kh gm2 olefin li qua nc brom d thy khi lng bnh tng 16,8g Hy tm CTPT cc olefin bt rng s nguyn t C trong mi olefin khng qu 5 b) t chy 560cm3 hn hp kh (kc) gm 2 hirocacbon c cng s nguyn t C ta thu c 4,4g CO2 v 1,9125g H2O . Xc nh CTPT cc hirocacbon Cu 93. Cho 2,24 lit 1 hh kh A(kc) gm etan, propan, propilen sc qua dd Br2 d , thy khi lng bnh tng thm 2,1g. Nu t chy kh cn li s thu c 1 lng CO2 v 3,24g H2O. a. Tnh % th tch mi kh b. Dn lng CO2 ni trn vo bnh ng 200ml dd KOH 2,6M. Hy xc nh CM cc cht trong dd sau phn ng

GV: Cao Vit Chung

Email: mrcaochung@gmail.com

ST: 0982 917 136