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Delta Release Notes v504 J
Delta Release Notes v504 J
V5.0.4
Delta NMR
1
2
3
4
............................................................................................................................ 1
........................................................................................................................... 1
Delta .................................................................................................. 2
................................................................................................................................. 3
4.1
Delta ................................................................................................. 3
4.1.1
(a. Delta )............ 3
4.1.2
(b. Control ) ............................. 7
4.2
........................................................................................ 9
4.3
................................................................................... 10
4.4
............................................. 12
4.5
............................... 13
4.6
Queue ....................................... 14
Delta NMR
2
Windows XP SP3/VISTA/7 32Intel
*
Mac OS X (10.4.11 ,10.5.x,10.6.x,10.7.x) 32IntelApple
* - OS X 10.4.xPDF
2GBRAM
1.5GHz Intel
OpenGL3D
CD-ROM
1280 80016
ECAII, ECXII, ECA, ECX, ECS
Rev B (GE VME 7751)
Rev C (USB1U)
Delta V5.0.4 JEOL
RESONANCEDelta V5.0.4
Delta
Delta NMR
3 Delta
Windows/Mac OS X
1.
NMRDelta
http://nmrsupport.jeol.com
2.
WindowsOS XDelta
3.
4.
zip/dmg
5.
6.
Delta
zipexe
Delta
[] []
Delta
Delta
Delta
Delta
CD-ROMWindows
1.
2.
3.
4.
5.
6.
7.
DeltaCD-ROM
CD-ROMDelta\Windows
Delta
Delta
CD-ROM
Delta
[] []
Delta
Delta
Delta
Delta
CD-ROMMac OS X
1.
2.
3.
4.
DeltaCD-ROM
OS XCD-ROMDelta/Mac_OS_X
Delta
Delta
Delta NMR
5.
6.
7.
CD-ROM
Delta
[] []
Delta
Delta
Delta
Delta
4
4.1
Delta
Delta2
a. Delta
b. Control
a
ab
b
4.1.1
(a.Delta)
Delta()
1.
DeltaDelta
2.
3.
Delta NMR
[OK]
Delta
DeltaDelta
Delta
Delta()[]
Delta()Control()
DeltaControl
Delta
()
Delta-Control
DeltaControl
Delta
Delta NMR
1.
Delta[][]
2.
[]
IP
()3
()Control
4.1.2 (b.Control)
Delta NMR
3.
[][]
Control4.1.2
(b.Control)
Delta NMR
4.1.2
(b.Control)
1.
JEOLRemote Maintenance
ToolRemote Maintenance Tool(Instrument)
2.
console
3.
4.
[ ]
Delta NMR
5.
[]
[]
[Control Service Management][ service is stopped]
[ Service]
Delta NMR
4.2
Delta
OS(
)
Delta
DeltaControl
DeltaControl
Delta
Delta
Delta4.1.1(a.Delta
)
Control()
4.1.2(b.Control)
Delta NMR
4.3
NULL
[NULL]
NULL
[NULL]
10
Delta NMR
1.
2.
[][][]
[NULL]
Control4.1.2(b.
Control)
Delta NMR
11
4.4
Delta V5.0.22H-
Delta V5.0.1
Delta V5.0.2
Relax Delay
4 (V5.0.1)
2 (V5.0.2)
2H Acetone-D6 Benzene-D6
D2ODMSO-D6Tetrahydrofuran-D8
4 ()
5 (V5.0.1)
1s (V5.0.2)
2H
5s ()
1H
2 ()
[]
()
[]
()
12
Delta NMR
4.5
1.
[]
2.
[]
3.
Delta NMR
13
4.6
Queue
[Queue]Queue
Control
QueueControl
Queue
Job#21
Job#22Queue
5 Delta V5.0.4
5.1
5.2
Shear(phase_x_y)
[Job]
(Auto Sample Changer(ASC))30
641003
ASC30ASC64ASC100Delta (1)
14
Delta NMR
Shear(phase_x_y)
MQMASShear(phase_x_y)
Delta
Delta
Control
[Job]
Job0:00Job
V503
Delta NMR
V504
15
[]
[][]
Delta V5.0.4
5.3
a. sat_transfer_difference
b. sat_transfer_difference_wgh
(x_points)40968192
(std_sel_onreso, std_sel_offreso)
(30ppm, -0.4ppm)(0.5ppm, -10ppm)
c. inadequate_2d
d. inadequate_2d_dept
e. inadequate_2d_dept_pfg
f. inadequate_2d_inept_si
g. inadequate_2d_jcp_pfg
h. inadequate_2d_pfg
i. inadequate_2d_phase
(x_points)40968192
(t1)(_sweep)(t2)(x_sweep)2
j. cpmas_spin_echo_t2
Pulse
k. waltz
WALTZWALTZ-16WALTZ-65
16
Delta NMR
5.3
5.3.1
single_pulse_wet180_slp
WET
WETsingle_pulse_wet_slp
[x_pulse]
[wet_pulse [wet_pulse
[wet_pulse
[wet_pulse]
[relaxat
[x_domain]
ion
[x_at
]
[acq_ti
[irr_atn_dec]
[irr_domain
PFG1
[wet_grad_amp]
PFG2
FG
[wet_grad_amp]/2
[wet_grad_amp]/4
[wet_grad_amp]/8
PFG3
PFG4
dante_presat
FALSE
tri_mode
OffPresaturationHomo Decouple
Off
x_domain
Proton
x_offset
5ppm
x_sweep
20[ppm]
x_points
32768
scans
x_prescans
x_pulse
H90
x90
x_atn
6dB2
xatn
composite_pulse
FALSE
relaxation_delay
5s
Delta NMR
17
repetition_time
relaxation_delay+x_acq_time
wet_pulse
WET
x90_
soft
wet_atn
WETRF
6dB, 2
xatn_
soft
wet_shape
GAUSS
wet180
wet180wet
TRUE
wet_number
WET
wet_offset1
WET
5ppm
wet_offset2
WET2
0ppm
wet_offset3
WET2
0ppm
wet_offset4
WET2
0ppm
wet_offset5
WET2
0ppm
wet_offset6
WET2
0ppm
wet_slp
WET
wet_grad
PFG
2ms
wet_grad_amp
PFG
0.144T/m
wet_grad_shape
PFG
SINE
wet_grad_recover
PFG
0.1[ms]
irr_domain
Carbon13
irr_offset
70ppm
irr_pwidth
irr90_hi
irr_noise
GARP
irr_atn_dec
RF3dB, RF
irratn_
hi
lock_hold
FALSE
lc nmr, 1D, liquids, Single_pulse, Water_Suppression
proton.list
effects
WET180WET
S.H.Smallcombe, S.L.Patt, P.A.Keifer, J.Magn.Reson., 117A, 295-303(1995)
18
Delta NMR
5.3.2
std_tocsy_pfg_phase_pn
TOCSY
[x_pulse]
[STD_sel_180] 90
[x_pulse]
[STD_sel_180] 90
[x_domain]
[relaxation_
delay]
[mix_time]
t1
STD_sel_shape
STD_sel_atn
STD_sel_onreso
phase_acq [relaxation_
delay]
MLEV17
[trim]
[grad_1]
[trim]
[grad_2]
STD_sel_shape
STD_sel_atn
STD_sel_offreso
[mix_time]
t1
phase_acq
MLEV17
[trim]
[trim]
[grad_1]
[grad_2]
FG
dante_presat
FALSE
irr_mode
OffPresaturationHomo Decouple
Off
tri_mode
OffPresaturationHomo Decouple
Off
t1_pfilter
FALSE
x_domain
Proton
x_offset
5ppm
x_sweep
15ppm
x_points
2048
scans
x_prescans
x_pulse
H90
x90
x_atn
6dB2
xatn
y_points
t1
128
Delta NMR
19
std_sel_180
180
x90_
soft2
std_sel_atn
RF6dB
2
x90_
soft
std_sel_onreso
0.5[ppm]
std_sel_offreso
-10[ppm]
std_sel_shape
GAUSS
std_loop
40
saturation_time
STD_sel_180
STD_loop
x_spinlock_pulse
90
x90_
spin
x_spinlock_atn
RF
xatn_
spin
trim
2.5[ms]
mix_time
50[ms]
mix_time_loop
total_mix_time
grad_1
1FG(PFG1)
1[ms]
grad_1_amp
1FG(PFG1)
0.09[T/m]
grad_2
2FG(PFG1)
grad_1
grad_2_amp
2FG(PFG1)
grad_1_amp
grad_shape
FG
SINE
grad_recover
FG
0.1[ms]
relaxation_delay
2.0[s]
repetition_time
relaxation_delay+x_acq_time+[saturation_time]
2D, noe, liquids
2d_homo2d_pn.list
Saturation STD_sel_onreso
STD_sel_offreso
20
Delta NMR
5.3.3
std_tocsy__pfg_phase_pn
TOCSYWATERGATE
[x_pulse]
[STD_sel_180] 90
[x_domain]
[relaxation_
delay]
W5
[mix_time]
t1
STD_sel_shape
STD_sel_atn
STD_sel_onreso
[x_pulse]
[STD_sel_180] 90
W5
phase_acq [relaxation_
delay]
MLEV17
[trim]
[grad_1]
[trim]
phase_wgh2
[grad_2] [wgh_grd]
W5
t1
STD_sel_shape
STD_sel_atn
STD_sel_offreso
W5
[mix_time]
phase_acq
MLEV17
[trim]
[grad_1]
[trim]
phase_wgh2
[grad_2]
[wgh_grd]
FG
dante_presat
FALSE
irr_mode
OffPresaturationHomo Decouple
Off
tri_mode
OffPresaturationHomo Decouple
Off
t1_pfilter
FALSE
x_domain
Proton
x_offset
5ppm
x_sweep
15ppm
x_points
2048
scans
x_prescans
x_pulse
H90
x90
x_atn
6dB2
xatn
y_points
t1
128
Delta NMR
21
22
std_sel_180
180
x90_
soft2
std_sel_atn
RF6dB
2
x90_
soft
std_sel_onreso
0.5[ppm]
std_sel_offreso
-10[ppm]
std_sel_shape
GAUSS
std_loop
40
saturation_time
STD_sel_180
STD_loop
x_spinlock_pulse
90
x90_
spin
x_spinlock_atn
RF
xatn_
spin
trim
2.5[ms]
mix_time
50[ms]
mix_time_loop
total_mix_time
grad_1
1FG(PFG1)
1[ms]
grad_1_amp
1FG(PFG1)
0.09[T/m]
grad_2
2FG(PFG1)
grad_1
grad_2_amp
2FG(PFG1)
grad_1_amp
grad_shape
FG
SINE
grad_recover
FG
0.1[ms]
watergate_selection
WATERGATE
W5
wgh_x_pulse
WATERGATE90
x90
wgh_null
WATERGATEnull
WATERGATE
5000[Hz]
wgh_tau
WATERGATE
1/wgh_null
wgh_grad
WATERGATEFG
1[ms]
wgh_grad_amp
WATERGATEFG
0.12[T/m]
wgh_grad_shape
WATERGATEFG
SQUARE
wgh_grad_recover
WATERGATEFG
0.1[ms]
Delta NMR
relaxation_delay
repetition_time
relaxation_delay+x_acq_time+[saturation_time]
2.0[s]
2D, noe, liquids
2d_homo2d_pn.list
Saturation std_sel_onreso
std_sel_offreso
T1
Delta NMR
23
5.3.4
waterlogsy
1H1H1HN
H2O1H180REBURPFG
(4.76[ppm])
180FGde-phase
1H
1
HN NOESY
WATERGATEWATER suppression by GrAdient Tailored Excitation
1H
W5
[obs_sel_180]
phase_acq
[mix_time]
[x_domain]
[relaxation_
delay]
W5
obs_sel_180_shape
phase_shape_1
obs_sel_180_atn
phase_wgh2
[grad_3] [grad_4]
[grad_1]
[mix_time]
FG
24
x_domain
Proton
x_offset
5ppm
x_sweep
15ppm
x_points
8192
scans
16
x_prescans
mod_return
x_pulse
H90
x90
x_atn
6dB2
xatn
Delta NMR
obs_sel_180
180
20[ms]
obs_sel_180_atn
RF
40[dB]
obs_sel_shape
REBURP
watergate_selection
WATERGATE
W5
wgh_x_pulse
WATERGATE90
x90
wgh_null
WATERGATE
nullWATERGATE
2500[Hz]
wgh_tau
WATERGATE
1/wgh_null
mix_time
1000[ms]
relaxation_delay
5.0[s]
repetition_time
relaxation_delay+x_acq_time
grad_1
1FG(PFG1)
1[ms]
grad_1_amp
1FG(PFG1)
0.04[T/m]
grad_2_amp
2FG(PFG1)
0.005[T/m]
grad_3
3FG(PFG1)
1[ms]
grad_3_amp
3FG(PFG1)
0.102[T/m]
grad_4
4FG(PFG1)
1[ms]
grad_4_amp
4FG(PFG1)
0.066[T/m]
grad_shape
FG
SINE
grad_recover
FG
0.1[ms]
lock_hold
TRUE
1D, noe, liquids, Water_Suppression
proton.list
H2O1H1HN
Delta NMR
25
5.3.5
waterlogsy_wf
1H1H1HN
waterlogsywater-flipbackT2T1
water-flipback
Z
T2T1
T2T1
1
waterlogsy_wf H2O H 180
REBURPFG(4.76[ppm])
180FGde-phase
1H
1HN NOESY
flipback90Z
WATERGATE WATER suppression by GrAdient
Tailored Excitation
W5
[obs_sel_180]
obs_sel_180_shape
phase_shape_1
obs_sel_180_atn
phase_shape2
phase_wgh2
[grad_3] [grad_4]
[grad_1]
FG
phase_acq
[mix_time]
[x_domain]
[relaxation_
delay]
W5
[mix_time]
elaxation_ilter
26
Off
Delta NMR
x_domain
Proton
x_offset
5ppm
x_sweep
15ppm
x_points
8192
scans
16
x_prescans
mod_return
x_pulse
H90
x90
x_atn
6dB2
xatn
obs_sel_180
180
20[ms]
obs_sel_180_atn
RF
40[dB]
obs_sel_180_shape
REBURP
obs_sel_180_offset
x_offset
obs_sel_90
90
x90_
soft
obs_sel_90_atn
RF
xatn_
soft
obs_sel_90_shape
GAUSS
obs_sel_90_offset
x_offset
watergate_selection
WATERGATE
W5
wgh_x_pulse
WATERGATE90
x90
wgh_null
WATERGATEnull
WATERGATE
2500[Hz]
wgh_tau
WATERGATE
1/wgh_null
mix_time
1000[ms]
relaxation_delay
5.0[s]
repetition_time
relaxation_delay+x_acq_time
grad_1
1FG(PFG1)
1[ms]
grad_1_amp
1FG(PFG1)
0.04[T/m]
grad_2_amp
2FG(PFG1)
0.005[T/m]
grad_3
3FG(PFG1)
1[ms]
grad_3_amp
3FG(PFG1)
0.102[T/m]
grad_4
4FG(PFG1)
1[ms]
Delta NMR
27
grad_4_amp
4FG(PFG1)
0.066[T/m]
grad_shape
FG
SINE
grad_recover
FG
0.1[ms]
lock_hold
TRUE
relaxation_filter
Off
delay_list
[relaxation_filter]=[ T2 Filter]
CPMG
1.0[s]
tau_step
[relaxation_filter]=[ T2 Filter]
CPMG2
200[ms]
tau_interval_t2
[relaxation_filter]=[ T2 Filter]
CPMG
(tau_step
x_pulse2)/2
loop_number
[relaxation_filter]=[ T2 Filter]
delay_listtau_step180
t1pfilter_time
100[ms]
t1pfilter_atn
xatn_
spin
1D, noe, liquids, Water_Suppression
proton.list
H2O1H1HN
28
Delta NMR