Olympic Ha hc sinh vin ton quc ln th V - 2008

K THI OLYMPIC HA HC SINH VIN CC TRNG I HC TON QUC

LN TH V - 2008

K THI THC HNH HA HU C (BNG A)

PHN II: NHN BIT MT S CHT HU C (Thi gian 30 pht)
Xc nh tn 4 ha cht trong 4 ng nghim cho sn. Mi ng nghim cha mt trong s
cc ha cht sau: Dung dch fomanehit, dung dch phenol, dung dch glixerin, dung dch axit
axetic, dung dch axit fomic, dung dch glucoz, dung dch lactoz, etanol v axeton.
in kt qu vo phiu tr li.
PHN III. IU CH HP CHT HU C (Thi gian 120 pht).
2. iu ch aspirin t cc ha cht v dng c cho sn di y:
Ha cht
Axit salixylic:
2,5 g
Anhirit axetic: 3,5 ml (d = 1,080)
Etanol
Axit sufuric c
Dung dch FeCl3 1%
Nc ct

Dng c
Bnh cu y trn 100 ml
Bt cch thy
Cc thy tinh 100 ml
Phu Bucne, n cn
Li amiang, mao qun
Nhit k, ng Thiele

Cch tin hnh

Cho vo bnh cu 2,5 g axit salixylic, 3,5 ml anhirit axetic vo 2 git axit sufuric c.
Khuy u hn hp, un cch thy nhit 60 0C v khuy trong 15 pht. Axit salixylic tan v
aspirin c to thnh kt tinh nhanh. Ly bnh phn ng ra khi bt cch thy, ngui. Thm
35 ml nc ct v khuy u. Lc ly sn phm trn phu Bucne. Ra 2 ln bng nc ct (mi
ln 10 ml), thu c aspirin th.
Tinh ch sn phm bng cch kt tinh li nh sau: Cho sn phm th vo cc thy tinh ri
cho thm 8 ml etanol, t vo bt cch thy, un nng n 600C v khuy trn n khi aspirin tan
ht. Thm 40 ml nc nng 600C khuy trn u hn hp cho tan. Nu khng tan th li un cch
thy cho n tan hon ton.
Lm li dung dch trong nc , aspirin s kt tinh. Lc ly sn phm trn phu Bucne.
Ra sn phm bng nc ct n khi dch lc khng cho mu tm vi dung dch FeCl 3 1%. Sy
kh sn phm 600C trong vng 30 pht. Cn sn phm v tnh hiu sut. Xc nh nhit
nng chy ca sn phm.
1.in kt qu vo phiu tr li
2. Vit c ch ca phn ng tng hp aspirin t axit salixylic v anhirit axetic.
3. Vic ra sn phm th n khi dch lc khng cho phn ng vi dung dch FeCl 3 nhm mc
ch g?
Lu :
- Mu ch c cp 1 ln, khng c i mu, khng c xin thm.
- Th sinh ghi kt qu vo phiu tr li.
- nh ha cht nh v dng c s b tr im

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