Beryllium 1rts order pert

H= h01 +h02 +h03+h04

+1/r12+1/r13+1/r14+1/r23+1/r24+1/r34
h01= -(1/2) +1/r1 etc
wave function (neglecting anti symmetry)
Hartree approximation
(1,2,3,4) = 1s(1) 1s(2) 2s(3) 2s(4)
The s are hydrogenic wave functions with Z= 4.
<E>= 2 < 1s/h01/ 1s> + 2< 2s/h02/ 2s>
+ i < j < /(1/rij)/>
i < j < /(1/rij)/> = <1s(1) 1s(2) /1/r12/ 1s(1) 1s(2) >
+ 4 <1s(1) 2s(2) /1/r12/ 1s(1) 2s(2) >
+ <2s(1) 2s(2) /1/r12/ 2s(1) 2s(2) >
All expressions have a closed form ( analytic formula).