Chemistry 1210-125 --- 2012 Halloween Special

Name:
Your signature below constitutes an agreement by you that you have not participated in any form of
academic dishonesty as defined by the University of Utah student handbook. You are bound by your
nce of cheafng that you observe during the exam.
___
The purpose of this exam is for you to display what you know about chemistry and how you can solve
problems in chemistry at the university level. Your responses to questions and problems should be clear and
organized, as this is an exam for a university course and not a high-school course. If I cannot read or follow
your work, you are likely to get little if any credit.
Page 1 li/24
Page 2 L{ () 145
Page 3 2 1.- 13 I
Total 1100 1S Cp
A. Multiplechoice. Circlethecorrectanswer. 3points each
' l.-C- /"
w.
b.Which pairofelements will form an ioniccompound? /'
sulfurand oxygen G nand C h I O ~
copperand iron bromine and oxygen
c. Chargefor an Se ion:
i- I+ 2+
C/ /
d. Polar:
/
XeF4 SiF
4
CF
4
Q 4J
C-Se C-Te
)-)
f. Based on eiectronegativities, whichofthe following would youexpectto be mostionic?
~ /
N2 ( CaF2 ~ CO2 CH4 CF4
~
g. Naturally occurringcopperexistsas 63CU and 65CU;theirmassesare approximately63 and 65 amu,
respectively. Theaverageatomic mass ofcopperis 63.55 amu. Whatis the approximatenatural abundance
63
of Cu?
5% 30% 50% 95%
h. ThehybridizationofPin PO/-:
./
sp
&
CI
B. Use average bond energies to calculate h
molecule, and clearly show all your change for the following reaction. Draw structures for
!
2c'l CH,CCOH + I } - \ I,. 'b
'7 ". 'tCO, + '1 H,O .
_'9: H p:::c c: D 9- _L -0: /-1- P - H
I
t-\
b. aluminum nitrate A 08)) "3 +- L-
ox'
,
J', yhOS\>hO 0
/'
d. vanadium(V) oxide

e. Ba(CNh
\3, 0-'"f ; \A""" ('Lr.,,', J.. t
J, 11"\ r0\.J?.(l/ t <. \,0... Lfl.\
g. iron(llI) sulfate
l.\
-\- 2- v( 50
.f- lc..t3'2.

t- Co'1<sU
- l \
0' ,.
6.. One molecule ofa compound has a mass of2.33 x 10-
22
g. Calculate the molar mass of this compound.
(4)
-I- \
-
-r/
&1, O7..?
"f
0 ,
E. For AS/+, what is the predicted Dond order of the molecule? Is the molecule diamagnetic or
paramagnetic? (8)
\x
, ,
" 0* \
,,' "
, ,

"L L
I' "
\"''rL L L n*
np. ,,.. np
'\\ L ':'
\\ I,"
--',
,
,
10 - 3 - -:I
E
n "
a
\ 1V /
'--'
a

z. Write the molecular formula, and give the approximate bond
angles (A and B) and the hybridization (1 and 2). (15)
molecular formula:
'3 .,....--
2: S?
C>
B: \O-"'f v
\.20
H. Nitroglycerin has the molecular formula C
3
H
5
N
3
0
9
. Calculate the number of molecules in 500. g of
nitroglycerin. (4)

x
c1-1- \
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