efi0iffffr 0:16lL-61

l. Gor$l* eroPorolulfr Peiroto (a) @writgd' eu,fieaou (b) flcoatuLrctrgt

K,-rn B <-(a) K, =

[o9otu : al (A $rear6lb (c) geagtfilcioerrort B-,ittO 2A {2. r*drorqbti crlleoseerfldr cro$oro ron$docir

2K,

2A-rig Kr-rir ggtir eroficb (b) K' = tKrtcl K' = (K,)'(4 K'

= tlK',2

3.

2HI :=-_: (a) K"-g astulogorr- : cl (A ggdt* (c) K.-i19i er.orb 2NH. erehp croflorn:u9dr cr$* 'l'nol l. lf, i 3H, + anrbGnnoflurn 6orr-riu5: (a') gapbp +llg74gth obgttb 'e1$)e Ooruuficrl,o-* (b) <g^,p,ijs eK44gb LDbgl,tb ,6aPFg 6)oruu4fle'ocu
6)oruupfloncut [onoru : dl et6la eK*&Fk -6gtJ @6'PPfi ilirtrl 5. 600 K Goriruflorq:uQeil fltt$tb Sdrcugrir e(gul+sprsr (Jun 06) croflecrnr oilorsruieb Kc-u9& sl6t)tS 4N0k) + 6Hrot*r 4NHrtrr * 5O*,# (c) (mol dmr)r0 (c/) (mol dm'fn tal fmof dm-'ii (b) (mol Cm:)

[o9teru : 6l KP 'trSi H2 + 12, erdrp crl$torsr erlorsu96b et@ab (b) K.-g efit t rgoopa4

(c)

;lt6aa ilottauSlclr,c,t

LDbgtLD

"st$s +.t(gfiptb

(A

[otorr- : ]l 1'0dm3 Gonchormo;sirsr sel$$cil 6. on1irg GlorcrflGulfiptur-rolnu{ Qc$u$pnuf L5l' r-urri $qqGroncilacir n"r g19 Grcrei:

6-.rrr6r-*ui6b NH3 6oc'ppg erofleure:lrleir NH, rnL$dt 61qi50 F6tpgl' StGlorpol oleoreulsb
roSnt{
\,i27116(mole
(c\2714(mole

Kc

dmr)2

(b)2118 (mole dmr)2

dmJ)2 {d) @aryEt';u

qgllria;eoou

[dcou :

al

(
7.

gq5 GlqrlutQcr* erofleror densuldl Tr ropgtli T2 Orriupooc.i6 crofoot onfdecir K, opgrir K, ereofleb Gloriupsro T, sgt Tr -A oiu crse rone
flgrigrirGrrrgr CIr t T)
(a) K, < K, (b) K,

S.

&r, - 0
(o)

tL

(c) K,

Kr(A

otg;ttb $)eircocLr[atorr--

ol

er&fq5r315rir Gungr

I1: K"
K": K"

(r) K" > K" (c)

I!. K. (4 Kn =: , ^ r\c 161166rr-

al

9.

M, (a)

*vG ercir;Dqtti(5rir Gungr (6) K; >

K. (c) K". K. (4 K,: t*-- bl f, 10. 4", - -ye er*f(trigrir Gung (Oct 06) (d Kr: r" (6) K, > K" (c) Kr. L (d) Iq: !Ot*-- tcl ll. docr S*tg.i, erdrgro ropgrn F-" O-$-p
prfrccrftiug
(a) daraa9dr Gantufiol,cu (b) o?arenu9dr stggg,b {c) dercruietu el.oSeoaytonfre8ug& u,guq (d) &erterrlu@ dung&eiclf,rlrr 6i,e6ol 12,

crofooddr t19 derrs Qufifqgriuglr (o\ @aw &qtcr,*,tir (b) A&a,curar cflaleare,on (r) o@6s9fi &ano,anir (d) e@Sp@pg 6a,(gtb etgteawadr [oiorr-- : cl 81ir&or&r-- Ge$i cupooecfiC> c.rgl crggpgpndr

[oloru

cl

ur$ie riu@or$r$coor (a) H*+ Irrrr # 2$l2{rr (6) N*r+ 3Hrrrl # (c) PCl"r,:;PCq* * C!*{d) 2SO*, + Oa*r +
t4" Nr+

2NHr,u, 2SOr,,,

3Hr-+

r-15rnpdl srriGung .lpeilrigrirr (o) q$a 6)ar*ug$oartfcir tb\ q$s q,gpg$@toiagdl (c\ g"r,pfu ergggfiawa9da (dl gthG*r&ur GtclSa.ru afiarfld;gth&ungt

2NHr+ 22kcatctdrp erosorent*

-l:Lt"#:

[olorr__

6l

15. Ggmurn qgecrpugci:, glilsrandnrn Qprgr!9r$ u'"udru$$pu u$ldr erqg$P$oteu errst? (c) 300 - 500 arorfiroedtru-eu elgipptb (c) 100
anatfrrr,aiwt-.att eYEx$qti:

: al 16. Glpn@qporpuSei:, 6rFp $u$pearw*sfisir r-&a .$Fs

@) 20A anaflnaioL-as .et{ryfrq,r

fa?mr--

srmo$eir SO, purnrfl*cu*r$hp5*; (a) 700 - 1200 arctfru,aiwt--at -st1g;41tt & 673 - ?23 K Gaviiu$e*art (q 20A e'tetffu,e.ivt-a) &g'firytb & 873 K Gleuiru$mru (c) irlO atr;lfr naivrt-or 8WP5b & 400" C Garuu$ora; td.\ 1 ar;rfr rocarrr--s! ;l;qE:Sg6 & 273 K 6)ar;-;l-rg$cna'{*oarl_ aj PCt*r,+ Clno, 5E&p cro$snsr dos*9d> Ar 17. Pcls(d <-

o9tq (c)l (SlS lollolt_ cI (a)-l {d)z 18" 8$sofur-or$$d: 6rprit' qgolar dsrqorr* p*rr--Guifug K: t0-r (c) K: 10 i,4 K: I [ds:r-- al 19. Kp rirqgrir K. r9;t5rir Sorr-Ger o-*sr Qginr--'*r4 (&i K, * K.: {xlf"r (a) Kr: Kc (RT) (d)4= KCGT)*' {s$cru til (c) K.: K.(RT)-" 20. Eeororl6rb aflorss{$$ Ang ddr ro$uq '.'.-."." (gril' 2NH3G) 3Hrrrl* Nqnt # (c} -2 (a)2 {r{)3 fc9or : cl {b) - I
21. Q>K"ereullcb {a) ggffieurmd;g efraocrrtg engs*n&pgr1 (b) rgor-rGeo'rnd;g efrawr&rg enga$nfrpgt (d) *rcfleaa:8;rg
22. Hzt"t+ Irtrl # (a) K, > K.
(c) Ko

lgltg otorr-qrirr (a) K: 10'? (b)

a+rpa;wa&gtgt
2Fll2is

la8err-

bi

errirp cof**:Efu[l

- K"

(6)4<K" (d) K,: 0

[dou

cl

23.

24.

2Oi <==----s 30, erdrp clororienw co$oro on$oS K" rsFljr{ ,. ,,. [o,]' (c) [q]' (4,, (') [olorr- : cl ' [or]' toly 730 K GorfiuSora:uidr, H, * Ior, T-* 2HI ercurp croponort anr K, = 49 ereileb, K. =

[o,]' toJ,

t'ffi

(a\24.5

(b) e8

{c)

49

(d)

4.9

25.

(a)47% tb\73% (c)27% (A37% [oteoru : dl 26. Gpnu* glorp$dl !-(D6uner qrirGroneiluJrorDt Fto 6rnot tggrluriu@orp,ir GBn*orir (a) e1Se,u ee 44ljoGu,nacfl wn e-qryanatgpg
(b) .eKg#pgag fleli,euuu@1pg (c) ercfirrl,a,anL fran,euuu@,p5 (d) GlatL ufirrl,c,rt anpn$t1q&a [olerrr-- : al 27. 2SO4j.+ Or,r, <.2S*r, -&p co$orouleb K" tqgrir K" ,irg,n uciren Gpnr-fiq (a) Ko: K" * RT (6) Kr= Kc * RT'
(d) Kr= Kc(RT)r [oloorr-- : cl 28. Ggour& qgoglutir uurou$$piriu@rir crlororGoro rorrpd (a) V,o, (b) Mo (c) Ti (d) Fe [oioru dl 29. SOr purndrifc$ uurcfou@rir dsos Gororon1bgD crgrr

Ggourt gtorpulei> Quptu@rir .otSeuLe 9tflrq

[oleorr-- : cl .5lrbGonadlurn

(c)Kr"ffi:K"

(4 VrO, loteor__ dl 30. 83irri+eiru- er.o$ooraerflcir 6r$6b .qqgpFFFEto crlor fnol S ci: err at.
(a) FeO (c)

(b)NiO

CuO

(a) 2Sor,r,* orrr) (6) Nrrrl * 3Hr,r, i-(") Ho"r+ Irrrr #

1d;

\-*

2sor,r,
2NHr,r,

2HI2G)

PClr,*,-+

PClr,.,

Clr,r,

32. 8$rii;rlnsrrri cra$lors:ugdl er$cb (o) Nr,r,n 3Hr,*, (---r 2NHr*, (D) Hrer+ Irt*i # 2HI2k) (c) FCI*',:>Pclrr*, + Cl"*, 2SOrrr {r0 2SOr(g}* Or,or i-

K, = K"

[criorr--

cl

[oilorr--

bl

33.

gqg olloreru9dr g>rirGeirn&q' drdrGernriqs oloroGcuo rongilo$leek grorPGu-r 8 x 10-s rDpJDli2xl0-4eroflci> coBoro ron$er9. (d) 0.4 (c)0.2 [oiorr-- : dl (b) 0.02 (a) 0.04 [3
ro$r:rGuoinoeirl Cl2

l.

or gloofloro:ulcb PCl, Oorpolenr--pcb qSorpolS't odrt [un'5'n'ol''81 PCLG) + Cl2(s) PCl,,r, # u r11c,re,c,fi ew 6 6 u ng1 at ns gg Gat6i, &e a,f ooa'rtgou eigeocnorflcocn

6;,eflq elfirnrflilgrh Gungt, a.rcflo,aswror.gt afloooru@ dunlryettaetr e-tgatrgth Seoseaw Gpnd;Gt F6(Dth' PClr-Ocurpol cri,uqb orflcoanuici: Cl, gteoarflaaug'do PC15 flrripatrri't-atgt g66t\uttb nffP'tr{fr
6'fl

eaetrru@

Gt

u rr(g6/rfi66r P

Cl, o-lgatrg

#leaeri'G

w giat-G uEl th'

2. rgoror(Dd eopeator ogoreireg&qqrb oqg&q5ronor crocirun@e orm 6r(95l'

eoflornr

ron$e$

[un'g'n'ot':91

(l)

HrOrrr,

cJ 2H2a2 <=

HrO,r,

%O,r,

2H2o + 02

Kc

lH,ol'? [o'z]

-fr{.pf
HrO,r,*
[co]
[H,o]
cor,r,

(iD co,r, *

Hr,*,

[H,] t, \ _ [co.]

(iir)

NrOo,*,
N-

[NO,]'
fNroo]

Iun.gn.ot.:1Ol 3. e8-enloslurii Geneironsorur6 egl' p-oir6'r grf anfi(n'].etuilot: eS-enLe$luti Gg netrd'',au'leuruth, " grteorcutgor t\g un$uau elbu@Sgc,vna xnfiaaDwnanrgt etbg unsufteoncis e-aiwtngli crflooorc'ora.r au,erl- Gi,elfuu1.jo @rri,rcow Gpni;6

'

D6(grn".

Gunlgaiwc;lou,e,erfletr Gu15ti;g$ 6pnooa&gt-b' e$aewu@ s i; tb 6 u n 1g en s aflew 6 x w fr u @ 6 u n qgaiveo n s orfl eo G u g d g$ G 5 nea 6

4. eo$lorrn: ronso9l odirpneb erdrort ptnfi Cirati u fi orioi,afl ou oflcocneti cri,er 6 u n75ot LDn

o,efi ow 6

Iun.gr.o0.:111 xw eio u@

e-6hcr'r

etll6tp

n$uLt *{g rcnfle9. $}rbrcnglcri

t<

.smpicu'rcu mrrfie?

ere*uu@n,

5. aro$leolo-o .gor g:lhcuuOff $r etcirr

or9eocur

' - K. : crnpilo'oou rcnStaEutngn" oscrorrsoir'S*,iog eroslonorun*ir'

k,

616irSl

ftrn.gn.e$.:12 i
o;,)

epot$g Epfgrb '*.r-- .sler.rarforrenu9ei.r 96 rgtetrG ew rr SRar erflo-u,'corq rb, E a*rG m e o B w o9l att eyrqr-b eroGo 6 gg f, b Ag G a naiv ty1ryfiR eu peo. e$t am fi a g' n taoio $l owgt efi @ w6Joucoeu. " Sd'+r,opfiooeuu9cu crflorcrruG nbgb aflc'o:orrcrflcoan 1y:ex**gtsetr q6w 6) roarr@t rb erfi ea es I a au a at ul do cg ft ur-i) r- r- .s1 onafloi.r @ g d;6 p ev. oqrG an S) eerogicua t @ n rge n fi er;,aa r;rdw u u @ Lh. 6. An. = 0, An, - -ve lopgli An, = +Ye q)6 S15,$tgd Gungt [un.gn.arll.,13| eq5 ornq er9ororu9cb crciror $leqgrirt An crcnugl anuqflottcouSlou er9leocrroflooar dunqryensefien 6nn$g
en$la,uotoou
c.,tr uL

Gmrrcucorfl erz arcuorarsfi doos

G

rgth a$l ea ew u @ 6 u n1rys,naefl on 6 n n$ g th tanm G ougt u n@ qgth. Kc - Sro;rzunri Aefleflo;a efila,aerr, Gam u,nfro$ \ - .cg$\ ercg$p$@a afior'aut 3arc u.nSlc,'Sl.
d;

nets se$l

dw

a.raiwaz,rfl &am

s&tg

(i)

Airn*,

: A

Gr-o noi.reafl
au

cn

orcirpnciu d$leli'ouru@ Gunrgetrsefiatr 6rcr$g wnuq orciw arirft 6 ott a ayb, r,S! ea eo etfl a ar 6 u n 19 c;tr ts qfl d: Gt rc n.g g
a-,vr

Ari,*. : 0 erclsrpnal,s K. : K, (ii) An,r, = *ve o-rdnptna etnq $leae'su9cir e-chon Ganpg etlldaos a9le'oenG) u n gjen s erfl an cr aiw osfl & oo $ w r66rgt, Gt n n g g; e$l om u@ Q u nqgetra;ofi sv ercierewfl I 6o*'6a ur e$l uti; 1qcri,pw n* Sg & 19 th. An(u) : -ve craorptn,ia Ko a K, (iii) An,*, = *v eretrptdv, @tfftll pena-ru9ei-r vei,er f,i tatr$$ afleoerrdlo'ocn 6 u n 1ryatr a efi dv orciw ozffl & a a e$l ea eo u @ 6 u n 19 dn a afl oar
eat

nq

G rr,rrdoe,efi

et aiwcrl,fi Saasqrb

+rntb.

erciwowfl&atta,eou-r

7. $r*rott5rb orlsrrcna"eDiii(g An,r, ro$riorurh co'or ti;Gl@. (D Hr,*, * lrr*r # (Mar 06) [un.gn"o!.:14] 2HIr"r

Arrni : *ve erairpneit & t K.

a9h- c1@snns @{ryi,$k"

An:2-2:0
2HrO,r, +

(iD

2Cl.,r,=J4HCIG)

* Or,r)
;. Kp> Kc

An:

(4

l)- (2+2)

=5

-4= l.

8. dorpppnrie ol$)oru, {hg.F. gA gdu&Le daituflaoa.ru9ar fitcgtb Gat8'aflo,rcwufilc,tr Garc-jo, cslanaruStoio n@u@ti e$loaewu@ 6unlgLaetfldv G)+u-ro.tu@
Gt

n 19 aiw e:at tn

s efi dtr 6 u

1ry6

fi u GD 66n b@

p rt

e$t

6g$

ao

deuLciou@?un1ryaiweau,, Gu,netnri

6*d^t

th

th.

erctruu@tb.

9. olleoorrigosraril erorriu@orgt urrgl? e$lclneo66errrr66 Q arotrugt eafiaetuLfrpr $lrrlouu96o ar9cooru@ 6 u nlgotrsefi ev Gt e fr 6t P6b efl crr,etrc,$lerl,cin 6 u n1ryonaefi err 6 eSt c$ fig rh @arGuLuneo e$l6gtb q@tb. aA + bB lAl tBl lLl rcfigb [M] g6)arcoat eu,Stc;oat eoou-erpfig lgew
e-en"r

lefiol,,.,tr

erefiao.

a=

10. ollcoarriqgmreri Q ropg,n eoflororrondd K" CIroin@d geironpGurlr6bgl ereiratng cnri'$glcirmor Q-etr a@uuncurgrr K"-cow afilt- eqfranna @q7tgtbGungt, Q > K, e$teoan o@uunaogt Q ro$)ncouti; gapS5rh atas8do 6l*(gb. oretrGau qflclr,arrle$leaer 6ungei,raefilt;" @Apg etg6 +46tt6ll cr9coeuru@ 6ungenaev e-1ryetniletrpotr. slfinatgt EotrGewr&g alleaear cagrfl&auu@6p9. Q-crr ro$lnunerr,gtKrcrrru e$ltt gaparrs @g&gth Gungt Q < K. efil a;oaw w natgt o9l eaerr- aflcoon 6 u nqryetrsafl eir 6 e fl q e1@ a rfl u u eog Gpn&6 fl*bhW. etqffltgr g:eoGewrtgefileoew 41srflhauu@Ary. @&ennq, Gattuth abgth eKggglb LDftpn $lcrl-euaefido sn&6uLan6ms,
11. r9rfloreo9prir erenuu@org,l u-rrgt?
ofloocuru@ 6un1g6nadffe E rflerl,s afgb erctru u@6 W.

+l+#f

gA ugfi

Eeoeoth Elcn.gateo.-atgl

Aangarca u$p G rc ndao'r;fl etr erciwawfl &c,oa' x= 6pntt*a$@dv e-r;vc;r Gnnioeefian ercftrewfl&ao . 2SO3G) $&eroSlorol oiocu9cfo cofloo& 12. 2SO2(s) * Or,r, <nnSoSl, Eillore ron$o$l 6l-p-p tr(Bgrlr. : dmr/mole sLDfl:taoor rongilai _ K. r =Fg. [so,], [or] fso'z]'z [o'?] (*^' : lErft"o.- rondag K.r \

tsql' \.

K./

13. Hr,r,

Ir,r)

F-=a 2HI,r, $1*co$looo

. uoeiirun@ceir
rrrdD6u?

oiorreoru9or

Kc,

Kp

qSGlu-rarSfleir

Nc -

(2.t)' lHll' _ @-x)(h-x) IH,l tt,l

v:4x2 'tP (a-x) (b-x) x

ercflcllcru o$leaatrtigt-*ut-t- Grcnouaaflav a,raiwerllfltcri,a

q, b

Hr, l, eunul&e'a,fietr eJTbu Ganda+oftew erai6t66{fld6oa, 14. Ggouri qgorpullei> et$s 4mo1 striiGonoflurr e-(Dorrorpfonor $u$ponorsorrm& 5'-Ets. Nr,r,* 3H.trr# 2NHr,r, (i) -gr9" ct(gfifi Steoawnan 300o - 500oC atotfllu'aivtcu eKgfigth. (ii) Alprcrctr Gtatuufleaexa96u 500" - 550" C 6aitu$lcrl,ou., (iii) anoEuGt-etfluLn 66iD# @<Otbqpsnen etflaetg&fituna uuanu@$5,i0. 15. 6lpn@ qg:eurpu5leir sr$e et6nq SO, pu-rnrf[ieu uu-rdr u@$pnu@6 $lu$porcure cir u-trqD6u? odnp e$la',o,u Gtpt@rg:cr'pa6o flai96pg' 2Sor,*, + oa*r (i) 700 - 1200 atotfl.r,ailrL-ou 4(!i6pnno, stg6 erctral st(gpgth, -)2Sou*, (ii) 400" C - 450'C 6auuflea6rwn6, Blgnnm 6erJu$)eocl..
46)uLeao;u

(iii)

o9)arcrrgo6) e-ourigg VrOr.

G u n 1q

Gnnevnn }eSlapatflev 6u7rytafiuewtflfiga, e$lcrr.ovu@ 6 u n6 Laof) evr G n net n n 6 e fl apefl an 6 u gd; a fi u o.lofi fi g th veiror atflBpda gg nrf)eEwn6tn.
Gat@c,r?crr,er;,,

16. ero$lorer: oll$)aour ollmriqqe. u E t- t- 6 an u u fl ea eu ull do, e$l ea ov e$l qa or @A g A

t-a; ofi

our

[A]" [B], Gnfiaaiwt- enarun@ e;Slrm,ou cE9) enetrurr@ q@th. 17. cro$loro:u5cb G"drt ongu@orpncb o$u@rn o0orrmq
er eir

aA+ bB (.--..... cC + dD I. _ [c]" [p]' .rc

or

g(5

GatSd'enSlcoouulcu atflcr;'r,tru@ 6unqryenaofidv Gteflaeu

et91

e1Safid;gtbGungt enfroawwnovgt o$looanc;flcrr,m 6urlqenaen cr;,enr,:fl a6n 6 u nlgenaotfr 66r a-rgat n g b @ ea eea uL G p rni;6 p s i6 ptgt. 6 e fi clnat 4@ a ff} d;g thG u rgt e rc Sl eaou u neagt r,t? ari,ev u @ 6 u ngotraotr zlryarrlqtb @eaeaw Gpnt6 pariflpgl

Geiii;rgbGungt, Geriilsuu@n N2 LnbEltb O, ofieaevuulG) eo pe* erevG at' g)6,nG 6$ n/it g $ ea e uil,io efit eoevo$r eaen 6 u n1geri,6ff$ 51ry6i alt aoowi ar;'r,ranor u9a-r N O -crr 6 e fl q e1@ a fi 6 etr pgl 18. eU Gor$*cro$leoo>u9eb Gloruu$pneb o1iru@ri o5lormol
d;

6r.6ff. sul6t6o6u Jry6otoulgcu Nr roprgrrb

O,

ooall- aflo'ocuroocuooorL?cu

uln SJ?

g:ewGerrnd;g n,bgtth fietrGatn&g agr,aatra.eficr' 'gt96 6attu 6)r.notrlrgantrr en$@ttrcn6,pgt' @GpGurdo' en$lc,aol.lu96'tt G ngl' 6 at u u fl eo et:a uL g ao rp ti 6 b G u ng, et fi n 6ilgl 15 o-rfl ri o$l 6; g tb u Lnbgrttb fi,avGr,trntrg agcri,oara,etfiv, 'glgtr Garuu eLAg
rg:eaGa;rrnd;g
a9 oaew uL netrgt an$@ w

g(t

Gat$t&eu,flcocuagou Giatuufteacucow a-uLti$gtbGungt'

ntQt Pgl.

,*Or,r, ; AH = + 59'0 kJlmole (NOr) e'15atngt-b @bs,i e.tnfidri,crt&civ, o?coearcrflco er G un1ryar (NrO4) ogcocrr Gt at u u G s n ett 6fi ea atr u na,o4 th, a$l a ov u @ 6 u n 1ry6tr e-rgatn5th a?teaeu- 6atuu e-6 p e$laatwnsa1th egaa$getrorgl' u u @ 69'l thG u ngl' A i 6 *rt* r- e rc $t a et eil ea ar t e ou ori,at a w 6 at L u 6 s n on ea 6 u u +' et p 66r Gt eu u u $l oa a e- w q5 6 pg. e$ o n r- a$l uL fi ear en fi eaoxuL natrgt G,ett u u fl r;r,at u9 ev aflaooneool ga ptg n @ areea uL Gpni;6 F6fAApg, eretrGat, enslaouuncrrgl NO, e-q5atnge$tetr Gpnd;6t Dngilpgl. arctrGeu, N"O. Glcogetteot-gda cr.en Nr,r,

Oo,r,.

fiaoeeow e1fiafid;6p9.
19. Hrt.l +
etf)

Ir(rl+
@6

2HIar, erorp ero$ocro olleoorugeb 4t1gppF$'dr

('/fl

ollormerror fr(3S15.
a neioa efi 6,tr er aiwc,wfi d 66,{6 u n 6619l e$l a asr ollcocn 6unlgetrsa?tetr Grcncivsefic,tr eraiwewfl &ettsti;6i sLDLAnls nnetrgt + a fl eaas u9)'io or$,aa uL an fi p#6a, ul th @1gu u greio, etg;$$ o1fiu@gttatt$)cueoou. 6,rer'.aat 6ewcit:1ry:oap (9(g6ttgtth I atm eqg$,th urglar&aJu@6pgr. ts ro$nGuoinoehl 1. K, = Kc iRT)a's 6r6rp eoeirunLorrril Gunglornor gqg (Mar 06) Gor$uto$loro ergororrhqg orq5ollriioolrb'
eoevu u ff15 61ra

otr

[un.gn.at.,15i
at nu..1 fl ea(,Uearougcil e-on6tT ag6|' el'.u@ ttbgt th a9oar,6rafl6a6rt ie a fl eoou q'tfl cri,c,rr,eo uL & Gt u ir1ryet aaen& 6 onaiv t- G u ngl at ncw Gat @ lL+ ntM + rN +....... alrytGounb, aA + 6g + cC +

w : p
e$l

PtrP-r,P"*""" ''P EPn*

erctrugl cunuld;aofieir ug$ etgppan5th. osleoerru@ LDbElb a ev esl a qr 6 u n E on",ofi air G rc n w n i 6 e Sl etflov an r uglas na e rc a urs fl arfie$l
[A]" [B]o [C]"........ seto'atuSler: p_eiro,r er$pGarrg

,, .

[L],[M]'[N]"..,....

atnulte^gl ,i,-t@ et7eo ugg eKgFF'b'p,'d6rh Gu,ncuri Gtc6t"t ,C)dgth o._ejrm Gtpm_ftq

q = h 'RT-iv
et5navgt
c'laivc;utfrSari,g,, n

G-qur.b P =4RT
e-6tr6n

= C. g1g a9r-r-rfldu

e^g i-air

lq;cute^gaafiafrr

Y : sotr gl.rrlr6t! a5)r_r_rflci.r eJ@b. 6 e $l o4 aa or u u g8 u fg $S gS aer an ugt a ns [.t

Gt

u n1q gg th3u ngtt,

_ @L/RTY(pJRrf (pJRr)"........ K '

{PA'RT)'(PB/RT)'(PcIRT)".......

: PtuP'ufN"""

f*P'"P".*

( Rt,

/--\{r+r+z+ "

)-(a}6+c+"

')

=(#,)
Ln" (atnul
a.flovteoc,9rrior

eraiwc'rtflteog) - (atnuq eftaevu@ 6i unlgn,trg,efiutr G',niod,ofieir eraiweofldao) 2. o8-cnLo$lu-rri 6cneirorqeurul& a-S-e.

6un1gaffedff6tr Gu

ndoa,c,fiovr

o49-J 2No(dAHo" = +43'2 K.Cal/mole erdrpr ollearoruieb st(tg p F6, 6rdlq ro p glir Gor l1uf or etlugrd'r olloor mol{r6o rn
Nrlgy+

erior ilI.

d - entoSlt-rri 6snoh6)ir
6lbu@tb
Nr,r,

Iun.gn.er9.:161
:

unfiuoaw elbu@p@erindo, ercficri,c.)un*lrgt et67 ungu9qrndo

a?ori,onori,ou elu,air

@66)e,rcverl,ar-fi,eiruty eu,fierl,cuu?lcio p-aror

gri

e4eanutSlw

Lggr

6etuu4h

@orr,eo,uL

Gpr;i;6 p6(ry;,.

O:rgl

-*

2No,r,

AIlo,: +43.2 K.Cal/mole

7
ofieosrq t Gr-oGou p-dror affaoc;rrri9)eu' or?oooa'u$') efl ea or 6 u rggonu efi ear 6 rcn$5 Gr-o,n'al'sarfi crr er aiw omfl tho6l' 6u;tb' afenan er ar. s-r;n n s e m rc ul tb aa a r alufl 6; en s efil eur G a n$ p G nols afl arr ar afu G u n lry .'. An=0

(i) gr$Bp

r-o

orcnG

o;o S; aror?eoarug

"eftgp s $$omnzu
:

u n@ u

a7

fi u @ e'tt
Qu

ciu

e'aeu'

(ii)

6lcSotlsor e$laoe:'ra1

G u ngt at n

a g15 G cr'$dsrn61aoou

u!)eu

all oa ca

tt

rgon s afl ov

6ung56{rsdn e*lryettnrgb Sol,aleaw Gar&;6 pstig'pgl' aflecarlr a9eaer 6 u rglnsr;rfr661 6+';rfi er;.eu .e1$tsfr 6;1qn Gu ngt ercfl crl.a;uLnengl etflcaentt@ Gtunrgcra'otr *'15etn'15tb frc,aar,aut Ggno6) pai6ytgt' afi ggo'tt or etr G a Gro Gor, p-eir 6n afi enenrr,gcu eo gt r- tt gl 66r s7 eu eogl .4n

Geftani =21fisfi*;6th Gungt

amsteaovuLnmgt

a?o-oeo-r ar?ao6n

4&aatt@ 8t*b6l* Geflaneu .gSarflil1gn Gungt, ag,t-rfl& orieocur w nti6t pSl' u@6 1ry:anGeo 7g*i uga cflooo-a-r glraiwr-u egsfitsuuG'6p$t. (iii) Oortu$'leooulleb erllorenol | 6abLqg@r' 4ther9gletr gg $t*bflffigpgt ari ptd',c .g.xoooru@ 7u-tnfrtgth $;ara9crnar
6
at u
uL
or-r

u,h Gt s n atrafr aaatr us n 6 b. er anG ou eS - e n L_eirl ri Oo,rohaoo uu rg tf 61tgt ea ea 6 u r 19 ei s-.9 oa uL t w i $s ew n,iio ot? oa e.'r G) ai u u pt oo g u u @ 6 pgl' er asr3 ot vuL rf) u Garuupico a; a B trfl & @ s u u @ $
otfl
61r

=v1

4acnaru@ s.'Qtat n 956al:u qlgjrfl dtil UgJ' 3. PCl5 Gleopqrb efiosreor&g I(. roSglri

G,snatrGatnth. +mgicoouufldu

crSr-r-rflou 65nt&s$@cio @guuPna6; PClr Gmnoirseh PCl, GietngoeaLSgl x nbgtlh Cl" anuli;sal,enp g$6pgt. au,fieaatsu9'6! PCl5, PCl, rcfigta Cl,

K, nn$er9lc$6cror zuq9o$iri;oo1rb. [un'gn'es':1?l e roorunsoeoor d-o tit ov a4g n ng1 at rr u-1 fi ea as r,ar-o agcu PC l. Ft eo I at ea t'at pear e o fl a PCl,,r,*Clr,*, PCI*., . 'a'
Grcnets;dn PCl, ovnurr

'V'

atnq&*uu$len Grcnetnn Gaflalr,en

1g)*e&rf , i *rr^i *t"*'

xiV x xlV
(c

Nc t/

IPCIJrI ICI-I r
(

tpctj -

.r2

-x)A/

../2

ta

x)

\ - (r_rv
x2

x:

arcnugt Erfleae. o$$tb.

etgornaru@ Glu n1ryltra;tftfu

gA ug$'

Eairantb @eagour,acat3p

Eftelnr, a$gtb arewuu@Aqgl

(
Glclngatclnt$p
G

nndoaotfr etr craiwewfl fior,ar

G

6 5 n td;a$@do zeirm

neiug,6,tfl

aii

qraiwewff 6a

Glpnt-ii;agScio 1 Gmnci-r PCl, S)qSuugns er@$g1&

Kc Kc
P*,.,P*., rcbElth

Gta,naiot_na-,u

x2 (l-r)V
-r2P

xzP

[PV:RT]

(l-x)RT

annuiletns,

Kp

P,n,-' P.
P,o,,

6tJ

6tll tD666r L-6D LD

t*,] t,-'4
['-'l
.'.K = ttP l-r, '
PC

x,p2
X

t'-''j
u,rn.
en

(l+xf

(1

'+x
-x)p

l.

6loogor ea t-gc6l

oi,lr

x'P: K^ : (l-x)y' KP= x'P l-x2 '

4. Hr,r, * Ir,r, <-2HI,r, e-qqornpcb olleoorugor croSloro: nngloSloonm ot(Dotl. Hr,r,nlrrrl # 2HI,*, en$leaou a$la,rl.evult,io efloianefllo'6n Gi'un66tra,ornoit @pp& Gtonetssertlefi o'taivo,wflto' {Bun66rgr etgtc,oenu@ Glunlryeinsofieir Ganasefleir orcioremflt*easdg,* ennn(qrh (L,,, = 0). H, tofigttb I, atnu-1&aeifldv Gnnasltr g:agtGu: 'a' rcfiEtrh ,b, Gtonoua,etr ,y' cr5lr-erflcir e$l oaevs at atfl a e-aretgl erctr & sqagt G at r b. e Ln ea a ug at x fl Gnndtle,a,tr H, Lofugtb l, etftoi,erruue@ 2x Grcnriua,ltr Hr e-ge'n6pg.
.

fl

caou@ n fr a

6t

et1leaeq* scllcllanuSlc.l H2, 12 GeftaLlaen ig;apGw

(a

nbgb HI

.g6)ulor

pflew

emfiell,er,e

- x)/Y, (b - x)lY rcbgb 2xlY 4gb.

An, = 0 croufiet K. = K,

(56.

f
I1

lHIl'" _ (2x/Y)'} _ lH,l- U,l- (o - x) (b - x)

X

4x2

v2

v2

(a-x)(b-x)

(a-x) (6-x) x q6rgt

o$leocrr.

Nr

An_ c

fttcgtb crkcrl,c.l ercnqb e4ap&aau@Qpg. 0; .'. K. = K.

.''Kc

Iq=

4xz

(a-x)(b-x)

(Jun 06) (5) er#uorp olen*qgo. og - cnLo6lu-rri Goncircuraturg. " eroficri,asufildu veirqr gri elcll,rcul5leir 6gt unfiuau 6tpu@#gavndu ercSl6o6lu q66rg,t sl6p un@u9condu esfiu@th
F6(Dtn
cfloac;lrari'ou

[10 ro$tcluooneeirl l. (.n) Ggor.lri qg:ecrglu$eb a4Groneuilurn purnfi$pcir nlleororSe ncor Slu$pororeeil urreDot? og - cnr_oSlu,rrt p$glolrn ercirorng Ggarurt Cg6)pdig uurdru@$puu@Glpgr

xlr,eo deturyb

@aeaw Gprd6
g:apuSldo
LA

Gpoui (gsrp :
fl a gt t- ryggotr
eu
uq

e;rirGr.onatflwnatnangt
a n S fl gt
eE @ en

Ggtui

clr,as

a a uSl glt 61 6r

m govfl n n net a p L q 966r

4q thG

bgt tb
uL

46

a$ ft

zlgou ngrio

erflcrr,elr,uL

netgt g1g

6gtt p uL n rfl i* a u u @ Gt pg1. eu'fic;ri,e;.t cfilaaeouL ngtb.

AHo, =

netfl

Nr,*,*
e$t

3Hrtu)

(i) .l q$pgpnc[: erfiu@rn oiorrmq t

a
ew ut n

.Ea

2NH,,r,

-22.0 kcaUmole

etgl

o-$l

ao u

gaytatap& ant@6pg. e8-enLe$lwri 6anerqaoufilov u+, stggpsc1rg e-wi$g1ary1 ey6ue$l6rl,owd;g& en$@war66,ltb, x n fr a a w n evgl e$l oa cv e$l a ar 6 u n g a 6ff e-qry at n rg b, @ a e a w
61r

6u

n 19 e'tr s

1g>ourGovnd;g efi otr G n n a; a ofi c,tr orciv c,:rlifl t ea o

Gpndhulrh elcrl.rr,$gleratgl. arec'Gan 3:l Gronoir Eonevrcnan Hr: N, arnu.1 sa a ou uil otr ofi ea ev t s et etfr eio e1 @ s u t-e 91 thG rc n eufl w na au u G u p 3 A0 500 atm et(gp47aag 6"gtpp Govcrur@r-b.

(ii) Goruu$pncil opu@rn oflmmq : c,$-enLc;6luLi 6 s nor a a 8 * u +, 6 eu u u $l ea eo ea u: a- uL i $gl atg'l e1 th G rc n etfl uL n

Acllpatorlepdo
6 at u tt
tfl oacru uSl,iv e n

e$lc,ri'eocri'w emd;ge$d;6pg. fi eaw c4 a t-at g fr s nev G p r tb

.e1 @ a

4err.ndo @6apbp n na z-enffigl

(
g(g sLn6r-,r G*'tsuluut,' r- Ga;uliEieinat erclenoo 500'C"55*'C6r) fl+,$gpuu@*p$. (iii) ollourorgiiiGu:neil o$ul@lil orieomo;, o?c'orowgd fliu rr<r 9t AW q s n fl ea a oo w u u ng] a n ii a, $ r n atll an u i 6 *gt p8 .si rhG n n atfl uL ir LA 6u n 64 L-dr e. uetr rg w n s G at orfl G uL $ 8; s u u 6 @ pg. $ gownei; enflaauLnavgt otllcoc,tra$ar;'ar Gtunigon uBstn $fffla$l@6pgr. o/o s4 @ s LL r- a n n,y, 3 7 e1 b G n n afl u n $1 tc ga p uil eit e-qryarr 8t pgl. (eliGpnG glcopu5lsi> -lr$*e16noi SO, purn"#lSgiei: crgoror&sros $u$pecreurcoir u-rnonor'l g4eilou gt) Glpn@qg:englu$eb dcmr-o8u"rr?
6r6dTc6tj,

q$laoclr

661

Goneheor

er cireun

uoruStGp

gl erdnleorp
-4

o$er ri 15 o.

(s)
2sor..,
-F

ort*)

Gmfusaivu eufieaets aicnou (6gr@g:ap)u9e;0, s@fi6u e-qtren atnul$leactclnn 4ti;Agwaou SO, 4th6lgGeofupn a4eon-$gr etfia ertlirafileia SO, eurul e-bup@ G\*wuLuu@frpg. (i) =gl<tgppppnei: q'pu$6 clllorrenq , SO, e-lgarngrb oflcoerru9ar c;f,leootru@ Gu ngatrsafien' G't nn$p Gan,iosofietr orotiworuffteu,s

Jf1.

2so.(u)

AH', =

kcVmole

pg. - e nLo$l w fi qlr 6u n etrcr;e,u u +, sl(gfip 6ap e1fr s rfl&6tb Gurgt lrywGewnig eitar;,;sr fltp*St en$@uth cl6p5t. a?tc;oan&aateffioit gtr* SO, roglglrb {J, eunul&aon 2:l Gr,rrwmi ot9t6p$@do 7C0 atm - 12AA atm ouerflucrrL*;r) .st(g)5gg@oi-r afleoo'uruu@$guut-@ e1@a eprE SO, 6upur-:$l&ragJ" (ii) 6oruu$pnei> ey$u@ri ollormol : SO, e-1garn6tb etidu,r,rr. 6atuu e-6lg efilamwngb. atewGan, Geuuu$lcri.,ou uuti$gtbGungt SO., 6orrgo a updu e n$@ uL u rc6 pg. Grogriil 6 at u fi er;'asoll" u I
6da p6
alS Ls

geop&gth Gutgt en$loaev 44aat_atgfrsnav GpyLb e1fiann6gtg1. ararGer, e.r flc,ri cuugds 400'C tgtgcio 450'C o.tl{rtr C)atuuficrl,as
unssntisitLt(AAng;,.

(iii) or$ourorgriGlurnei: er$u@rn erlormo; : SO, e-lgatnpe$letr a on' tll eio G at G acr rg w tb 6 u dnr t- n d; a+@ (VrO r) aSleocurgd6) uL n s it uwetru@$puu@dtpg1. rcvuttgtb @<guugt a9eoeurge6)ugcn 6euL<iu9ptoaar,i* 6eapd;6pg. arevGat e-oti$p gnur SO, nfigb O, at n u1 8; seh of)o'ocurgo6 r0eor dg, 6 sg1 $g tlt u u: r.,tru @ $g u u @ fr atr paar. SO, e-fiuflfi GeuLw s-fiEfupg. YrO, 4owgtH2SO{-6tr $,ffta;$ 4gth. qe,srGan @th1g:oapu9ldu SOj sJ66rgt $qff6llqL-66r G*ri$gt gcCIr-lir nbgtb H2SO4 guLnrfltsu uwowu@6pg. @bg:apuSl<io 97% SO,
a;fl

5ioi,t-g':sj-,ns,t.

5o8r&(g66ir

l. An <----------s B, er6rp crgcoorugrdr c.opeoo .ondoSl Kc = 2.5 x 10-2

qgleirGen-nriqg

esororuldr oierrorGors ronSoS 0.05 sec-r srcdr$ ricbGernriqg olororu9cir erianorGorc' rorglo6lcou-lri (Mar 06) [un.gr.ot.:181 oewri6@. 2'5 x l0-2 r, = 0.05 sec-' Ii Got8,i.aloflcrr'oou9dv r, = r,
eul.flollertulnfio,5l

K"

: /'
t,
o'05
tz

2.5

lo-20.05

j'r, : :.

Ec,ir3arrri;g e0leoerruiler;. o9ooorGo.rs u,nflorSl : 2 sec-l 2HI ollororu96$ H2, 12 DpJDrit HIdr Gronoi>ocrfldr 2. Ho + I, # erairemfl*eera glcurpGur 1'2 rn$gri 3 Goneboeir 4bqg6. oiecrorri ao:ororug* 6on$p .lt119pp6 60 atm ero{leb H, ropOrrn HI-6to uqg6l 4113$prxcormri conrd;G)@' (Jun 06) [un.gr.ol.:191 6nngg Grr,ndoe'afldv erciricwffaeos I + 2 + 3 : 6 cflqteo&a'cuanelr:uflour 6nn$g etgqg,h: 60 atm.
Hr-ev ug@

L5xro., =2sec-'

eKgpgh -

?
2

x 60 = l0 atm x 60 = 20 atm

lr-a* ug@ 4(ryggn

Hl-co ug@

eKgepth:

"60

= 30 atm

H* l, rcbgtta Hl -6dr ugg et(g#grilaer lgapGuL l0 atm, 20 atm LDbEttb 30 atm eJ@th. 3. g$ o$r.r-ri {bdn Jl6nq 6enrdnr- oscuror&eooflci> PClr+ Cl, olleroruSld'r croSoro rondlerSl 2 x l0rlift PCls + qi(Oril. PCls r.6le& 6flpmGor Oorporoor--u1rb Gungt I Gnncb PCl.-# Erf,ore olp$orprfl coxrriGl@. [un.gn.ol.,2ol x' K. (l -r) V' '

Kc &afl6o6D tnffdail V a.66r el6'n6\ Effleaa' prb 6la& ^f @$tgercln8rir (1 -.t) : I dratri* Gta,ndr;rraxn.i,. 'v:*' "'tc
2

v
x2

x l0-{
.'.

i
2

lit

x2 .'. x

x l}a x 1 lit i"e.,

-9-rfloa.,a'af9-l: 1.414

": x

fi "
l0-2

tO

2: l.4l4x

l}-'z

4. Glorriu$lonco T,-S e(D crllorsruSdr croS'lcoro:ongfloSl K, ebgd. o-ulri$p GzuuuSeoer: T2- u96b K2 ,srgt 1070 Kr eb156. cropFleurournrorgr Golr}urir 6e neir +l16boSl 6lorrlurir o-rfl$ copeuretu-rn 6rdrgl $!iooru$rie qrir"

K AH"fT--'rl 2.303x los ' = ----r I ' " K, R L T,T, 'l

atnerrL

pnu

+navunr-tyoir

ut4
J o-rarflei.r

[un.gn.ol.,21l

K, . K, a'c,r;ftdo AHo : -ve. (G)aruu e-6lp e$leaam) K, t K, orctflciv AHo = +ve. (6aluub Gi,o,n6fia9aa6,5r) GroGcur ydr6n e$tatquurg T, t T, ; K, = l0% K, :. @tpS qt,9eaen 9]16 6auu eLfl$ efl6f',eu. 2NO, ollororundr Kp 6$drr{ = 0.3174 5. 35'C-6b N2O4 \-: P 0.2382 atm o-ehmGungl Erflore o9p$eorpri oeuorri;G)@. NrO4 \--=J 2NO, [un.gn.efi.'22] Kp 4x2xP K_ 0.3 t74 : 4f 1.132 P 0.2382

@$g enetrunLtgatr e.r* Tz > T,

^-l

r.3324

x 10-6 4trqgr6. K.-tr ro$rioruri; ocorriGtQ 2NOCI <-- 2NO.*, * Clr,*, Iun.gn.ot.:231 Kp 3.75 x l0-d T 790'C : QgA + 273)K: i063K An (2 + 1) -2= l; R = 0.0821 dm3atm. K-r mol-r
3.75

'

--'-(e)

---2(d ---------'--

--

7
t
I

x l0{ (8'314 x 1063) 3.31 x lOj atm' cri-orulleb 700"C ull6i) 2SOr,r,*^Or,r, 7. 2SO3(s) r-l1rrp ronsoouioir-'lDOntl' 4'8 x 10-3 e ro$leuroug6i) SO3 "t6t;ropgd SO2-fr Gesqecir groopGu-r 0'60M tapgltit 0'l5M c-.ir* Grrn5l Or-drr 6+$ooo16 oomrriGl@ [un'5n'oi':241 [0.151' x [Or] lSor]'?x [or] K. _ Iso.]'
3.75

KP Kp

Kc (RT)

*'

i.e.,4.8x10-3=ff

...

[o,] :

4.8xl0rx[0'60]'
(o

lry

0.0768 M

8. 2H2S + Kp : 1.18

'2H'rt"t + 2S,r, 6rd'rP ollororugeb I 065"C-d\) x l0rrofigtrir 1200"C-u!l6i) 5.09 x 10-2 e-ehmGungl

olleuronugor

AH-gri

eeorriGl@'

Kp' l.l8 x 104 atm Kp' 5.09 x l0-2 atm Tr 133SK T2 1473K at raiw L ann&u ercetru nLtgotru+' Kp. = aHo /r" - r'\ toec z:orn \-F-J
log Ker- log Kn,

=#* '+
AH

.'. log Kr,

log Kr,

= ,56;T5.*
l0{
=

.'.log 5.09 x l0-2 ...

log 1.18

9.

grg oorsflcb 458"C

GoruuSoro>u9eb HI 6egu$pti ,rOerrhpsr. 15ptrir-_r-- elsnq HI Oorpororr--F5l H, tDpgri) I, gg pqUGfpgr coporougeir HI-dr Geflcq 0'421M roflnqrrir H' ,iOi*'rra1eru-r gen6ornrir$rir Geflo$r 6'04 x 10'?M q166" crGp, GroruuSlorou$e$ K.-E& eeuorr$Gt@' [un'$'n'crt':25]

log 5.09 x lOa - logJ'18 AH = ---:6.g5 AHo 177 K'J mole-'

x l0r x 2'303 x 8'314

zHl i=.:! H, + l, [6.Mx lO']x [6.04x t0l v - =206x l0-'z Nc - [Hr] [,] _ tHIf - ----t*rlf Kc = 2.06x10a
10.

6lorporanup6sl6ir urofloro:rongDo6l 4Sg"C Gorrlu $learou9eir 2.06 x lOa 45qgd,. erosloro:ul$ HI rofigrir lr_ch Gcglqecir qgrccrprGu_r 0.36M ropgri, 0.15M eb15; Hr-tr croStoran 6cgiooorri ooor&6t@. (Oct 06) [un.gn.ofi.,26l 2HI <-. H, + I,

HI

Kc [,] =

2.06
0.36

x
M

I0-2

o.l5 M

lFrrl

".Kc =

ffi
1.78 2SO.or,

i.e.,2.o6xlo-2:-H#
0.15 1.78

[2.06x10r]x[0.36], :

l0-2M

:.Hr-& 6edq =
11. 2SO3

x l0+M
Or,r, erdrpr ogorcrui6fu 900Kd) ero$leurct + ()2 i--2SO*., crdrpr

i-

nngicr5lu9cor tD$drq 0.15 crollob 2SO2

olloororuloh ero$lorreu ondo6lulrdr @caroluSleb eeorriGl@.

2SO,

o$uonu crGp'-'6orr:lu

s:=+

2SO, + O,

lsorl, [o,].
ls03l3 2Sor,r,
t-t",

* or,r) <[so']'?

lsorl,

2sor,r,

v- .". EeirGovntg

[sq], [o,]
etglorevugev

eulflolau u:nfroil K"-,

: "Kc

.'. 2SO, +

I
0.15

= 6.67 mol-r dm!

2SO, oflcoerru9en rlurfieacu an$la$l

O, <---r

6.67 mol-'dm3

3C oeirp oneoearu$cb 25"C-'b 3 e$lr_r--ri eoofleb i2. A + B =:J 1,2 ropgrb 4 Gronebseir qpeoprGur A' B ropglti'} C 25'C-6b Kc eoul& 4SGlurolor ,irrn$leoleuu9eb o-ehmeur' lun'5n'o9':28l ccrrriGlQ. A+B F---+ 3C I : A eurf)canct ?e.slaPtitr
J

-J
-;J

.'. K^

'

:- lcl' [Al [B]

r+i *t iil

= 32 = 10.66 mol dm-3

K.:13.

I oir.uri,

l0'66 mol dmJ oor .916116{ 6enoinr-ereirormol

Cl, QeSol 6orr--6e

sooflob 250'C-6b I Groneir PCl"-g Gcri&s Goroin@rbt

[un'5n'o9''291

PCls+PCl, +

clretglettanugeoK' n@uq 0'0414 mol dm-l

v _ ,,c

[pcr,] x [clr] :0.414. [pcl,]

=0.414. IPCU

'lx'l K . ...

[pcl5]

: 'l*l

aqvt

=.2415.

.'. Pcl5-6tr *lt61t6l:0'2415 mote

t4.

540

K ropgrn I atm-cb PCl. Ocorpororr--posleir KP = 1'77 atm [un'gn'os':30] t6r:roaru& oeroreGl$' eroflob i.* PCir + Cl2 Pcl, FK-KRTa" ..P
L

An ." KP

2-l=l K.K

L77 K. 8.3 t4 x 540 Kc = *#^

4xt|-2mots/litres

K. :4x10-2molsr'litres 15, N2 a 3Hr i-2NHr ailomrtgeh Kp oguq 400"C6b 1"64 x l0-a erofleb K.-E& ocumd;Gl@. L,:2-4=-2 T = 400"C or 673 K, R : 0.0821 litres / atm, K, = K. RTA.

.K '-( -5RT;' =
:
1

K-

i*T)'a

Ko x (RT):

.64

x l0

(0.082

I x 673)r:

0.5006 mol2 lir2