cfi

u-rn 66r

olooueour$

pri $Gp@$

gl er q35te:

l.

C2H.OC2H., CH3

O
I

- CH * CHr 6orofluu$l$g'rrir
(b) @c,ac,w ntfifiuLtb

[un.gn.er9', 1-1o

on$flurrir

CH,

(a)
2.

a$)eaewi?euL,iu 6pncg@

bl

{B$rhonainuoror1ilgeir 6rSt ererflul rprir

3.

(b)C,H,-O-CHj (a)CH,-O- C2H5 (d) C,Hr- O - C2H5 [olleou (c) CrH,- O - C2H5 rp6Dr& Glerrpuup$(5 e-cFp sn[omfl 6nr"rp96i)
(a) HI (b) KMnOo
(d) H,o
(c) NaOH Icrleoru

cl

al

rBrfldr 4lrh6lgor u4@l

(Oct 06)

(a) filge$lclnan e$rfluLdt*;agt (b) ugo,S@ 1afuutuuergl (c) 4ti;flglGetbEttb gadrcrlrl (d) tAbpfi porranuleat-wgl
dl

5. gurusun'tr JtdlGD,

cntr.;

GencircaraugoiT

urg, -i*
(Mar, Oct 06)

(a) p@Slcli,cog geireau,ulear-'uJgl (b) ctlflalfi penoanqat-uLgt (c) anq$ gdircrl,toulcr;,tgt (d) nrfluLciotq$ getranqaot-ugl
[oleurr--

cl

6.

(g*,h*g6eDtGtcoruGul
(a) CH.COOH (c)

6utgD+[g;66r CrH5NH,

l9ooroorriq

{l$rri;ooilrr--orpgt.ir 6196b Sebooo:t

(b) crH5ocrHs (d)

lo!orr-- : Dl 7. er$$eb srGurnecrr-O, o-curi Glcborri 4trrieoc@r--efo 516)F

CHTCHTOH

c-oinun&qgGpglt (a) e$@e;o 4,ioa,qlI,neio (b) ater$$eio rngi

(c)
24
Qcioc,un

npniae@

(O *$90;o 6rc$@6o rr'gri [olorr-- :

Dl

8.

g${i6eirL 6rppg ddre8ulicrir

ag*a;arft Gerttas &crl,rrr (b\ crafiLqn;frt e,afi Gerttaa (c\ oravi;Lrn& e,ari u@efit@ (d) aqg*;aatft uSait-@ efrrrlc,v
(a')

GpnqS$p6b 9q5 enr*rgt t

eticrr'err.

eficrl,eo

[crtorr--

dl

rE,orr* enpf$ Sr: rodl Gpurir orlL@ enor*grirGungl (Jun 06) rcdrr-ngrir Golgrilgrir GunqSch (b) 4d;c.,ooa@ (a) 6ugn&cll,6$A (d) gu,i 48ae@ [cfiorr-- : cl (c) TNT 10. g$ertoreenu, dlorar$ g[tn oro:Ol-dr oleocrlu@po rporgri Quponri. SglG* (b) e$t,ioc,$lwrheev 6pngp5do (a) gtnurcar doror (d) Ga,ndorJi,an e0terr,m [olorr-- : Dl (c) e*fiLeiv &anr;w tf. C.H,p 6rdrp ornrirriunLrgcb er$poror rpriocir OtUti'
9.

crndrriqcirangr (a\ e@rgt (b) Qro*r@ (c) <ry*gt (O p"eog [oiorl- : cl 12. 15anp$gi efirror&oorms Ganednr-- rpriocrficb St9pgt rurfi rprieormri GuP r-Pololst (o\ etLi H'SQ (b) Genryub :5doan6eaon@ (c) e-oni Agp (d) Erfltherrni@ eslori,euruGi,unlry,tr [oieor-- : dl
13.

sr-rt
@)

eFFa 4r8o$5,1t--dr ereopt Gcri'$5,t

(D) gci-rrgcnry@se*r

FFri

p,urnfirie tu@ClPglt

srtln ey-freorh

(c) 4rior'gtnotsa,c,ir {d) Et-Gtnewcov [efiorr'- : cl 14. eurr- 6rE,Fd, FFri SUernci: q5GmnrflGor$prir '4errr-u1rir Gungl or(gorgr (a) CHTCHCI - O-CHCI .CH,(r) CHiCClz - O - CCl2' CHI (c) CrCl, - O - CrCl5 @) e$laeoeLgu,dlcbcoo [oleor- : al
15.

seilGcroror& rgsnosci: Oq9FSt GorgluS$$l a$tu Lpollit ertrelfl (b) tnc;uao a'nqowfl (a) Guui anqffi (c\ gGqntfr& erfreudo (d) L1GvffL$lanSrt [c$oru : cl

16,

Gcnqurril r9ornrfioorenrGt-on, Grn$pdl

(c)

g4Glrnorr--ccrr--*

6@u@$$llorneb 6learrrhgrir Gunlgeir (a) GenryuLtb l4GuLneat@ (b) .qGuLntn GLLeirfiatr

ep$l3endo

(d)

g3annqtrd

[olerr--

cl

17.

(c) cor-6rog@cio wpri (d) Sevrrdo [oieor- :.al 18. qg6rRft enBeorri 6uLrguicb lqcrflficrftiunarr+ir uurrfou@rir Gcriroril (a) epflGemio (b) r,ri,t-ag$cio npi ( d) (c) tlanrdo 6G6nrrcyn "/lgGpr;ll' [oterr-- : Dl 19. o-errrrriol SrhGluno uurdru@ri Gcrirorir (a) gGennGgff L8gGgi66r (b) tfeumio (c) oor-- erp@ciu nggn ($ epfrGerdo loloru : cl 20. PCl. c-r--etr olleoorqfi$gl HCI prnp Gcrtrorir (b) qy;oagtn6oa,c,n (a) ey6letwaer (c) ngisar (d) Semriosen logorr-- : cl 21. rpqgudr cr9orreu*Gcu-rci: 6Bng@ ronfi$ulir r-66u-rr Gcrirorir (a) 4dosggndoa'efi (b) cldamis'air (d) 46oryrrl,9gr/@een [olorr-- : al (c) EtGLnewaen 22. anr-ir eoflro strflorirceir *pqgr--oto oforoqf,$S p(96!gt ......(a) 4eioe'gtndsa,etr (b) 4d;GenofiuL6 e-uq (c) =e1rdo qGennaq@dr (d) gmtt 6rgt6t#h gdr66ra, [oteou : Dl 23. goflGcndD6Dt qGrndlGerfglri: 6crirulirGungl Gor-riugl (a) O, m qGqn6an .qofrGenio (b) O, - p q3qn13ruln elr;tf|C*rxia (c) m, p qGffinr s1off@nci.r (d) g6rl,6u ergryd,dta'rlu lo9orr-- : Dl 24. .......... qbfh, gcrfru$ci: qgGmirrf,gn--eh olooqrfi$g . GurigGerrnGsn eDr- 6rp96b Fpolrtr pq5hpgr. (a) atGag@eio rngn ($ atorg@riv npi (c) =g66flGen,d) (d) n$gnd;A duetr&qtr folsurr- : 6l 25. Glrfld; eor n i' @ oller eor ri Gl u r (D eD & (5 een trrl un cir (a) .sleafrGendo (b) ogfiao 4,iosgtn,io
26.

orncororrjr Gunqgerrneu uu-reiru$rir Gunlqsk (a) .qoffiGen,io {b\ r,atc,r$fioia *gn

r$pn*61 6ludrGofleir Gluu-rri 1a) OuoflGr-nci; tb) ctefiG+,ndu (c) .e$6n646,:r (d) @aaou ergtc,4Lflc,oeoou [oterr-- : cl

so:Fgt 6uLG6rgp*qgri u$.i, (Mar 06) uu.rciru@gglGlpniioeh (a) wgrt (b) GL-Gt*nan (c) .gtdteurh (A 4dorycal,p6 [oiool-- : al 28. erflro$ 6pnqnq aieurorserfleb qg:o:uOunlgmnor-)
27. 45ei>ogorngur-dr ereorpt

uuletru@olgt

(d) 46osgndo 29.'l-qGqn*u6rneb, d$pnrhfi r$Gpcin 0-* ron$Su-r crreDlr (a) erirflotil $6pn urt an fi rft uL th (b) Sltto@frwrh
(c') a1eaeft}euLots Glpng@ rc@fl
u,t

.s1etfie,iain (c) eauer$$do ngi

(a)

(b) .gctflGeneio
[ogeor-- : Dl Gonoirrqqqriqgrir

tit

npfluLth lerloru : t6) gonGorrchSgurb p6rrpntrdrlp$ GprtfiGp@.

(d)
S)cneozio

cl

lun.gr.erl.' 1-31

l. (q) SrialAuLppt wplgt*6 e-gnqatb CHTOC2H5 ($ ng naotr, 4eioe'gn neioaefi otr e$l eaari ew'iv rc n fi fr u: th. (c) gw nagG ow fup np i aotr, 4eio a gn ngt t-arr a eor Ll ffl Eg,t e-uJ i npiaaevg fiUdpgl @) [orneorr-- : cl ".Sn $cr;.ya:$t @Gawnetgt 2. (a) grfluL gcrfia9o, crir-er9,io ngi gGarnrflgtten eflloaovqrflpgt (CrClJrO gp p,ghpg].
G) c,tll

(b) a t*er$@du 4d; Ge netfl uL th

(crH5)2-o"c!(c)
.gl

rgG dr n6oq t+ar at

r fu u n@

e#t G e n etfl <io 4d; A g eu G u en I ew an ea or uL $gt t-..on et otila n w n s u Eooew&suut-ryq7&6pgt. @) e-crun Frgi 6i,rfld;ownrt@ snvewfluSletr aagriunavnsu

uuLeou@6pgt.
e-oun HI

Io0eorr--

Dl

3. (a) CHTOCHT

Cil,i + CHrOH -+ (b) 1uLGqngl&gu u@ans rngri uuetru@6W. (c) ofla-ralu", neev 6gngfig6$d0 gcucndorc6)r--eir, qeiron
6D uL

gp n6a u u am u @ $gt 6 G p n rh. (A 4iflgletna Aaewu9dp rc@uL--r eroltLqrcir 0-*

@lguugncio

gnaI snyans& 6euLdou@,6W. [otorr- : cl

13 ropuGurr+ehl

l. tB$rienciruor$prnr IUPAC Gluurii acrrqr

(a) CrH'O.CH,

lun,5r.o0,:1-

1.Ol

6rq35t.

- r,6ggrre Ft rgGpew (b) C6H5.O.C rH, - rnpgn&@ Gtueisrfistr 2. rprieeom rorr.qriororrr Qolrjuiu0F$* rrr_n$,t. rdr? elGl es ofi do e4 u G u rrgl e! @, 6,r u n t! d: zsirer q<iedlggr__ecr $l Geri$gt Glu yndaow@ a-1goun&pg. gg gu;ri Glorir-r$eocuaedci.r 6an4&gth poncri,:o s.-6a L_ug!C6H5.O.C2H' + Oz

CrH,

C?H5 or_ srgpdr

ourynderrou@

3. Glrf,riernri@ engmnce5ri(g rpfteeh Spfg asrEriunehedr 'cngarrrir a.4ry.

6fid;eoni@ snyewflB arli qec,$ds e-eirqr trg,rt, 4ryenerureryi Gerircana e-clnergt. aatri pflcoeu86a *$pqnriu 8,fiti;aroft@ a,nqowfl flaauu@1figutt@6pg.
2R,o + R'MgX

--r

Rror'

\"*toO \x

C2H5--H2H, + CHrMgt (olL-ogfiiorrgil Gta:g@6oGlul*diuLb

CrHr..

.
u@6tpgt.

(Crlr)rd \X

)Ui

-l%CruS,

4GuLnort_@)

@g Arfl*tanni@ r;fitol,r;rr.l?ungefiorr a,o,gilunwna,& 6i,suiv

4. ctld:ogrrrirceir Opnqg$p$

upd& .gdrfq cror{D. 4eilaoeci.r Eoncoa@s@r_6ir Genr4wrh (ai Gtunt_t_rflui

4doanSaeo@ Gengg Oa:ttuu u@ggt,h Gungl eggolalut rg,iaeir 6irll,tL*6owp*. $pp g:ap gd;6w Gtpnguq gtolrprang.ix
RX + NaOR

----+ -t

R-O-R'+ NaX CrHr-O-C2H, +NaBr rg;En*o@) (or_-erJgir r*,r0)

cHs

CrHrBr+ NaOCrHs
Grli;$io qGqnrrl,o@) (Qenryuth

cHrBr + NaOCuHs

--+

_o _ crH; + NaBr ki;g6o 6,ll,!;8a r''t)

Rown''|,a66t .gtguatl--6ir @eo.tr'r&auut-t- sniuan 9tgu6't6u ag5&al,afi gn&ab elbu@SgfrW. R-,O" + R' -Br --+ R- O - P' + Br

Epg g:eopasl'60 qafrut,

gasnrfl&aamh.

tBbE

tb sanuEetr tpriaaffi$

5. $'tof Oeir

5,?p,' CrH, o c2Hi + H2o c2HioH - 6. rprtc& odr fifri, oornor$ci:ora:r

*gftoefido olr9gr,+sy6frr
tsrrr,ewrur-1 @6ocr.n55ncio

glcrlat

$rfleiu

e,rri,yatS6tana.

?. oruer$Pir rPd& uurdrceh ulr6)erl? al_er$sdo*pftgefifterfg'ffiruOur-q-u9ci.rgofirie$luurr^firnsi pg' 6 rfl tet n i@ 6i,ala-t,6a u@6 pgr e-mtia1 $t6 u: na L u w oir u @6 6euL6ou@Etpgt' srflni efiral,rlrrrtGtunqgaffetr aaqiunarnst Gsri.llilrcrllreru A rfl$6 p@8;s& a,eaqu u neonsti 6 euLdo u @6 pgl @ D 5 *gria6n er$grarrngtt-olr s@)pgl 6uLGqffgl69u u@et'nau uuaru@6ry. 8. stdGcndl gurulciu er6o$5lueto ercirornnry oiotorryflGlpglt epflG en 6o gt ug Giv eyy', titag tev etlt r;oerl-l rn tigt 4ti G @ neofl uL rh Geriuitueiolar$ 5@AW. Alclr
ars

Alclr c6HrocH3

> cuHr-o-cHl BF,

c6H,ocH3 "', t cuH, - J -a", 9. gtdGenors: enpr-Grn ofiprb Gcrirginei: 6lerrr--uugt u:r$l?

elSarfl,itdpg. ercrtLrnatr aatti 5n*g56ttr66rgl 4ripGgn, uryn @t-war,fido Sla$eDgr erc-i HNO, ropgvtb s1t-i
&rlnelrr$@pw

G,uetuEw atai,c,rrut$@,io -OMe,

6prg9

@<gqptdo ctgtgtaaL-uJ

10. Sornooo: .rlloilGcncrna ronfigorog,& err.:@rir cro*un@

ulrrSt?

Setngttetr at-uGer 8pGpefrr dorerur.@ qdGenei,eu$

p5gtpgt.

1.

dawnctilt

6gGpco,
cuH,

-OH

du,

gtrdo eopLqgair

zeirerg,ndo rlrrr_utGen

Gtlu,gSe;o

6gng,$uLns angtfuryt.

-o-

H + cH2-N2
aeuLGen 6pGS&

cuHr-o-cH3 +N2
fy,elrefieoeuageil Bqrnelleu cl,t_

-> 2. Gentgwth crrptqntrri,ew@

NUOH,

6rogSc;o +cUGuL@c-eu 6ng@6a efup4@bg e_t_u@ggtthGung 6 ug$c;o 6/bptb s4eri,t-6i,pgt

c6H5oH +(cHr)rSOo
C6H5OCH3

+ CH3.HSO.

Oen$pcure>grur8 Geneirqqgriugr o&r wgison 6ap+rg66r Erri,etwtrri,uu Gtufifidoaan crerGor srcuro, @6ap4p Gtsn@ florr,ouari.uLd 6anatur@**gr 12. rE,ft

ll. rprtocir qgotpFp

6'tpp H2SO. rueto crcirorngry doreqrfiGpgrr C,H, - O - c2H5 t+?rp2C'H5OH cr6eleorn6o

rnpn

$ri$g

H2SO4 p_t_en e$leoeotlrflfot er$g,arn.'',a$

g@AW.

13.

rpri 4uri wpi c4t-i

HrSOn ar-_cb erolorng doreryfiOpgrr

H2SO4 e--r-etr aflrr;,ecrqrfl$g4 4tGreoraftu.jo e_ur;ou$

g@apgt.

(c2Hr)2o + H2so4

_>

[(crHs)roH]'HSqcrtt_r$anpdo 4tiGeandutth

agotgg,s c6ofittL

14.

rpri Hl c-ud ercirorng olororqrflGlpglr (Mar 06) g1g gtad;a,g HI e_r_cir rreoga 44Gunat_ol.tqrjr,, rol,o,eu
neoa.l

4doaetn
CrH,

qtb 9g6 pg.

C2H5

-o-

HI

> c,HjoH + c2H5l

nrrr,pdo lLGutnat_al,t_uqrh $ol,yq.io

p@gtpgt.
CrH,

@g g:crud;a,g Hl e-r--ah

C2H5

2HI

zc'P.rl+

H2O

--*

15.

srr- crFFCt rpfi PCl, r-r-dr ercirorngg otoroqrfiGlpglt 2C2H5C|+ POCI3 CrHr-O-C2Hi+ PCI
61o19o;0

qgri PCl, eL-dr- &al,arqrfl$gt

16. oredGcnil

gGenneoveoe$ Sg6tpgl

HI rr.& crcirorng olencqrf,Clpglr (Sawrdo) + cH3l C.H, - o - cHr + ru 4fC6H5oH Qag getuoloo 4tiefigeo E<li,rlrrruq Aera1g16tpgr 17. gtcdGcrs)c) qGrrrCIGcpprir Qcd-rE ndr poruGugdr
o9orseurrr ff(35t. ocH-

d' ,mor C"' .+

ocH3 Br
o-qGynGan

ocH3

4af,Gareir p-q3vnGan std,Gso'io

18. orr-erpcb
CrH,

rpfi .lr-ri
CrH, +

HCI

u-cb ereirorntr4 dorcr;f,Glpglt

[(CTHJTOH]'

HCI

Cf

-+
19.

eor-*giongeu 4t?avtrllfl u th 6Gmtay@

rpriaeir eretrueool ulreDcrr? etiotloufip eorirlq r-5lrgcrir S(t6goi'alllt@tdrcr $}qD a6ilJ6u'56i'r 6g'Ag8@[b aaa@* A-guriO Qg;i,til<x l6ae,r ?rtanwfipt aat0qt ngiaen
oaruu@th.

q@igttsnt-@

crHr-o-c2H5
gtefiGcneir

cHr-o-c2H5
rr;4go;D Gtlr,$@6o *7rt-

tG-''4
ercbo>r

l5 o$uGueirecirl
Iun.gr.ot.'1-81

l. C.HreO orrdrriunl@crrr--rr erqg$li Ourrfi@e- npgntfl w$Ggeo crHr-O-c2H' cHr-o-cH2.cH2.CHl - 1-6ppnd;Gt qGqnuGuat - Z-tBpprAA qGqffuGu66r crHr-o-cH-CH,
I

gGcnroriaormulrb

CH,

cFL.cq.cq.GLoH

n-r9g,r-eoudo 4doe'gpdo

CH,

C{.CH2.CH.CH, '
I

nfial,ewar r9g{r-orr-dr 4doa,gtndo

OH

CH,
I

CH,-C-OH
I

goo?eneunurr9g,uorr-eu ga;epuneu'

CH,

2. orr.-er$$cb rporr$ purnrfi6e Cl&!tr qg!rp6sror& aga' (i) gilagglnir grer.iag6$*(9 fleruGrr fifi fiTorn' .ry$a starlrl 4doa,gntndo etL-rt H2SO4 gtanaJgi, H3P04 e-r--eir 6lo'rr-rr-lr-r u@gguu@6pg. @rr;tur6_ 1qcu&a^gt $ft 6Eni*al-:r,cli't-6gt *g;ftaen

e-l,wr^tpgt

R -O - R + H2O R-OH + H - OR (4doegsn6o @6 Eglaxtt^gl,aiil . e4n 4r3 K c2H5-o-H + H - o - c2H5

H-SO. --2--1>

_ffio .,tjr""*

4ei;eoeeu Eunncoa.r@ e,altotr, Glei;orri qr*orenr@r-qr u@gp rprio,eir e-16anhetrPeo. R - X + AgrO + X - R---ar+ R - O - R + zAgX CrH, - O - C2Hr + 2Agl CrH, - I + Ag2O + I - C:Hs T+ (iii) gS21 ldt qr n (g ) G p nrtl ut na1 u-<hr' 4eoasatna9sr qoflcou-r'$' }egalttgtthGung $n $ia dooan d"gew.

(ii)

Gtafiui

2c,H.oH

523

Al,o,

\ crHr-o-c2Hi+HP

3. gdGcnolo)S purnfl&q5rir (Ursrptr{Dst 5r(351' efldleElrrrircefo GpnlSriq (gl6rp : Genrgurril r-fcnniene@c-eir 6i,u,gS6o s13utnoi,t@ Gen$g G)oruuuu@liigbGung =e1aflGcrrci: frlnl,u-gilpgt SN2 ogaoerr at$ly:erlprrl,ut &aufigtdpg' C6HJO (doond,'''4i@ aautl'fi) s16&o,aui ay6dD dorou@Oungdr 6ho$$ci:
:ryGrunore@

+l-+Na*
CuHrO- + C2H5I
'

qGunGun

-----1l C#, - O -

C2H5 G'o9errGt_neio)

+ l-

Gi,uefufirllteo &rll,arru@dunqqarns Genr4uLth n$gnd;

ell,sertt-i Glanafu@ a4afG+nan,ou$ guLnrftds (g+urngt. eSGi,eoc,tfrio atan,mat$@,6o s-eirc,r' sniudr etg)t6tlt-6tt aqGuLrryeir ana9eolounsfr Eawrts*ut-@eirargt. @p^* *ertlgna Bt* (g+arng. Bnngyt-eh at-uGsn 6$Gpdn c$t<ri.awut@ elottlGeneoa$ 5@apgt. 7. Beona9d -OH aJ, q8a) eogttqggetr e-enffigndD eot_wGer 6$Gpen, 6-g9,tu Gtgng@uLna anEtilpgl

dudnfiir

coH'

-o-

H .--i*;IL**

cuH'

- o - cHr + N2
.fr,rr noriou eu.t-

2. Gentgutb aptTntaaw@
@u$@60

1y:etretflaaufi,io

ctbpth slant-flgtg.
C6H5OCH3 + CH3.HSO4

C#'OH +{CHr)rSq

--r 4. {lfrtec&rr- erterfic6rr_cb 6rl- 6rpFct, rpfi eroiorng doeqd0p5rr (a) O, al$e Gprp 6pnr-fir4 : at-ergQdo trp66rq qtffiggttdn Gcrtgg Gl-g Gpqth Gtatuuhu@ggrhGurg, a-(Dat ff6r Gt u yntarca@ e,ar I rri,patan tggtt c,fit@6 eir patr. Vb"nat
CrHr-O-C2Hj + HCI (C2H5)2O2 --t (b) PCls uneiouqeio 6u&t_n gGennaq@, *plgteir
q,eiloreeir gGmnaq@a,ol,m$ F@Apg, CrHr-O-CF, + PClr -----+ ZC2HsCl + pOCl3 efraoantt-@, np$ofu l40,usnart_oi.,tq:jo $ayuqtb pAhW. CrHr-O-C2HJ+2HI 2C2H5l + H2O'
eftal,anuL@

(c) =ry$e =tetro, Hl : oi,cerg$,cio rgn qg6 g1tffiq HI

e_L6dr

-; r;iggdD npfi ga1.;iiloug$ratr @6n66ncoa.rugcu : ett6<E-ri, Gafi u t u@gp $rnfi u gu u a t_r1gt 4do ap neooug p(DA pgt. CrHr-O-CzH, +H-O-H ---4 2C2H5OH
(dl 6tip
H2SO.

reirm ribpgriqlil 5. creuflG*ngl,igrn, *gesunqt (Oct 06) GorElun@ e ch ulr6)6ut :rye9"?unl-rqi *Ptisor elGynGlot-t4-t *Priscir (at er$@d rPft) (e,r*rflGe nda)
I.

g g 6 /*

s nSgilcocueo

u"r

4&lu:n6tb $rtl:;h.

Oe,naiwc $rircth.
2. at

nseaatrit

6 u nTryetraetr
uwcou@$P

e-crtrrtq $i;fiuLnau
u@apg-

uaten

gwnfrSsu

uuLofrru@frpgl.

aaqLunetnai

$^pr;t aaquunarnstt u,;r&

u@$pasnljc.

(g+wngt. uFa) 4. 6Jur- Grngtt6u 6ungdrisu uweinu@at

$)cucoar.
5. epdflGendo

@*S q5o;uapngttdr ecvbgt }ut-Gyngltgu u$'ia ul.ls6r

u@$patnth.

Hl ulteo dafiuh

u@qgJ
u,bEJLb

thG u

ngt

Sewnda

CH,I 6)en@,itdW.

AdS*q HI qL-t# Geft$gi C2H5OH tobgtrb CzHrl qth $$AMI et@a ge'r,q HI qr-ar
Geri$gt
zC.zH.sl

+ HzO #{DAW-

6.

6aDLG ry n es fi pti; t56D66tar qucor cagt-Gryr eofiGan'eoaYi

agt9qn ctbp,h patGtugtan

@ctuora;.

p@apg.
ad@r@
U&rv-n61fu Clugmt'66snA

mfifldo

e-eirqr
Gl

4AaSggtt-m
u gni,crl.,riaent-$

e-qgatnat6io'l,aoet.

egoor;rrq rfi $g't

5$apg6. sedlGcno0rir ero&Llncir oorri u$efr:6 c8grsesren ff(gsr6. 6,uetrflatr ato,orw$@do OMe, 6gni98 figpg"do alpgtatut e$cnncwg6ipew eqfisrfld;ilpg. ereu&Lqneit e.atri g;n&gq6tn@gt rcplglb eg-ii 4npGgn, unqn, @uri;ta,efitiu fieg699r er-:t HNO, glef'G.ananat$ apLGyn urqt HrSOoe or.rqco ltrwrrdrg! 4ftgGpn,
5@apgt.

0 ;=#:: d*o'* q",

ocH3

9CH,

9t",

gryeufiGenci;

qGsnGron alaf,Galnerlcog

qGqnGnn ctbppfl6v Gungt 4ftpGgn, untrff,

5$Ap!tl

7. "erdGcndl HI
u@pfuilrbGung
g1Gu-rnorr-en CuH,

rr--cb Goruuriu@$grriGungr CH'I, &r9sr$, QcouriOpgr. olen&er.ir p(D6. gryarfiG.rrreoer; all,orl.L3qn a4Guntgt e16ta$gtatr Gettiuu
*qft Eerr,wuq $lmqu@6pgl
a-qgon 6;g6 ry1.
C6Hs OH

d".

ocH:l

gCH,

Q
Br

4efiGenda laqlr,L_Gtrn

t
:

- O: CHr ----)

+ CH3l

H:l
gyeu8Ganei:

I- +CH,

- O-

C5H5

----+ I - CH3 + HOCeHs

"? -fcrmio
GtanflGugt th 6 prg/

I
&Serrndo

H QlGvnttn.* elEptb stortLip *pn) CIue,Cq ;ryGurnenr-@ st aJelfl alggsw ri a qerofl,

q6dr

glefiGcnalei; *ryor4e,b C - O &ol,atriq Emalu@ot@eilcoar. Sgerrndr Glro$$ir 46oo,ggr,rglttb slc,utnc,urauefutlgtl.jD e_eiwt_ran

$cilloral.

8. orr-er$,pdr FFi Ourn&srcoru ererfi$dl rcirr--ntqgrir Gungt a;dGerdl gr;drolnjg Gcriror$$srar. 616hl

nfiFas +4Lrt. 66rgga,+ry96r l4Gwnau@t_aw Gtattuuu@pp geiroeeir :llGarnorr-@ a,arllr$ p@A W. cHr-o-CzlI5
e-chcn
2HI

> CH'I + c2H5l + Hzo

fupS oiomr gciuonar@ Gunewpt fiuficrr,a- efleli,,rGlunlgeneiofido ge-i'cndfi 6l'g,ng$au 7ys&etwuna 6$patd dgng@aout
qgoorpa$efu

Ogarecir

asiutfi u
uL

uweiru@6pg1.

Gp"g$

9. rpri-ecfleil encrnr@rir ronfi$uihaeh rrrenor r dorrilg. (Jun 06) rgde*rrfldo anwuu@ang Qolrcwulrfifi wth, t-obgtth estolrqvriiileutdv
nrrfrfruLb.

olooor* Gcu-rei> GpntO$ on$$u-rrir I Frgiisgt-b, 4'ioagtngltn g3t e$lpnnar 1y:ertta.El aufrdLunLco-tu
anfufl uLb enewruu@Qtptgl

6ufu$t1g$gtth, ?at'ilGatgt aftpanatr e$loaeri$ 6)cu"tcu 6prg@ ar fuSl uL $ap u 6 u fifi 1Eu u p ndx e.ar b dl dD c,$l aaoi dcusdo G, pog@
n -r-9gr-cor-ou geilegolncu at arg@60 ngri cHrcH2ocl{zcHr cH3 - cH'- cH2- cH2- oH $ooouor ronp$lurrir : npisofigtever 46erElgetr Qaewrbgoir* aniuotr 4glti;sotr tnnElu@atpncu @coeror arPfl uLtb snewruu@

6i1.6n.

ddrrns. CHj- O - CHr- CH2 - CH3 CHr- Ctlz- O- CH2- CHI otl,u ar$@,io wgi. 6ag$c;o n- qGqnLaaudo wgri er@$glti;cnt_@ p(D6 10. grGunGronLq* rpriogrig
6r.4lrr.

ornrirriun@
c6IJ5OCHr

6ungluGuu.rri

IUPAC Quurr?

}rc$ffdo Eeoardo npri (eD getflGen6v

6rpgo;,) &c,oeoeio

6pr&;A ?ueofietr

c6Hroc2H5

(g)

*gi

npndfl duqofictr
SqrruiGl dueo$etr

&Eow3rndo

CuIj,-O

CuH,

c;rl.ull/crl,an,io

npi

ll.

I. .qcufl G+nci-r n{r6a66ru 6 u n1$6tra6tr g u: n rfl 8a i u w eb u @ I pg. 2. arfln!; dpnguq e$lrrr,erro-c,fidu lgauGlunlgernsD
6)r

"etoflGena$eir

uurdroch

u-rretror?

uuteou@6ptg1

12. Gkflri;ornn@ olorerrjr6unq6cirecrflcb OtUpgt FFri purnrflriqgdr (9)6fip66rur ffQ9St. gt nasgGeo fl w ng ria.arler, 6 rfl Iev n ri@ efil eaariL 6 u nqggt-co a rfl w gtt & s oa en* 6 s naiw t- np ri setr e0l clnorr L u @ $g bG u ng e- uL i e-lgatn6eurpe*

R-O-CHrX+X-MgRl +R-O-CHrRr+MgX,
Br

Cq -

CHrCI + BrMgCHj

-+
*pn)

CHj

- O-

CHr-

CH3+M;/ -\
*pil

(G.rlnGeun

gGetrrGyr rlriuilu,gSdo

Grg@do G,ag$e;o

-Cl

G)ilSenrri@ t g@6flufil6$(tt1ig haat$g sgIseu ri 6u rrqgarnets (sniGu{v s4u&) pnGexngaffietr agdsatri SltuGuuLi&'Ft
naatt
6irLL

ntfrmst.

13"

rsrie,ch $rgutn,f,t Ggoro:goroqDr-cir oreiralngt eSleoorqrfl

Gtctopor

rrgrtueorcnti; iqGr,nnrtlctu etdDGDgJ qGrynt9letr gr-oir S)garflA (gcrn @1e;ootng G u ngil aflooarr' q rt| uL & G s dL p neiu a - 6aW + qgen algt tisai
u

6r$f) G e fu u

L.t

ts @

etr paw"

CI
I

R'- O -CH.C[-I-

R O- CH cH,

CHra-1gG*o3qneae ngri

c.lll-o - CrH,

- cHCl- o - cH,cHr ---+

$g"tn,;t (rt-rg5GmnGvnootor$Seit ngn) CHTCHCI - O - CHCI - CH, {tr-a'-cat-lgGmnGqn rr,,uc'g$da wgn) rprtsotr grflu gofiu9ou rgGawnrtlgt tarr e'$lcrl'eoqrfl ultbGu ngt rl@afr-$t ot?cttalr. lgt4evat6tpgt. o-lgoungn e$looetrGtunlgotr
1urilgGarnGryn ng;i.

l0HCl c-H,-o*crH, + t0cl.,gffi'I %c,cl,-o-c-cl.-r\

l. ("9) *prteck
aiorrfi.

l"s6t

JVI

ane8orrorfi&c c;r.6lcr:rbeqg

1to n$uou*roeir| r-- eir olorer uu@ porei>

(5)

.,$riGcnefrurrir uriq rqgornpeb : ngffldo e-drer 46erEgetr arcflcoro 6l&a 4t$lmaaEgteir qGqnut-netr 6Jbptb +.t6aL_bgt 4&Genevfr u: rh zuettu$ 96A W.

R--O-+HX--+

L
-+

ll.
l-*l
- c,H,l J
en
atfl w

C,H,-'o - C,H, + HCI

+ Cl

l.,n-1

(a tor g@ 60 4tG

LH

rh 6G

etr

ra

ry@

6oL,6r6gdt) At*Ge'0naflut,jD

eogl-ygan

scirGr.lc-.

(g)rpriaorm firrfiug$pr$
$qnpuguuat-$gg
R

c$qrorcurur

olorfiL6r Glat u u u u
@

(i)
$p

C-O rlorcurnq r@u@rir olorcrecto : firnpuq5ppctr.

4tioa'gtnari'oup F@AW.

np ti6 66r6tr e1 6l a$@ ow 1y:etrorfl aa 6l do $1g

- R + H - O - H ------r 2R - OH CrHr-o - c2Hj + H - o - H ""Q, 212H5AH

O

@pS c0lell,err.uil,io rprfl,6o teirm 4d;efigstr qGynr-t-nar arppth c4atQtpgl.

R2O

+
O
H

H* -----i
OH,

+ R OH

R-

l+

- R'

R-

OH + R'

- OH + H*

-1

ngiaaer HBr eycfuargl HI e-L6ir a9rllwruu@$g al6oat Ec,rapu-@ 4rdoa,gtnio nbg b gcUeoecil ewrcttevat--$ gg6wpaw.
H

R-O-R+ HI
Aflw
CrH,

R-O-R
t-

------) RI +HOR
sniuah etgyoi,anGu pnagan

e4Gpanna pni;66p9.

4aiveae,do GtgrgSuSlerSlgpg

CH3

------t

HI

C2H'OH + CHrI