Unexpected feature of homogeneous reactions C9-C12 alkynes carbonylation

Sergey N. Gorodsky Lomonosow's Moscow state academy of fine chemical technology (MITHT), Vernadsky Av. 86, 119571 Moscow, Russian Federation, Gorodsky@yandex.ru

For several years in MITHT investigations of oscillating modes of the oxidative carbonylation reactions in homogeneous catalysis by metal complex in alcohol solutions of palladium salts with various organic substrates were conducted. The modes of developed oscillations in reactions involving phenyl- and methyl acetylene, 2-methyl-3-butin-2-ol, 2-propin-1-ol in the systems PdI2-KI-CO-O2-CH3OH; have been

PdBr2-LiBr-CO-O2-CH3OH;

PdBr2-LiBr-CO-O2-(CH3)2CO-H2O

found1-3 . Recently interesting modes of oscillations in carbonylation reactions of 1-nonin, 1-decin and 1-dodecin in the system PdI2-KI-CO-O2-CH3OH were found with a number of features depending on the nature of the substrate4-5.

Oscillating mode of 1-nonyne oxidative carbonylation reaction [KI]0 = 0,4 M; [Pdl2]0 = 0,01 M; [l-nonyne]0 = 0,1 M; [CO]0: [O2]o = 3:2, VCH3OH = 10 mL This work was supported by RFBR (grants 05-03-33151 and 09-03-01072). Thanks to ACS and RCS for membership.

References: 1. S. N Gorodsky, A. N. Zakharov, A. V. Kulik, L. G. Bruk, O. N. Temkin, Kinetics and Catalysis, 2001, 42, 2, 285-293. 2. S. N Gorodsky, E. N. Kalenova, L. G. Bruk, O. N. Temkin, Russian Chemical Bulletin, Ser. Chem., 2003, 7, 1452-1461. 3. Gorodsky S. N., Bruk, L.G., Istomina, A.E., Kurdiukov, A.V., Temkin, O.N., Topics in Catalysis, 2009, 52, 6-7, 557-562. 4. Gorodsky S. N., 43rd IUPAC World Chemistry Congress, San Juan, Puerto Rico July 27 - August 7, 2011. 5. Gorodsky S. N., XIX Mendeleev Congress on General and Applied Chemistry, Volgograd, Russia, 2530 September, 2011.