Reaction conditions:

Isobutane-Isobutene
Temperature
contact time

Chemcad Data
component
2,2,4-TMP
2,3,4-TMP
2,3,3-TMP
DimethylHexane
2,3-DMP
dodecane
isopentane
methylpentane
RESIDENCE TIME
150 min (10:1)
2,2,4-TMP
2,3,3-TMP
2,2,3-TMP
2,3,4-TMP
2,4,4-TMPentene
2,4-DMH
Dodecane
Isobutene

104 F
6 min
30 min
150
10:01
1:01
10:01
1:01
10:01
RUN-1
RUN-2
RUN-3
RUN-4
RUN-5
wt%
wt%
0.174395 0.05175
0.175192 0.051986
0
0
0.17519 0.051986
0
0
0.311125 0.00426
0
0
0
0
weight %
0.061484
0.0041
0.000205
6.83E-05
1.74E-05
0.000232
2.7E-05
1.26E-12

wt%
wt%
0.174392 0.051750273
0.175189 0.051986523
0
0
0.175187 0.051986068
0
0
0.309399 0.004260279
0
0
0
0

K values
900
60
3
1
5
3.4
5.3
8
7

6.148434
0.410016
0.020501
0.006831
0.001737
0.023234
0.002695
1.26E-10

wt%
wt%
0.174395 0.05175
0.175192 0.051987
0
0
0.17519 0.051986
0
0
0.311125 0.00426
0
0
0
0

RUN-1
experimental K values weight%
66.2
150 4.951671
7.1
15 0.496095
0
12 0.396876
12.8
10 0.330023
0
13 0.021969
3.4
10 0.330727
5.3
7 0.014898
8 0.02262
22

RUN-10
K values
66.2
6
3
6
5
3.4
5.3
12
8

weight%
4.531303
0.411893
0.205947
0.40918
0.019402
0.233404
0.023808
0.369852

min
1:01
RUN-6
wt%
0.174395
0.175192
0
0.17519
0
0.311125
0
0
RUN-2
RUN-3
RUN-4
RUN-5
RUN-6
K values weight% K values weight% K values weight% K values weight% K values
300 5.451625
3000 5.800627
5000 5.604668
6600 5.648734
7800
30 0.545725
300 0.580127
500 0.561487
750 0.642793
600
12 0.21829
50 0.096688
100 0.112297
80 0.068565
40
10 0.181694
59 0.114077
200 0.224431
200 0.171316
170
13 0.012012
20 0.001966
120 0.006849
100 0.004357
100
10 0.181907
10 0.019337
70 0.078607
70 0.059994
70
7 0.008707
7 0.00097
200 0.015457
200 0.011844
100
8 0.000386
8 3.11E-15
80 3.11E-15
80 3.11E-15
80
27
30
30
50

RUN-11
K values
75
6
3
6
5
3.4
5.3
12
7

RUN-12
weight% K values
4.772677
125
0.382854
20
0.191427
3
0.380505
6
0.017678
5
0.216949
3.4
0.022881
5.3
0.297193
12
9

RUN-13
weight% K values
5.12164
200
0.820905
40
0.123136
3
0.245293
1
0.010622
5
0.139553
3.4
0.014905
5.3
0.060913
8
6

RUN-14
weight% K values
5.31553
350
1.064321
40
0.079824
3
0.026562
1
0.006775
5
0.090466
3.4
0.009125
5.3
0.006596
8
5

RUN-15
weight% K values
5.811338
900
0.664627
60
0.049847
3
0.016598
1
0.004223
5
0.056493
3.4
0.00621
5.3
0.000163
8
7

RUN-6
RUN-7
RUN-8
RUN-9
weight% K values weight% K values weight% K values weight%
5.931322
7800 6.005187
7800 6.196456
9200 6.337041
0.456537
550 0.423707
370 0.293972
285 0.196333
0.030436
15 0.011556
15 0.011918
15 0.010333
0.129288
140 0.107799
70 0.055588
35
0.0241
0.003867
80 0.003133
60 0.002423
30 0.001051
0.053262
70 0.053926
65 0.051643
65 0.044777
0.005548
100 0.00567
20 0.001232
20 0.001071
3.11E-15
80 3.11E-15
80 3.11E-15
80 3.11E-15
300
300
400

weight%
6.148434
0.410016
0.020501
0.006831
0.001737
0.023234
0.002695
1.26E-10